CN105116697A - Nonmagnetic negative electricity laser printer ink powder - Google Patents
Nonmagnetic negative electricity laser printer ink powder Download PDFInfo
- Publication number
- CN105116697A CN105116697A CN201410458559.9A CN201410458559A CN105116697A CN 105116697 A CN105116697 A CN 105116697A CN 201410458559 A CN201410458559 A CN 201410458559A CN 105116697 A CN105116697 A CN 105116697A
- Authority
- CN
- China
- Prior art keywords
- ink powder
- laser printer
- adhesive resin
- negative electricity
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Developing Agents For Electrophotography (AREA)
Abstract
The invention provides a nonmagnetic negative electricity laser printer ink powder. A styrene-acrylic acid copolymer is selected as an adhesive resin, a carbon black is selected as a pigment, zinc salicylate is selected as a charge conditioning agent, low molecular poly propylene wax is selected as an inner additive, and hydrophobic silica is selected as an external additive. The weight percentage of each component is as follows: 78-90% of adhesive resin, 3-9% of pigment, 2.1-8% of charge conditioning agent, 0.4-2.8% of inner additive and 0.1-4% of external additive. The styrene-acrylic acid copolymer is selected as the adhesive resin, so that two different ingredients are contained, thereby improving performance index of the ink powder, simplifying production technology, and reducing cost. Furtherly, hydrophobic degree of the hydrophobic silica can be controlled, thereby preventing influence to the printing effect due to moisture absorbing and clustering of a toner. According to the invention, the printing image obtained by using the nonmagnetic negative electricity laser printer ink powder has high image resolution and small backgrounding.
Description
Technical field
The present invention relates to the technical field of ink powder of laser printer, is a kind of non magnetic negative electricity ink powder of laser printer specifically.
Background technology
The ink powder of laser printer can be divided into positive electricity powder and negative electricity powder by being divided into electrical property, can be divided into by magnetic property and have magnetic and non-magnetic, one-component and bi-component can be divided into by component, due to the iron powder containing pitchy in one-component magnetic toner, so can not be used in color printer, think and ensure the versatility of ink powder in printer, the exploitation of one-component non-magnetic toner more and more comes into one's own, the non magnetic negative electricity ink powder of one-component is recycling and almost without useless powder, make photosensitive drums without cleaning balde, drum assembly does not have waste powder hopper, structure simplifies greatly.But in the use of the non magnetic negative electricity ink powder of one-component, the migration of ink powder is entirely by mobility and the charging stability of ink powder self, therefore all much higher than one-component magnetic developer mode to the size-grade distribution of ink powder, spheroidization, charging uniformity and electrification speed, stability.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of non magnetic negative electricity ink powder of laser printer.
The technical scheme that the present invention takes for the technical matters existed in solution known technology is:
Non magnetic negative electricity ink powder of laser printer of the present invention, by adhesive resin, pigment, charge adjusting agent, in add agent and additive forms, above-mentioned adhesive resin is Styrene-acrylic copolymer, pigment is carbon black, described charge adjusting agent selects zinc salicylate, add agent in described and select low-molecular polypropylene wax, described additive selects the hydrophobic silica through alkylene oxide process, and the percentage by weight of above-mentioned each component is:
Adhesive resin 78 ~ 90%,
Pigment 3 ~ 9%,
Charge adjusting agent 2.1 ~ 8%,
Inside add agent 0.4 ~ 2.8%,
Additive 0.1 ~ 4%.
The present invention can also adopt following technical measures:
In adhesive resin, the melting index MI of Styrene-acrylic copolymer is 1.5 ~ 5.5.
The hydrophobic deg of described hydrophobic silica is 20 ~ 40.
The advantage that the present invention has and good effect are:
In non magnetic negative electricity ink powder of laser printer of the present invention, adhesive resin selects Styrene-acrylic copolymer, both contained two kinds not between composition component, improve the performance index of ink powder, in turn simplify production technology and reduce cost.In addition the hydrophobic deg of hydrophobic silica is controlled, in case the conglomeration of the toner moisture absorption affects printing effect.The printing image resolution ratio using non magnetic negative electricity ink powder of laser printer of the present invention to obtain is high, bottom ash is little.
Embodiment
Referring to embodiment, the present invention will be described in detail.
In embodiment 1, non magnetic negative electricity ink powder of laser printer of the present invention, adhesive resin to be MI be 1.5 Styrene-acrylic copolymer, pigment is carbon black, charge adjusting agent selects zinc salicylate, inside add agent and select low-molecular polypropylene wax, additive selects hydrophobic deg to be 30 hydrophobic silicas, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 90%,
Carbon black accounts for 6%,
Zinc salicylate accounts for 2.1%,
Low-molecular polypropylene wax accounts for 1.8%,
Hydrophobic silica accounts for 0.1%.
After Styrene-acrylic copolymer, carbon black, zinc salicylate, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 9.61 μm, less than 6.35 μm: 23.57%,
Volume mean diameter: 10.37 μm, more than 16.O μm: 1.17%
Added in above-mentioned classification product by hydrophobic silica additive, namely abundant mixing obtains required ink powder.
In embodiment 2, non magnetic negative electricity ink powder of laser printer of the present invention, adhesive resin to be MI be 5.5 Styrene-acrylic copolymer, pigment is carbon black, charge adjusting agent selects zinc salicylate, inside add agent and select low-molecular polypropylene wax, additive selects hydrophobic deg to be 20 hydrophobic silicas, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 78%,
Carbon black accounts for 9%,
Zinc salicylate accounts for 8%,
Low-molecular polypropylene wax accounts for 2.8%,
Hydrophobic silica accounts for 2.2%.
After Styrene-acrylic copolymer, carbon black, zinc salicylate, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 9.57 μm, less than 6.35 μm: 27.57%,
Volume mean diameter: 10.24 μm, more than 16.O μm: 1.20%
Added in above-mentioned classification product by hydrophobic silica additive, namely abundant mixing obtains required ink powder.
In embodiment 3, non magnetic negative electricity ink powder of laser printer of the present invention, adhesive resin to be MI be 5.5 Styrene-acrylic copolymer, pigment is carbon black, charge adjusting agent selects zinc salicylate, inside add agent and select low-molecular polypropylene wax, additive selects hydrophobic deg to be 20 hydrophobic silicas, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 86.6%,
Carbon black accounts for 3%,
Zinc salicylate accounts for 6%,
Low-molecular polypropylene wax accounts for 0.4%,
Hydrophobic silica accounts for 4%.
After Styrene-acrylic copolymer, carbon black, zinc salicylate, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 9.77 μm, less than 6.35 μm: 26.48%,
Volume mean diameter: 10.43 μm, more than 16.O μm: 1.16%
Added in above-mentioned classification product by hydrophobic silica additive, namely abundant mixing obtains required ink powder.
The above, it is only preferred embodiment of the present invention, not any pro forma restriction is done to the present invention, although the present invention with preferred embodiment openly as above, but, and be not used to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, certainly the technology contents of announcement can be utilized to make a little change or modification, become the Equivalent embodiments of equivalent variations, in every case be the content not departing from technical solution of the present invention, according to any simple modification that technical spirit of the present invention is done above embodiment, equivalent variations and modification, all belong in the scope of technical solution of the present invention.
Claims (3)
1. a non magnetic negative electricity ink powder of laser printer, by adhesive resin, pigment, charge adjusting agent, in add agent and additive forms, it is characterized in that: above-mentioned adhesive resin is Styrene-acrylic copolymer, pigment is carbon black, described charge adjusting agent selects zinc salicylate, add agent in described and select low-molecular polypropylene wax, described additive selects the hydrophobic silica through alkylene oxide process, and the percentage by weight of above-mentioned each component is:
Adhesive resin 78 ~ 90%,
Pigment 3 ~ 9%,
Charge adjusting agent 2.1 ~ 8%,
Inside add agent 0.4 ~ 2.8%,
Additive 0.1 ~ 4%.
2. non magnetic negative electricity ink powder of laser printer according to claim 1, is characterized in that: in adhesive resin, the melting index MI of Styrene-acrylic copolymer is 1.5 ~ 5.5.
3. non magnetic negative electricity ink powder of laser printer according to claim 1, is characterized in that: the hydrophobic deg of described hydrophobic silica is 20 ~ 40.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410458559.9A CN105116697A (en) | 2014-09-11 | 2014-09-11 | Nonmagnetic negative electricity laser printer ink powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410458559.9A CN105116697A (en) | 2014-09-11 | 2014-09-11 | Nonmagnetic negative electricity laser printer ink powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105116697A true CN105116697A (en) | 2015-12-02 |
Family
ID=54664719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410458559.9A Withdrawn CN105116697A (en) | 2014-09-11 | 2014-09-11 | Nonmagnetic negative electricity laser printer ink powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105116697A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151007A (en) * | 2017-07-12 | 2017-09-12 | 合肥信亚达智能科技有限公司 | A kind of regeneration technology of printer waste carbon powder |
| CN109613805A (en) * | 2018-12-28 | 2019-04-12 | 天津市中环天佳电子有限公司 | A kind of non magnetic elecrtonegativity duplicator color toner and preparation method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1420393A (en) * | 2001-07-11 | 2003-05-28 | 精工爱普生株式会社 | Mono-component non-magnetic toner, its mfg. method and image forming device using same |
| CN101401040A (en) * | 2006-03-03 | 2009-04-01 | 陶氏环球技术公司 | Aqueous dispersions for use as toners |
| CN101727034A (en) * | 2010-02-02 | 2010-06-09 | 天津市中环天佳电子有限公司 | Black ceramic inkpowder |
| CN102033445A (en) * | 2009-10-08 | 2011-04-27 | 施乐公司 | Toner composition |
| CN103529669A (en) * | 2013-10-23 | 2014-01-22 | 天津市中环天佳电子有限公司 | Non-magnetic single-component electropositive color matching agent for laser printer |
| CN103642281A (en) * | 2013-12-19 | 2014-03-19 | 宁波佛来斯通新材料有限公司 | Modified carbon black, and preparation method and application thereof in preparation of black chemical powdered ink |
-
2014
- 2014-09-11 CN CN201410458559.9A patent/CN105116697A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1420393A (en) * | 2001-07-11 | 2003-05-28 | 精工爱普生株式会社 | Mono-component non-magnetic toner, its mfg. method and image forming device using same |
| CN101401040A (en) * | 2006-03-03 | 2009-04-01 | 陶氏环球技术公司 | Aqueous dispersions for use as toners |
| CN102033445A (en) * | 2009-10-08 | 2011-04-27 | 施乐公司 | Toner composition |
| CN101727034A (en) * | 2010-02-02 | 2010-06-09 | 天津市中环天佳电子有限公司 | Black ceramic inkpowder |
| CN103529669A (en) * | 2013-10-23 | 2014-01-22 | 天津市中环天佳电子有限公司 | Non-magnetic single-component electropositive color matching agent for laser printer |
| CN103642281A (en) * | 2013-12-19 | 2014-03-19 | 宁波佛来斯通新材料有限公司 | Modified carbon black, and preparation method and application thereof in preparation of black chemical powdered ink |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151007A (en) * | 2017-07-12 | 2017-09-12 | 合肥信亚达智能科技有限公司 | A kind of regeneration technology of printer waste carbon powder |
| CN109613805A (en) * | 2018-12-28 | 2019-04-12 | 天津市中环天佳电子有限公司 | A kind of non magnetic elecrtonegativity duplicator color toner and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100474138C (en) | Method for forming composite color image | |
| JP2018092154A (en) | toner | |
| JP2012073304A (en) | Electrophotographic toner | |
| CN102804079B (en) | Magnetic carrier and manufacture method and two-component system developer for electrophotographic developing | |
| CN102844717A (en) | Developer carrier and developing device using same | |
| JP2015121580A (en) | Toner | |
| KR20130129291A (en) | Ferrite particles, electrophotography carrier using same, and electrophotography developer | |
| CN105116697A (en) | Nonmagnetic negative electricity laser printer ink powder | |
| KR20090000506A (en) | Electrophotographic non-magnetic one-component toner | |
| US8871414B2 (en) | Positively chargeable toner for electrostatic image development | |
| CN103728852A (en) | Transparent electrostatic charge image developing toner, method of manufacturing the same, developer, toner cartridge, image forming method, and image forming apparatus | |
| US20180259868A1 (en) | Toner, toner cartridge, and image forming apparatus | |
| KR20020033046A (en) | Electrophotographic carrier, developer using the same, and developing method | |
| US20130040235A1 (en) | Positively chargeable toner | |
| US6468705B2 (en) | Optical fixing toner | |
| CN103529669A (en) | Non-magnetic single-component electropositive color matching agent for laser printer | |
| US6803165B2 (en) | Toner for electrophotography, developing agent for electrophotography using the toner, image forming method, and image forming device | |
| CN110114729A (en) | Electrophotographic developing magnetic core material, electrophotographic developing carrier and developer | |
| CN106933074A (en) | A kind of ultralow magnetic single component powdered ink and preparation method suitable for magnetic developer roller | |
| CN102621841B (en) | Preparation method for electropositive magnetic single component developer for laser printer | |
| CN102063030A (en) | Xerographic insulating dry single-component electropositive developer | |
| US10248039B2 (en) | Carrier, electrophotographic developer, and method of manufacturing carrier | |
| US9740127B2 (en) | Toner | |
| JP2017167311A (en) | Core material for carrier, carrier, developer, and electrophotography development system | |
| US20220404728A1 (en) | Toner, toner cartridge, and image forming apparatus |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20151202 |