A kind of reactive printing gum of uncomplicated laundering
Technical field
Present invention relates particularly to a kind of reactive printing gum of uncomplicated laundering.
Background technology
Sodium alginate is commonly called as the hat of printing gum, due to characteristics such as good rheological characteristic, higher de- paste rates, it is deep by
Print works are liked.But as sodium alginate is in the popularization of different field (such as food, cosmetics industry), it is worth also therewith
Improve, also constantly lifted along with price, great cost burden is brought to print works.In addition, sodium alginate is apt to deteriorate, surely
It is qualitative that there is also very big deficiency.
A kind of printing gum suitable for all-cotton fabric is disclosed in patent CN103911887 A, the thickener includes carboxylic
Methyl starch, sodium alginate, nano silicon, albumen pulp components, in the formula containing substantial amounts of CMS and
A small amount of sodium alginate, although can meet stamp requirement to a certain degree, the de- paste rate of CMS is not high, is not easy
Remove, influence PRINTED FABRIC feel, while contain sodium alginate in raw material, cost is higher.One disclosed in patent CN104389202 A
Kind complex printing gum and preparation method thereof, the thickener includes alkyl polysaccharide salt, sodium alginate, biology enzyme, diutan and fat
Amine APEO component, but to include atomization drying, complex procedures, and biology enzyme steady in formula by thickener preparation technology
It is qualitative also not illustrate.
Therefore, most researcher has done many work on paste formula, and effect lays particular emphasis on paste making rate and stamp depth,
And it is inadequate to de- paste performance concern, in view of the above-mentioned problems, on the premise of stamp requirement is ensured, it is good to develop a kind of printing quality
, (i.e. de- paste rate high) of uncomplicated laundering, cost be low, stable, the simple printing gum of preparation technology is urgently to be resolved hurrily
Problem.
The content of the invention
The technical problems to be solved by the invention are overcome in the prior art as substitution completely or part substitution alginic acid
Sodium, the printing quality of the complex printing gum of research and development, take off the defects of paste rate can not improve simultaneously, there is provided a kind of work of uncomplicated laundering
Property printing gum and preparation method thereof.The preparation method of the present invention is relatively easy, easy to operate.The original of reactive printing gum of the present invention
Expect that Component Source is extensive, without sodium alginate, cost is relatively low, on the premise of stamp requirement is met, uncomplicated laundering, takes off paste easily,
Soft, stability is good, and combination property is suitable with sodium alginate, and cost is relatively low, is with a wide range of applications.
The present invention solves above-mentioned technical problem by the following technical programs.
The invention provides a kind of reactive printing gum of uncomplicated laundering, and it includes the raw material components of following portions by weight:With
100 parts of meters, 44~80 parts of thickener component, 4~20 parts of scrubbed component, 1~5 part of stabilizer component, 2~30 parts of filling components and profit
Wet 0.1~1 part of component;
Wherein, the thickener component be selected from sodium carboxymethylcellulose, sodium carboxymethyl starch, HPG, xanthans,
One or more in lithium magnesium silicate, diatomite and casein;The scrubbed component is selected from polyvinylpyrrolidone, dodecyl
Sodium sulphate, beta-schardinger dextrin, methyl-B-cyclodextrin, 2,6- dimethyl-β-cyclodextrins, metasilicate pentahydrate sodium, sodium acid carbonate and phosphoric acid
One or more in trisodium.
Preferably, the reactive printing gum, it is made up of the raw material components of following portions by weight:It is described in terms of 100 parts
44~80 parts of thickener component, 4~20 parts of the scrubbed component, 1~5 part of the stabilizer component, 2~30 parts of the filling components
With 0.1~1 part of the moistening components.
Preferably, the reactive printing gum does not include sodium alginate.
In the present invention, the thickener component is preferably 50~80 parts, is more preferably 55~70 parts.
In the present invention, the scrubbed component is preferably 8~20 parts, is more preferably 12~15 parts.
In the present invention, the stabilizer component is preferably 3~5 parts, is more preferably 3~4 parts.
In the present invention, the filling components are preferably 6~30 parts, are more preferably 10~20 parts.
In the present invention, the moistening components are preferably 0.1~0.8 part, are more preferably 0.5~0.8 part.
In the present invention, the thickener component is preferably selected from lithium magnesium silicate, sodium carboxymethylcellulose and sodium carboxymethyl starch
In one or more, be more preferably sodium carboxymethylcellulose and the mixture of sodium carboxymethyl starch, be most preferably that carboxymethyl is fine
Plain sodium is tieed up with sodium carboxymethyl starch using weight ratio as (1~2):4 mixtures mixed.Wherein, the carboxymethyl cellulose
The substitution value of sodium or the sodium carboxymethyl starch is respectively preferably 1.0~1.5, more preferably respectively 1.0~1.2.
In the present invention, the scrubbed component is preferably selected from polyvinylpyrrolidone, lauryl sodium sulfate and 2,6- bis-
One or more in methyl-B-cyclodextrin, it is more preferably polyvinylpyrrolidone and the mixture of lauryl sodium sulfate, most
It is polyvinylpyrrolidone and lauryl sodium sulfate goodly using weight ratio as (2~4):The mixture of 1 mixing, it is further optimal
Ground is polyvinylpyrrolidone and lauryl sodium sulfate using weight ratio as 3:The mixture of 1 mixing.
In the present invention, the stabilizer component is generally the conventional use of stabilizer component in reactive printing gum field, compared with
One or more in citric acid, two adjacent sodium of sodium citrate, sodium gluconate and ethylenediamine goodly, more preferably
For sodium citrate and/or sodium gluconate.
In the present invention, the filling components are generally the conventional use of filling components in reactive printing gum field, preferably
Selected from sodium chloride and/or sodium sulphate.The filling components are to effects such as finished product main landing low cost, raising flowings.
In the present invention, the moistening components are generally the conventional use of moistening components in reactive printing gum field, preferably
Selected from NEOFor the 8 carbon alcohol APEO of isomery 13, SAS, sodium sulfate of polyethenoxy ether of fatty alcohol, dodecane
Base benzene sulfonic acid sodium salt, diisobutyl sodium naphthalene sulfonate salt, disecoctylmaleate sodium sulfonate, ethoxylated fatty-acid methyl ester sulfonic acid
One or more in salt and α-sodium olefin sulfonate, more preferably selected from NEOFor the 8 carbon alcohol APEO of isomery 13, secondary alkyl
One or more in sodium sulfonate and sodium sulfate of polyethenoxy ether of fatty alcohol.
Present invention also offers a kind of preparation method of the reactive printing gum of uncomplicated laundering, the reactive printing gum includes
The raw material components of following portions by weight:In terms of 100 parts, 44~80 parts of thickener component, 4~20 parts of scrubbed component, stabilizer component 1
~5 parts, 0.1~1 part of 2~30 parts of filling components and moistening components;
Wherein, the thickener component be selected from sodium carboxymethylcellulose, sodium carboxymethyl starch, HPG, xanthans,
One or more in lithium magnesium silicate, diatomite and casein;The scrubbed component is selected from polyvinylpyrrolidone, dodecyl
Sodium sulphate, beta-schardinger dextrin, methyl-B-cyclodextrin, 2,6- dimethyl-β-cyclodextrins, metasilicate pentahydrate sodium, sodium acid carbonate and phosphoric acid
One or more in trisodium;
The preparation method comprises the following steps:(1) by the thickener component, the scrubbed component and the moistening components
It is well mixed, obtain mixture;(2) mixture described in step (1) is mixed with the stabilizer component, the filling components
It is even, produce.
Preferably, the reactive printing gum, it is made up of the raw material components of following portions by weight:It is described in terms of 100 parts
44~80 parts of thickener component, 4~20 parts of the scrubbed component, 1~5 part of the stabilizer component, 2~30 parts of the filling components
With 0.1~1 part of the moistening components.
Preferably, the reactive printing gum does not include sodium alginate.
In the present invention, the thickener component is preferably 50~80 parts, is more preferably 55~70 parts.
In the present invention, the scrubbed component is preferably 8~20 parts, is more preferably 12~15 parts.
In the present invention, the stabilizer component is preferably 3~5 parts, is more preferably 3~4 parts.
In the present invention, the filling components are preferably 6~30 parts, are more preferably 10~20 parts.
In the present invention, the moistening components are preferably 0.1~0.8 part, are more preferably 0.5~0.8 part.
In the present invention, the thickener component is preferably selected from lithium magnesium silicate, sodium carboxymethylcellulose and sodium carboxymethyl starch
In one or more, be more preferably sodium carboxymethylcellulose and the mixture of sodium carboxymethyl starch, be most preferably that carboxymethyl is fine
Plain sodium is tieed up with sodium carboxymethyl starch using weight ratio as (1~2):4 mixtures mixed.Wherein, the carboxymethyl cellulose
The substitution value of sodium or the sodium carboxymethyl starch is respectively preferably 1.0~1.5, more preferably respectively 1.0~1.2.
In the present invention, the scrubbed component is preferably selected from polyvinylpyrrolidone, lauryl sodium sulfate and 2,6- bis-
One or more in methyl-B-cyclodextrin, it is more preferably polyvinylpyrrolidone and the mixture of lauryl sodium sulfate, most
It is polyvinylpyrrolidone and lauryl sodium sulfate goodly using weight ratio as (2~4):The mixture of 1 mixing, it is further optimal
Ground is polyvinylpyrrolidone and lauryl sodium sulfate using weight ratio as 3:The mixture of 1 mixing.
In the present invention, the stabilizer component is generally the conventional use of stabilizer component in reactive printing gum field, compared with
One or more in citric acid, two adjacent sodium of sodium citrate, sodium gluconate and ethylenediamine goodly, more preferably
For sodium citrate and/or sodium gluconate.
In the present invention, the filling components are generally the conventional use of filling components in reactive printing gum field, preferably
Selected from sodium chloride and/or sodium sulphate.The filling components are to effects such as finished product main landing low cost, raising flowings.
In the present invention, the moistening components are generally the conventional use of moistening components in reactive printing gum field, preferably
Selected from NEOFor the 8 carbon alcohol APEO of isomery 13, SAS, sodium sulfate of polyethenoxy ether of fatty alcohol, dodecane
Base benzene sulfonic acid sodium salt, diisobutyl sodium naphthalene sulfonate salt, disecoctylmaleate sodium sulfonate, ethoxylated fatty-acid methyl ester sulfonic acid
One or more in salt and α-sodium olefin sulfonate, more preferably selected from NEOFor the 8 carbon alcohol APEO of isomery 13, secondary alkyl
One or more in sodium sulfonate and sodium sulfate of polyethenoxy ether of fatty alcohol.
In the present invention, in step (1), the time of the mixing is preferably 10~20 minutes, is more preferably 10~15 points
Clock.The temperature of the mixing is that this area is conventional, generally room temperature, i.e., 10~30 DEG C.
In the present invention, in step (1), the mixture is made preferably by following step:First by the thickener component
With the scrubbed component while cone-type mixer mixes, the moistening components are added.
Wherein, the inventory per minute of the moistening components is preferably 15~25%, is more preferably 20%, percentage
The percentage by weight of moistening components total amount is accounted for for inventory per minute.
In the present invention, in step (2), the time of the mixing is preferably 30~60 minutes, is more preferably 30~35 points
Clock.
It on the basis of common sense in the field is met, above-mentioned each optimum condition, can be combined, it is each preferably real to produce the present invention
Example.
Agents useful for same and raw material of the present invention are commercially available.
The positive effect of the present invention is:
1st, preparation method of the invention is relatively easy, easy to operate.
2nd, the raw material components wide material sources of reactive printing gum of the present invention, can be without sodium alginate, and cost is relatively low, is meeting
On the premise of stamp requirement, uncomplicated laundering, paste is taken off easily, soft, stability is good, and combination property is suitable with sodium alginate, tool
Have a wide range of applications.
Embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to described reality
Apply among a scope.The experimental method of unreceipted actual conditions in the following example, conventionally and condition, or according to business
Product specification selects.
Number used in following embodiments, unless otherwise specified, refer both to the parts by weight of material.
The weight fraction of each raw material components in the embodiment 1~6 of table 1 and comparative example 2~3
Embodiment 1
Raw material components described in table 1 below prepare the reactive printing gum of the uncomplicated laundering of the present embodiment.Wherein, carboxymethyl is fine
The substitution value for tieing up plain sodium is 1.0, and the substitution value of sodium carboxymethyl starch is 1.0.
The preparation method of the reactive printing gum of uncomplicated laundering comprises the following steps:
At room temperature, by sodium carboxymethylcellulose, sodium carboxymethyl starch, lithium magnesium silicate, polyvinylpyrrolidone, dodecyl
Sodium sulphate is added in cone-type mixer, starts agitator, adds moistening components (the carbon alcohol APEO of isomery 13 and fat
Alcohol polyethenoxy ether sodium sulfate), the inventorys per minute of moistening components is that 15% (percentage is that inventory per minute accounts for wetting group
Divide the percentage by weight of total amount), add sodium citrate, sodium gluconate, sodium chloride, sodium sulphate, stirring after stirring 15min
30min, you can.
Embodiment 2
The reactive printing gum of the uncomplicated laundering of the present embodiment is prepared with the raw material components described in table 1.Wherein, carboxymethyl cellulose
The substitution value of plain sodium is 1.2, and the substitution value of sodium carboxymethyl starch is 1.0.
At room temperature, by sodium carboxymethylcellulose, sodium carboxymethyl starch, lithium magnesium silicate, polyvinylpyrrolidone, dodecyl
Sodium sulphate is added in cone-type mixer, starts agitator, adds moistening components (the carbon alcohol APEO of isomery 13 and fat
Alcohol polyethenoxy ether sodium sulfate), the inventorys per minute of moistening components is that 20% (percentage is that inventory per minute accounts for wetting group
Divide the percentage by weight of total amount), add sodium citrate, sodium gluconate, sodium chloride, sodium sulphate, stirring after stirring 20min
45min, you can.
Embodiment 3
The reactive printing gum of the uncomplicated laundering of the present embodiment is prepared with the raw material components described in table 1.Wherein, carboxymethyl cellulose
The substitution value of plain sodium is 1.5, and the substitution value of sodium carboxymethyl starch is 1.2.
At room temperature, by sodium carboxymethylcellulose, sodium carboxymethyl starch, lithium magnesium silicate, polyvinylpyrrolidone, dodecyl
Sodium sulphate is added in cone-type mixer, starts agitator, adds moistening components (the carbon alcohol APEO of isomery 13 and fat
Alcohol polyethenoxy ether sodium sulfate), the inventorys per minute of moistening components is that 20% (percentage is that inventory per minute accounts for wetting group
Divide the percentage by weight of total amount), add sodium citrate, sodium gluconate, sodium chloride, sodium sulphate, stirring after stirring 10min
45min, you can.
Embodiment 4
The reactive printing gum of the uncomplicated laundering of the present embodiment is prepared with the raw material components described in table 1.Wherein, carboxymethyl cellulose
The substitution value of plain sodium is 1.0, and the substitution value of sodium carboxymethyl starch is 1.5.
At room temperature, by sodium carboxymethylcellulose, sodium carboxymethyl starch, lithium magnesium silicate, polyvinylpyrrolidone, dodecyl
Sodium sulphate is added in cone-type mixer, starts agitator, adds moistening components (the carbon alcohol APEO of isomery 13), wetting
The inventory per minute of component is 25% (percentage is the percentage by weight that inventory per minute accounts for moistening components total amount), is stirred
Sodium citrate, sodium gluconate, sodium chloride, sodium sulphate are added after 15min, stirs 60min, you can.
Embodiment 5
The reactive printing gum of the uncomplicated laundering of the present embodiment is prepared with the raw material components described in table 1.Wherein, carboxymethyl cellulose
The substitution value of plain sodium is 1.2, and the substitution value of sodium carboxymethyl starch is 1.2.
At room temperature, by sodium carboxymethylcellulose, sodium carboxymethyl starch, lithium magnesium silicate, polyvinylpyrrolidone, dodecyl
Sodium sulphate is added in cone-type mixer, starts agitator, adds moistening components (sodium sulfate of polyethenoxy ether of fatty alcohol), wetting
The inventory per minute of component is 20% (percentage is the percentage by weight that inventory per minute accounts for moistening components total amount), is stirred
Sodium citrate, sodium chloride, sodium sulphate are added after 10min, stirs 45min, you can.
Embodiment 6
The reactive printing gum of the uncomplicated laundering of the present embodiment is prepared with the raw material components described in table 1.Wherein, carboxymethyl cellulose
The substitution value of plain sodium is 1.0, and the substitution value of sodium carboxymethyl starch is 1.2.
At room temperature, by sodium carboxymethylcellulose, sodium carboxymethyl starch, lithium magnesium silicate, polyvinylpyrrolidone, dodecyl
Sodium sulphate is added in cone-type mixer, starts agitator, adds moistening components (the carbon alcohol APEO of isomery 13), wetting
The inventory per minute of component is 20% (percentage is the percentage by weight that inventory per minute accounts for moistening components total amount), is stirred
Sodium gluconate, sodium sulphate are added after 10min, stirs 35min, you can.
Comparative example 1
Printing gum is only used as using sodium alginate.
Comparative example 2
The printing gum of this comparative example is prepared with the raw material components described in table 1.Wherein, the substitution value of sodium carboxymethylcellulose
For 1.0, the substitution value of sodium carboxymethyl starch is 1.2.
At room temperature, by sodium carboxymethylcellulose, sodium carboxymethyl starch, lithium magnesium silicate, polyvinylpyrrolidone, dodecyl
Sodium sulphate is added in cone-type mixer, starts agitator, adds moistening components (the carbon alcohol APEO of isomery 13 and fat
Alcohol polyethenoxy ether sodium sulfate), the inventorys per minute of moistening components is that 20% (percentage is that inventory per minute accounts for wetting group
Divide the percentage by weight of total amount), add sodium citrate, sodium gluconate, sodium chloride, sodium sulphate, stirring after stirring 10min
30min, you can.
Comparative example 3
The printing gum of this comparative example is prepared with the raw material components described in table 1.Wherein, the substitution value of sodium carboxymethylcellulose
For 1.0, the substitution value of sodium carboxymethyl starch is 1.2.
The preparation method of this comparative example printing gum is identical with comparative example 2.
Embodiment 7~10
The printing gum of embodiment 7~10 is prepared with the raw material components described in table 2.Wherein, sodium carboxymethylcellulose takes
Dai Du is 1.0, and the substitution value of sodium carboxymethyl starch is 1.2.
The preparation method of embodiment 7~10 is carried out in the steps below:
At room temperature, thickener component and scrubbed component are added in cone-type mixer, start agitator, add wetting group
Point, the inventorys per minute of moistening components be that 20% (percentage accounts for the weight percent of moistening components total amount for inventory per minute
Than), stabilizer component and filling components are added after stirring 10min, stir 30min, you can.
The weight fraction of each raw material components in the embodiment 7~10 of table 2
Raw material components |
Embodiment 7 |
Embodiment 8 |
Embodiment 9 |
Embodiment 10 |
HPG |
22 |
--- |
--- |
--- |
Xanthans |
22 |
--- |
--- |
--- |
Diatomite |
--- |
40 |
--- |
--- |
Casein |
--- |
40 |
--- |
--- |
Sodium carboxymethylcellulose |
--- |
--- |
26 |
15 |
Sodium carboxymethyl starch |
--- |
--- |
50.9 |
60 |
Polyvinylpyrrolidone |
--- |
--- |
6 |
--- |
Lauryl sodium sulfate |
--- |
--- |
2 |
--- |
Beta-schardinger dextrin |
5 |
--- |
--- |
--- |
Methyl-B-cyclodextrin |
10 |
--- |
--- |
--- |
2,6- dimethyl-β-cyclodextrins |
5 |
--- |
--- |
10 |
Metasilicate pentahydrate sodium |
--- |
2 |
--- |
10 |
Sodium acid carbonate |
--- |
1 |
--- |
--- |
Tertiary sodium phosphate |
--- |
1 |
--- |
--- |
Citric acid |
2.5 |
2.5 |
--- |
--- |
Two adjacent sodium of ethylenediamine |
2.5 |
2.5 |
--- |
1 |
Sodium chloride |
10 |
5 |
15 |
3 |
Sodium sulphate |
20 |
5 |
--- |
--- |
SAS |
0.4 |
--- |
--- |
--- |
Neopelex |
0.3 |
--- |
--- |
--- |
Diisobutyl sodium naphthalene sulfonate salt |
0.3 |
--- |
--- |
--- |
Disecoctylmaleate sodium sulfonate |
--- |
0.5 |
--- |
--- |
Ethoxylated fatty-acid methyl ester sulfonate |
--- |
0.5 |
--- |
--- |
α-sodium olefin sulfonate |
--- |
---- |
0.1 |
1 |
Effect example
The thickener printing performance of each embodiment and comparative example passes through following experimental verification.
1st, fabric:Pure cotton poplin cloth.
2nd, thickener:The printing gum of the reactive printing gum of embodiment 1~6 and comparative example 1~3.
3rd, print paste formula (such as table 3):
" g/kg " refers to the ratio between the quality of each composition of raw materials and the gross mass of print paste in print paste in table 3.
Table 3
Print paste composition of raw materials |
Dosage (g/kg) |
Active red P-4BH |
40 |
Sodium acid carbonate |
30 |
Reservehao S |
10 |
Urea |
100 |
Thickener |
45 |
Water |
775 |
4th, printing technology
Stamp → drying → decatize (102~104 DEG C, 7~10min) → washing → soap → washing → dry.
5th, performance test
(1) paste rate is taken off
De- paste rate=(W1-W2)/(W1-W0) × 100%
Wherein, W0、W1And W2Dry fabric weight after dry fabric weight and de- paste is represented before stamp after dry fabric weight, stamp respectively.Hundred
It is point higher than numerical value, illustrate that de- paste property is better.
(2) weighed intensities front/reverse side
Table 4 is the printing gum application performance contrast in embodiment 1~6 and comparative example 1~3, the wherein number of weighed intensities
According to be by HunterLab companies of the U.S. color measurement and color match instrument test and obtain.The data are strong with the weighting of the calico of comparative example 1 front
Spend to be tested for 100 and obtained.Weighed intensities numerical value is higher, illustrates that printing gum Color is better.
Printing gum application performance contrast in the embodiment of the present invention 1~6 of table 4 and comparative example 1~3
The application performance of reactive printing gum is suitable with embodiment 1~6 made from embodiment 7~10.
From table 4 using result, it is apparent that the reactive printing gum weighed intensities and de- paste rate of the present invention are better than
Sodium alginate, or it is suitable with sodium alginate.The reactive printing gum uncomplicated laundering of the present invention, take off paste easily, soft, stability
Good, combination property is suitable with sodium alginate, and cost is relatively low, is with a wide range of applications.