CN105153686A - Impact-resistant composite material - Google Patents
Impact-resistant composite material Download PDFInfo
- Publication number
- CN105153686A CN105153686A CN201510594540.1A CN201510594540A CN105153686A CN 105153686 A CN105153686 A CN 105153686A CN 201510594540 A CN201510594540 A CN 201510594540A CN 105153686 A CN105153686 A CN 105153686A
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- Prior art keywords
- composite material
- resistant composite
- impact resistant
- material according
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an impact-resistant composite material which comprises the following components in parts by weight: 55-70 parts of modified nylon composite, 5-15 parts of ABS (acrylonitrile-butadiene-styrene), 1-10 parts of anti-stress-cracking agent, 1-6 parts of toughener, 0.1-0.5 part of antioxidant and 2-15 parts of flame retardant. The modified nylon composite is added into the common plastic, thereby enhancing the comprehensive properties (especially shock strength) of the plastic, widening the application range and lowering the application cost.
Description
Technical field
The present invention relates to a kind of impact resistant composite material, belong to technical field of polymer materials.
Background technology
Plastics are because possess good electricity, mechanics, the characteristic such as low temperature resistant, be widely used in the every field that mechanical means, electronic product, automobile making etc. are produced, lived, but also there is poor fluidity, easily stress cracking, the easily aging and shortcoming such as to wear no resistance, its application is in a lot of fields restricted.The appearance of matrix material, provides good path for solution problems.
Summary of the invention
For solving the deficiencies in the prior art, the object of the invention is to the defect overcoming prior art, a kind of impact resistant composite material is provided.
In order to realize above-mentioned target, the present invention adopts following technical scheme: a kind of impact resistant composite material, is characterized in that, comprises following component and the parts by weight of each component are:
Aforesaid a kind of impact resistant composite material, is characterized in that, the composition of described modification of nylon mixture and weight fraction are respectively nylon 70-85 part, coupling agent 2-3 part, phosphatization silicon 5-10 part, nano kaoline 2-3 part;
Aforesaid a kind of impact resistant composite material, is characterized in that, described coupling agent is vinyltriethoxysilane.
Aforesaid a kind of impact resistant composite material, is characterized in that, described anti-stress cracking agent is ethyl-hydrogenated nitrile-CALCIUM ACRYLATE terpolymer grafts or acrylic acid-grafted polyolefin elastic precursor copolymer.
Aforesaid a kind of impact resistant composite material, is characterized in that, described toughner is at least one in POE, ethylene-butylene copolymer, ethylene propylene copolymer and this ethylene butadiene copolymers.
Aforesaid a kind of impact resistant composite material, is characterized in that, described oxidation inhibitor is the one in antioxidant 1010, irgasfos 168, oxidation inhibitor 2921.
Aforesaid a kind of impact resistant composite material, is characterized in that, described fire retardant is halogen-free inorganic flame retardant, can be the one in phosphorus system, phosphorus-nitrogen system, phosphorus-silicon system.
Beneficial effect of the present invention is: the present invention adds the nylon composite of modification in common plastics, thus improves the over-all properties of plastics, particularly resistance to impact shock, expands Application Areas, and reduces its application cost.
Embodiment:
Below in conjunction with specific embodiment, the present invention is described further.
The proportioning of each component of table 1 embodiment 1-4 and comparative example
Wherein, the composition of modification of nylon mixture and weight fraction are respectively nylon 70-85 part, coupling agent 2-3 part, phosphatization silicon 5-10 part, nano kaoline 2-3 part;
Described coupling agent is vinyltriethoxysilane.
Described anti-stress cracking agent is ethyl-hydrogenated nitrile-CALCIUM ACRYLATE terpolymer grafts or acrylic acid-grafted polyolefin elastic precursor copolymer.
Described toughner is at least one in POE, ethylene-butylene copolymer, ethylene propylene copolymer and this ethylene butadiene copolymers.
Described oxidation inhibitor is the one in antioxidant 1010, irgasfos 168, oxidation inhibitor 2921.
Described fire retardant is halogen-free inorganic flame retardant, can be the one in phosphorus system, phosphorus-nitrogen system, phosphorus-silicon system.
The performance test results of each embodiment of table 2 and comparative example
Note: reference standard is: GB13525/T-92 and UL94.
As can be seen from Table 2, from notched Izod impact strength, the notched Izod impact strength of embodiment 1-4 is relatively better.For other indexs, embodiment 1-4 also has advantage, and associative list 1 can draw, due to adding of modification of nylon mixture, its notched Izod impact strength be improved significantly.
More than show and describe ultimate principle of the present invention, principal character and advantage.The technician of the industry should understand, and above-described embodiment does not limit the present invention in any form, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, and all drops in protection scope of the present invention.
Claims (7)
1. an impact resistant composite material, is characterized in that, comprises following component and the parts by weight of each component are:
Modification of nylon mixture 55-75 part;
ABS5-15 part;
Anti-stress cracking agent 1-15 part;
Toughner 1-6 part;
Oxidation inhibitor 0.1-0.5 part;
Fire retardant 2-15 part.
2. a kind of impact resistant composite material according to claim 1, is characterized in that, the composition of described modification of nylon mixture and weight fraction are respectively nylon 70-85 part, coupling agent 2-3 part, phosphatization silicon 5-10 part, nano kaoline 2-3 part.
3. a kind of impact resistant composite material according to claim 2, is characterized in that, described coupling agent is vinyltriethoxysilane.
4. a kind of impact resistant composite material according to claim 1, is characterized in that, described anti-stress cracking agent is ethyl-hydrogenated nitrile-CALCIUM ACRYLATE terpolymer grafts or acrylic acid-grafted polyolefin elastic precursor copolymer.
5. a kind of impact resistant composite material according to claim 1, is characterized in that, described toughner is at least one in POE, ethylene-butylene copolymer, ethylene propylene copolymer and this ethylene butadiene copolymers.
6. a kind of impact resistant composite material according to claim 1, is characterized in that, described oxidation inhibitor is the one in antioxidant 1010, irgasfos 168, oxidation inhibitor 2921.
7. a kind of impact resistant composite material according to claim 1, is characterized in that, described fire retardant is halogen-free inorganic flame retardant, can be the one in phosphorus system, phosphorus-nitrogen system, phosphorus-silicon system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510594540.1A CN105153686A (en) | 2015-09-18 | 2015-09-18 | Impact-resistant composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510594540.1A CN105153686A (en) | 2015-09-18 | 2015-09-18 | Impact-resistant composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105153686A true CN105153686A (en) | 2015-12-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510594540.1A Pending CN105153686A (en) | 2015-09-18 | 2015-09-18 | Impact-resistant composite material |
Country Status (1)
| Country | Link |
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| CN (1) | CN105153686A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885335A (en) * | 2016-05-11 | 2016-08-24 | 南京京锦元科技实业有限公司 | ABS (acrylonitrile, butadiene and styrene) resin composite material |
| CN106313390A (en) * | 2016-08-31 | 2017-01-11 | 江苏新华东尼龙有限公司 | Casting technology for automobile leaf spring baffle |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010222392A (en) * | 2009-03-19 | 2010-10-07 | Kaneka Corp | Resin composition, molded article thereof, and automotive member |
| CN102051045A (en) * | 2009-10-30 | 2011-05-11 | 上海普利特复合材料股份有限公司 | High-rigidity glass fiber reinforced PA6/ABS composite material |
| CN103160110A (en) * | 2011-12-14 | 2013-06-19 | 上海杰事杰新材料(集团)股份有限公司 | Halogen-free flame retardant PA / ABS blend and preparation method thereof |
| CN103319875A (en) * | 2013-07-01 | 2013-09-25 | 深圳市兴盛迪新材料有限公司 | Polycarbonate/acrylonitrile-styrene-butadiene alloy and preparation method thereof |
-
2015
- 2015-09-18 CN CN201510594540.1A patent/CN105153686A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010222392A (en) * | 2009-03-19 | 2010-10-07 | Kaneka Corp | Resin composition, molded article thereof, and automotive member |
| CN102051045A (en) * | 2009-10-30 | 2011-05-11 | 上海普利特复合材料股份有限公司 | High-rigidity glass fiber reinforced PA6/ABS composite material |
| CN103160110A (en) * | 2011-12-14 | 2013-06-19 | 上海杰事杰新材料(集团)股份有限公司 | Halogen-free flame retardant PA / ABS blend and preparation method thereof |
| CN103319875A (en) * | 2013-07-01 | 2013-09-25 | 深圳市兴盛迪新材料有限公司 | Polycarbonate/acrylonitrile-styrene-butadiene alloy and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885335A (en) * | 2016-05-11 | 2016-08-24 | 南京京锦元科技实业有限公司 | ABS (acrylonitrile, butadiene and styrene) resin composite material |
| CN106313390A (en) * | 2016-08-31 | 2017-01-11 | 江苏新华东尼龙有限公司 | Casting technology for automobile leaf spring baffle |
| CN106313390B (en) * | 2016-08-31 | 2018-11-27 | 江苏新华东尼龙有限公司 | Leaf springs of car baffle casting process |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151216 |
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| RJ01 | Rejection of invention patent application after publication |