CN104987108A - Jade-powder-containing tabular alumina porous ceramic for LED lamp heat dissipation, and preparation method thereof - Google Patents
Jade-powder-containing tabular alumina porous ceramic for LED lamp heat dissipation, and preparation method thereof Download PDFInfo
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Abstract
The invention relates to jade-powder-containing tabular alumina porous ceramic for LED lamp heat dissipation. The porous ceramic is prepared from the raw materials of, by weight, 34-36 parts of alpha-Al2O3 (with particle size of 2-8mum), 100-105 parts of deionized water, 0.2-0.3 parts of sodium polyacrylate, 2-2.3 parts of methylcellulose, 1.6-1.8 parts of glycerol, 1.1-1.4 parts of jade powder, 0.5-0.6 parts of a terpineol solution of ethyl cellulose, 0.8-1.1 parts of kaolin, 0.3-0.4 parts of ultrafine VC powder, 4-5 parts of nano-grade aluminum hydroxide, 1.2-1.5 parts of nano-grade copper, and 0.9-1.1 parts of a PVA binding agent. According to the tabular alumina porous ceramic, nano-grade aluminum hydroxide is adopted, such that a phenomenon that alumina particles are prone to agglomeration is ameliorated. With jade powder and kaolin, ceramic roughness, thermal conductivity and heat resistance are improved. With the ultrafine VC powder, nano-grade copper oxidation is prevented, and ceramic compounding performance with metal is improved.
Description
Technical field
The present invention relates to porous heat dissipation ceramic field, particularly relate to a kind of LED heat transmission tabular alumina porous ceramics containing jade powder and preparation method thereof.
Background technology
Photodiode (LED) is that a class directly by the luminescent device that electric energy conversion is visible ray and radiating capacity, have powerful market potential, and great power LED can be thought the Main way 1 in lighting source market by industry.Under present level, the power input of 10% ~ 20% can only be converted into luminous energy by great power LED, and all the other 80% ~ 90% are all converted into heat energy.For ensureing that it normally works, need ensure that the working temperature of LED is in allowed band by effective heat dissipation design.Therefore great power LED chip cooling problem has become the obstacle that current LED technology is applied in illuminating engineering.
Scholar is had to use powder metallurgic method to prepare metal/ceramic heat sink compound.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If will there is small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, when can also reduce metal and Ceramic Composite, have scholar to use powder metallurgic method to prepare metal/ceramic heat sink compound because two-phase thermal expansivity does not mate to cause in use.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If by having small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when can also reduce metal and Ceramic Composite.And prepare the key that this flake porous pottery is this technical development.
Flow casting molding prepares one of big area, the most effective means of thin plate stupalith at present.Replace the casting technology of organic solvent to become the emphasis of research at present due to its hypotoxicity, oligosaprobic feature using water as solvent.Simultaneously freeze-drying in the porous ceramics of controlled, the high through-hole rate of preparation aperture size also tool have great advantage." multilayer low temperature curtain coating legal system is for tabular alumina porous ceramics " literary composition describes the method preparing alumina porous ceramic, and the thermal fatigue of ceramics performance of making is good.But the method can not be even by alumina dispersion, and easily reunite, ceramic structure is uneven, and if this ceramic plate is applied to LED radiator element, also need the problem such as toughness, thermal conductivity, crack resistence, thermotolerance improving pottery.The consistency of this ceramic plate and metal is poor, needs to improve.
Summary of the invention
The object of the present invention is to provide a kind of LED heat transmission tabular alumina porous ceramics containing jade powder, the toughness of this tabular alumina porous ceramics, thermal conductivity, good heat resistance, good with metal composite performance.
Technical scheme of the present invention is as follows:
A LED heat transmission tabular alumina porous ceramics containing jade powder, is characterized in that being made up of the raw material of following weight part: α-Al
2o
3(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, jade powder 1.1-1.4, terpineol solution of ethyl cellulose 0.5-0.6, kaolin 0.8-1.1, ultra-fine VC powder 0.3-0.4, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.
The production method of the described LED heat transmission tabular alumina porous ceramics containing jade powder, is characterized in that:
(1) by α-Al
2o
3, jade powder, kaolin, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add terpineol solution of ethyl cellulose, ultra-fine VC powder, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;
(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al
2o
3ceramic size;
(3) by Al that (2) step obtains
2o
3ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;
(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.
Beneficial effect of the present invention
Tabular alumina porous ceramics interlayer duct of the present invention is communicated with, and transition is good, and thermal fatigue property is good; By using nano-aluminum hydroxide, improve the phenomenon that alumina particle is easily reunited; By using Nanometer Copper, improve pottery and the consistency of metal, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when reducing metal and Ceramic Composite; By using jade powder, kaolin, improve toughness, thermal conductivity, the thermotolerance of pottery, by using ultra-fine VC powder, preventing Nanometer Copper to be oxidized, improve pottery and metal composite performance.
Embodiment
A LED heat transmission tabular alumina porous ceramics containing jade powder, is made up of the raw material of following weight part (kilogram): α-Al
2o
3(particle diameter is 2-8 μm) 35, deionized water 103, sodium polyacrylate 0.3, methylcellulose gum 2.1, glycerol 1.7, jade powder 1.2, terpineol solution of ethyl cellulose 0.5, kaolin 1, ultra-fine VC powder 0.3, nano-aluminum hydroxide 4.5, Nanometer Copper 1.3, PVA binding agent 1.
The production method of the described LED heat transmission tabular alumina porous ceramics containing jade powder, is characterized in that:
(1) by α-Al
2o
3, jade powder, kaolin, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5h, add terpineol solution of ethyl cellulose, ultra-fine VC powder, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.7h, leaves standstill 50min, obtains slurry;
(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 21h, then add other remaining component, continue ball milling 2h, then carry out froth in vacuum 6min, obtain Al
2o
3ceramic size;
(3) by Al that (2) step obtains
2o
3ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;
(4) by after multilayer cast sheet lyophilize 23h, sinter at 1650 DEG C, insulation 2.3h, then be chilled to room temperature with stove, to obtain final product.
Experimental data: by sample after 300 slow cooling (25 DEG C), 200 chillings (25 DEG C) and 195 chillings (– 20 DEG C), the cycle index that sample crackle occurs is 690 times, finds out that the thermal fatigue property of this sample is fine.
Claims (2)
1. the LED heat transmission tabular alumina porous ceramics containing jade powder, is characterized in that being made up of the raw material of following weight part: α-Al
2o
3(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, jade powder 1.1-1.4, terpineol solution of ethyl cellulose 0.5-0.6, kaolin 0.8-1.1, ultra-fine VC powder 0.3-0.4, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.
2. the production method of the LED heat transmission tabular alumina porous ceramics containing jade powder according to claim 1, is characterized in that:
(1) by α-Al
2o
3, jade powder, kaolin, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add terpineol solution of ethyl cellulose, ultra-fine VC powder, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;
(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al
2o
3ceramic size;
(3) by Al that (2) step obtains
2o
3ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;
(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109832673A (en) * | 2019-02-27 | 2019-06-04 | 深圳市合元科技有限公司 | Electronic smoke atomizer, electronic cigarette, atomizing component and preparation method thereof |
CN115446301A (en) * | 2021-05-21 | 2022-12-09 | 中国科学院大连化学物理研究所 | Copper nanoparticle material and preparation and application thereof |
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CN1498876A (en) * | 2002-11-04 | 2004-05-26 | 原效坤 | Method for preparing composite engineering ceramics material of nano ZrO2 (Y2O3)/A12O3/Cu |
CN103910535A (en) * | 2012-12-31 | 2014-07-09 | 华越科技股份有限公司 | Porous ceramic radiating fin and preparation method |
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2015
- 2015-07-24 CN CN201510440187.1A patent/CN104987108A/en active Pending
Patent Citations (2)
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CN1498876A (en) * | 2002-11-04 | 2004-05-26 | 原效坤 | Method for preparing composite engineering ceramics material of nano ZrO2 (Y2O3)/A12O3/Cu |
CN103910535A (en) * | 2012-12-31 | 2014-07-09 | 华越科技股份有限公司 | Porous ceramic radiating fin and preparation method |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109832673A (en) * | 2019-02-27 | 2019-06-04 | 深圳市合元科技有限公司 | Electronic smoke atomizer, electronic cigarette, atomizing component and preparation method thereof |
CN115446301A (en) * | 2021-05-21 | 2022-12-09 | 中国科学院大连化学物理研究所 | Copper nanoparticle material and preparation and application thereof |
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