CN105123776B - A kind of high-content pyrethrin insecticide - Google Patents

A kind of high-content pyrethrin insecticide Download PDF

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Publication number
CN105123776B
CN105123776B CN201510600470.6A CN201510600470A CN105123776B CN 105123776 B CN105123776 B CN 105123776B CN 201510600470 A CN201510600470 A CN 201510600470A CN 105123776 B CN105123776 B CN 105123776B
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pyrethrin
content
polyoxyethylene ether
oil
insecticide
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CN105123776A (en
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毛润乾
郑基焕
张宇宏
董冰雪
肖英方
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Institute of Zoology of Guangdong Academy of Sciences
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Guangdong Institute of Applied Biological Resources
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Priority to CN201510600470.6A priority Critical patent/CN105123776B/en
Priority to PCT/CN2015/095313 priority patent/WO2017045268A1/en
Priority to JP2018532494A priority patent/JP2018530602A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/12Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Abstract

The invention discloses a kind of high-content pyrethrin insecticides.As mass fraction, including pyrethrin 49~66.5% and emulsifier 5~30%, the emulsifier is the mixture of both fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, polyethylene glycol dioleic acid ester, polyethylene glycol monooleate or alkyl phenol polyoxyethylene ether or fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether.High-content pyrethrin insecticide of the invention is a kind of pyrethrin insecticide of environment-friendly type high-content, has good insecticidal effect, and market prospects are good.The insecticide can be used for hygienic medication, the generation of mosquito, fly, bedbug and cockroach can be effectively suppressed, it can also be used to which agriculture and forestry injurious insect prevention and treatment, the medicament can also make additive with gutter oil, an approach is provided for the effective use of gutter oil, is flowed back on dining table to prevent and treat gutter oil.

Description

A kind of high-content pyrethrin insecticide
Technical field:
The invention belongs to novel pesticide development and application field and environment protection fields, and in particular to a kind of high-content pyrethrin kills Worm agent.
Background technique:
Dalmatian chrysanthemum (Pyrethrum cinerariaefolium Trey) is a kind of ancient pesticide plant, alive at present It is widely applied in boundary, is one of three big pesticide plants.Pesticidal substance in Dalmatian chrysanthemum pyrethrin, to insect knock down or Killing effect is rapid;It is a kind of broad spectrum pesticide, can be used for agriculture, woods, health pest control, such as aphid, thrips, trialeurodes vaporariorum, fruit A variety of lepidopterous larvaes such as fly, beetle, noctuid, bollworm have good control efficiency, and imitate to mosquito, fly, bedbug and cockroach Fruit is obvious.Toxicological testing is the result shows that Dalmatian chrysanthemum is extremely low to the toxicity of people and mammal, without teratogenesis, carcinogenic, mutagenic Chronic toxicity can not be a kind of safely and effectively botanical pesticide and nuisanceless vegetable in accumulation residual in the mammalian body The ideal insecticide of dish production.
The medicament is unstable in the natural environment, is easy to be decomposed into water and carbon dioxide rapidly, any have although not remaining Noxious material, it is free from environmental pollution, but also influence its effect.
The current content of the medicament is lower, according in Chinese pesticide Information Network announce highest content be 5% missible oil and 3% it is solvable Property liquor, patent searching is also without high-content pyrethrin product and technology.
Summary of the invention:
The object of the present invention is to provide a kind of environmental protection, stable and efficient high-content pyrethrin insecticide.
High-content pyrethrin insecticide of the invention, which is characterized in that as mass fraction, including pyrethrin 49~ 66.5% and emulsifier 5~30%, the emulsifier is fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, poly- second two Alcohol dioleic acid ester, polyethylene glycol monooleate or alkyl phenol polyoxyethylene ether or fatty alcohol polyoxyethylene ether and nonyl phenol are poly- The mixture of both ethylene oxide ether.
The mixture of the fatty alcohol polyoxyethylene ether and both nonylphenol polyoxyethylene ether is preferably fatty alcohol polyoxy The mixture of vinethene and nonylphenol polyoxyethylene ether 3:2 in mass ratio mixing.
Pyrethrin of the invention is added in the form of pyrethrosin primary medicine, and raw medicine is oily liquids, effective component 70%, other are fatty acid and a small amount of moisture, and raw medicine usage amount is 70~95% when preparing high-content pyrethrin insecticide, folding Conjunction effective ingredient pyrethrin content is 49-66.5%.
It is preferred that the high-content pyrethrin insecticide, as mass fraction, including pyrethrosin primary medicine 90% and rouge Fat alcohol polyoxyethylene ether 10%.
It is preferred that the high-content pyrethrin insecticide, as mass fraction, including pyrethrosin primary medicine 95% and rouge Fat alcohol polyoxyethylene ether 5%.
Above-mentioned high-content pyrethrin method for producing insecticide are as follows: in its component ratio, in pyrethrosin primary medicine Emulsifier is added, emulsifies pyrethrin by emulsifier, forms pyrethrin and the mutually uniform liquid of fatty alcohol polyoxyethylene ether Body.It can be dispersed in water after being watered.
A second object of the present invention is to provide another high-content pyrethrin insecticides, which is characterized in that presses matter Score meter, including pyrethrin 56~63%, oil 5~10% and emulsifier 5~10% are measured, the emulsifier is poly alkyl alcohol Ethylene oxide ether, nonylphenol polyoxyethylene ether, polyethylene glycol dioleic acid ester, polyethylene glycol monooleate or alkylphenol-polyethenoxy The mixture of both ether or fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether, the oil are mineral oil, vegetable oil Or gutter oil.
The mixture of the fatty alcohol polyoxyethylene ether and both nonylphenol polyoxyethylene ether is preferably fatty alcohol polyoxy The mixture of vinethene and nonylphenol polyoxyethylene ether 3:2 in mass ratio mixing.
Pyrethrin of the invention is added in the form of pyrethrosin primary medicine, and raw medicine is oily liquids, effective component 70%, other are fatty acid and a small amount of moisture, and raw medicine usage amount is 80-90%, folding when preparing high-content pyrethrin insecticide Closing effective ingredient pyrethrin content is 56~63%.
The mineral oil is preferably agricultural sprinkling oil, such as 125SN base oil or the narrow agricultural sprinkling oil of 16-21 carbon;Institute The vegetable oil stated is preferably corn oil, soybean oil, ready-mixed oil or palm oil etc.;The gutter oil is thick from regular bleeding point Gutter oil after refining.
It is preferred that the high-content pyrethrin insecticide, as mass fraction, including pyrethrosin primary medicine 80%, oil 10% and the mixture 10% that is mixed with nonylphenol polyoxyethylene ether 3:2 in mass ratio of fatty alcohol polyoxyethylene ether.
It is preferred that the high-content pyrethrin insecticide, as mass fraction, including pyrethrosin primary medicine 90%, jade The mixture 5% that rice bran oil 5% and fatty alcohol polyoxyethylene ether are mixed with nonylphenol polyoxyethylene ether 3:2 in mass ratio.
High-content pyrethrin method for producing insecticide of the invention are as follows: its component content is pressed, in pyrethrosin primary medicine Middle addition emulsifier and oil, stir evenly, and form pyrethrin, oil and the mutually uniform liquid of emulsifier, thus obtain high-content Pyrethrin insecticide.It can be dispersed in water after being watered.
The application method of high-content pyrethrin insecticide of the invention are as follows: the application method in crop field and greenhouse is born Formula or other model sprayers take high-content pyrethrin insecticide of the invention to be watered, and stirring divides medicament uniformly in water It dissipates, then foliage spray.There is good control efficiency to small insects, as included pyrethrosin primary medicine 80%, 8000 It uses again.Citrus red mite control efficiency reaches 90% or more, while having killing effect to ovum.It is used in family's control of insect Method takes the above-mentioned high-content pyrethrin insecticide of 1mL in watering can, converts 4L, and shake keeps medicament evenly dispersed in water, then Directly spray pest activity area and generating region or pest infestation area.
The present invention emulsifies pyrethrin by screening suitable emulsifier, does not use solvent, obtains pyrethrin Content is up to the pyrethrin insecticide of 49% or more high-content.The high-content pyrethrin insecticide not only has good Desinsection deinsectization effect, indoor measurement the result shows that, high-content pyrethrin insecticide of the invention is to flour mite killing effect highest Reach 100%, to the trapping effect of cockroach up to 90%.The product developed is to person poultry harmless, to baby safe, to pet without Poison is family's preferably hygienic medication, the generation of pest can be effectively suppressed.
High-content pyrethrin insecticide of the invention is suitable for crop field or greenhouse corps pest, such as harmful mite, a red-spotted lizard shell The controls of insect such as worm, aleyrodid, aphid, diamondback moth, flea beetle;It can also be used in home gardening control of plant disease, such as plant white powder The diseases such as disease, dark mildew;It is nontoxic to pet to baby safe to person poultry harmless.
High-content pyrethrin insecticide of the invention eliminates the use of solvent, thus the risk to reduce environmental pollution, The control efficiency of medicament is improved simultaneously.The present invention adds mineral oil, vegetable oil and gutter oil, increases the stabilization of pyrethrin Property, increase its insecticidal effect.
High-content pyrethrin insecticide of the invention is a kind of pyrethrin insecticide of environment-friendly type high-content, is had good Good insecticidal effect, market prospects are good.The insecticide can be used for hygienic medication, and the hair of mosquito, fly, bedbug and cockroach can be effectively suppressed It is raw, it can also be used to which that agriculture and forestry injurious insect prevention and treatment, the medicament can also make additive with gutter oil, provide for the effective use of gutter oil One approach, flows back on dining table to prevent and treat gutter oil.
Specific embodiment:
The following examples are further illustrations of the invention, rather than limiting the invention.
Embodiment 1:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 95% and fatty alcohol polyoxyethylene ether 5%, the pyrethrosin primary medicine, effective component pyrethrin content is 70%, other For fatty acid and a small amount of moisture.Under normal temperature and pressure, fatty alcohol polyoxyethylene ether is added in pyrethrosin primary medicine, is stirred It is even, 66.5% pyrethrin emulsion is formed, the high-content pyrethrin insecticide of the present embodiment is obtained.12000 times are watered, is used for The prevention and treatment of citrus red mite, control efficiency are more than 95%;For preventing and treating the maintenance of family flowers and trees, to coccid, thrips and aleyrodid There is good control efficiency.
Embodiment 2:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 90% and fatty alcohol polyoxyethylene ether 10%, the pyrethrosin primary medicine, effective component pyrethrin content is 70%, other For fatty acid and a small amount of moisture.Under normal temperature and pressure, fatty alcohol polyoxyethylene ether is added in pyrethrosin primary medicine, is stirred It is even, 63% pyrethrin emulsion is formed, the high-content pyrethrin insecticide of the present embodiment is obtained.12000 times are watered, mandarin orange is used for The prevention and treatment of Exocarpium Citri Rubrum spider, control efficiency are more than 95%;For preventing and treating the maintenance of family flowers and trees, have to coccid, thrips and aleyrodid Good control efficiency.
Embodiment 3:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 80% and fatty alcohol polyoxyethylene ether 20%, the pyrethrosin primary medicine, effective component pyrethrin content is 70%, other For fatty acid and a small amount of moisture.Under normal temperature and pressure, fatty alcohol polyoxyethylene ether is added in pyrethrosin primary medicine, is stirred It is even, 56% pyrethrin emulsion is formed, the high-content pyrethrin insecticide of the present embodiment is obtained.10000 times are watered, mandarin orange is used for The prevention and treatment of Exocarpium Citri Rubrum spider, control efficiency are more than 95%;For preventing and treating the maintenance of family flowers and trees, have to coccid, thrips and aleyrodid Good control efficiency.
Embodiment 4:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 70% and fatty alcohol polyoxyethylene ether 30%, the pyrethrosin primary medicine, effective component pyrethrin content is 70%, other For fatty acid and a small amount of moisture.Under normal temperature and pressure, fatty alcohol polyoxyethylene ether is added in pyrethrosin primary medicine, is stirred It is even, 49% pyrethrin emulsion is formed, the high-content pyrethrin insecticide of the present embodiment is obtained.10000 times are watered, mandarin orange is used for The prevention and treatment of Exocarpium Citri Rubrum spider, control efficiency are more than 95%;For preventing and treating the maintenance of family flowers and trees, have to coccid, thrips and aleyrodid Good control efficiency.
Embodiment 5:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 80%, mineral oil 10% and emulsifier 10%, the pyrethrosin primary medicine, effective component pyrethrin content are 70%, He is fatty acid and a small amount of moisture, the emulsifier be fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether in mass ratio The mixture of 3:2 mixing.Under normal temperature and pressure, mineral oil (125SN base oil) and emulsifier are added in pyrethrosin primary medicine, stirs Mix it is uniformly mixed, formed 56% pyrethrin emulsion, obtain the high-content pyrethrin insecticide of the present embodiment.It is watered 10000 Times, for the prevention and treatment of citrus red mite, control efficiency is more than 95%;For preventing and treating the maintenance of family flowers and trees, to coccid, thrips There is good control efficiency with aleyrodid.
Embodiment 6:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 80%, palm oil 10% and emulsifier 10%, the pyrethrosin primary medicine, effective component pyrethrin content are 70%, He is fatty acid and a small amount of moisture, the emulsifier be fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether in mass ratio The mixture of 3:2 mixing.Under normal temperature and pressure, palm oil and emulsifier are added in pyrethrosin primary medicine, is uniformly mixed, shape At 56% pyrethrin emulsion, the high-content pyrethrin insecticide of the present embodiment is obtained.10000 times are watered, it is red for citrus The prevention and treatment of spider, control efficiency are more than 95%;For preventing and treating the maintenance of family flowers and trees, have well to coccid, thrips and aleyrodid Control efficiency.
Embodiment 7:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 80%, gutter oil 10% and emulsifier 10%, the pyrethrosin primary medicine, effective component pyrethrin content are 70%, He is fatty acid and a small amount of moisture, the emulsifier be fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether in mass ratio The mixture of 3:2 mixing.Under normal temperature and pressure, gutter oil and emulsifier are added in pyrethrosin primary medicine, is uniformly mixed, shape At 56% pyrethrin emulsion, the high-content pyrethrin insecticide of the present embodiment is obtained.10000 times are watered, it is red for citrus The prevention and treatment of spider, control efficiency are more than 95%;For preventing and treating the maintenance of family flowers and trees, have well to coccid, thrips and aleyrodid Control efficiency, for vegetable-crop pest-insect prevent and treat, can be used for preventing and treating thrips, flea beetle and plant hopper etc..
Embodiment 8:
The high-content pyrethrin insecticide of the present embodiment, based on total mass fraction 100%, including pyrethrosin primary medicine 90%, corn oil 5% and emulsifier 5%, the pyrethrosin primary medicine, effective component pyrethrin content are 70%, other For fatty acid and a small amount of moisture, the emulsifier is fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether in mass ratio 3: 2 mixed mixtures.Under normal temperature and pressure, corn oil and emulsifier are added in pyrethrosin primary medicine, is uniformly mixed, is formed 63% pyrethrin emulsion obtains the high-content pyrethrin insecticide of the present embodiment.2000 times are watered, citrus red mite is used for Prevention and treatment, control efficiency is more than 95%;For preventing and treating the maintenance of family flowers and trees, have to coccid, thrips and aleyrodid good anti- Control effect.
Embodiment 9
Indoor " tetranychid slide infusion process " (NY/T1154.12) (Slide-dip method immersion) measurement pair The female adult mite lethal effect of panonychus citri evaluates its synergy level.The female adult mite of the panonychus citri of raising is taken, is chosen afterwards for 24 hours except dead Mite hurts mite, then is handled with medicament (infusion process), chooses mite list worm raising 10d living, the female adult mite of observation and record survival afterwards for 24 hours Quantity.Meter record adult mite death number, calculates the female adult mite death rate and corrected mortality.5 repetitions.
Death population number/insect population * 100 after control efficiency (%)=processing
Medicament preparation: by preparation method preparation in embodiment, 5% pyrethrin missible oil of comparison medicament and 95% mineral oil cream Agent is bought in the market.
Concrete outcome is as shown in table 1:
The control of 1 different formulations product insecticidal effect of table
Medicament Formula Insecticidal effect (%)
66.5% 12000 times of pyrethrin emulsion (embodiment 1) Pyrethrin+emulsifier 100%A
63% 12000 times of pyrethrin emulsion (embodiment 2) Pyrethrin+emulsifier 100%A
56% 10000 times of pyrethrin emulsion (embodiment 3) Pyrethrin+emulsifier 100%A
49% 10000 times of pyrethrin emulsion (embodiment 4) Pyrethrin+emulsifier 100%A
56% 10000 times of pyrethrin emulsion (embodiment 5) Pyrethrin+mineral oil+emulsifier 100%A
56% 10000 times of pyrethrin emulsion (embodiment 6) Pyrethrin+vegetable oil+emulsifier 100%A
56% 10000 times of pyrethrin emulsion (embodiment 7) Pyrethrin+gutter oil+emulsifier 100%A
63% 2000 times of pyrethrin emulsion (embodiment 8) Pyrethrin+vegetable oil+emulsifier 100%A
1500 times of 5% pyrethrin missible oil (commodity) Pyrethrin+organic solvent+auxiliary agent 89.3%B
200 times of 95% mineral oil emulsion (commodity) Mineral oil+emulsifier 87.4%B
* capitalization is indicated in 0.01 level difference conspicuousness.

Claims (8)

1. a kind of high-content pyrethrin insecticide, which is characterized in that as mass fraction, by 49~66.5% He of pyrethrin Emulsifier 5~30% forms, and the emulsifier is fatty alcohol polyoxyethylene ether or fatty alcohol polyoxyethylene ether and nonyl phenol The mixture of both polyoxyethylene ether;
The pyrethrin is added in the form of pyrethrosin primary medicine, effective component pyrethrin 70%, by mass fraction It counts, pyrethrosin primary medicine usage amount is 70~95% in the high-content pyrethrin insecticide.
2. high-content pyrethrin insecticide according to claim 1, which is characterized in that the aliphatic alcohol polyethenoxy The mixture of both ether and nonylphenol polyoxyethylene ether be fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether in mass ratio The mixture of 3:2 mixing.
3. high-content pyrethrin insecticide according to claim 1, which is characterized in that the high-content pyrethrin Insecticide, as mass fraction, including pyrethrosin primary medicine 90% and fatty alcohol polyoxyethylene ether 10%.
4. high-content pyrethrin insecticide according to claim 1, which is characterized in that the high-content pyrethrin Insecticide, as mass fraction, including pyrethrosin primary medicine 95% and fatty alcohol polyoxyethylene ether 5%.
5. a kind of high-content pyrethrin insecticide, which is characterized in that as mass fraction, by pyrethrin 56~63%, oil 5 ~10% and emulsifier 5~10% form, the emulsifier be fatty alcohol polyoxyethylene ether or fatty alcohol polyoxyethylene ether With the mixture of both nonylphenol polyoxyethylene ether, the oil is mineral oil, vegetable oil or gutter oil;
The pyrethrin is added in the form of pyrethrosin primary medicine, effective component pyrethrin 70%, by mass fraction It counts, pyrethrosin primary medicine usage amount is 70~95% in the high-content pyrethrin insecticide.
6. high-content pyrethrin insecticide according to claim 5, which is characterized in that the aliphatic alcohol polyethenoxy The mixture of both ether and nonylphenol polyoxyethylene ether be fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether in mass ratio The mixture of 3:2 mixing.
7. high-content pyrethrin insecticide according to claim 5, which is characterized in that the mineral oil is 125SN Base oil or the narrow agricultural sprinkling oil of 16-21 carbon;The vegetable oil is corn oil, soybean oil, ready-mixed oil or palm oil.
8. high-content pyrethrin insecticide according to claim 5, which is characterized in that the high-content pyrethrin Insecticide, as mass fraction, including pyrethrosin primary medicine 80%, oil 10% and fatty alcohol polyoxyethylene ether and polyoxyethylene nonyl phenyl The mixture 10% of vinethene 3:2 in mass ratio mixing;Or the high-content pyrethrin insecticide, by mass fraction Meter, including pyrethrosin primary medicine 90%, corn oil 5% and fatty alcohol polyoxyethylene ether and nonylphenol polyoxyethylene ether are in mass ratio The mixture 5% of 3:2 mixing.
CN201510600470.6A 2015-09-18 2015-09-18 A kind of high-content pyrethrin insecticide Active CN105123776B (en)

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PCT/CN2015/095313 WO2017045268A1 (en) 2015-09-18 2015-11-23 Insecticide with high content of pyrethrin
JP2018532494A JP2018530602A (en) 2015-09-18 2015-11-23 Pyrethrin-rich insecticide

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