CN105132222A - Cleaning agent with low surface tension for automobile glass - Google Patents
Cleaning agent with low surface tension for automobile glass Download PDFInfo
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- CN105132222A CN105132222A CN201510526320.5A CN201510526320A CN105132222A CN 105132222 A CN105132222 A CN 105132222A CN 201510526320 A CN201510526320 A CN 201510526320A CN 105132222 A CN105132222 A CN 105132222A
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- surface tension
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Abstract
The invention discloses a cleaning agent with low surface tension for automobile glass. The cleaning agent for the automobile glass consists of the following raw materials in parts by weight: 46-76.5 parts of activated water with low surface tension, 23-53 parts of an antifreezing deoiling agent, 0.1-0.5 part of a non-ionic surfactant, 0.1-0.3 part of an anionic surfactant, 0.1-0.2 part of an inhibitor, 0.1-0.5 part of a lubricant and 0.1-0.2 part of an anticorrosive mildewproof agent. According to the cleaning agent with low surface tension for the automobile glass disclosed by the invention, activated water with low surface tension, which is used in the cleaning agent, can thoroughly moisten the surface of the glass, clean more spots, so that the usage quantity of surfactants is reduced, and the pollution of the surfactants to environment is reduced. The cleaning agent with low surface tension for the glass disclosed by the invention, is energy-saving, environmental-friendly, long in shelf life, high in dirt removal capability and good in antifogging and anti-frosting properties.
Description
Technical field
The present invention relates to clean-out system technical field, more specifically relate to a kind of low surface tension automobile glass cleaning agent.
Background technology
Nowadays, automobile has become the vital vehicles in people's daily life, and the clean light levels of windshield glass drastically influence the sight line of driver, is related to its personnel safety.Automobile park in outdoor or driving process time, windshield glass have accumulated a certain amount of dust, greasy dirt and shellac etc., cause pilot's line of vision fuzzy, the impact of frost mist during cold weather on windshield glass is even more serious.Simple tap water is difficult to all removed by the dirt on windshield glass and easily leave washmarking, and the non-dedicated washing composition such as life-time service washing powder, dish detergent then can cause the corrosion of each component of automobile.So common tap water or simple clean-out system cleaning can not meet the requirement of numerous car owners, and special automobile glass cleaning agent arises at the historic moment.
Automobile glass cleaning agent is windshield cleaning special agent, for removing the dust, greasy dirt, shellac etc. on windshield glass, and has certain anti-fog and antifrost function.General bath of glass forms primarily of water, ethanol, ethylene glycol, lubricant, inhibiter, various tensio-active agent and other additives; wherein ethanol and ethylene glycol can dissolve part dirt as organic solvent; and reduce freezing point of solution; lubricant can reduce the friction between rain brush and windshield; farthest reducing rain brush to the wearing and tearing of glass extends work-ing life of rain brush, and inhibiter can protect glass, rubber, lacquer painting and metallic element on automobile not to be damaged corrosion by the chemical composition in automobile glass cleaning agent.And tensio-active agent can reduce the surface tension of liquid as additive vital in automobile glass cleaning agent, and improve the solubility of organic compound, greatly reduce the clean difficulty of windshield glass.
At present, commercially available various brands automobile glass cleaning agent quality is uneven, in order to meet the requirements of cleaning capacity and longer quality guaranteed period, with the addition of a large amount of tensio-active agents and Antisepticize and mildew preventive etc. in automobile glass cleaning agent.Tensio-active agent is as a kind of chemical industry synthetic agent, and its production process needs certain water, electricity, the resources such as industrial chemicals, consumes certain Energy resources; Tensio-active agent is discharged in air, water body, soil the environmental pollution that can bring to a certain degree, and can accumulate final arrival in human body in biologic chain, causes certain harm to human body.In today of scarcity of resources bad environments, under the prerequisite ensureing automobile glass cleaning agent quality, reduce the usage quantity of the various additive such as tensio-active agent and Antisepticize and mildew preventive, development environment friendly product innovation is very necessary.
Summary of the invention
(1) technical problem that will solve
The technical problem to be solved in the present invention is exactly the pollution that the addition that how to reduce tensio-active agent in automobile glass cleaning agent reduces to environment, and reduces the cost of automobile glass cleaning agent, and provides a kind of low surface tension automobile glass cleaning agent of environmental protection.
(2) technical scheme
In order to solve the problems of the technologies described above, the invention provides a kind of low surface tension automobile glass cleaning agent, this automobile glass cleaning agent is made up of the raw material of following weight part: low surface tension activated water 46 ~ 76.5 parts, antifreeze degreaser 23 ~ 53 parts, nonionic surface active agent 0.1 ~ 0.5 part, aniorfic surfactant 0.1 ~ 0.3 part, inhibiter 0.1 ~ 0.2 part, lubricant 0.1 ~ 0.5 part, Antisepticize and mildew preventive 0.1 ~ 0.2 part.
Preferably, this automobile glass cleaning agent is made up of the raw material of following weight part: low surface tension activated water 46 ~ 56 parts, antifreeze degreaser 43 ~ 53 parts, nonionic surface active agent 0.3 ~ 0.5 part, aniorfic surfactant 0.2 ~ 0.3 part, inhibiter 0.1 ~ 0.15 part, lubricant 0.1 ~ 0.2 part, Antisepticize and mildew preventive 0.1 ~ 0.15 part.
Preferably, the gross weight of described raw material is 100 parts.
Preferably, described antifreeze degreaser selects the combination of ethanol, Virahol and ethylene glycol three kinds of raw materials; The adding proportion of ethanol, Virahol and ethylene glycol is 5 ~ 40:4 ~ 8:2 ~ 6.More preferably the adding proportion of ethanol, Virahol and ethylene glycol is 40:8:5.
Preferably, described nonionic surface active agent selects one or more of octyl phenol Soxylat A 25-7 (OP-10), polyoxyethylene nonylphenol ether (TX-10) or dimethyl dodecyl amine oxide; More preferably octyl phenol Soxylat A 25-7 (OP-10).
Preferably, one or more of sulfosuccinate dihexyl sodium salt, sodium lauryl sulphate or Sodium palmityl sulfate selected by described aniorfic surfactant; More preferably sodium lauryl sulphate.
Preferably, composite inhibiter AK-700 selected by described inhibiter.
Preferably, one or more of glycerine, water-soluble silicon oil or anhydrous sodium metasilicate selected by described lubricant; More preferably water-soluble silicon oil.
Preferably, described Antisepticize and mildew preventive selects Kathon CG.
Preferably, this automobile glass cleaning agent is made up of the raw material of following weight part: low surface tension activated water 46 parts, antifreeze degreaser 53 parts, nonionic surface active agent 0.5 part, aniorfic surfactant 0.2 part, inhibiter 0.1 part, lubricant 0.1 part, Antisepticize and mildew preventive 0.1 part.
The present invention prepares the raw materials used all commercially available acquisition of low surface tension automobile glass cleaning agent.
Preferably, described low surface tension activated water is prepared by following method: with far-infrared radiation ceramic powder (being purchased from energy and environment institute of Hebei University of Technology) for raw material through batch mixing, ball milling, shaping, sinter at 1000 ~ 1300 DEG C and be incubated 3 ~ 5h and make the ceramic particle with function far infrared radiation function, its radiation infrared wavelength is within the scope of 5 ~ 30 μm; The made ceramic particle with function far infrared radiation function of 1/5 ~ 1/4 volume is added in filter bed, deionized water is passed at water-in, deionized water residence time in filter bed controls, at 1 ~ 6 hour, to obtain low surface tension activated water at water outlet, and its surface tension is 6.50 ~ 7.00 × 10
-2within the scope of N/m.
In medical science neck, infrared spectra medium wavelength range is called far infrared rays at the light of 1.5 ~ 400 μm.Far infrared rays has stronger seepage force and radial force, has significant temperature control effect and resonance effect, and it is easily absorbed by object and is converted into energy in object.At present, far infrared rays has been widely used in the fields such as agricultural, industry, medical treatment, health care.
The ceramic particle with function far infrared radiation function adopted in the present invention has far infrared rays launching effect significantly, far infrared rays wavelength is within the scope of 5 ~ 30 μm, good with the resonance effect of water, its resonance effect makes water molecules produce resonant absorption effects, on the one hand, because the hertzian wave of far infrared rays and water molecules resonate, hydrogen bond between water molecules is destroyed, reduce the degree of association of water molecule group, on the other hand, the vibration of water molecules is caused to aggravate with rotation, add the energy of motion, becoming macromole water is micromolecular water, obtain the activated water compared with low surface tension.
For solid surface, can judge that can liquid soak solid surface and wetness degree with contact angle, the Young's equation by interfacial chemistry:
Above-mentioned formula describes solid and gas, solid-liquid, liquid gas interface free energy γ
sv, γ
sL, γ
lvand the relational expression between the actual contact angle θ ', wherein the free energy of liquid gas interface refers to the surface energy of liquid, solid surface can be wetted prerequisite under, for solid, gas medium of the same race, the surface energy of liquid is higher, and COS θ ' is worth larger, and θ ' value is less, namely the actual contact angle is less, and solid surface is more wetted.
Therefore, the low surface tension activated water obtained by the ceramic particle process with function far infrared radiation function has the higher surface energy of more common deionized water, less with the contact angle of glass, to glass surface, there is wetting effect better, such water will be that " folder is split " shape enters between dirt and glass automatically, under the washing action of glass cleaner, dirt strips down from glass surface.Thus under the prerequisite ensureing identical cleaning capacity, decrease the addition of tensio-active agent.
The preparation process of low surface tension automobile glass cleaning agent of the present invention is as follows: each component is added successively about stirring at normal temperature 5min in low surface tension activated water and fully dissolve to each raw material and mix.
(3) beneficial effect
Automobile glass cleaning agent of the present invention greatly reduces the addition of tensio-active agent, thus decreases the discharge of objectionable impurities in automobile glass cleaning agent use procedure, both ensure that the clean bright pollution additionally reduced environment of glass.
The present invention can Reusability for the preparation of the ceramic particle with function far infrared radiation function of activated water, and therefore the preparation cost of activated water is very low, reduces the production cost of automobile glass cleaning agent.
Embodiment
Below in conjunction with embodiment, embodiments of the present invention are described in further detail.Following examples for illustration of the present invention, but can not be used for limiting the scope of the invention.
Embodiment 1
The raw material composition of the low surface tension automobile glass cleaning agent weight part as shown in Table 1 of the present embodiment environmental protection:
Table 1:
| Sequence number | Component | Consumption (Kg) |
| 1 | Low surface tension activated water | 76 |
| 2 | Ethanol | 10 |
| 3 | Virahol | 8 |
| 4 | Ethylene glycol | 5 |
| 5 | OP-10 | 0.4 |
| 6 | Sodium lauryl sulphate | 0.2 |
| 7 | Composite inhibiter AK-700 | 0.1 |
| 8 | Water-soluble silicon oil | 0.2 |
| 9 | Kathon CG | 0.1 |
In the present embodiment, the preparation process of low surface tension automobile glass cleaning agent is as follows: above-mentioned each component is added successively about stirring at normal temperature 5min in low surface tension activated water and fully dissolve to each raw material and mix.
In the present embodiment, the preparation process of low surface tension activated water is as follows: the ceramic particle with function far infrared radiation function adding 1/5 volume in filter bed, deionized water is passed at water-in, deionized water residence time in filter bed is 1h, obtains low surface tension activated water at water outlet.The present embodiment gained activated water is 6.98 × 10 the surface tension of 20 DEG C
-2n/m.
Embodiment 2
The raw material composition of the low surface tension automobile glass cleaning agent weight part as shown in Table 2 of the present embodiment environmental protection:
Table 2:
| Sequence number | Component | Consumption (Kg) |
| 1 | Low surface tension activated water | 66 |
| 2 | Ethanol | 20 |
| 3 | Virahol | 8 |
| 4 | Ethylene glycol | 5 |
| 5 | OP-10 | 0.3 |
| 6 | Sulfosuccinate dihexyl sodium salt | 0.3 |
| 7 | Composite inhibiter AK-700 | 0.1 |
| 8 | Anhydrous sodium metasilicate | 0.2 |
| 9 | Kathon CG | 0.1 |
Preparation process is with embodiment 1.
In the present embodiment, the preparation process of low surface tension activated water is as follows: the ceramic particle with function far infrared radiation function adding 1/5 volume in filter bed, deionized water is passed at water-in, deionized water residence time in filter bed is 3h, obtains low surface tension activated water at water outlet.The present embodiment gained activated water is 6.82 × 10 the surface tension of 20 DEG C
-2n/m.
Embodiment 3
The raw material composition of the low surface tension automobile glass cleaning agent weight part as shown in Table 3 of the present embodiment environmental protection:
Table 3:
| Sequence number | Component | Consumption (Kg) |
| 1 | Low surface tension activated water | 56 |
| 2 | Ethanol | 30 |
| 3 | Virahol | 8 |
| 4 | Ethylene glycol | 5 |
| 5 | OP-10 | 0.3 |
| 6 | Sodium palmityl sulfate | 0.2 |
| 7 | Composite inhibiter AK-700 | 0.15 |
| 8 | Glycerine | 0.2 |
| 9 | Kathon CG | 0.15 |
Preparation technology is with embodiment 1.
In the present embodiment, the preparation process of low surface tension activated water is as follows: the ceramic particle with function far infrared radiation function adding 1/4 volume in filter bed, deionized water is passed at water-in, deionized water residence time in filter bed is 5h, obtains low surface tension activated water at water outlet.The present embodiment gained activated water is 6.95 × 10 the surface tension of 20 DEG C
-2n/m.
Embodiment 4
The raw material composition of the low surface tension automobile glass cleaning agent weight part as shown in Table 4 of the present embodiment environmental protection:
Table 4:
| Sequence number | Component | Consumption (Kg) |
| 1 | Low surface tension activated water | 46 |
| 2 | Ethanol | 40 |
| 3 | Virahol | 8 |
| 4 | Ethylene glycol | 5 |
| 5 | TX-10 | 0.5 |
| 6 | Sodium palmityl sulfate | 0.2 |
| 7 | Composite inhibiter AK-700 | 0.1 |
| 8 | Glycerine | 0.1 |
| 9 | Kathon CG | 0.1 |
Preparation technology is with embodiment 1.
In the present embodiment, the preparation process of low surface tension activated water is as follows: the ceramic particle with function far infrared radiation function adding 1/4 volume in filter bed, deionized water is passed at water-in, deionized water residence time in filter bed is 6h, obtains low surface tension activated water at water outlet.The present embodiment gained activated water is 6.53 × 10 the surface tension of 20 DEG C
-2n/m.
Experimental example 1
The low surface tension automobile glass cleaning agent performance measurement result of the environmental protection of embodiment 1-4 is as shown in table 6.Wherein carry out clearing power mensuration according to the experimental technique in GB/T23436-2009, contrast standard fluid component is in table 5.
Table 5:
| Reagent | Volume ratio/% |
| Ethanol | 26.00 |
| Virahol | 4.00 |
| Alkylphenol polyoxyethylene | 0.03 |
| Diethanolamine | 0.50 |
| Water | 69.47 |
Table 6:
Above embodiment is only for illustration of the present invention, but not limitation of the present invention.Although with reference to embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, various combination, amendment or equivalent replacement are carried out to technical scheme of the present invention, do not depart from the spirit and scope of technical solution of the present invention, all should be encompassed in the middle of right of the present invention.
Claims (10)
1. a low surface tension automobile glass cleaning agent, it is characterized in that, this automobile glass cleaning agent is made up of the raw material of following weight part: low surface tension activated water 46 ~ 76.5 parts, antifreeze degreaser 23 ~ 53 parts, nonionic surface active agent 0.1 ~ 0.5 part, aniorfic surfactant 0.1 ~ 0.3 part, inhibiter 0.1 ~ 0.2 part, lubricant 0.1 ~ 0.5 part, Antisepticize and mildew preventive 0.1 ~ 0.2 part.
2. low surface tension automobile glass cleaning agent according to claim 1, it is characterized in that, this automobile glass cleaning agent is made up of the raw material of following weight part: low surface tension activated water 46 ~ 56 parts, antifreeze degreaser 43 ~ 53 parts, nonionic surface active agent 0.3 ~ 0.5 part, aniorfic surfactant 0.2 ~ 0.3 part, inhibiter 0.1 ~ 0.15 part, lubricant 0.1 ~ 0.2 part, Antisepticize and mildew preventive 0.1 ~ 0.15 part.
3. low surface tension automobile glass cleaning agent according to claim 1 and 2, is characterized in that, described antifreeze degreaser selects the combination of ethanol, Virahol and ethylene glycol three kinds of raw materials; The adding proportion of ethanol, Virahol and ethylene glycol is 5 ~ 40:2 ~ 4:1 ~ 3.
4. the low surface tension automobile glass cleaning agent according to any one of claim 1-3, it is characterized in that, described nonionic surface active agent selects one or more of octyl phenol Soxylat A 25-7, polyoxyethylene nonylphenol ether or dimethyl dodecyl amine oxide.
5. the low surface tension automobile glass cleaning agent according to any one of claim 1-4, is characterized in that, one or more of sulfosuccinate dihexyl sodium salt, sodium lauryl sulphate or Sodium palmityl sulfate selected by described aniorfic surfactant.
6. low surface tension automobile glass cleaning agent according to claim 1 and 2, is characterized in that, composite inhibiter AK-700 selected by described inhibiter.
7. low surface tension automobile glass cleaning agent according to claim 1 and 2, is characterized in that, one or more of glycerine, water-soluble silicon oil or anhydrous sodium metasilicate selected by described lubricant.
8. the low surface tension automobile glass cleaning agent of environmental protection according to claim 1 and 2, is characterized in that, described Antisepticize and mildew preventive selects Kathon CG.
9. the low surface tension automobile glass cleaning agent of the environmental protection according to any one of claim 1-8, it is characterized in that, this automobile glass cleaning agent is made up of the raw material of following weight part: low surface tension activated water 46 parts, antifreeze degreaser 53 parts, nonionic surface active agent 0.5 part, aniorfic surfactant 0.2 part, inhibiter 0.1 part, lubricant 0.1 part, Antisepticize and mildew preventive 0.1 part.
10. the low surface tension automobile glass cleaning agent according to any one of claim 1-8, it is characterized in that, described low surface tension activated water is prepared by following method: the ceramic particle with function far infrared radiation function adding 1/5 ~ 1/4 volume in filter bed, deionized water is passed at water-in, deionized water residence time in filter bed controls at 1 ~ 6 hour, obtain low surface tension activated water at water outlet, its surface tension is within the scope of 6.50 ~ 7.00 × 10-2N/m.
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105586166A (en) * | 2016-03-04 | 2016-05-18 | 苏州圣谱拉新材料科技有限公司 | Corrosion-resistant glass cleaner and preparation method thereof |
| CN105838511A (en) * | 2016-04-11 | 2016-08-10 | 河南工程学院 | A novel environmental-friendly automobile windshield washing concentrated liquid |
| CN106544195A (en) * | 2016-10-07 | 2017-03-29 | 常州市鼎日环保科技有限公司 | A kind of preparation method of automobile glass cleaning agent |
| CN107236603A (en) * | 2017-07-17 | 2017-10-10 | 苏州龙腾万里化工科技有限公司 | A kind of automotive trim efficient cleaner |
| CN107384621A (en) * | 2017-08-06 | 2017-11-24 | 淄博长宝新材料股份有限公司 | A kind of efficient automobile glass cleaning solution |
| CN109666546A (en) * | 2019-01-15 | 2019-04-23 | 深圳宏威新材料科技有限公司 | Cleaning agent for optical glass |
| CN109810803A (en) * | 2019-03-29 | 2019-05-28 | 盐城工业职业技术学院 | A kind of freeze proof bath of glass and preparation method thereof |
| CN111057623A (en) * | 2019-12-31 | 2020-04-24 | 东莞市华畅机电科技有限公司 | Glass oil film cleaning agent and preparation method thereof |
| CN111100763A (en) * | 2019-12-31 | 2020-05-05 | 东莞市华畅机电科技有限公司 | Atomized cleaning agent and preparation method thereof |
| CN111117808A (en) * | 2019-12-31 | 2020-05-08 | 东莞市华畅机电科技有限公司 | Cleaning agent for evaporator and preparation method thereof |
| CN112057357A (en) * | 2020-06-22 | 2020-12-11 | 河北深思新材料技术有限公司 | Washing-free disinfectant |
| CN115322843A (en) * | 2022-05-19 | 2022-11-11 | 浙江奇领节能环保科技有限公司 | Automobile maintenance cleaning agent and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105586166A (en) * | 2016-03-04 | 2016-05-18 | 苏州圣谱拉新材料科技有限公司 | Corrosion-resistant glass cleaner and preparation method thereof |
| CN105838511A (en) * | 2016-04-11 | 2016-08-10 | 河南工程学院 | A novel environmental-friendly automobile windshield washing concentrated liquid |
| CN106544195A (en) * | 2016-10-07 | 2017-03-29 | 常州市鼎日环保科技有限公司 | A kind of preparation method of automobile glass cleaning agent |
| CN107236603A (en) * | 2017-07-17 | 2017-10-10 | 苏州龙腾万里化工科技有限公司 | A kind of automotive trim efficient cleaner |
| CN107384621A (en) * | 2017-08-06 | 2017-11-24 | 淄博长宝新材料股份有限公司 | A kind of efficient automobile glass cleaning solution |
| CN109666546A (en) * | 2019-01-15 | 2019-04-23 | 深圳宏威新材料科技有限公司 | Cleaning agent for optical glass |
| CN109810803A (en) * | 2019-03-29 | 2019-05-28 | 盐城工业职业技术学院 | A kind of freeze proof bath of glass and preparation method thereof |
| CN111057623A (en) * | 2019-12-31 | 2020-04-24 | 东莞市华畅机电科技有限公司 | Glass oil film cleaning agent and preparation method thereof |
| CN111100763A (en) * | 2019-12-31 | 2020-05-05 | 东莞市华畅机电科技有限公司 | Atomized cleaning agent and preparation method thereof |
| CN111117808A (en) * | 2019-12-31 | 2020-05-08 | 东莞市华畅机电科技有限公司 | Cleaning agent for evaporator and preparation method thereof |
| CN112057357A (en) * | 2020-06-22 | 2020-12-11 | 河北深思新材料技术有限公司 | Washing-free disinfectant |
| CN115322843A (en) * | 2022-05-19 | 2022-11-11 | 浙江奇领节能环保科技有限公司 | Automobile maintenance cleaning agent and preparation method thereof |
| CN115322843B (en) * | 2022-05-19 | 2024-03-15 | 浙江奇领节能环保科技有限公司 | Automobile maintenance cleaning agent and preparation method thereof |
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