CN104987111A - High-thermal-conductivity tabular alumina porous ceramic for LED lamp heat dissipation, and preparation method thereof - Google Patents

High-thermal-conductivity tabular alumina porous ceramic for LED lamp heat dissipation, and preparation method thereof Download PDF

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Publication number
CN104987111A
CN104987111A CN201510440244.6A CN201510440244A CN104987111A CN 104987111 A CN104987111 A CN 104987111A CN 201510440244 A CN201510440244 A CN 201510440244A CN 104987111 A CN104987111 A CN 104987111A
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parts
nano
ceramic
tabular alumina
alumina porous
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董照海
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Hefei Kaishi New Material Trading Co Ltd
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Hefei Kaishi New Material Trading Co Ltd
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Abstract

The invention relates to high-thermal-conductivity tabular alumina porous ceramic for LED lamp heat dissipation. The ceramic is prepared from the raw materials of, by weight, 34-36 parts of alpha-Al2O3 (with particle size of 2-8,mum), 100-105 parts of deionized water, 0.2-0.3 parts of sodium polyacrylate, 2-2.3 parts of methylcellulose, 1.6-1.8 parts of glycerol, 1.6-1.9 parts of molybdenum disilicide powder, 0.5-0.6 parts of NbC, 0.1-0.2 parts of sodium hypophosphite, 0.2-0.4 parts of nano-grade montmorillonite, 0.4-0.6 parts of titanium dioxide nano-tube, 4-5 parts of nano-grade aluminum hydroxide, 1.2-1.5 parts of nano-grade copper, and 0.9-1.1 parts of a PVA binding agent. According to the tabular alumina porous ceramic, with the molybdenum disilicide powder, ceramic high-temperature oxidation resistance and thermal conductivity are improved, and ceramic thermal expansion coefficient is reduced. With NbC, nano-grade montmorillonite and titanium dioxide nano-tube, ceramic toughness is improved. The porous ceramic is suitable for heat dissipation of high-power LED chips.

Description

A kind of high thermal conductivity LED heat transmission tabular alumina porous ceramics and preparation method thereof
Technical field
The present invention relates to porous heat dissipation ceramic field, particularly relate to a kind of high thermal conductivity LED heat transmission tabular alumina porous ceramics and preparation method thereof.
Background technology
Photodiode (LED) is that a class directly by the luminescent device that electric energy conversion is visible ray and radiating capacity, have powerful market potential, and great power LED can be thought the Main way 1 in lighting source market by industry.Under present level, the power input of 10% ~ 20% can only be converted into luminous energy by great power LED, and all the other 80% ~ 90% are all converted into heat energy.For ensureing that it normally works, need ensure that the working temperature of LED is in allowed band by effective heat dissipation design.Therefore great power LED chip cooling problem has become the obstacle that current LED technology is applied in illuminating engineering.
Scholar is had to use powder metallurgic method to prepare metal/ceramic heat sink compound.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If will there is small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, when can also reduce metal and Ceramic Composite, have scholar to use powder metallurgic method to prepare metal/ceramic heat sink compound because two-phase thermal expansivity does not mate to cause in use.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If by having small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when can also reduce metal and Ceramic Composite.And prepare the key that this flake porous pottery is this technical development.
Flow casting molding prepares one of big area, the most effective means of thin plate stupalith at present.Replace the casting technology of organic solvent to become the emphasis of research at present due to its hypotoxicity, oligosaprobic feature using water as solvent.Simultaneously freeze-drying in the porous ceramics of controlled, the high through-hole rate of preparation aperture size also tool have great advantage." multilayer low temperature curtain coating legal system is for tabular alumina porous ceramics " literary composition describes the method preparing alumina porous ceramic, and the thermal fatigue of ceramics performance of making is good.But the method can not be even by alumina dispersion, and easily reunite, ceramic structure is uneven, and if this ceramic plate is applied to LED radiator element, also need the problem such as toughness, thermal conductivity, crack resistence, thermotolerance improving pottery.The consistency of this ceramic plate and metal is poor, needs to improve.
Summary of the invention
The object of the present invention is to provide a kind of high thermal conductivity LED heat transmission tabular alumina porous ceramics, high-temperature oxidation resistance, the thermal conductivity of this tabular alumina porous ceramics are good, and thermal expansivity is low, good toughness.
Technical scheme of the present invention is as follows:
A kind of high thermal conductivity LED heat transmission tabular alumina porous ceramics, is characterized in that being made up of the raw material of following weight part: α-Al 2o 3(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, molybdenum silicide powder 1.6-1.9, NbC0.5-0.6, inferior sodium phosphate 0.1-0.2, nano imvite 0.2-0.4, titania nanotube 0.4-0.6, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.
The production method of described high thermal conductivity LED heat transmission tabular alumina porous ceramics, is characterized in that:
(1) by α-Al 2o 3, molybdenum silicide powder, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add NbC, inferior sodium phosphate, nano imvite, titania nanotube, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;
(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al 2o 3ceramic size;
(3) by Al that (2) step obtains 2o 3ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;
(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.
Beneficial effect of the present invention
Tabular alumina porous ceramics interlayer duct of the present invention is communicated with, and transition is good, and thermal fatigue property is good; By using nano-aluminum hydroxide, improve the phenomenon that alumina particle is easily reunited; By using Nanometer Copper, improve pottery and the consistency of metal, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when reducing metal and Ceramic Composite; By using molybdenum silicide powder, improve high-temperature oxidation resistance, the thermal conductivity of pottery, reducing thermal expansivity; By using NbC, nano imvite, titania nanotube, improve the toughness of pottery; This porous ceramics and metal composite, be applicable to high-power LED chip heat radiation.
Embodiment
A kind of high thermal conductivity LED heat transmission tabular alumina porous ceramics, is made up of the raw material of following weight part (kilogram): α-Al 2o 3(particle diameter is 2-8 μm) 35, deionized water 103, sodium polyacrylate 0.2, methylcellulose gum 2.1, glycerol 1.7, molybdenum silicide powder 1.7, NbC0.5, inferior sodium phosphate 0.1, nano imvite 0.3, titania nanotube 0.5, nano-aluminum hydroxide 4.5, Nanometer Copper 1.4, PVA binding agent 1.
The production method of described high thermal conductivity LED heat transmission tabular alumina porous ceramics, is characterized in that:
(1) by α-Al 2o 3, molybdenum silicide powder, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5h, add NbC, inferior sodium phosphate, nano imvite, titania nanotube, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.8h, leaves standstill 50min, obtains slurry;
(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 21h, then add other remaining component, continue ball milling 2.5h, then carry out froth in vacuum 6min, obtain Al 2o 3ceramic size;
(3) by Al that (2) step obtains 2o 3ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;
(4) by after multilayer cast sheet lyophilize 24h, sinter at 1650 DEG C, insulation 2.5h, then be chilled to room temperature with stove, to obtain final product.
Experimental data: by sample after 300 slow cooling (25 DEG C), 200 chillings (25 DEG C) and 195 chillings (– 20 DEG C), the cycle index that sample crackle occurs is 708 times, finds out that the thermal fatigue property of this sample is fine.

Claims (2)

1. a high thermal conductivity LED heat transmission tabular alumina porous ceramics, is characterized in that being made up of the raw material of following weight part: α-Al 2o 3(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, molybdenum silicide powder 1.6-1.9, NbC0.5-0.6, inferior sodium phosphate 0.1-0.2, nano imvite 0.2-0.4, titania nanotube 0.4-0.6, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.
2. the production method of high thermal conductivity LED heat transmission tabular alumina porous ceramics according to claim 1, is characterized in that:
(1) by α-Al 2o 3, molybdenum silicide powder, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add NbC, inferior sodium phosphate, nano imvite, titania nanotube, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;
(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al 2o 3ceramic size;
(3) by Al that (2) step obtains 2o 3ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;
(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.
CN201510440244.6A 2015-07-24 2015-07-24 High-thermal-conductivity tabular alumina porous ceramic for LED lamp heat dissipation, and preparation method thereof Pending CN104987111A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106365638A (en) * 2016-08-31 2017-02-01 阮丽丽 High-toughness ceramic material based on nano montmorillonoid and preparing method thereof
CN112503494A (en) * 2020-10-30 2021-03-16 江西森通新材料科技有限公司 Radiating fin for LED radiator and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1498876A (en) * 2002-11-04 2004-05-26 原效坤 Method for preparing composite engineering ceramics material of nano ZrO2 (Y2O3)/A12O3/Cu
CN1498877A (en) * 2002-11-04 2004-05-26 原效坤 Method for preparing combined functional ceramic material of nano ZrO2 (Y203)/Cu

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1498876A (en) * 2002-11-04 2004-05-26 原效坤 Method for preparing composite engineering ceramics material of nano ZrO2 (Y2O3)/A12O3/Cu
CN1498877A (en) * 2002-11-04 2004-05-26 原效坤 Method for preparing combined functional ceramic material of nano ZrO2 (Y203)/Cu

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
韩沈丹 等: ""多层低温流延法制备片状氧化铝多孔陶瓷"", 《硅酸盐学报》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106365638A (en) * 2016-08-31 2017-02-01 阮丽丽 High-toughness ceramic material based on nano montmorillonoid and preparing method thereof
CN112503494A (en) * 2020-10-30 2021-03-16 江西森通新材料科技有限公司 Radiating fin for LED radiator and preparation method thereof
CN112503494B (en) * 2020-10-30 2023-05-23 裕鑫丰(广东)照明科技有限公司 Radiating fin for LED radiator and preparation method thereof

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Application publication date: 20151021