A kind of ancient imitation floor board and its coating method of surface specially treated
Technical field
The invention belongs to floor field, it is related to a kind of ancient imitation floor board, specifically a kind of ancient imitation floor board and its surface are special
The coating method of processing.
Background technology
Current ancient imitation floor board has very big market.The sheet material of consolidated floor is medium and high density fibre panel, inherently hot
Swaging into, its surface is changed by hot pressing with formed bumps texture, reach antique effect.And solid wood blank can not be directly warm
Pressure generation antique effect.As Application No. 201110025680.9 Chinese invention patent, disclose a kind of solid wood be combined it is modelled after an antique
The manufacture method on floor, first makes composite plate made from solid wood front have depression in composite plate made from solid wood front by engraving roller processing
Imitative wood texture, then composite plate made from solid wood front is carried out at the hot pressing charing of surface by the hot-pressing roller with protrusion texture
Reason, finally carries out sanding surface to composite plate made from solid wood front and application is handled;Protrusion texture on the hot-pressing roller with it is described
The imitative wood texture of depression matches.The invention solve solid wooden compound floor can not directly after wire drawing hot pressing it is modelled after an antique so as to generate
The problem of effect.But it is due to the imitative wood texture of ancient imitation floor board, its surface irregularity, the application influence on the later stage is very big,
Existing application techniques and existing coating, are also adaptable to plane floor, the surface texture effect special to ancient imitation floor board
It is very poor, or even can not be applicable.It is primarily now to be solved by thickening coating layer, but it is also not only that the coating layer of various functions is former
This function can not embody, and the quality degradation on floor, feel is poor, and cost is high.
The content of the invention
It is an object of the invention to provide a kind of ancient imitation floor board, it is improved, is obtained by structure, the component of coating to floor
To floor either in quality, outward appearance still in feel, all more optimize than existing ancient imitation floor board.
The present invention realizes above-mentioned purpose by following technical scheme:A kind of ancient imitation floor board, it is characterised in that including imitative
Ancient element flaggy, the stereoeffect layer being arranged on the plain flaggy modelled after an antique, the cross-linked layer being coated on the stereoeffect layer, painting
In the packed layer on the cross-linked layer and the protective layer being coated on the packed layer and on the protective layer
Surface layer;The protective layer includes the wear-resistant layer, hardening layer and scratch-resistant layer for setting gradually or being arranged alternately.
Preferably, the cross-linked layer includes the component of following parts by weight:The mono- official's urethane acrylates of 10-20 parts of UV,
5-20 parts of UV pure acrylic resins, 10-20 parts of UV propylene oxide olefin(e) acids esters, 10-30 parts of list official UV monomers, 5-20 parts of modified glass
Powder filler, 3-15 part composite photoinitiator.
The mono- official's urethane acrylates of UV, UV pure acrylic resins, the single official's UV monomers of cross-linked layer use have lower shrinkage
The characteristics of with height attachment, UV modified epoxy propylene olefin(e) acid esters have good intensity and adhesive force, modified glass powder filler silicon
Alkane is coupling agent modified, can not only be embedded in base material and can be embedded in follow-up coating, forms the interlocking formed a connecting link, and
There can be good compatibility with whole coating system.Improve the transparency of coating and the comprehensive strength of coating.Using compound
Light trigger, has taken into account deep cure and shallow-layer solidification effect, the coating that base material is immersed in part is fully solidified, finally
So that coating has good adhesive force.
Preferably, the packed layer includes the component of following parts by weight:15-25 parts of UV propylene oxide olefin(e) acids esters, 10-
15 parts of official's urethane acrylates of UV two, 5-15 parts of UV polyester acrylates, the official UV monomers of 10-20 parts two or three official UV are mono-
Body, 5-15 part compounded mix, 3-6 parts of composite photoinitiators.
Preferably, compounded mix in the packed layer is glass dust and the mixture of talcum powder, the glass dust with
The mass mixing ratio of talcum powder is 1:0.1-5.
The UV propylene oxide olefin(e) acid esters that packed layer is used have the advantages that intensity is good, and the official's urethane acrylates of UV two can be with
The toughness of paint film is balanced, UV polyester acrylates can improve wetting, levelability, and compounded mix is combined by glass dust with talcum powder
Form, glass dust can improve whole paint film strength and hardness, talcum powder can improve filling and the polishing characteristic of paint film, no
Being only filled with property is good, and strength of coating, toughness are all very excellent.
Preferably, the surface layer includes the component of following parts by weight:The official's urethane acrylate of 30-40 parts of UV6 ~ 9,
10-20 parts of the official's urethane acrylates of UV two, 30-40 parts of UV compound monomers, 3-8 parts of UV composite nano inoganics materials, 0.5-
3 parts of tetrafluoro wax powders, 0.2-1 parts of organosilyl surface controlling agents.
The official's urethane acrylate of the UV6 of surface layer ~ 9 can provide good cross-linking effect, the officials of UV two for good toughness of arranging in pairs or groups
Urethane acrylate, the hardness and toughness of resin system can be balanced well so that resistance to scratch finish paint is hard without crisp.Tie again
UV composite nano inoganic materials are closed, good scratch resistant can be improved, tetrafluoro wax powder and photo curable organosilyl surface is introduced
State controlling agent, makes product have good scratch resistant, feel and antifouling effect, finally cause film there is high rigidity, it is good
Resistance to marring and feel.
Preferably, the wear-resistant layer includes the component of following parts by weight:The official's polyurethane acroleic acid of 15-25 parts of UV6 ~ 9
Ester, 15-25 parts of UV modified epoxy propylene olefin(e) acids esters, the official UV monomers of 15-25 parts two or three official UV monomers, 10-20 parts it is modified high hard
Spend wear-resistant powder, 1-5 portion anti-settling agent, 2-4 parts of light triggers.
Preferably, the wear-resistant powder of modified high rigidity is surface-modified alundum (Al2O3).
The official's urethane acrylate of UV6 ~ 9 that wear-resistant layer is used can provide good cross-linking effect, UV modified epoxies third
Alkene olefin(e) acid ester has the advantages that intensity is good, and two/three official UV monomers can well be changed with the official's urethane acrylate of UV6 ~ 9
Crosslinking is learned, being formed has highdensity tridimensional network, the wear-resistant powder of modified high rigidity is the three of surface-modified high-purity
Al 2 O(AL2O3), highly mixed with resin system, can fully show the ultrahigh hardness super-high wear-resistant of alundum (Al2O3),
The filler reinforcement of highly cross-linked resin system combination ultrahigh hardness so that whole coating reaches optimal abrasion resistant effect.
Preferably, the hardening layer includes the component of following parts by weight:20-30 parts of UV propylene oxide olefin(e) acids esters, 5-10
Part UV two official's urethane acrylates, many official's urethane acrylates of 5-10 parts of UV, the official UV monomers of 20-35 parts two or three official UV
Monomer, 3-6 part composite photoinitiator.
Hardening layer has the advantages that intensity is good using UV propylene oxide olefin(e) acid esters, and the official's urethane acrylates of UV two can be put down
The toughness of weighing apparatus paint film, reduces cure shrinkage, it is hard that many official's urethane acrylates of UV all improve coating using phenyl ring hard segment structure
Degree, two/three official UV monomers can provide good cross-linking effect, and two/three official UV monomers and UV are triggered by composite photoinitiator
The many official's urethane acrylates of modified epoxy propylene olefin(e) acid ester, the official's urethane acrylates of UV two, UV carry out depth chemical crosslinking,
Make paint film that there is high intensity, good toughness, lower shrinkage, high attachment, coating is reached good hardening effect.
Preferably, the scratch-resistant layer includes the component of following parts by weight:20-30 parts of UV propylene oxide olefin(e) acids esters, 10-
15 parts of official's urethane acrylates of UV two, the official UV monomers of 20-30 parts two or three official UV monomers, 15-25 parts of glass dust fillers, 3-6
Part composite photoinitiator.
Scratch-resistant layer has the advantages that intensity is good using UV propylene oxide olefin(e) acid esters, and the official's urethane acrylates of UV two can be put down
Weigh the toughness of paint film, and two/three official UV monomers can provide good cross-linking effect, modified glass powder filler can well with coating
Resin mixes, and can fully show the high rigidity of glass dust, high transparency, high scratch resistant, using composite photoinitiator, can improve painting
The double bond conversion rate of film, makes the increase of painting film strength, residual smell reduction.
Further object of the present invention, is to provide the coating method of ancient imitation floor board surface specially treated, comprises the following steps:
(1)Plain flaggy modelled after an antique is made in plain plate polishing grinding modelled after an antique, aqueous coloring, drying are carried out to the plain flaggy modelled after an antique;(2)Coating
Cross-linked layer, treats that its is half-dried;Coating filling coating, is coated with filling paint after its is half-dried, treats its surface drying again on cross-linked layer,
Obtain packed layer;(3)Sanding processing is carried out to packed layer, wear-resistant layer is coated with, its surface drying is treated, coating hardening layer is treated that its is half-dried, applied
Cloth scratch-resistant layer, treats its surface drying, then carries out sanding processing, is coated with surface layer, treats that its is absolutely dry, obtain finished product.
By implementing above-mentioned technical proposal, the present invention is improved by the component to each coating layer, with reference to every layer of group
Dtex point, improves the hierarchical structure of ancient imitation floor board, and each coating layer of reasonable layout, the flatness of product surface is more preferable, between each layer
Attachment force it is strong, the quality of product is protected, and product surface hardness gets a promotion, and adds surface scratch-resistant and surface abrasion resistance
Revolution, while also ensure that the toughness of coating layer, improves the comfort level of feel;Coating method is simple to operate, by the spy of each layer
Point can be fully demonstrated, and cost is also low.
Brief description of the drawings
Accompanying drawing 1 is the structural representation of one embodiment of the invention.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1:
A kind of ancient imitation floor board, as shown in Figure 1, including solid wood plain flaggy 101 modelled after an antique, it is coated on plain flaggy 101 modelled after an antique
Stereoeffect layer 102, the stereoeffect layer 102 on coat successively cross-linked layer 103, packed layer 104, wear-resistant layer 105, increase
Hard formation 106 and scratch-resistant layer 107, surface layer 108.Wherein, 107 3 layers of wear-resistant layer 105, hardening layer 106 and scratch-resistant layer are used as protective layer.
Wherein, the cross-linked layer 103 includes the component of following parts by weight:The mono- official's urethane acrylates of 10 parts of UV, 10 parts
UV pure acrylic resins, 20 parts of UV propylene oxide olefin(e) acids esters, 30 parts of list official UV monomers, 5 parts of modified glass powder fillers, 15 parts be combined
Light trigger;
The packed layer 104 includes the component of following parts by weight:15 parts of UV propylene oxide olefin(e) acids esters, 12 parts of officials of UV two gather
Urethane acrylate, 15 parts of UV polyester acrylates, 20 part of three official UV monomers, 5 parts of compounded mixs, 6 parts of composite photoinitiators;
Compounded mix is the mixture of glass dust and talcum powder, and the mass mixing ratio of the glass dust and talcum powder is 1:0.1;
The wear-resistant layer 105 includes the component of following parts by weight:The official's urethane acrylate of 20 parts of UV6 ~ 9,25 parts of UV
Modified epoxy propylene olefin(e) acid ester, 20 part of two official UV monomers, 10 parts of wear-resistant powder of modified high rigidity, 5 parts of anti-settling agents, 3 parts of light triggers;
The wear-resistant powder of modified high rigidity is that the alundum (Al2O3) of surface oleophylic modification is carried out via stearic acid;
The hardening layer 106 includes the component of following parts by weight:20 parts of UV propylene oxide olefin(e) acids esters, 8 parts of officials of UV two gather
Urethane acrylate, many official's urethane acrylates of 10 parts of UV, 35 part of two official UV monomers, 3 parts of composite photoinitiators;
The scratch-resistant layer 107 includes the component of following parts by weight:26 parts of UV propylene oxide olefin(e) acids esters, 15 parts of officials of UV two gather
Urethane acrylate, 24 part of three official UV monomers, 15 parts of glass dust fillers, 6 parts of composite photoinitiators;
The surface layer 108 includes the component of following parts by weight:The official's urethane acrylate of 35 parts of UV6 ~ 9,16 parts of UV two
Official's urethane acrylate, 35 parts of UV compound monomers, 5 parts of UV composite nano inoganics materials, 2 parts of tetrafluoro wax powders, 0.5 part it is organic
Silicon face controlling agent;
Specific covering with paint step is as follows:(1)Plain flaggy 101 modelled after an antique is made in plain plate polishing grinding modelled after an antique, to the element modelled after an antique
Flaggy 101 carries out aqueous coloring, drying;(2)Cross-linked layer 103 is coated with, treats that its is half-dried;Filling paint is coated with cross-linked layer 103,
Filling paint is coated with again after its is half-dried, its surface drying is treated, obtains packed layer 104;(3)Sanding processing is carried out to packed layer 104,
Wear-resistant layer 105 is coated with, its surface drying is treated, coating hardening layer 106 treats that its is half-dried, is coated with scratch-resistant layer 107, treats its surface drying, then carry out sand
Light processing, is coated with surface layer 108, treats that its is absolutely dry, obtain finished product.
Embodiment 2:
A kind of ancient imitation floor board, including plain flaggy 101 modelled after an antique is combined, imitative wood texture is carved with plain flaggy 101 modelled after an antique and is made
For stereoeffect layer 102, cross-linked layer 103, packed layer 104, wear-resistant layer 105, increasing are coated successively on stereoeffect layer 102
Hard formation 106 and scratch-resistant layer 107, surface layer 108.Wherein, 107 3 layers of wear-resistant layer 105, hardening layer 106 and scratch-resistant layer are used as protective layer.
Wherein, the cross-linked layer 103 includes the component of following parts by weight:The mono- official's urethane acrylates of 20 parts of UV, 5 parts of UV
Pure acrylic resin, 10 parts of UV propylene oxide olefin(e) acids esters, 20 parts of list official UV monomers, 15 parts of modified glass powder fillers, 3 parts of complex lights
Initiator;
The packed layer 104 includes the component of following parts by weight:25 parts of UV propylene oxide olefin(e) acids esters, 10 parts of officials of UV two
Urethane acrylate, 5 parts of UV polyester acrylates, 15 part of two official UV monomer or three official UV monomers, 10 parts of compounded mixs, 3 parts
Composite photoinitiator;Compounded mix is the mixture of glass dust and talcum powder, the mass mixing ratio of the glass dust and talcum powder
For 1:5;
The wear-resistant layer 105 includes the component of following parts by weight:The official's urethane acrylate of 25 parts of UV6 ~ 9,15 parts of UV
Modified epoxy propylene olefin(e) acid ester, 15 part of two official UV monomers, 15 parts of wear-resistant powder of modified high rigidity, 3 parts of anti-settling agents, 2 parts of light triggers;
The wear-resistant powder of modified high rigidity is that the alundum (Al2O3) of surface oleophylic modification is carried out via stearic acid;
The hardening layer 106 includes the component of following parts by weight:30 parts of UV propylene oxide olefin(e) acids esters, 5 parts of officials of UV two gather
Urethane acrylate, many official's urethane acrylates of 5 parts of UV, 25 part of three official UV monomers, 5 parts of composite photoinitiators;
The scratch-resistant layer 107 includes the component of following parts by weight:30 parts of UV propylene oxide olefin(e) acids esters, 10 parts of officials of UV two
Urethane acrylate, 20 part of three official UV monomers, 20 parts of glass dust fillers, 4 parts of composite photoinitiators;
The surface layer 108 includes the component of following parts by weight:The official's urethane acrylate of 40 parts of UV6 ~ 9,20 parts of UV two
Official's urethane acrylate, 40 parts of UV compound monomers, 8 parts of UV composite nano inoganics materials, 3 parts of tetrafluoro wax powders, 1 part of organosilicon
Surface control agent;
Specific covering with paint step is as follows:(1)Plain flaggy 101 modelled after an antique is made in plain plate polishing grinding modelled after an antique, to the element modelled after an antique
Flaggy 101 carries out aqueous coloring, drying;(2)Cross-linked layer 103 is coated with, treats that its is half-dried;Filling paint is coated with cross-linked layer 103,
Filling paint is coated with again after its is half-dried, its surface drying is treated, obtains packed layer 104;(3)Sanding processing is carried out to packed layer 104,
Wear-resistant layer 105 is coated with, its surface drying is treated, coating hardening layer 106 treats that its is half-dried, is coated with scratch-resistant layer 107, treats its surface drying, then carry out sand
Light processing, is coated with surface layer 108, treats that its is absolutely dry, obtain finished product.
Embodiment 3:
A kind of ancient imitation floor board, including solid wood plain flaggy modelled after an antique, are carved with imitative wood texture as solid on plain flaggy modelled after an antique
Effect layer, coats cross-linked layer 103, packed layer 104, wear-resistant layer 105,106 and of hardening layer successively on stereoeffect layer 102
Scratch-resistant layer 107, surface layer 108.Wherein, 107 3 layers of wear-resistant layer 105, hardening layer 106 and scratch-resistant layer are used as protective layer.
Wherein, the cross-linked layer 103 includes the component of following parts by weight:The mono- official's urethane acrylates of 15 parts of UV, 20 parts
UV pure acrylic resins, 15 parts of UV propylene oxide olefin(e) acids esters, 10 parts of list official UV monomers, 20 parts of modified glass powder fillers, 10 parts it is multiple
Closing light initiator;
The packed layer 104 includes the component of following parts by weight:20 parts of UV propylene oxide olefin(e) acids esters, 12 parts of officials of UV two gather
Urethane acrylate, 10 parts of UV polyester acrylates, 10 part of two official UV monomers, 15 parts of compounded mixs, 5 parts of composite photoinitiators;
Compounded mix is the mixture of glass dust and talcum powder, and the mass mixing ratio of the glass dust and talcum powder is 1:1;
The wear-resistant layer 105 includes the component of following parts by weight:The official's urethane acrylate of 15 parts of UV6 ~ 9,20 parts of UV
Modified epoxy propylene olefin(e) acid ester, 25 part of three official UV monomers, 20 parts of wear-resistant powder of modified high rigidity, 1 part of anti-settling agent, 4 parts of light triggers;
The wear-resistant powder of modified high rigidity is that the alundum (Al2O3) of surface oleophylic modification is carried out via stearic acid;
The hardening layer 106 includes the component of following parts by weight:26 parts of UV propylene oxide olefin(e) acids esters, 10 parts of officials of UV two gather
Urethane acrylate, many official's urethane acrylates of 8 parts of UV, 20 part of three official UV monomers, 6 parts of composite photoinitiators;
The scratch-resistant layer 107 includes the component of following parts by weight:20 parts of UV propylene oxide olefin(e) acids esters, 12 parts of officials of UV two gather
Urethane acrylate, 30 part of three official UV monomers, 25 parts of glass dust fillers, 3 parts of composite photoinitiators;
The surface layer 108 includes the component of following parts by weight:The official's urethane acrylate of 30 parts of UV6 ~ 9,10 parts of UV two
Official's urethane acrylate, 30 parts of UV compound monomers, 3 parts of UV composite nano inoganics materials, 0.5 part of tetrafluoro wax powder, 0.2 part have
Organic silicon surface controlling agent;
Specific covering with paint step is as follows:(1)Plain flaggy 101 modelled after an antique is made in plain plate polishing grinding modelled after an antique, to the element modelled after an antique
Flaggy 101 carries out aqueous coloring, drying;(2)Cross-linked layer 103 is coated with, treats that its is half-dried;Filling paint is coated with cross-linked layer 103,
Filling paint is coated with again after its is half-dried, its surface drying is treated, obtains packed layer 104;(3)Sanding processing is carried out to packed layer 104,
Wear-resistant layer 105 is coated with, its surface drying is treated, coating hardening layer 106 treats that its is half-dried, is coated with scratch-resistant layer 107, treats its surface drying, then carry out sand
Light processing, is coated with surface layer 108, treats that its is absolutely dry, obtain finished product.
Embodiment 4:
A kind of ancient imitation floor board, including solid wood plain flaggy 101 modelled after an antique, are coated in the stereoeffect layer on plain flaggy 101 modelled after an antique
102, cross-linked layer 103, packed layer 104, wear-resistant layer 105, scratch-resistant layer 107, hardening are coated successively on stereoeffect layer 102
Layer 106, wear-resistant layer 105, hardening layer 106 and scratch-resistant layer 107, surface layer 108.Wherein, wear-resistant layer 105, the hardening layer being arranged alternately
106 and scratch-resistant layer 107 be used as protective layer.
Wherein, the cross-linked layer 103 includes the component of following parts by weight:The mono- official's urethane acrylates of 15 parts of UV, 20 parts
UV pure acrylic resins, 15 parts of UV propylene oxide olefin(e) acids esters, 10 parts of list official UV monomers, 20 parts of modified glass powder fillers, 10 parts it is multiple
Closing light initiator;
The packed layer 104 includes the component of following parts by weight:20 parts of UV propylene oxide olefin(e) acids esters, 12 parts of officials of UV two gather
Urethane acrylate, 10 parts of UV polyester acrylates, 10 part of three official UV monomers, 15 parts of compounded mixs, 5 parts of composite photoinitiators;
Compounded mix is the mixture of glass dust and talcum powder, and the mass mixing ratio of the glass dust and talcum powder is 1:1;
The wear-resistant layer 105 includes the component of following parts by weight:The official's urethane acrylate of 15 parts of UV6 ~ 9,20 parts of UV
Modified epoxy propylene olefin(e) acid ester, 25 part of two official UV monomers, 20 parts of wear-resistant powder of modified high rigidity, 1 part of anti-settling agent, 4 parts of light triggers;
The wear-resistant powder of modified high rigidity is that the alundum (Al2O3) of surface oleophylic modification is carried out via stearic acid;
The hardening layer 106 includes the component of following parts by weight:26 parts of UV propylene oxide olefin(e) acids esters, 10 parts of officials of UV two gather
Urethane acrylate, many official's urethane acrylates of 8 parts of UV, 20 part of three official UV monomers, 6 parts of composite photoinitiators;
The scratch-resistant layer 107 includes the component of following parts by weight:20 parts of UV propylene oxide olefin(e) acids esters, 12 parts of officials of UV two gather
Urethane acrylate, 30 part of two official UV monomers, 25 parts of glass dust fillers, 3 parts of composite photoinitiators;
The surface layer 108 includes the component of following parts by weight:The official's urethane acrylate of 30 parts of UV6 ~ 9,10 parts of UV two
Official's urethane acrylate, 30 parts of UV compound monomers, 3 parts of UV composite nano inoganics materials, 0.5 part of tetrafluoro wax powder, 0.2 part have
Organic silicon surface controlling agent;
Specific covering with paint step is as follows:(1)Plain flaggy 101 modelled after an antique is made in plain plate polishing grinding modelled after an antique, to the element modelled after an antique
Flaggy 101 carries out aqueous coloring, drying;(2)Cross-linked layer 103 is coated with, treats that its is half-dried;Filling paint is coated with cross-linked layer 103,
Filling paint is coated with again after its is half-dried, its surface drying is treated, obtains packed layer 104;(3)Sanding processing is carried out to packed layer 104,
Wear-resistant layer 105 is coated with, its surface drying is treated, scratch-resistant layer 107 is coated with, treats that its is half-dried, coating hardening layer 106 is treated that its is half-dried, is coated with wear-resistant
Layer 105, treats its surface drying, coating hardening layer 106, treats that its is half-dried, is coated with scratch-resistant layer 107, treats its surface drying, then carries out sanding processing,
Surface layer 108 is coated with, treats that its is absolutely dry, obtains finished product.