CN105087917B - The efficient chemical combination leaching device of environmental type copper mine - Google Patents
The efficient chemical combination leaching device of environmental type copper mine Download PDFInfo
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- CN105087917B CN105087917B CN201510637661.XA CN201510637661A CN105087917B CN 105087917 B CN105087917 B CN 105087917B CN 201510637661 A CN201510637661 A CN 201510637661A CN 105087917 B CN105087917 B CN 105087917B
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- chemical combination
- combination leaching
- exhaust purifier
- axle
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
The invention discloses a kind of efficient chemical combination leaching device of environmental type copper mine, chemical combination leaching barrel and exhaust purifier are connected by flange;Stirring motor is inserted in chemical combination leaching barrel after hollow axle connection cone cover, is provided with blade and inlet opening in cone cover, and the air inlet that axle circumference uniform distribution is opened is arranged at hollow axle top, and the disk that surges in chemical combination leaching barrel is by axle connection auger conveyor again on bottom valve;It is provided with chuck outside exhaust purifier, inside is provided with intervalve and is constituted with helical fin cylinder jacket structured, and exhaust purifier outlet is provided with cyclone.Chemical combination of the present invention leaches atmosphere in the tub(Oxygen)Supplement convenient, liquid stream immixture automatically and improve abundant, chemical combination leaching efficiency is very high;Prevent material deposition blocking convenient, reliable, efficient;Exhaust purifier is multistage, efficiently complete heat transfer, mass transfer, gas-liquid separation effect are especially good, effectively prevents the leakage of ammonia, realizes the environmental protection of copper mine chemical combination leaching and automatical and efficient, with important using value.
Description
Technical field
The present invention relates to a kind of efficient chemical combination leaching device of environmental type copper mine.
Background technology
It is that, in the form of copper sulfide, copper sulfide is molten in the ammonia of suitable concentration that copper mine in nature has quite a few
In liquid, there are enough air to blast(Mainly oxygen participates in reaction), copper-amine complex can be formed and dissolved, complete chemical combination simultaneously
Leaching after dissolving, then carry out solid-liquid separation to carry out next step operation.
Therefore, the chemical combination leaching device of copper mine is the requisite key equipment of process for copper processed, but existing copper mine chemical combination
There are two big defects in leaching device, so as to constrain the development of copper technology processed.One insufficient and inconvenient, the air that is that air is blasted
(Oxygen)Mix insufficient contact with ore pulp, leaching agent, the chemical combination leaching velocity of copper sulfide is slow, efficiency is low, need to increase special
Air blast equipment, increase equipment investment, also cause unnecessary trouble;Two is that ammonia is easily leaked, as ammonia is with height
Zest, volatile toxic and harmful, thus effect on environment is very big, also very big to the loss of ammonia, but if using close
Hull closure is reacted, and not only cost of investment is high, is also easy to cause the security incidents such as blast.
Therefore, if can design a kind of air it is automatically convenient blast, ammonia is not easy leakage, and be not the copper mine of pressure vessel
Efficient chemical combination leaching device, then with important actual application value.
The content of the invention
The technical problem to be solved in the present invention is exactly to overcome the deficiencies in the prior art, there is provided a kind of simple and practical, empty
Gas is automatically convenient to be blasted, ammonia is not easy leakage, and be not the efficient chemical combination leaching device of environmental type copper mine of pressure vessel.
To overcome the deficiencies in the prior art, the present invention to take technical scheme below:
A kind of efficient chemical combination leaching device of environmental type copper mine, including chemical combination leaching barrel and exhaust purifier, its feature
It is:The intervalve of chemical combination leaching barrel and exhaust purifier is detachably connected by flange, exhaust purifier by overflow pipe and
Return liquid inclined tube to be linked back chemical combination leaching barrel;Chemical combination leaching barrel is provided with manhole, liquid feed valve and heating jacket, and stirring motor passes through hollow axle
Insert in chemical combination leaching barrel after connection cone cover, in cone cover, be provided with blade and inlet opening, hollow axle top has axle circumference uniform distribution open-minded
Air inlet, hollow axle bottom have axle sleeve rise dynamic state limit and stable support function, be provided with chemical combination leaching barrel surge disk and its
Axle sleeve, the disk that surges connect auger conveyor by axle, and auger conveyor is on bottom valve;Chuck is provided with outside exhaust purifier and leads to cold
But water or chilled water, inside are provided with that open intervalve is jacket structured with the helical fin cylinder composition of closing, and helical fin cylinder is
Inwall welding helical fin is formed, and the gap of helical fin cylinder and exhaust purifier inwall is provided with packing layer, and exhaust purifier goes out
Mouth is provided with cyclone, and cyclone is formed by connecting by spinning disk with outer tube for axis.
The heating jacket is provided with heating agent inlet pipe and outlet pipe.
The tail gas recycle device chuck is provided with coolant inlet pipe and outlet pipe.
The core of the design is exactly that chemical combination leaching barrel is detachably connected by flange with exhaust purifier.
Chemical combination leaching barrel has heating jacket, operates the solid-phase materials such as certain liquid level, copper-sulphide ores by opening people
The removable cover in hole is added, and the liquid phase material such as ammonia is added by liquid feed valve control, and stirring motor connects impeller cone by hollow axle
Cover, hollow axle top have the air inlet that axle circumference uniform distribution is opened, and bottom has axle sleeve to play dynamic state limit and stable support function.Surge
Disk connects auger conveyor, countershaft dynamic support of axle sleeve and Stabilization by axle, and bottom valve plays discharge control action.
Impeller cone cover connection hollow axle is driven by motor and is rotated at a high speed, and inlet opening feed liquor is accelerated to be centrifuged by blade, along cone cover
Inner surface movement, is thrown away by boring shroud rim, so can be produced high speed liquid flow in upper speed cone cover and be produced then vacuum, so
Large quantity of air is drawn in mixed liquor stream by vacuum along hollow axle by air inlet, is thrown away by boring shroud rim, realizes that gas liquid high-efficiency is mixed
Close and air(Oxygen)Supply.In addition, liquid stream drives the disk that surges by the vanelets that effect is surged on disk, the disk that surges is driven by axle
Dynamic auger conveyor, effectively prevents from boring the deposition of substrate material and blocking.
The logical steam of heating jacket or hot water realize heat temperature raising, can also lead to cold water and be lowered the temperature, and the gas for overflowing liquid level is same
When can carry vapor, ammonia and become tail gas, gaseous mixture is realized reclaiming and tail gas clean-up by exhaust purifier, it is to avoid ammonia is let out
Leakage.
Exhaust purifier has chuck lead to cooling water or chilled water, and intervalve is jacket structured with helical fin cylinder composition,
Overflow gas and top is risen to again by the downward water conservancy diversion of helical fin cylinder by intervalve, due to having spiral wing in helical fin cylinder
Piece, can be realized guiding rotation, produce downward helical air flow path, overflowed by helical fin cylinder lower edge to gas in interlayer
And packing layer is passed through, and overflowing from liquid level and rise, air-flow is forced cyclone by spinning disk effect in cyclone, effectively can be centrifuged point
From the liquid phase that may wherein carry, discharge gas is made to realize purification, liquid phase meeting automatic dipping wall is flowed back downwards.
The clean-up effect of exhaust purifier depends on overcoming difficulties the heat and mass transport for carrying out, the wherein controlled overflow pipe of liquid level
Position, many rear overflow pipes of condensed fluid can overflow, returning liquid inclined tube can effectively prevent return slag from blocking, chilled water and tail gas in chuck
In depurator, liquid phase has very high overall heat-transfer coefficient, and in exhaust purifier, liquid is good as temperature and gas overflowing can be produced
Automatic stirring convection circulation, helical fin cylinder have bigger gas phase side heat exchange area, while subsurface liquid phase efficiently can be passed
Heat, realizes cooling ammonia condensing to gas phase in cylinder, and the cryogenic gas that ullage point is spilled off realizes gas phase pre-cooling in cylinder;Spiral wing
In piece cylinder, swirling eddy can promote heat and mass transfer with effective disturbance air film, carry out one-level cooling, condensation, gas-liquid separation, then
The heat and mass transfer of two grades of directly contacts is realized through filler liquid phase layer, realizes that ammonia efficiently catches, ascending vapor is finally in eddy flow
Realize cyclonic separation in device once again, make emission reach purification and require.
The design adopts basic closed interlayer pot chemical combination leaching system, then supporting tail gas recycle ammonia, larger in air capacity
In the case of, condensation and the efficient recovery of ammonia are realized, while completing tail gas clean-up discharge.Exist in incoagulable gas in a large number and serious
In the case of affecting condensing interface heat and mass transport state, the high-efficiency condensation for realizing ammonia catches.
Compared with prior art, beneficial effects of the present invention are also resided in:
Chemical combination leaches atmosphere in the tub(Oxygen)Supplement because negative pressure is automatically drawn into, contact fully with serosity immixture, chemical combination
Leaching efficiency is high;The disk that surges is driven to prevent material deposition blocking convenient, reliable, efficient with auger conveyor by liquid stream;Tail gas
Depurator is multistage, efficiently complete heat transfer, mass transfer, gas-liquid separation effect are especially good, effectively prevents the leakage of ammonia.
The present invention realizes the environmental protection of copper mine chemical combination leaching and automatical and efficient, with weight by above Integration ofTechnology
The using value wanted.
Description of the drawings
Fig. 1 is the planar structure schematic diagram of the present invention
Fig. 2 is the three dimensional structure diagram of impeller cone cover.
Fig. 3 is the three dimensional structure diagram of disk of surging.
Fig. 4 is the three dimensional structure diagram of cyclone.
Fig. 5 is helical fin bobbin mouth three dimensional structure diagram.
Fig. 6 is helical fin cylinder section view three dimensional structure diagram.
In figure, each label is represented:
A, impeller cone cover;B, surge disk;C, cyclone;D, helical fin cylinder;1st, stirring motor;2nd, air inlet;3rd, manhole;
4th, liquid feed valve;5th, chemical combination leaching barrel;6th, hollow axle;7th, liquid level in chemical combination leaching barrel;8th, heating agent inlet pipe;9th, heating jacket;10th, it is empty
Heart axle axle sleeve;11st, heating agent outlet pipe;12nd, dish axle of surging set;13rd, auger conveyor;14th, bottom valve;15th, return liquid inclined tube;21st, tail gas
Depurator;22nd, coolant outlet pipe;23rd, exhaust purifier liquid level;24th, overflow pipe;25th, freeze chuck;26th, flow spiral path;
27th, filler;28th, intervalve;29th, coolant inlet pipe;31st, cone cover;32nd, inlet opening;33rd, blade;34th, hollow axis hole;35th, surge
Disk;36th, surge disk vanelets;37th, spinning disk;38th, axis;39th, outer tube;40th, helical fin.
Specific embodiment
In conjunction with accompanying drawing, the present invention is further elaborated with.
As shown in Figure 1, Figure 2, the efficient chemical combination leaching device of environmental type copper mine shown in Fig. 3, Fig. 4, Fig. 5 and Fig. 6, including chemical combination
The intervalve 28 of leaching barrel 5 and exhaust purifier 21, chemical combination leaching barrel 5 and exhaust purifier 21 is detachably connected by flange,
Exhaust purifier 21 is by overflow pipe 24 and returns liquid inclined tube 15 and is linked back chemical combination leaching barrel 5;Chemical combination leaching barrel 5 is provided with manhole 3, feed liquor
Valve 4 and heating jacket 9, stirring motor 1 are provided with cone cover 31 by inserting in chemical combination leaching barrel 5 after the connection cone of hollow axle 6 cover 31
Blade 33 and inlet opening 32,6 top of hollow axle have the air inlet 2 that axle circumference uniform distribution is opened, and hollow axle axle sleeve is arranged at 6 bottom of hollow axle
10 dynamic state limits and stable support function, are provided with surge disk 35 and its dish axle of surging set 12 in chemical combination leaching barrel 5, surge disk 35
Auger conveyor 13 is connected by axle, auger conveyor 13 is on bottom valve 14;Freezing chuck 25 is provided with outside exhaust purifier 21
Logical cooling water or chilled water, inside are provided with open intervalve 28 and constitute jacket structured, spiral wing with the helical fin cylinder D of closing
Piece cylinder D is that inwall welding helical fin 40 is formed, and the gap of 21 inwall of helical fin cylinder D and exhaust purifier is provided with filler 27,
The outlet of exhaust purifier 21 is provided with cyclone C, and cyclone C is formed by connecting by spinning disk 37 with outer tube for axis 38.
The heating jacket 9 is provided with heating agent inlet pipe 8 and heating agent outlet pipe 11.
The tail gas recycle device chuck is provided with coolant inlet pipe 29 and coolant outlet pipe 22.
The core of the design is exactly that chemical combination leaching barrel 5 is detachably connected by flange with exhaust purifier 21.
Chemical combination leaching barrel 5 has the solid-phase materials such as the liquid level of heating jacket 9 and certain altitude, copper-sulphide ores by opening manhole
3 removable cover is added, and the liquid phase material such as ammonia is added by the control of liquid feed valve 4, and stirring motor 1 connects impeller by hollow axle 6
Cone cover A, 6 top of hollow axle have the air inlet 2 that axle circumference uniform distribution is opened, and there are 10 dynamic state limits of hollow axle axle sleeve bottom and stablize
Supporting role.The disk B that surges connects auger conveyor 13 by axle, and dish axle of surging covers 12 countershaft dynamic supports and Stabilization,
14 discharge control actions of bottom valve.
Impeller cone cover A connection hollow axles 6 drive rotation at a high speed, 32 feed liquor of inlet opening to be accelerated by blade 33 by stirring motor 1
Centrifugation, along cone 31 inner surface movements of cover, is thrown away by boring 31 edges of cover, so can produce high speed liquid flow in upper speed cone cover 31
Then vacuum is produced, such large quantity of air is drawn in mixed liquor stream by vacuum along hollow axle 6 by air inlet 2, by boring 31 sides of cover
Edge throws away, and realizes gas liquid high-efficiency mixing and air(Oxygen)Supply.In addition, liquid stream is little by acting on the disk that surges that surges on disk B
Blade 36 drives the disk that surges, and the disk B that surges drives auger conveyor 13 by axle, effectively prevents from boring the deposition of substrate material and blocking.
Heating jacket 9 leads to steam or hot water realizes heat temperature raising, can also lead to cold water and be lowered the temperature, and the gas for overflowing liquid level is same
When can carry vapor, ammonia and become tail gas, gaseous mixture is realized reclaiming and tail gas clean-up by exhaust purifier 21, it is to avoid ammonia is let out
Leakage.
Exhaust purifier 21 has freezing chuck 25 lead to cooling water or chilled water, intervalve 28 and helical fin cylinder D structures
Into jacket structured, overflow gas and top is risen to again by the downward water conservancy diversion of helical fin cylinder D by intervalve 28, due to spiral wing
There is helical fin 40 in piece cylinder D, guiding rotation can be realized to gas in interlayer, downward flow spiral path 26 is produced, is led to
Cross helical fin cylinder D lower edges and overflow and pass through filler 27, overflow from exhaust purifier liquid level 23 and rise, air-flow is in cyclone C
By spinning disk 37 effect force cyclone, can effectively centrifugation wherein may carry liquid phase, make discharge gas realize purify,
Liquid phase meeting automatic dipping wall is flowed back downwards.
The clean-up effect of exhaust purifier 21 depends on overcoming difficulties the heat and mass transport for carrying out, wherein exhaust purifier liquid
23 controlled overflow pipe of face, 24 position, many rear overflow pipes 24 of condensed fluid can overflow, to return liquid inclined tube 15 can effectively prevent return slag from blocking up
Plug, in freezing chuck 25, in chilled water and exhaust purifier, liquid phase has very high overall heat-transfer coefficient, in exhaust purifier liquid by
Good automatic stirring convection circulation can be produced in temperature and gas overflowing, helical fin cylinder D has bigger gas phase side heat-transfer surface
Product, while the liquid phase under exhaust purifier liquid level 23 can realize cooling ammonia condensing, tail gas clean-up with efficient heat transfer to gas phase in cylinder
The cryogenic gas being partly spilled off on device liquid level 23 realizes gas phase pre-cooling in cylinder;In helical fin cylinder D, swirling eddy can be effective
Disturbance air film promotes heat and mass transfer, carries out one-level cooling, condensation, gas-liquid separation, is then passed through 27 liquid phase layer of filler and realizes two
The heat and mass transfer of level directly contact, realizes that ammonia efficiently catches, and ascending vapor finally realizes that eddy flow divides in cyclone C once again
From, make emission reach purification require.
Above-mentioned simply presently preferred embodiments of the present invention, not makees any pro forma restriction to the present invention.It is any to be familiar with sheet
The technical staff in field, in the case of without departing from technical solution of the present invention scope, all using the technology contents of the disclosure above
Many possible variations and modification, or the Equivalent embodiments for being revised as equivalent variations are made to technical solution of the present invention.Therefore, it is all
It is the content without departing from technical solution of the present invention, any simply repaiies to made for any of the above embodiments according to the technology of the present invention essence
Change, equivalent variations and modification, all should fall in the range of technical solution of the present invention protection.
Claims (3)
1. the efficient chemical combination leaching device of a kind of environmental type copper mine, including chemical combination leaching barrel and exhaust purifier, its feature exist
In:The intervalve of chemical combination leaching barrel and exhaust purifier is detachably connected by flange, and exhaust purifier is by overflow pipe and returns
Liquid inclined tube is linked back chemical combination leaching barrel;Chemical combination leaching barrel is provided with manhole, liquid feed valve and heating jacket, and stirring motor is connected by hollow axle
Insert after connecing cone cover in chemical combination leaching barrel, in cone cover, be provided with blade and inlet opening, hollow axle top has what axle circumference uniform distribution was opened
Air inlet, hollow axle bottom have axle sleeve to play dynamic state limit and stable support function, and surge disk and its axle are provided with chemical combination leaching barrel
Set, the disk that surges connect auger conveyor by axle, and auger conveyor is on bottom valve;The logical cooling of chuck is provided with outside exhaust purifier
Water or chilled water, it is jacket structured with the helical fin cylinder composition closed that inside is provided with open intervalve, and helical fin cylinder is interior
Wall welding helical fin is formed, and the gap of helical fin cylinder and exhaust purifier inwall is provided with packing layer, exhaust purifier outlet
Cyclone is provided with, cyclone is formed by connecting by spinning disk with outer tube for axis.
2. the efficient chemical combination leaching device of environmental type copper mine according to claim 1, it is characterised in that:The heating jacket
It is provided with heating agent inlet pipe and outlet pipe.
3. the efficient chemical combination leaching device of environmental type copper mine according to claim 1 or claim 2, it is characterised in that:The tail gas
Depurator chuck is provided with coolant inlet pipe and outlet pipe.
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CN201510637661.XA CN105087917B (en) | 2015-10-07 | 2015-10-07 | The efficient chemical combination leaching device of environmental type copper mine |
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CN201510637661.XA CN105087917B (en) | 2015-10-07 | 2015-10-07 | The efficient chemical combination leaching device of environmental type copper mine |
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CN105087917B true CN105087917B (en) | 2017-03-29 |
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RU2187567C1 (en) * | 2001-08-22 | 2002-08-20 | Общество с ограниченной ответственностью "МАГОЛОС" | Apparatus for electrochemical leaching of precious metals from sludge and concentrates |
CN201520793U (en) * | 2009-08-27 | 2010-07-07 | 浙江华友钴业股份有限公司 | NPT ammonia leached copper device |
CN201598320U (en) * | 2010-01-08 | 2010-10-06 | 厦门紫金矿冶技术有限公司 | Gold-containing copper pyrite reaction device |
CN203075926U (en) * | 2013-02-26 | 2013-07-24 | 长春黄金研究院 | Impeller stirred reactor with self-suction function |
CN103657471B (en) * | 2013-11-27 | 2015-10-28 | 江苏浩特隆搅拌设备有限公司 | Rubbish fermentation special-purpose stirring machine |
CN203990638U (en) * | 2014-08-20 | 2014-12-10 | 潍坊科技学院 | Cathode electrophoresis dope reaction unit |
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Effective date of registration: 20191106 Address after: 314100 Room 204, No.158 Yaozhuang Avenue, Yaozhuang Town, Jiashan County, Jiaxing City, Zhejiang Province Patentee after: Jiashan Yaozhuang modern service industry comprehensive development Co., Ltd Address before: 416000 Hunan, Xiangxi Tujia and Miao Autonomous Prefecture, Jishou City People's road, No. 120 Patentee before: Jishou University |