CN105131777A - Coating solution used on tire bead steel wire surface and preparation method of coating solution - Google Patents
Coating solution used on tire bead steel wire surface and preparation method of coating solution Download PDFInfo
- Publication number
- CN105131777A CN105131777A CN201510673630.XA CN201510673630A CN105131777A CN 105131777 A CN105131777 A CN 105131777A CN 201510673630 A CN201510673630 A CN 201510673630A CN 105131777 A CN105131777 A CN 105131777A
- Authority
- CN
- China
- Prior art keywords
- rubber
- coating solution
- bead wire
- parts
- steel bead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011324 bead Substances 0.000 title claims abstract description 84
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 71
- 239000010959 steel Substances 0.000 title claims abstract description 71
- 239000011248 coating agent Substances 0.000 title claims abstract description 53
- 238000000576 coating method Methods 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229920001971 elastomer Polymers 0.000 claims abstract description 69
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 21
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 20
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920001021 polysulfide Polymers 0.000 claims abstract description 11
- 239000003960 organic solvent Substances 0.000 claims description 12
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 claims description 10
- 239000004971 Cross linker Substances 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 244000043261 Hevea brasiliensis Species 0.000 abstract description 2
- 229920003052 natural elastomer Polymers 0.000 abstract description 2
- 229920001194 natural rubber Polymers 0.000 abstract description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000003292 glue Substances 0.000 abstract 1
- 239000005077 polysulfide Substances 0.000 abstract 1
- 150000008117 polysulfides Polymers 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 10
- 239000000284 extract Substances 0.000 description 8
- 238000000605 extraction Methods 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- 101100191136 Arabidopsis thaliana PCMP-A2 gene Proteins 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 238000011179 visual inspection Methods 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Tires In General (AREA)
- Ropes Or Cables (AREA)
Abstract
The invention provides a coating solution used on a tire bead steel wire surface and a preparation method of the coating solution. The coating solution is prepared from, by weight, 9-16 parts of methyl methacrylate grafted natural rubber, 2-5 parts of liquid polysulfide rubber, 3-7 parts of coumarone resin, 2-8 parts of terpene resin, 1-3 parts of auxiliary crosslinking agents PDM, 530-600 parts of methylbenzene and 360-440 parts of acetone. By means of a coating formed by applying the coating solution to a tire bead steel wire, the performance of the tire bead steel wire for bonding with tire bead glue can be effectively improved, and a certain antirust effect is achieved.
Description
Technical field
The present invention relates to tire production technical field, be specifically related to a kind of steel bead wire top coat liquid and preparation method thereof.
Background technology
Steel bead wire is a kind of bronzing, brass etc., is used for the steel wire of fortified tyre tyre bead.Steel bead wire will bear extremely complicated stress alternation and impact load in tire, and this just requires to have excellent bond properties between steel bead wire and rubber.Otherwise tire in use body generation steel wire is loose, stings out, even blows out.Steel bead wire ingress of air gets rusty easily, can the serious quality reducing steel bead wire.Therefore, improve steel bead wire bond properties and strengthen steel bead wire antirust ability, concerning steel bead wire, there is important Practical significance.
Summary of the invention
The present invention is to provide a kind of steel bead wire top coat liquid and preparation method thereof, smear with this coating solution the coating that steel bead wire formed and effectively can improve the bond properties of steel bead wire and bead rubber, and there is certain rust inhibition, the present invention realizes by the following technical solutions:
A kind of steel bead wire coating for surfaces liquid, is made up of following component, methyl methacrylate rubber 9-16 part, liquid polysulphide rubber 2-5 part by weight, coumarone indene resin 3-7 part, terpine resin 2-8 part, additional crosslinker PDM1-3 part, toluene 530-600 part, acetone 360-440 part.
Present invention also offers the preparation method of above-mentioned steel bead wire top coat liquid, comprise the steps:
(1) toluene, acetone are mixed with mixed organic solvents in proportion;
(2) methyl methacrylate rubber pulverizes the rubber grain for diameter 3-5mm, joins in mixed organic solvents, soaks and within 24 hours, makes methyl methacrylate rubber become fully dissolving, use strainer filtering to fall insoluble composition;
(3) in the mixed organic solvents being dissolved with methyl methacrylate rubber, liquid polysulphide rubber, coumarone indene resin, terpine resin, additional crosslinker PDM is added, stir at normal temperatures and make solute dissolves, then insoluble composition is fallen with strainer filtering, obtained steel bead wire coating solution.
Use methyl methacrylate rubber in steel bead wire top coat liquid provided by the invention, can form one deck rubber film on steel bead wire surface, methyl methacrylate rubber is the multipolymer of natural rubber and methacrylic acid rubber, all has good adhesive effect to rubber and metal.
Add liquid polysulphide rubber in coating solution, strengthen the bounding force of steel bead wire and rubber, after liquid polysulphide rubber sulfuration, there is excellent ageing-resistant performance.
Add coumarone indene resin in coating solution, have the effect of plasticising and thickening, coumarone indene resin also has certain rust inhibition.
Add terpine resin in coating solution, strengthen the bond properties of steel bead wire and rubber, terpine resin also has excellent anti-oxidant and thermostability.
Add additional crosslinker PDM in coating solution, in steel bead wire and vulcanization of rubber adhesion process, PDM can cross-linked rubber, enhancing adhesive strength.
In coating solution, rubber and resin Composition form the coating film of certain thickness rubber and plastic compound jointly on steel bead wire surface, and this layer film plays the effect of isolated moisture in air and oxygen to a certain extent, plays certain rust inhibition.
According to the dissolution characteristics of solute, use toluene, acetone as solvent.
At the uniform antirust coating of copper facing steel bead wire surface-coated one deck, effectively isolated air and moisture, play steel bead wire antirust.At the uniform tackifier coating of copper facing steel bead wire surface-coated one deck, the bond properties of steel bead wire and rubber can be improved.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in detail, but scope of the present invention is not by the restriction of these embodiments.
Embodiment 1
Present embodiments provide a kind of steel bead wire coating solution, be made up of following component by weight:, methyl methacrylate rubber 13 parts, liquid polysulphide rubber 3 parts, coumarone indene resin 5 parts, terpine resin 6 parts, additional crosslinker PDM1 part, toluene 550 parts, 400 parts, acetone.
Present invention also offers the preparation method of above-mentioned steel bead wire top coat liquid, comprise the steps:
(2) toluene, acetone are mixed with mixed organic solvents in proportion;
(2) methyl methacrylate rubber pulverizes the rubber grain for diameter 3-5mm, joins in mixed organic solvents, soaks and within 24 hours, make methyl methacrylate rubber fully dissolve, and uses strainer filtering to fall insoluble composition;
(3) in the mixed organic solvents being dissolved with methyl methacrylate rubber, liquid polysulphide rubber, coumarone indene resin, terpine resin, additional crosslinker PDM is added, stir at normal temperatures and make solute dissolves, then insoluble composition is fallen with strainer filtering, obtained steel bead wire coating solution.
Dipping coating solution with cotton thread smears without coating steel bead wire twice, dries, has made coating steel bead wire.With mill, bead rubber is moulded white silk, bottom sheet, cutting.Bead rubber and steel bead wire are together put into mould, uses vulcanizing press press vulcanization.Curing temperature 160 DEG C, curing time 20min, sulfide stress 10MPa, the embedding length of steel bead wire in rubber is 5cm.The sample vulcanizated does after placing 24 hours extracts experiment out.The baking oven having coating steel wire to be placed in 145 DEG C, after 10 minutes, take out steel wire, the oxidization condition of visual inspection Steel Wire Surface copper coating.
According to standard GB/T/T5755-2000, universal testing machine carries out extraction experiment to vulcanized test specimens, and draw speed is 50mm/min.Visual observations extracts the binding efficiency of Steel Wire Surface out.Employ the bead rubber of two tire manufacturer production in experiment, be respectively bead rubber A and bead rubber B.Wherein, it is 12.5mm that the fixture that bead rubber A uses extracts aperture out, and it is 4mm that the fixture that bead rubber B uses extracts aperture out.The Φ 0.95mm that the steel wire that experiment uses is produced for steel cord company limited of Jiangsu Xingda is without coating tempering height tin steel bead wire.
Use coating solution provided by the invention to make have the bonding of coating steel wire and bead rubber A to extract out power is 1087N, binding efficiency 75%; The bonding power of extraction out without coating steel bead wire and bead rubber A is 926N, binding efficiency 60%.Use coating solution provided by the invention to make have the bonding of coating steel bead wire and bead rubber B to extract out power is 902N, binding efficiency 70%; The bonding power of extraction out without coating steel bead wire and bead rubber B is 592N, binding efficiency 35%; After oxidation experiment, there is the basic nondiscoloration in coating steel bead wire surface, without the obviously oxidation stain of coating steel bead wire surface.
Embodiment 2
Present embodiments provide a kind of steel bead wire coating solution, be made up of following component by weight: methyl methacrylate rubber 15 parts, liquid polysulphide rubber 3 parts, coumarone indene resin 4 parts, terpine resin 8 parts, additional crosslinker PDM1 part, toluene 580 parts, 420 parts, acetone.
Present invention also offers the preparation method of above-mentioned steel bead wire top coat liquid, comprise the steps:
(3) toluene, acetone are mixed with mixed organic solvents in proportion;
(2) methyl methacrylate rubber pulverizes the rubber grain for diameter 3-5mm, joins in mixed organic solvents, soaks and within 24 hours, make methyl methacrylate rubber component dissolves, uses strainer filtering to fall insoluble composition;
(3) in the organic solvent of mixing methyl methacrylate rubber, add liquid polysulphide rubber, coumarone indene resin, terpine resin, additional crosslinker PDM, stir at normal temperatures and make solute dissolves, then fall insoluble composition with strainer filtering, obtained steel bead wire coating solution.
Dipping coating solution with cotton thread smears without coating steel bead wire twice, dries, has made coating steel bead wire.With mill, bead rubber is moulded white silk, bottom sheet, cutting.Bead rubber and steel bead wire are together put into mould, uses vulcanizing press press vulcanization.Curing temperature 160 DEG C, curing time 20min, sulfide stress 10MPa, the embedding length of steel bead wire in rubber is 5cm.The sample vulcanizated does after placing 24 hours extracts experiment out.The baking oven having coating steel wire to be placed in 145 DEG C, after 20 minutes, take out steel wire, the oxidization condition of visual inspection Steel Wire Surface copper coating.
According to standard GB/T/T5755-2000, universal testing machine carries out extraction experiment to vulcanized test specimens, and draw speed is 50mm/min.Visual observations extracts the binding efficiency of Steel Wire Surface out.Employ the bead rubber of two tire manufacturer production in experiment, be respectively bead rubber A and bead rubber B.Wherein, it is 12.5mm that the fixture that bead rubber A uses extracts aperture out, and it is 4mm that the fixture that bead rubber B uses extracts aperture out.The Φ 0.95mm that the steel wire that experiment uses is produced for steel cord company limited of Jiangsu Xingda is without coating tempering height tin steel bead wire.
Use coating solution provided by the invention to make have the bonding of coating steel wire and bead rubber A to extract out power is 1114N, binding efficiency 75%; The bonding power of extraction out without coating steel bead wire and bead rubber A is 930N, binding efficiency 60%.Use coating solution provided by the invention to make have the bonding of coating steel bead wire and bead rubber B to extract out power is 915N, binding efficiency 70%; The bonding power of extraction out without coating steel bead wire and bead rubber B is 603N, binding efficiency 35%; After oxidation experiment, there is the basic nondiscoloration in coating steel bead wire surface, without the obviously oxidation stain of coating steel bead wire surface.
Claims (2)
1. steel bead wire coating for surfaces liquid and preparation method thereof, is made up of following component by weight, methyl methacrylate rubber 9-16 part, liquid polysulphide rubber 2-5 part, coumarone indene resin 3-7 part, terpine resin 2-8 part, additional crosslinker PDM1-3 part, toluene 530-600 part, acetone 360-440 part.
2. prepare steel bead wire top coat liquid and preparation method thereof described in claim 1 for one kind, it is characterized in that, comprise the steps:
(1) toluene, acetone become mixed organic solvents by proportions described in claim 1;
(2) methyl methacrylate rubber pulverizes the rubber grain for diameter 3-5mm, joins in mixed organic solvents, soaks and within 24 hours, makes methyl methacrylate rubber become fully dissolving, fall insoluble composition with strainer filtering;
(3) in the mixed organic solvents being dissolved with methyl methacrylate rubber, liquid polysulphide rubber, coumarone indene resin, terpine resin, additional crosslinker PDM is added, stir at normal temperatures and make solute dissolves, then insoluble composition is fallen with strainer filtering, obtained steel bead wire coating solution.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510673630.XA CN105131777B (en) | 2015-10-16 | 2015-10-16 | A kind of steel bead wire face coat liquid and preparation method thereof |
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CN201510673630.XA CN105131777B (en) | 2015-10-16 | 2015-10-16 | A kind of steel bead wire face coat liquid and preparation method thereof |
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CN105131777A true CN105131777A (en) | 2015-12-09 |
CN105131777B CN105131777B (en) | 2017-10-10 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106148923A (en) * | 2016-08-16 | 2016-11-23 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
CN106189711A (en) * | 2016-08-16 | 2016-12-07 | 无锡益联机械有限公司 | A kind of preparation method of steel bead wire coating |
CN108587531A (en) * | 2018-05-11 | 2018-09-28 | 湖北福星新材料科技有限公司 | A kind of steel bead wire adhesive and preparation method thereof |
CN109181456A (en) * | 2018-08-13 | 2019-01-11 | 山东大业股份有限公司 | A kind of new style beads steel wire coating and its coating method |
CN110525129A (en) * | 2019-09-18 | 2019-12-03 | 湖北奥莱斯轮胎股份有限公司 | A kind of all-steel load-bearing radial tire carcass |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007291349A (en) * | 2006-03-31 | 2007-11-08 | Sumitomo Rubber Ind Ltd | Rubber composition for coating cord |
CN101451041A (en) * | 2007-11-30 | 2009-06-10 | 昊华南方(桂林)橡胶有限责任公司 | Rubber composition for coating radial ply tyre steel wire cord |
FR2967604A1 (en) * | 2010-11-22 | 2012-05-25 | Michelin Soc Tech | SELF-ADHERENT COMPOSITE REINFORCEMENT |
-
2015
- 2015-10-16 CN CN201510673630.XA patent/CN105131777B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007291349A (en) * | 2006-03-31 | 2007-11-08 | Sumitomo Rubber Ind Ltd | Rubber composition for coating cord |
CN101451041A (en) * | 2007-11-30 | 2009-06-10 | 昊华南方(桂林)橡胶有限责任公司 | Rubber composition for coating radial ply tyre steel wire cord |
FR2967604A1 (en) * | 2010-11-22 | 2012-05-25 | Michelin Soc Tech | SELF-ADHERENT COMPOSITE REINFORCEMENT |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106148923A (en) * | 2016-08-16 | 2016-11-23 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
CN106189711A (en) * | 2016-08-16 | 2016-12-07 | 无锡益联机械有限公司 | A kind of preparation method of steel bead wire coating |
CN106189711B (en) * | 2016-08-16 | 2018-09-25 | 无锡益联机械有限公司 | A kind of preparation method of steel bead wire coating |
CN106148923B (en) * | 2016-08-16 | 2018-12-11 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
CN108587531A (en) * | 2018-05-11 | 2018-09-28 | 湖北福星新材料科技有限公司 | A kind of steel bead wire adhesive and preparation method thereof |
CN109181456A (en) * | 2018-08-13 | 2019-01-11 | 山东大业股份有限公司 | A kind of new style beads steel wire coating and its coating method |
CN110525129A (en) * | 2019-09-18 | 2019-12-03 | 湖北奥莱斯轮胎股份有限公司 | A kind of all-steel load-bearing radial tire carcass |
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CN105131777B (en) | 2017-10-10 |
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Effective date of registration: 20180613 Address after: 225721 88 West Renmin Road, Dai Nan Town, Xinghua City, Taizhou, Jiangsu Patentee after: Jiangsu Xingda Steel Cord Co., Ltd. Address before: 266000 Qingdao University of Science & Technology, 99 Songling Road, Laoshan District, Qingdao, Shandong Patentee before: Qingdao University of Science & Technology |
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