CN105112912A - Coating process for fin of bi-absorption type air source heat pump water heater - Google Patents

Coating process for fin of bi-absorption type air source heat pump water heater Download PDF

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Publication number
CN105112912A
CN105112912A CN201510582368.8A CN201510582368A CN105112912A CN 105112912 A CN105112912 A CN 105112912A CN 201510582368 A CN201510582368 A CN 201510582368A CN 105112912 A CN105112912 A CN 105112912A
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CN
China
Prior art keywords
fin
coating process
heat pump
source heat
heat
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Pending
Application number
CN201510582368.8A
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Chinese (zh)
Inventor
王玉军
刘军
许春林
王颖
王天舒
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Jiangsu Tianshu Electric Appliance Co Ltd
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Jiangsu Tianshu Electric Appliance Co Ltd
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Publication date
Application filed by Jiangsu Tianshu Electric Appliance Co Ltd filed Critical Jiangsu Tianshu Electric Appliance Co Ltd
Priority to CN201510582368.8A priority Critical patent/CN105112912A/en
Publication of CN105112912A publication Critical patent/CN105112912A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Chemically Coating (AREA)

Abstract

The invention relates to a coating process for a fin of a bi-absorption type air source heat pump water heater. The coating process comprises the steps that firstly, the fin surface is cleaned; secondly, the fin surface is covered with a layer of high infrared reflection film through chemical copper plating, and the thickness of the high infrared reflection film is 0.013-0.017 mg/cm<3>; thirdly, nickel sulfate, zinc sulfate, potassium thiocyanate, boric acid and sodium sulfate are used for preparing a heat-absorption coating containing black nickel elements at the temperature of 21-35 DEG C; and finally, the aluminum fin surface is covered with the heat-absorption coating containing the black nickel elements through a dual-layer surging mode. The coating process has the advantages that the fin surface of the bi-absorption type air source heat pump water heater is covered with the high infrared reflection film and the heat-absorption coating containing the black nickel elements in sequence, and accordingly, not only can heat in circulating air be absorbed, but also heat energy in sunlight is fully absorbed when sunlight is available, the heat absorption capacity of the air source heat pump water heater is improved, and the heating capacity and the energy efficiency are greatly improved.

Description

A kind of biabsorption formula air-source heat pump hot water fin coating process
Technical field
The present invention relates to a kind of coating process, particularly a kind of biabsorption formula air-source heat pump hot water fin coating process.
Background technology
Air-source heat pump hot water all needs hot water preparing throughout the year, due to its accessibility, uses very general in life.
Traditional air-source heat pump hot water, mainly through stringed alumium fin on copper pipe, by blower fan by air circulation flow through aluminum fin-stock, in copper pipe, low temperature liquid refrigeration agent is by aluminum fin-stock, from air, absorb heat.But this kind of air-source heat pump hot water can only heat in absorption cycle air, to the radiant heat absorbent weak effect in sunlight, causes structure heating effect poor; Therefore the biabsorption formula air-source heat pump hot water fin coating process that a kind of heat absorption of development is good, heating effect is strong is badly in need of.
Summary of the invention
The technical problem to be solved in the present invention is to provide the biabsorption formula air-source heat pump hot water fin coating process that a kind of heat absorption is good, heating effect is strong.
For solving the problems of the technologies described above, technical scheme of the present invention is: a kind of biabsorption formula air-source heat pump hot water fin coating process, and its innovative point is: this coating process is specific as follows:
(1) clean is carried out to fin surface;
(2) electroless copper is adopted to cover one deck high infrared reflection film at fin surface;
(3) adopt single nickel salt, zinc sulfate, potassium sulfocyanate, boric acid and sodium sulfate at the temperature of 21 DEG C ~ 35 DEG C, configure the heat absorbing coating containing black nickel element;
(4) by the surface of the heat absorbing coating surge containing black nickel element to aluminum fin-stock;
Further, in described step (2), the thickness of high infrared reflection film is 0.013 ~ 0.017mg/cm 3.
Further, double-deck surge mode is adopted to carry out coating in described step (4).
Further, described coat-thickness is 0.052 ~ 0.067mg/cm 3.
Further, in described step (4), the coating specific absorption α of black nickel element is 0.93 ~ 0.96, and heat emission is 0.08 ~ 0.15 than ε.
The invention has the advantages that:
(1) biabsorption formula air-source heat pump hot water covers high infrared reflection film and the heat absorbing coating containing black nickel element successively at its fin surface, can not only heat in absorption cycle air, and when there being sunlight, heat energy in abundant absorption sunlight, improve the heat absorption capacity of air-source heat pump hot water, heating capacity, efficiency are all greatly improved.
(2) have the solar time in envrionment temperature lower than 5 DEG C, fin can absorb heat, because fin temperature is higher than dew-point temperature, thus effectively avoids fin frosting and causes heating performance to decline and the heat waster caused that defrosts.
(3) fin surface is coated with one deck high infrared reflection film, and is 0.013 ~ 0.017mg/cm by gauge control 3, this high infrared reflection film has highly reflective, and with the heat absorbing coating compound use containing black nickel element, make the specific absorption of radiation higher.
(4) heat absorbing coating containing black nickel element adopts the mode of double-deck surge to cover, and is 0.052 ~ 0.067mg/cm by gauge control 3, effectively raise bonding force and the solidity to corrosion of coating and matrix.
(5) the coating specific absorption α of black nickel element is 0.93 ~ 0.96, heat emission than ε be 0.08 ~ 0.15, α/ε close to 6 ~ 12, simultaneously black coating does not reflect the light of any color, and therefore can absorb the heat energy in the light of any color, its absorptive character are better.
Embodiment
embodiment 1
The invention discloses a kind of biabsorption formula air-source heat pump hot water fin coating process, this coating process is specific as follows:
(1) clean is carried out to fin surface;
(2) adopt electroless copper to cover one deck high infrared reflection film at fin surface, the thickness of this high infrared reflection film is 0.008 ~ 0.013mg/cm 3;
(3) adopt single nickel salt, zinc sulfate, potassium sulfocyanate, boric acid and sodium sulfate at the temperature of 15 DEG C ~ 21 DEG C, configure the heat absorbing coating containing black nickel element;
(4) adopted by the heat absorbing coating containing black nickel element double-deck surge mode to cover the surface of aluminum fin-stock, this coat-thickness is 0.039 ~ 0.052mg/cm 3, specific absorption α is 0.93 ~ 0.96, and heat emission is 0.08 ~ 0.15 than ε.
In the now unit time, in hot water machine, the average raised temperature of water is 0.7 DEG C/min.
embodiment 2
A kind of biabsorption formula air-source heat pump hot water fin coating process is specific as follows:
(1) clean is carried out to fin surface;
(2) adopt electroless copper to cover one deck high infrared reflection film at fin surface, the thickness of this high infrared reflection film is 0.013 ~ 0.017mg/cm 3;
(3) adopt single nickel salt, zinc sulfate, potassium sulfocyanate, boric acid and sodium sulfate at the temperature of 21 DEG C ~ 35 DEG C, configure the heat absorbing coating containing black nickel element;
(4) adopted by the heat absorbing coating containing black nickel element double-deck surge mode to cover the surface of aluminum fin-stock, this coat-thickness is 0.052 ~ 0.067mg/cm 3, specific absorption α is 0.93 ~ 0.96, and heat emission is 0.08 ~ 0.15 than ε.
In the now unit time, in hot water machine, the average raised temperature of water is 1.6 DEG C/min.
embodiment 3
A kind of biabsorption formula air-source heat pump hot water fin coating process is specific as follows:
(1) clean is carried out to fin surface;
(2) adopt electroless copper to cover one deck high infrared reflection film at fin surface, the thickness of this high infrared reflection film is 0.018 ~ 0.024mg/cm 3;
(3) adopt single nickel salt, zinc sulfate, potassium sulfocyanate, boric acid and sodium sulfate at the temperature of 35 DEG C ~ 43 DEG C, configure the heat absorbing coating containing black nickel element;
(4) adopted by the heat absorbing coating containing black nickel element double-deck surge mode to cover the surface of aluminum fin-stock, this coat-thickness is 0.067 ~ 0.081mg/cm 3, specific absorption α is 0.93 ~ 0.96, and heat emission is 0.08 ~ 0.15 than ε.
In the now unit time, in hot water machine, the average raised temperature of water is 1.1 DEG C/min.
According to above-described embodiment, in embodiment 2, the interior rising of the water temperature unit time of hot water machine is the highest, and endothermic effect is best, and the thickness therefore controlling high infrared reflection film is 0.013 ~ 0.017mg/cm 3, the preparation temperature of the heat absorbing coating of black nickel element is 21 DEG C ~ 35 DEG C, and thickness is 0.052 ~ 0.067mg/cm 3.
More than show and describe ultimate principle of the present invention and principal character.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.

Claims (5)

1. a biabsorption formula air-source heat pump hot water fin coating process, is characterized in that: described coating process is specific as follows:
Clean is carried out to fin surface;
Electroless copper is adopted to cover one deck high infrared reflection film at fin surface;
Adopt single nickel salt, zinc sulfate, potassium sulfocyanate, boric acid and sodium sulfate at the temperature of 21 DEG C ~ 35 DEG C, configure the heat absorbing coating containing black nickel element;
By the surface of the heat absorbing coating surge containing black nickel element to aluminum fin-stock.
2. a kind of biabsorption formula air-source heat pump hot water fin coating process according to claim 1, is characterized in that: in described step (2), the thickness of high infrared reflection film is 0.013 ~ 0.017mg/cm 3.
3. a kind of biabsorption formula air-source heat pump hot water fin coating process according to claim 1, is characterized in that: adopt double-deck surge mode to carry out coating in described step (4).
4. double-deck surge coating according to claim 2, is characterized in that: described coat-thickness is 0.052 ~ 0.067mg/cm 3.
5. a kind of biabsorption formula air-source heat pump hot water fin coating process according to claim 1, it is characterized in that: in described step (4), the coating specific absorption α of black nickel element is 0.93 ~ 0.96, heat emission is 0.08 ~ 0.15 than ε.
CN201510582368.8A 2015-09-15 2015-09-15 Coating process for fin of bi-absorption type air source heat pump water heater Pending CN105112912A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510582368.8A CN105112912A (en) 2015-09-15 2015-09-15 Coating process for fin of bi-absorption type air source heat pump water heater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510582368.8A CN105112912A (en) 2015-09-15 2015-09-15 Coating process for fin of bi-absorption type air source heat pump water heater

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109297106A (en) * 2018-08-28 2019-02-01 珠海格力电器股份有限公司 Super-hydrophobic infrared absorption coating, heat exchanger and air conditioner outdoor unit
CN109297105A (en) * 2018-08-28 2019-02-01 珠海格力电器股份有限公司 Super-hydrophobic infrared absorption coating, heat exchanger and air conditioner outdoor unit

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101762081A (en) * 2010-01-15 2010-06-30 大连希奥特检测设备有限公司 Heat collecting module of metal-glass sheathing heat collecting pipe

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101762081A (en) * 2010-01-15 2010-06-30 大连希奥特检测设备有限公司 Heat collecting module of metal-glass sheathing heat collecting pipe

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
王快社等: "《金属涂镀工艺学》", 30 September 2014, 冶金工业出版社 *
程沪生: "镀黑镍工艺及其故障排除", 《电镀与涂饰》 *
胡文旭: "黑镍涂层的制备与光学性能研究", 《太阳能学报》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109297106A (en) * 2018-08-28 2019-02-01 珠海格力电器股份有限公司 Super-hydrophobic infrared absorption coating, heat exchanger and air conditioner outdoor unit
CN109297105A (en) * 2018-08-28 2019-02-01 珠海格力电器股份有限公司 Super-hydrophobic infrared absorption coating, heat exchanger and air conditioner outdoor unit

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Application publication date: 20151202

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