CN105110772A - High temperature creep-resistant flake alumina porous ceramic used for LED lamp heat dissipation, and preparation method thereof - Google Patents

Abstract

The invention discloses a high temperature creep-resistant flake alumina porous ceramic used for LED lamp heat dissipation. The flake alumina porous ceramic is prepared from, by weight, 34 to 36 parts of alpha-Al2O3 (particle size ranging from 2 to 8<mu>m), 100 to 105 parts of deionized water, 0.2 to 0.3 part of sodium polyacrylate, 2 to 2.3 parts of methylcellulose, 1.6 to 1.8 parts of glycerin, 1.3 to 1.8 parts of yttrium aluminum garnet fiber, 0.6 to 0.8 part of nanometer tin dioxide, 0.3 to 0.5 part of tantalum nitride, 1.5 to 1.8 parts of silicon-calcium-barium alloy powder, 4 to 5 parts of nano-aluminium hydroxide, 1.2 to 1.5 parts of nano-copper, and 0.9 to 1.1 parts of PVA binder. According to the preparation method, yttrium aluminum garnet fiber, nanometer tin dioxide, and tantalum nitride are added, so that oxidation resistance, high temperature resistance, high temperature creep resistance, and thermal conductivity of ceramic are improved; silicon-calcium-barium alloy powder is added, so that recombination property with metal is improved, and thermal conductivity is increased.

Description

LED heat transmission tabular alumina porous ceramics of a kind of high temperature creep-resisting and preparation method thereof

Technical field

The present invention relates to porous heat dissipation ceramic field, LED heat transmission tabular alumina porous ceramics particularly relating to a kind of high temperature creep-resisting and preparation method thereof.

Background technology

Photodiode (LED) is that a class directly by the luminescent device that electric energy conversion is visible ray and radiating capacity, have powerful market potential, and great power LED can be thought the Main way 1 in lighting source market by industry.Under present level, the power input of 10% ~ 20% can only be converted into luminous energy by great power LED, and all the other 80% ~ 90% are all converted into heat energy.For ensureing that it normally works, need ensure that the working temperature of LED is in allowed band by effective heat dissipation design.Therefore high-power LED chip heat dissipation problem has become the obstacle that current LED technology is applied in illuminating engineering.

Scholar is had to use powder metallurgic method to prepare metal/ceramic heat sink compound.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If will there is small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, when can also reduce metal and Ceramic Composite, have scholar to use powder metallurgic method to prepare metal/ceramic heat sink compound because two-phase thermal expansivity does not mate to cause in use.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If by having small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when can also reduce metal and Ceramic Composite.And prepare the key that this flake porous pottery is this technical development.

Flow casting molding prepares one of big area, the most effective means of thin plate stupalith at present.Replace the casting technology of organic solvent to become the emphasis of research at present due to its hypotoxicity, oligosaprobic feature using water as solvent.Simultaneously freeze-drying in the porous ceramics of controlled, the high through-hole rate of preparation aperture size also tool have great advantage." multilayer low temperature curtain coating legal system is for tabular alumina porous ceramics " literary composition describes the method preparing alumina porous ceramic, and the thermal fatigue of ceramics performance of making is good.But the method can not be even by alumina dispersion, and easily reunite, ceramic structure is uneven, and if this ceramic plate is applied to LED radiator element, also need the problem such as toughness, thermal conductivity, crack resistence, thermotolerance improving pottery.The consistency of this ceramic plate and metal is poor, needs to improve.

Summary of the invention

The object of the present invention is to provide a kind of LED heat transmission tabular alumina porous ceramics of high temperature creep-resisting, the oxidation-resistance of this tabular alumina porous ceramics, high thermal resistance, high temperature creep resistance and thermal conductivity are good, are applicable to high-power LED chip heat radiation.

Technical scheme of the present invention is as follows:

A LED heat transmission tabular alumina porous ceramics for high temperature creep-resisting, is characterized in that being made up of the raw material of following weight part: α-Al ₂o ₃(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, yttrium aluminium garnet fibers 1.3-1.8, nano-stannic oxide 0.6-0.8, tantalum nitride 0.3-0.5, calsibar alloy powder 1.5-1.8, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.

The production method of the LED heat transmission tabular alumina porous ceramics of described high temperature creep-resisting, is characterized in that:

(1) by α-Al ₂o ₃, yttrium aluminium garnet fibers, calsibar alloy powder, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add nano-stannic oxide, tantalum nitride, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;

(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al ₂o ₃ceramic size;

(3) by Al that (2) step obtains ₂o ₃ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;

(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.

Beneficial effect of the present invention

Tabular alumina porous ceramics interlayer duct of the present invention is communicated with, and transition is good, and thermal fatigue property is good; By using nano-aluminum hydroxide, improve the phenomenon that alumina particle is easily reunited; By using Nanometer Copper, improve pottery and the consistency of metal, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when reducing metal and Ceramic Composite; By using yttrium aluminium garnet fibers, nano-stannic oxide, tantalum nitride, improve the oxidation-resistance of pottery, high thermal resistance, high temperature creep resistance and thermal conductivity; By using calsibar alloy powder, strengthening pottery and metal composite performance, improve thermal conductivity, be applicable to high-power LED chip heat radiation.

Embodiment

A LED heat transmission tabular alumina porous ceramics for high temperature creep-resisting, is made up of the raw material of following weight part (kilogram): α-Al ₂o ₃(particle diameter is 2-8 μm) 35, deionized water 103, sodium polyacrylate 0.3, methylcellulose gum 2.1, glycerol 1.7, yttrium aluminium garnet fibers 1.5, nano-stannic oxide 0.7, tantalum nitride 0.4, calsibar alloy powder 1.6, nano-aluminum hydroxide 4.5, Nanometer Copper 1.3, PVA binding agent 1.

The production method of the LED heat transmission tabular alumina porous ceramics of described high temperature creep-resisting, is characterized in that:

(1) by α-Al ₂o ₃, yttrium aluminium garnet fibers, calsibar alloy powder, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5h, add nano-stannic oxide, tantalum nitride, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.8h, leaves standstill 50min, obtains slurry;

(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 21h, then add other remaining component, continue ball milling 2h, then carry out froth in vacuum 5min, obtain Al ₂o ₃ceramic size;

(3) by Al that (2) step obtains ₂o ₃ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;

(4) by after multilayer cast sheet lyophilize 23h, sinter at 1630 DEG C, insulation 2h, then be chilled to room temperature with stove, to obtain final product.

Experimental data: by sample after 300 slow cooling (25 DEG C), 200 chillings (25 DEG C) and 195 chillings (– 20 DEG C), the cycle index that sample crackle occurs is 725 times, finds out that the thermal fatigue property of this sample is fine.

Claims (2)

1. a LED heat transmission tabular alumina porous ceramics for high temperature creep-resisting, is characterized in that being made up of the raw material of following weight part: α-Al ₂o ₃(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, yttrium aluminium garnet fibers 1.3-1.8, nano-stannic oxide 0.6-0.8, tantalum nitride 0.3-0.5, calsibar alloy powder 1.5-1.8, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.

2. the production method of the LED heat transmission tabular alumina porous ceramics of high temperature creep-resisting according to claim 1, is characterized in that:

(1) by α-Al ₂o ₃, yttrium aluminium garnet fibers, calsibar alloy powder, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add nano-stannic oxide, tantalum nitride, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;

(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al ₂o ₃ceramic size;

(3) by Al that (2) step obtains ₂o ₃ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;

(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.