CN105111885B - Stable coating of a kind of special reversible temperature indicating light of transformer pile head and preparation method thereof - Google Patents
Stable coating of a kind of special reversible temperature indicating light of transformer pile head and preparation method thereof Download PDFInfo
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- CN105111885B CN105111885B CN201510494259.0A CN201510494259A CN105111885B CN 105111885 B CN105111885 B CN 105111885B CN 201510494259 A CN201510494259 A CN 201510494259A CN 105111885 B CN105111885 B CN 105111885B
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Abstract
The present invention provides stable coating of the special reversible temperature indicating light of a kind of transformer pile head and preparation method thereof, including following component and its mass fraction:Component A:40~75 parts of epoxy resin, 10~30 parts of temperature-sensitive powder, 1~5 part of dispersant, 1~5 part of levelling agent, 1~3 part of defoamer, 1~5 part of anti-settling agent, 5~20 parts of solvent, 1~10 part of sericite in powder, 1~5 part of aluminium-magnesium silicate, 1~10 part of ultraviolet absorber;B component:50~100 parts of epoxy hardener, 0~50 part of dimethylbenzene;The mass ratio of the component A and B component is 1 ︰ 0.7~1.Product of the present invention has good sun-proof, ageing resistace, can be by the change of the change indicating transformer pile crown temperature of color, and temperature changing speed is fast, and rewarming time is short, meanwhile, preparation method is simple, with low cost.
Description
Technical field
The present invention relates to coating manufacturing technology field, and in particular to a kind of special reversible temperature indicating light of transformer pile head is stable to be applied
Material and preparation method thereof.
Background technology
Power transformer is the important electric equipment in supply network, and the quality of its performance can directly affect electric service water
Flat, transformer plays the vital task of energy conversion and conveying in power system, and power transformer is exposed to the weather for a long time, gesture
The oxidation and weathering of transformer pile head coating must be caused, Paint Falling is effectively caused, serious consequence may will be caused.
Thermo-color is a kind of new sapecial coating, it be with color or outward appearance phenomenon come indicator body surface temperature and
A kind of coating of Temperature Distribution, indicates that temperature has the advantages that with thermo-color measurement simple, fast and easy, directly perceived, is general
Glass-stem thermometer, thermocouple, less than thermal resistance thermometer.Due to its special use value, so by scientific and technological circle of various countries
Attention, and carried out substantial amounts of research work.The research and application of thermo-color have the history of 50 or six ten years abroad.It is early
Before and after second of Great War, some countries are just studied and produced to thermo-color.
Check that transformer pile head temperature uses infrared measurement of temperature method at present, this method cost of labor is high, and when equipment peace
Dress apart from ground it is higher when, operation maintenance personnel need to ascend a height operation, increase danger.Therefore, transformer can be adapted to by developing one kind
The thermo-color with anti-oxidant and weatherability used also just turns into the task of top priority.
The content of the invention
It is an object of the invention to provide stable coating of the special reversible temperature indicating light of a kind of transformer pile head and preparation method thereof, production
Product have good sun-proof, ageing resistace, can pass through the change of the change indicating transformer pile crown temperature of color, Er Qiewen
Spend pace of change fast, rewarming time is short, meanwhile, preparation method is simple, with low cost.
To achieve these goals, the technical solution adopted by the present invention is as follows:
A kind of stable coating of special reversible temperature indicating light of transformer pile head, including following component and its mass fraction:Component A:
40~75 parts of epoxy resin, 10~30 parts of temperature-sensitive powder, 1~5 part of dispersant, 1~5 part of levelling agent, 1~3 part of defoamer, anti-settling agent
1~5 part, 5~20 parts of solvent, 1~10 part of sericite in powder, 1~5 part of aluminium-magnesium silicate, 1~10 part of ultraviolet absorber;B component:Ring
50~100 parts of oxygen curing agent, 0~50 part of dimethylbenzene;The mass ratio of the component A and B component is 1 ︰ 0.7~1.
According to above scheme, the temperature change interval of the temperature-sensitive powder is 50 DEG C~70 DEG C.
According to above scheme, the solvent is dimethylbenzene.
According to above scheme, the ultraviolet absorber is 2-hydroxy-4-n-octoxybenzophenone.
According to above scheme, the particle diameter of the sericite in powder is 1250 mesh, and the particle diameter of aluminium-magnesium silicate is 5000 mesh.
According to above scheme, the anti-settling agent is organobentonite, absolute ethyl alcohol, the mixture of dimethylbenzene or gas phase dioxy
SiClx, the organobentonite, absolute ethyl alcohol, the mass ratio of dimethylbenzene are the ︰ 15~20 of 1~2 ︰ 1.
A kind of preparation method of the stable coating of special reversible temperature indicating light of transformer pile head, comprises the following steps:
1) stirred after mixing epoxy resin, dispersant, levelling agent, defoamer, anti-settling agent, solvent, progress is pre-dispersed, obtains
Obtain pre-dispersed mixture;
2) temperature-sensitive powder, sericite in powder, ultraviolet absorber, aluminium-magnesium silicate and pre-dispersed mixture are put into grinder in the lump
In, it is ground after adding bead, is ground to fineness and reaches less than 40 μm, component A is obtained after filtering;
3) epoxy hardener and dimethylbenzene are proportionally prepared and are added in container, be uniformly mixing to obtain B component;
4) component A is prepared in proportion with B component, product is made after stirring.
According to above scheme, the step 1) in the rotating speed of stirring be 600r/min, pre-dispersed time is 1-3h.
According to above scheme, the step 2) in grinder rotating speed be more than or equal to 1500r/min, the outlet of grinder
Temperature control is at 40~60 DEG C, and because sand mill is metal bucket, if not controlling outlet temperature, its internal temperature is too high will to be made to disperse
Agent is constantly evaporated, so as to component A will be made slowly to solidify.
Step 1 in the preparation method of the present invention) in the pre-dispersed time be less than 1h, it is epoxy resin, dispersant, levelling agent, anti-
Heavy agent, defoamer, solvent are scattered incomplete, if the pre-dispersed time is more than 3h, will cause temporal waste;Anti-settling agent needs
Addition in 30min has been configured, result of prevention is otherwise influenceed.Step 2) in, if fineness will make to contain in corrosion resistant coating higher than 40 μm
Particulate material.
After the completion of component A is prepared with B component, preferably mixed in 3h and carry out coating decoration.
If the mixture of anti-settling agent organobentonite, absolute ethyl alcohol, dimethylbenzene preparing in 30min, it is necessary to use.
Dispersant is high 750 dispersant of enlightening (Tego Dispers 750W), high 715 dispersant (the Tego Dispers of enlightening
715W), it is any one in high 710 dispersant of enlightening (Tego Dispers 710), EFKA dispersant 4310 (EFKA 4310)
Kind.
High 1484 stream of high 100 levelling agent of levelling agent enlightening (Tego Glide 100), the levelling agents of Bi Ke 333 (BYK-333), enlightening
Flat agent (Tego Glide 1484), Taiwan add up to any one in defoamer and levelling agent D201 (D201).
Defoamer is that modest 5300 defoamer (Deform 5300) of moral, high 825 defoamer (Tego 825) of enlightening, enlightening high 900 disappear
Infusion (Tego Airex 932), Taiwan add up to any one in defoamer and levelling agent D201 (D201).
The beneficial effects of the invention are as follows:
1) resinoid bond of the invention selection epoxy resin, not only with closely knit, water resistant, the features such as intensity is high, and
Also have adhesive force strong, normal-temperature operation, the good manufacturability such as easy construction, and also it is moderate;
2) rational proportion of each component, with reference to the addition of unique temperature-sensitive powder, can not be suitable for transformer stake in arrival
Quick color-changing under the temperature environment of head, to staff with warning function, reduces the possibility that failure occurs, simultaneously for short
The elevated situation of time-temperature, treats that temperature lowers, and color is understood oneself and restored, and staff is had the temperature of transformer pile head
One easier intuitively to recognize;
3) 1250 mesh sericites in powder are added, the unique two-dimensional sheet barrier of sericite in powder, shielding ultraviolet light, chemical constitution
The functions such as stability effectively improve the performances such as permeability resistance, weatherability, the corrosion resistance of film, in addition, sericite in powder is free of
Any radioactive element, can lead the trend of paint field environmental protection.
4) ultraviolet absorber GJ-UV is added in formula component A, intramolecular hydrogen bond can be formed and constitute chelate ring, work as suction
Receive after ultraviolet light, thermal vibration occurs for molecule, hydrogen bond is destroyed, chelate ring is opened, and now compound is in unstable high energy shape
State, in original low energy steady-state phase is returned to, discharges unnecessary energy, so, and high energy, harmful ultraviolet light become
Into low energy, harmless heat energy.
In summary, function admirable of the present invention, raw material is simple and easy to get, easy construction, excellent performance, it is adaptable to extensive work
Industry is produced, after use, and obtained coating not only has the function of reversible temperature indicating, while having excellent sun-proof ultra-violet resistance
Can, future can have good development prospect.
Embodiment
Technical scheme is illustrated with reference to embodiment.
Embodiment 1:
The present invention provides stable coating of the special reversible temperature indicating light of a kind of transformer pile head and preparation method thereof, including following step
Suddenly:
1) by 200g epoxy resin, 20g dispersants (EFKA 4310), 4g defoamers (Deform 5300), 8g anti-settling agents
(organobentonite, absolute ethyl alcohol, the mixture of dimethylbenzene), 8g levelling agents (D201), 20g solvents (dimethylbenzene) are mixed to join
In beaker, then stir, speed of agitator is 600r/min, carry out pre-dispersed 60min, obtain pre-dispersed mixture;
2) by 80g temperature-sensitive powder, 20g sericites in powder, 20g aluminium-magnesium silicates, 20g ultraviolet absorbers (2- hydroxyl -4- n-octyloxies
Benzophenone) it is put into the lump in grinder with pre-dispersed mixture, it is ground after adding bead, leads to condenser pipe, adjust out
40 DEG C of temperature of mouth, regulation rotating speed surveys fineness every 30min, is ground to fineness and reaches less than 40 μm, mistake to 2500r/min
Component A is obtained after filter;
3) 350g epoxy hardeners and 150g dimethylbenzene are added in beaker, are uniformly mixing to obtain B component;
4) component A and B component are prepared in 1 ︰ 1 ratio, product is made after stirring.
Embodiment 2:
The present invention provides stable coating of the special reversible temperature indicating light of a kind of transformer pile head and preparation method thereof, including following step
Suddenly:
1) by 200g epoxy resin, 20g dispersants (Tego Dispers 715W), 4g defoamers (Deform 5300),
8g anti-settling agents (organobentonite, absolute ethyl alcohol, the mixture of dimethylbenzene), 8g levelling agents (D201) and 20g solvents (dimethylbenzene)
It is mixed to join in beaker, then stirs, speed of agitator is 600r/min, carry out pre-dispersed 60min, obtains pre-dispersed mixing
Thing;
2) by 60g temperature-sensitive powder, 20g sericites in powder, 20g aluminium-magnesium silicates, 8g ultraviolet absorbers (2- hydroxyl -4- n-octyloxies
Benzophenone) it is put into the lump in grinder with pre-dispersed mixture, it is ground after adding bead, leads to condenser pipe, adjust out
40 DEG C of temperature of mouth, regulation rotating speed surveys fineness every 30min, is ground to fineness and reaches less than 40 μm, mistake to 2500r/min
Component A is obtained after filter;
3) 350g epoxy hardeners and 150g dimethylbenzene are added in beaker, are uniformly mixing to obtain B component;
4) component A and B component are prepared in 1 ︰ 1 ratio, product is made after stirring.
Embodiment 3:
The present invention provides stable coating of the special reversible temperature indicating light of a kind of transformer pile head and preparation method thereof, including following step
Suddenly:
1) 200g epoxy resin, 20g dispersants (EFKA 4310), 4g defoamers (Tego 825), 8g anti-settling agents (are had
Machine bentonite, absolute ethyl alcohol, the mixture of dimethylbenzene), 8g levelling agents (D201) and 20g solvents (dimethylbenzene) be mixed to join burning
In cup, then stir, speed of agitator is 600r/min, carry out pre-dispersed 60min, obtain pre-dispersed mixture;
2) by 100g temperature-sensitive powder, 12g sericites in powder, 20g aluminium-magnesium silicates, 8g ultraviolet absorbers (2- hydroxyl -4- n-octyloxies
Benzophenone) it is put into the lump in grinder with pre-dispersed mixture, it is ground after adding bead, leads to condenser pipe, adjust out
40 DEG C of temperature of mouth, regulation rotating speed surveys fineness every 30min, is ground to fineness and reaches less than 40 μm, mistake to 2500r/min
Component A is obtained after filter;
3) 320g epoxy hardeners and 80g dimethylbenzene are added in beaker, are uniformly mixing to obtain B component;
4) component A and B component are prepared in 1 ︰ 1 ratio, product is made after stirring.
The product effect of embodiment 1 to 3 is verified by testing, in the verification, from the tinplate of state's dimensioning,
The iron plate is polished with 500 mesh sand paper, is polishing to and washes one's face and clean up, respectively numbering 1, and 2,3, sprayed, sprayed with spray gun
Finish and be put into 80 DEG C of baking ovens, its performance is tested afterwards, test result such as table 1.
The properties of product test result of table 1
Test result shows that product of the present invention has excellent combination property, and temperature changing speed is fast, and rewarming time is short,
The special requirement of transformer pile head can be met.
Embodiment 4:
The present invention provides stable coating of the special reversible temperature indicating light of a kind of transformer pile head and preparation method thereof, including following step
Suddenly:
1) by 750g epoxy resin, 50g dispersants (EFKA 4310), 40g defoamers (Tego 825), 30g anti-settling agents
(organobentonite, absolute ethyl alcohol, the mixture of dimethylbenzene), 50g levelling agents (BYK-333) and 200g solvents are mixed to join burning
In cup, then stir, speed of agitator is 600r/min, carry out pre-dispersed 100min, obtain pre-dispersed mixture;
2) by 300g temperature-sensitive powder, (2- hydroxyls -4- is just pungent for 100g sericites in powder, 50g aluminium-magnesium silicates, 100g ultraviolet absorbers
Epoxide benzophenone) it is put into the lump in grinder with pre-dispersed mixture, it is ground after adding bead, leads to condenser pipe, is adjusted
Save 60 DEG C of outlet temperature, regulation rotating speed to 2500r/min, survey fineness every 30min, be ground to fineness reach 40 μm with
Under, component A is obtained after filtering;
3) 800g epoxy hardeners and 800g dimethylbenzene are added in beaker, are uniformly mixing to obtain B component;
4) component A and B component are prepared in 1 ︰ 0.7 ratio, product is made after stirring.
Embodiment 5:
The present invention provides stable coating of the special reversible temperature indicating light of a kind of transformer pile head and preparation method thereof, including following step
Suddenly:
1) by 400g epoxy resin, 10g dispersants (Tego Dispers 750W), 10g defoamers (Tego 825), 10g
Anti-settling agent (aerosil), 10g levelling agents (BYK-333) and 50g solvents (dimethylbenzene) are mixed to join in beaker, then
Stirring, speed of agitator is 600r/min, carries out pre-dispersed 180min, obtains pre-dispersed mixture;
2) by 100g temperature-sensitive powder, 12g sericites in powder, 20g aluminium-magnesium silicates, 8g ultraviolet absorbers (2- hydroxyl -4- n-octyloxies
Benzophenone) it is put into the lump in grinder with pre-dispersed mixture, it is ground after adding bead, leads to condenser pipe, adjust out
Mouth temperature 50 C, regulation rotating speed surveys fineness every 30min, is ground to fineness and reaches less than 40 μm, mistake to 1500r/min
Component A is obtained after filter;
3) 600g epoxy hardeners are weighed as B component;
4) component A and B component are prepared in 1 ︰ 0.8 ratio, product is made after stirring.
Above example is only used to illustrative and not limiting technical scheme, although above-described embodiment enters to the present invention
Detailed description is gone, the person skilled of this area should be understood:The present invention can be modified or replaced on an equal basis, but
Not departing from any modification and local replacement of spirit and scope of the invention all should cover in scope of the presently claimed invention.
Claims (9)
1. the stable coating of a kind of special reversible temperature indicating light of transformer pile head, it is characterised in that including following component and its mass parts
Number:Component A:It is 40 ~ 75 parts of epoxy resin, 10 ~ 30 parts of temperature-sensitive powder, 1 ~ 5 part of dispersant, 1 ~ 5 part of levelling agent, 1 ~ 3 part of defoamer, anti-
Heavy 1 ~ 5 part of agent, 5 ~ 20 parts of solvent, 1 ~ 10 part of sericite in powder, 1 ~ 5 part of aluminium-magnesium silicate, 1 ~ 10 part of ultraviolet absorber;B component:Epoxy
50 ~ 100 parts of curing agent, 0 ~ 50 part of dimethylbenzene;The mass ratio of the component A and B component is 1 ︰ 0.7 ~ 1.
2. the stable coating of the special reversible temperature indicating light of transformer pile head according to claim 1, it is characterised in that the temperature-sensitive
The temperature change interval of powder is 50 DEG C ~ 70 DEG C.
3. the stable coating of the special reversible temperature indicating light of transformer pile head according to claim 1, it is characterised in that the solvent
For dimethylbenzene.
4. the stable coating of the special reversible temperature indicating light of transformer pile head according to claim 1, it is characterised in that described ultraviolet
Absorbent is 2-hydroxy-4-n-octoxybenzophenone.
5. the stable coating of the special reversible temperature indicating light of transformer pile head according to claim 1, it is characterised in that the thin,tough silk cloud
The particle diameter of female powder is 1250 mesh, and the particle diameter of aluminium-magnesium silicate is 5000 mesh.
6. the stable coating of the special reversible temperature indicating light of transformer pile head according to claim 1, it is characterised in that described anti-settling
Agent be organobentonite, absolute ethyl alcohol, the mixture or aerosil of dimethylbenzene, the organobentonite, absolute ethyl alcohol,
The mass ratio of dimethylbenzene is the ︰ 15 ~ 20 of 1 ~ 2 ︰ 1.
7. a kind of preparation method of the stable coating of special reversible temperature indicating light of transformer pile head as claimed in claim 1, its feature exists
In comprising the following steps:
1)Stirred after epoxy resin, dispersant, levelling agent, defoamer, anti-settling agent, solvent are mixed, progress is pre-dispersed, obtain pre-
Dispersed mixture;
2)Temperature-sensitive powder, sericite in powder, ultraviolet absorber, aluminium-magnesium silicate and pre-dispersed mixture are put into grinder in the lump, plus
Enter and be ground after bead, be ground to fineness and reach less than 40 μm, component A is obtained after filtering;
3)Epoxy hardener and dimethylbenzene are proportionally prepared and are added in container, B component is uniformly mixing to obtain;
4)Component A is prepared in proportion with B component, product is made after stirring.
8. the preparation method of the stable coating of the special reversible temperature indicating light of transformer pile head according to claim 7, its feature exists
In the step 1)The rotating speed of middle stirring is 600r/min, and the pre-dispersed time is 1-3h.
9. the preparation method of the stable coating of the special reversible temperature indicating light of transformer pile head according to claim 7, its feature exists
In the step 2)The rotating speed of middle grinder is more than or equal to 1500r/min, and the outlet temperature of grinder is controlled at 40 ~ 60 DEG C.
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CN108467659B (en) * | 2018-04-02 | 2020-11-06 | 苏州迈创信息技术有限公司 | Reversible temperature indicating coating and preparation method thereof, fuse fusing core and fuse |
CN112852301B (en) * | 2021-01-05 | 2022-03-15 | 中国第一铅笔有限公司 | Photosensitive color-changing pencil paint and process for producing photosensitive color-changing pencil by using same |
CN115820082B (en) * | 2022-11-24 | 2023-09-08 | 国网浙江省电力有限公司超高压分公司 | Thermochromic temperature-indicating paint and preparation method thereof |
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KR101286988B1 (en) * | 2011-03-03 | 2013-07-23 | 성락두 | Paint composition, method for coating and case for portable electronic device comprising the coating layer |
CN102695388A (en) * | 2012-06-14 | 2012-09-26 | 赖勇 | Electronic product protection device with temperature sensing function |
CN103333582B (en) * | 2013-07-04 | 2015-08-05 | 江苏科技大学 | The organic irreversible thermochromic coatings of a kind of low temperature, preparation method and application thereof |
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