CN105126739B - A kind of water treating suspended formula filler for strengthening the absorption of nitrogen phosphorus and its production and use - Google Patents
A kind of water treating suspended formula filler for strengthening the absorption of nitrogen phosphorus and its production and use Download PDFInfo
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- CN105126739B CN105126739B CN201510541822.5A CN201510541822A CN105126739B CN 105126739 B CN105126739 B CN 105126739B CN 201510541822 A CN201510541822 A CN 201510541822A CN 105126739 B CN105126739 B CN 105126739B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28095—Shape or type of pores, voids, channels, ducts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Hydrology & Water Resources (AREA)
- Biodiversity & Conservation Biology (AREA)
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- Environmental & Geological Engineering (AREA)
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- Water Treatment By Sorption (AREA)
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Abstract
The invention discloses a kind of water treating suspended formula filler and preparation method thereof, the method that filler is prepared using zeolite and cullet, first zeolite and glass are mixed, obtain powder batch through ball milling, then foamed, annealing obtains new biologic packing material；It is common ore that filler, which prepares zeolite used, and glass is common plate glass.The microcellular structure of zeolite is adapted to microbial growth, carried out microorganism it is appropriate introduce a fine variety, cultivate and tame after, it is applied to sewage water denitrification field, the performance of its excellent adsorption of nitrogen phosphorus can be not only played, and can effectively remove the materials such as organic matter and the nitrogen phosphorus of various forms using microbial action.In addition, floating filler can be controlled in the density close to water body by microorganism attachment, have in terms of sewage disposal without fixed support, in full pond good fluidity, power consumption is small, and porosity is big, it is a kind of very promising water treatment filler not the advantages that easy to knot groups.
Description
Technical field
The invention belongs to environment-friendly materials field, especially relates to a kind of water treating suspended formula filler and its system for strengthening the absorption of nitrogen phosphorus
Preparation Method and purposes.
Background technology
Sewage treatmentmethod is more, the application advantage of biomembrance process, and the appearance of membrane technology alleviates the phenomenon of water pollution.With
The continuous development in city, emerging industry constantly occurs, the deterioration that the phenomenon of environmental pollution also accelerates.Therefore at the water in China
Industry is managed also in the development need according to overall situation, accelerates update method.Alleviate in sewage disposal with technology of biological membrane
Pollution of the water process pressure and sewage of enterprise to people's living environment.In technology of biological membrane, filler is particularly significant.Suspension is filled out
Material, mainly there is porous rotary spherical floating stuffing, is that country's processing sewage, biomembrane suspended biological filler method treatment technology are adopted
The newest series of products developed in a variety of fillers.Mainly play biofilm carrier, while have retention suspension concurrently
Effect, with biological attachment power is strong, specific surface area is big, porosity is high, chemical and biological stability is good, durable in use, not dissolution
Nuisance, do not cause secondary pollution, antiultraviolet, it is anti-aging, hydrophilicity is strong the features such as, in use, microorganism is easy
Generation, easily replacings, acid and alkali-resistance, it is anti-aging, not by water currents, service life length, excess sludge is few, easy for installation.
Foam glass refers in various mineral wastes by adding appropriate foaming agent, cosolvent and various modified additions
Agent etc. is blended to form uniform batch, is then placed in specific mould, by preheating, melting, foaming, the work such as cooling down
Porous glass material made of skill.Stomata of the foam glass inside full of countless small, uniform, connections or closing, is a kind of equal
Even gas phase and solid system.Foam glass has that density is low, it is more to close pore amount, thermal coefficient of expansion is low, thermal conductivity factor is small, hot
Learn stable performance, do not burn, operating temperature range is wide, service life is long, not by insect pest, corrosion resistant light up performance it is strong, easily machining,
The various advantages such as easy for construction, it is a kind of the heat-insulated of superior performance, sound-absorbing, protection against the tide, fireproof light building material and decoration material
Material, is referred to as environmental type heat-insulating material by user.Now, foam glass is applied seldom at home, is a kind of new material
Material, can be as energy-conservation glass pane or the heat preserving and insulating material of architectural exterior-protecting construction.
The content of the invention
It is an object of the invention to solve problems of the prior art, and one kind is provided and utilizes zeolite and glass preparation
Strengthen the water treating suspended formula filler of nitrogen phosphorus absorption, concrete technical scheme is as follows：
Using zeolite and glass preparation strengthen the water treating suspended formula filler of nitrogen phosphorus absorption by powder batch it is foamed, move back
Fire processing is made, and biologic packing material contains the hole of foaming, bulk density 0.5-0.8g/cm3, specific surface area 8.2m2/ g with
On, porosity is more than 50%；The composition and mass fraction of powder batch be：
Glass powder：16-20 parts;
Marble dust：1-3 parts；
Wherein glass powder and marble dust are powder more than 200 mesh.
Preferably, the composition of filler also includes：
Zeolite powder：2-4 parts；
Wherein zeolite powder is powder more than 200 mesh.
Another object of the present invention is to provide a kind of preparation method of the water treating suspended formula filler, specific steps
For：Powder batch will be obtained after each raw material of powder batch uniformly mixing；Batch is fitted into mould, according to following burning
Temperature processed is burnt till：400-500 DEG C is warming up to 10-15 DEG C/min heating rate, is incubated 20-30min；Again with 10-15 DEG C/
Min heating rate is warming up to 1000-1100 DEG C, is incubated 10-20min；Then it is cooled to 20-25 DEG C/min rate of temperature fall
850-900 DEG C, normal temperature is finally naturally cooled to, obtains the water treating suspended formula filler；
Each material composition and mass fraction of wherein powder batch are divided into two schemes：
Scheme one：
Glass powder：16-20 parts;
Marble dust：1-3 parts；
Scheme two：
Glass powder：16-20 parts;
Marble dust：1-3 parts；
Zeolite powder：2-4 parts；
Wherein glass powder, marble dust and zeolite powder are powder more than 200 mesh.
Third object of the present invention is that provide a kind of water treating suspended formula filler of above two handles waste water at the same time
The purposes of middle nitrogen and phosphorus.
As the preferred of such use, its specific processing method is：Biologic packing material is filled in artificial swamp, makes to wait to locate
Waste water is managed by the biologic packing material, the phosphorus in waste water is handled by the absorption property of biologic packing material itself；Continue life
Thing filler, which is placed in wetland, treats its biofilm, after biofilm by microorganism further to the nitrogen in waste water, phosphorus and organic matter at
Reason.
Fourth object of the present invention is the purposes for providing the water treating suspended formula filler of another above two, its feature
It is, is filled in above-mentioned in artificial swamp, the biologic packing material for having handled waste water and failure is clayed into power, as soil conditioner
Shed or turn in soil.
Beneficial effects of the present invention：
1. the water treating suspended formula filler of the present invention contains the hole of foaming, the bulk density of filler is in 0.8g/cm3It is left
The right side, than surface in 4.2m2/ more than g, porosity is more than 50%, and for water absorption rate more than 30%, specific surface area is big, easy biofilm, and into
The film time is shorter, and film is uniform and difficult for drop-off, and species are advanced, abundant in film.
2. water treating suspended formula packing density is less than water, there is the suspension characteristic as hollow suspension ball filler is commonly used,
It is fluidity good, it is not easily blocked, equipment is simple, low cost, and operating cost is low；And to employ cost cheap for the preparation of the filler
Discarded object, realize recycling recycling.
3. water treating suspended formula filler fully combines high removal of the fixed biological zeolite packing to ammonia nitrogen in sewage
Can, and anti-load variations ability is stronger, preferable prospect will be had by being generalized in the regeneration water treatment technology of sewage.
4. water treating suspended formula filler is after artificial wetland treatment failure is carried out, moreover it can be used to soil conditioner is prepared, it is real
Existing multiple utilization.
Embodiment
Embodiment 1：
Cullet and marble are milled to more than 200 mesh, powder is obtained after taking 18g glass powders and the mixing of 2g marble dusts
Body batch, biologic packing material is prepared for foamed, annealing.Cullet can be discarded plate glass, pattern glass,
Container glass or cathode-ray tube glass etc..The specific preparation method of water treating suspended formula filler is：
Powder batch obtained above is stacked into the mould in chamber type electric resistance furnace, powder batch is in heating furnace
Quick cooling is carried out after preheated, heating heating and foaming heating sintered and foamed heating thing is made, then by sintered and foamed heating
Thing naturally cools to the biologic packing material that room temperature can obtain having adsorption effect, actual temp control after being taken out from resistance furnace
Situation is：400 DEG C are warming up to 10 DEG C/min heating rate from room temperature, is incubated 30min；Again with 10 DEG C/min heating speed
Rate is warming up to 1000 DEG C, is incubated 10min；Then 850 DEG C are cooled to 25 DEG C/min rate of temperature fall, finally naturally cooled to often
25 DEG C of temperature, obtains the water treating suspended formula filler.The form of the filler is：The surface of filler with inside full of it is small, connect or
The stomata of closing.Filler overall mechanical strength is stronger.Filler contains the hole of foaming, in multiple sintering process, due to resistance
The distribution of stove heat itself is uneven, therefore the filling property that sintering obtains slightly has differences, but generally：The volume of filler is close
Spend for 0.5-0.8g/cm3, specific surface area 8.2m2/ more than g, porosity are more than 50%.Obtained filler water absorption rate is sintered to exist
More than 30%, acid resistance has excellent chemical stability more than 99.5%.And packing density is less than water, has and commonly uses
The same suspension characteristic of hollow suspension ball filler, it is fluidity good, it is not easily blocked, equipment is simple, low cost, and operating cost is low.
Its adsorption effect to Phosphorus From Wastewater is verified by tests below：
The preparation of Nitrogen-and Phosphorus-containing waste water：Take the concentration of Nitrogen-and Phosphorus-containing waste water, wherein potassium hydrogen phosphate that 100ml is prepared in 2 beakers
For 10mg/L, the concentration of ammonium chloride is after 50mg/L is well mixed, to stand.
In 2 beakers one be put into 6g biologic packing materials, remaining one be control group, 2 beakers are sealed with preservative film.Every
12 hours, totally 36 hours, the concentration of nitrogen and phosphorus in two groups of waste water is measured.
Ammonia nitrogen, total phosphorus concentration unit mg/L of the waste water of embodiment 1 in different periods
It is indicated above that filler has obvious and quick absorbability to the phosphorus in waste water, but under the proportioning, filler is to nitrogen
Adsorption capacity it is weaker.Therefore the biologic packing material can be used for Removal of Phosphorus in Wastewater.Specifically processing method is：Biologic packing material is filled
In the packing layer of artificial swamp, pending waste water is set to pass through the adsorptivity of biologic packing material itself first by the biologic packing material
Preliminary treatment can be carried out to the phosphorus in waste water, reduce its initial concentration；Then proceed to biologic packing material being placed in wetland, make micro- life
Thing is further handled the nitrogen in waste water, phosphorus and organic matter after its biofilm by microorganism in filler superficial growth.
Based on above-mentioned processing method, the biologic packing material of the reinforcing Phosphate Sorption can realize another purposes, i.e., will be above-mentioned
The biologic packing material that waste water and failure have been handled in artificial swamp is filled in, i.e. filler can not meet manually to the disposal ability of waste water
After wetland requirement, it is drawn off, and is clayed into power, sheds or turn in soil as soil conditioner.
Embodiment 2
In the present embodiment, cullet, marble and zeolite are milled to more than 200 mesh, take 18g glass powders, 2g marbles
Powder batch is obtained after powder and the mixing of 3g zeolite powders, biologic packing material is prepared for foamed, annealing.Cullet can
To be discarded plate glass, pattern glass, container glass or cathode-ray tube glass etc..Water treating suspended formula filler it is specific
Preparation method is same as Example 1.But actual temp control situation has differences.
Temperature control is in the present embodiment：
500 DEG C are warming up to 15 DEG C/min heating rate, is incubated 20min；Heated up again with 15 DEG C/min heating rate
To 1100 DEG C, 20min is incubated；Then 900 DEG C are cooled to 20 DEG C/min rate of temperature fall, finally naturally cool to normal temperature.Burn
Tie obtained filling property and the filling property that embodiment 1 obtains is essentially identical, each index is in above range.
Verified also according to the adsorption effect of biologic packing material of the test method of embodiment 1 to being prepared in this example, as a result
It is as follows：
Ammonia nitrogen, total phosphorus concentration unit mg/L of the waste water of embodiment 2 in different periods
It is indicated above that filler is respectively provided with obvious and quick absorbability, therefore the biologic packing material to the nitrogen in waste water, phosphorus
Available for simultaneously handle nitrogen and phosphorus in waste water.The biologic packing material is used as Performance of Constructed Wetlands Substrates.Waste water and failure are handled
Biologic packing material can clay into power, shed or turn in soil as soil conditioner.
Comparative example 1
The foamed glass that the present embodiment is generated using certain the commercially available environmental protection company being commercially available（With the filler of the present invention
It is similar）, its adsorption effect to Phosphorus From Wastewater, obtained experimental result are verified according to the testing program of embodiment 1：
Ammonia nitrogen, total phosphorus concentration unit mg/L of the waste water of comparative example 1 in different periods
The adsorption capacity that commercially available foam glass is indicated above to ammonia nitrogen in waste water, phosphorus is weaker.And the preparation side of the present invention
The innovative adsorptivity having using zeolite in method, coordinating glass, what is be fabricated to is floated in the case where marble foams
Biologic packing material also has this effect of good absorption in addition to filler characteristic in itself to the phosphorus in water.This is to biology
A kind of improvement of filler, and provide the application field of new foam glass.The filler phase that commercially available filler is prepared with the present invention
Than adsorption capacity is far smaller than the present invention.Therefore, it is of the invention to have preferably to Phosphorus From Wastewater relative to existing foamed glass
Adsorption capacity, be it is a kind of environmental protection, low cost novel absorption material.
Claims (1)
1. a kind of purposes of water treating suspended formula filler, the preparation method of the water treatment filler are：By each original of powder batch
Material obtains powder batch after uniformly mixing；Batch is fitted into mould, burnt till according to following firing temperature：With 10-15 DEG C/
Min heating rate is warming up to 400-500 DEG C, is incubated 20-30min, then be warming up to 10-15 DEG C/min heating rate
1000-1100 DEG C, 10-20min is incubated, is then cooled to 850-900 DEG C with 20-25 DEG C/min rate of temperature fall, it is last natural
Normal temperature is cooled to, obtains the water treating suspended formula filler；Each material composition and mass fraction of wherein powder batch be：Glass
Powder 16-20 parts, marble dust 1-3 parts, wherein zeolite powder 2-4 parts, glass powder, marble dust and zeolite powder are equal
For powder more than 200 mesh；The filler being prepared contains the hole of foaming, bulk density 0.5-0.8g/cm3, compare surface
Product is 8.2m2/ more than g, porosity are more than 50%；It is characterized in that：The water treating suspended formula filler is used to handle waste water simultaneously
In nitrogen and phosphorus.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510541822.5A CN105126739B (en) | 2015-08-31 | 2015-08-31 | A kind of water treating suspended formula filler for strengthening the absorption of nitrogen phosphorus and its production and use |
| CN201710966884.XA CN107855101B (en) | 2015-08-31 | 2015-08-31 | Water treatment suspended filler for strengthening nitrogen and phosphorus adsorption prepared from zeolite and glass and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510541822.5A CN105126739B (en) | 2015-08-31 | 2015-08-31 | A kind of water treating suspended formula filler for strengthening the absorption of nitrogen phosphorus and its production and use |
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| CN201710966884.XA Division CN107855101B (en) | 2015-08-31 | 2015-08-31 | Water treatment suspended filler for strengthening nitrogen and phosphorus adsorption prepared from zeolite and glass and preparation method thereof |
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| CN105126739A CN105126739A (en) | 2015-12-09 |
| CN105126739B true CN105126739B (en) | 2018-01-12 |
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| CN201510541822.5A Active CN105126739B (en) | 2015-08-31 | 2015-08-31 | A kind of water treating suspended formula filler for strengthening the absorption of nitrogen phosphorus and its production and use |
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| CN111003804A (en) * | 2019-12-27 | 2020-04-14 | 浙江永续环境工程有限公司 | Biological filler for anaerobic membrane bioreactor, preparation method thereof and anaerobic membrane bioreactor based on anaerobic biological bacteria |
| CN111170453B (en) * | 2020-02-29 | 2022-01-07 | 辽宁中舟得水环保科技有限公司 | Novel biological filler anaerobic reactor |
| CN111892176A (en) * | 2020-08-04 | 2020-11-06 | 四川达沃斯生态环保科技股份有限公司 | Method for removing pollutants from wastewater |
| CN112811436A (en) * | 2021-01-11 | 2021-05-18 | 洛阳理工学院 | Method for synthesizing MCM-41 mesoporous material by using waste glass |
| CN114133029B (en) * | 2021-12-13 | 2024-01-05 | 北京桑德环境工程有限公司 | Fungus-rich porous denitrification filler and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073184A (en) * | 2013-02-05 | 2013-05-01 | 江阴市京澄玻璃有限公司 | Micro-pore foaming glass pumice stone and preparation method thereof |
| CN103396000A (en) * | 2013-08-15 | 2013-11-20 | 景德镇陶瓷学院 | High-strength foam glass prepared by using zeolite as pore-forming agent and preparation method thereof |
| CN104016710A (en) * | 2014-06-17 | 2014-09-03 | 江苏晶瑞特环保新材料有限公司 | Light thermal insulation concrete block and preparation method thereof |
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| US7445735B2 (en) * | 2004-12-07 | 2008-11-04 | Daramic Llc | Method of making microporous material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073184A (en) * | 2013-02-05 | 2013-05-01 | 江阴市京澄玻璃有限公司 | Micro-pore foaming glass pumice stone and preparation method thereof |
| CN103396000A (en) * | 2013-08-15 | 2013-11-20 | 景德镇陶瓷学院 | High-strength foam glass prepared by using zeolite as pore-forming agent and preparation method thereof |
| CN104016710A (en) * | 2014-06-17 | 2014-09-03 | 江苏晶瑞特环保新材料有限公司 | Light thermal insulation concrete block and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 利用牡蜘壳和废玻璃粉制备废水除磷吸附材料的研究;颜俊瑜等;《材料导报》;20091130;第23卷(第14期);第452-454页 * |
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| CN107855101B (en) | 2020-04-03 |
| CN105126739A (en) | 2015-12-09 |
| CN107855101A (en) | 2018-03-30 |
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