CN105087918B - The efficient chemical combination leaching device of ammonia No leakage formula copper mine - Google Patents

The efficient chemical combination leaching device of ammonia No leakage formula copper mine Download PDF

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Publication number
CN105087918B
CN105087918B CN201510637662.4A CN201510637662A CN105087918B CN 105087918 B CN105087918 B CN 105087918B CN 201510637662 A CN201510637662 A CN 201510637662A CN 105087918 B CN105087918 B CN 105087918B
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chemical combination
exhaust purifier
combination leaching
ammonia
hollow shaft
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CN201510637662.4A
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CN105087918A (en
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刘志雄
银永忠
陈义光
罗青梅
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Jiashan Weitang Asset Management Co ltd
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Jishou University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

The invention discloses a kind of efficient chemical combination leaching device of ammonia No leakage formula copper mine, chemical combination leaching barrel and exhaust purifier are connected by flange;Stirring motor is provided with blade and inlet opening by being inserted after hollow shaft connection cone cover in chemical combination leaching barrel in cone cover, the air inlet that axle circumference uniform distribution is opened is arranged at hollow shaft top, and chemical combination leaching barrel is interior to be passed on the external bottom valve of staving provided with inlet and return tube;Exhaust purifier outside is provided with chuck, and inside is jacket structured provided with intervalve and helical fin cylinder composition, and exhaust purifier outlet is provided with cyclone.Chemical combination of the present invention leaches atmosphere in the tub(Oxygen)Automatic convenient, the liquid stream immixture of supplement improves abundant, and chemical combination leaching efficiency is very high;Prevent material deposition from blocking convenient, reliable, efficient;Exhaust purifier is multistage, efficiently complete heat transfer, mass transfer, gas-liquid separation effect are especially good, effectively prevents the leakage of ammonia, environmental protection that copper mine chemical combination leaches is realized and automatical and efficient, with important application value.

Description

The efficient chemical combination leaching device of ammonia No leakage formula copper mine
Technical field
The present invention relates to a kind of efficient chemical combination leaching device of ammonia No leakage formula copper mine.
Background technology
Copper mine in nature is that in the form of copper sulfide, copper sulfide is molten in the ammonia of suitable concentration with the presence of quite a few In liquid, there are enough air to blast(Mainly oxygen participates in reaction), copper-amine complex can be formed and dissolved, chemical combination is completed simultaneously Next step process can be carried out by leaching after dissolving, then carrying out separation of solid and liquid.
Therefore, the chemical combination leaching device of copper mine is the essential key equipment of process for copper processed, but existing copper mine chemical combination There are two big defects in leaching device, so as to constrain the development of copper technology processed.One is that air blasts insufficient and inconvenience, air (Oxygen)Mix insufficient contact with ore pulp, leaching agent, the chemical combination leaching velocity of copper sulfide is slow, efficiency is low, it is necessary to which it is special to increase Air blast equipment, increase equipment investment, also cause unnecessary trouble;Two be that ammonia is easily leaked, because ammonia is that have height Excitant, volatile toxic and harmful gas, thus effect on environment is very big, also very big to the loss of ammonia, but if using close Hull closure is reacted, and not only cost of investment is high, is also easy to trigger the security incidents such as blast.
Therefore, if can design a kind of air it is automatic it is convenient blast, ammonia is not easy to leak and be not the copper mine of pressure vessel Efficient chemical combination leaching device, then with important actual application value.
The content of the invention
The technical problem to be solved in the present invention is exactly to overcome the deficiencies in the prior art there is provided one kind is simple and practical, empty Gas it is automatic it is convenient blast, ammonia is not easy to leak and be not the efficient chemical combination leaching device of ammonia No leakage formula copper mine of pressure vessel.
To overcome the deficiencies in the prior art, the present invention takes following technical scheme:
A kind of efficient chemical combination leaching device of ammonia No leakage formula copper mine, including chemical combination leaching barrel and exhaust purifier, it is characterised in that: The intervalve of chemical combination leaching barrel and exhaust purifier is detachably connected by flange, and exhaust purifier is oblique by overflow pipe and time liquid Pipe is linked back chemical combination leaching barrel;Chemical combination leaching barrel is provided with manhole, liquid feed valve and heating jacket, and stirring motor is connected by hollow shaft and bored Inserted after cover in chemical combination leaching barrel, be provided with blade and inlet opening in cone cover, the air inlet that axle circumference uniform distribution is opened is arranged at hollow shaft top Mouthful, hollow shaft bottom has axle sleeve to play dynamic state limit and stable support function, and chemical combination leaching barrel is interior to be worn provided with inlet and return tube Go out on the external bottom valve of staving;Lead to cooling water or chilled water provided with chuck outside exhaust purifier, inside is provided with open intervalve Constituted with the helical fin of closing cylinder jacket structured, helical fin cylinder forms for inwall welding helical fin, helical fin cylinder and The gap of exhaust purifier inwall is provided with packing layer, and exhaust purifier outlet is provided with cyclone, and cyclone is that axis leads to outer barrel Spinning disk is crossed to be formed by connecting.
The heating jacket is provided with heating agent inlet pipe and outlet pipe.
The tail gas recycle device chuck is provided with refrigerant inlet pipe and outlet pipe.
The core of the design is exactly that chemical combination leaching barrel is detachably connected with exhaust purifier by flange.
Chemical combination leaching barrel has a heating jacket, operates certain liquid level, and the solid-phase material such as copper-sulphide ores is by opening people The removable cover in hole is added, and the liquid phase material such as ammonia controls to add by liquid feed valve, and stirring motor connects impeller by hollow shaft and bored The air inlet that axle circumference uniform distribution is opened is arranged at cover, hollow shaft top, and bottom has axle sleeve to play dynamic state limit and stable support function, bottom valve Play discharge control action.
Impeller cone cover connection hollow shaft is driven by motor to be rotated at a high speed, and inlet opening feed liquor is accelerated to centrifuge by blade, along cone cover Inner surface movement, is thrown away by boring shroud rim, and so high speed liquid flow can be produced in upper speed cone cover then produces vacuum, so Large quantity of air pulls in mixed liquor stream along hollow shaft by air inlet by vacuum, is thrown away by boring shroud rim, realizes that gas liquid high-efficiency is mixed Close and air(Oxygen)Supply.Liquid stream can be collected by inlet simultaneously, be backflowed by return tube, formed bottom and gushed Stream, effectively prevents from boring deposition and the blocking of substrate material.
Heating jacket leads to steam or hot water realizes heat temperature raising, can also lead to cold water and be cooled, and the gas for overflowing liquid level is same When can carry vapor, ammonia as tail gas, gaseous mixture passes through exhaust purifier is realized and reclaims and tail gas clean-up, it is to avoid ammonia is let out Leakage.
Exhaust purifier has chuck to lead to cooling water or chilled water, and intervalve and helical fin cylinder composition are jacket structured, Overflow gas and top is risen to again by the downward water conservancy diversion of helical fin cylinder by intervalve, due to having spiral wing in helical fin cylinder Piece, guiding rotation can be realized to gas in interlayer, downward helical air flow path is produced, and overflowed by helical fin cylinder lower edge And through packing layer, overflow and rise from liquid level, air-flow is forced cyclone in cyclone by spinning disk effect, can effectively be centrifuged point From the liquid phase that may wherein carry, discharge gas is set to realize purification, liquid phase meeting automatic dipping wall flows back downwards.
The clean-up effect of exhaust purifier depends on overcoming difficulties the heat and mass transport of progress, the wherein controlled overflow pipe of liquid level Position, many rear overflow pipes of condensate liquid can overflow, returning liquid inclined tube effectively can prevent return slag from blocking, chilled water and tail gas in chuck Liquid phase has liquid in very high overall heat-transfer coefficient, exhaust purifier good because temperature and gas overflowing can be produced in clarifier Automatic stirring convection circulation, helical fin cylinder has bigger gas phase side heat exchange area, while subsurface liquid phase can be passed efficiently Heat, cooling ammonia condensing is realized to gas phase in cylinder, and the cryogenic gas that ullage point is spilled off realizes gas phase precooling in cylinder;Spiral wing Swirling eddy can promote heat and mass transfer with effective disturbance air film in piece cylinder, carry out one-level cooling, condensation, gas-liquid separation, then Two grades of heat and mass transfers directly contacted are realized through filler liquid phase layer, realize that ammonia is efficiently caught, ascending vapor is finally in eddy flow Cyclonic separation is realized in device once again, emission is reached that purification is required.
The design is larger in air capacity using basic closed interlayer pot chemical combination leaching system, then supporting tail gas recycle ammonia In the case of, the condensation and effectively recovery of ammonia are realized, while completing tail gas clean-up discharge.Largely exist and serious in incoagulable gas In the case of influenceing condensing interface heat and mass transport state, the high-efficiency condensation for realizing ammonia is caught.
Compared with prior art, beneficial effects of the present invention are also resided in:
Chemical combination leaches atmosphere in the tub(Oxygen)Supplement is automatically drawn into because of negative pressure, is contacted fully with slurries immixture, chemical combination is leached Efficiency high;By producing cone ground swell stream by return tube after collection liquid stream, prevent material deposition from blocking especially convenient, reliable, efficient; Exhaust purifier multistage, efficiently completion heat transfer, mass transfer, gas-liquid separation effect are especially good, effectively prevent the leakage of ammonia.
The present invention realizes the environmental protection of copper mine chemical combination leaching and automatical and efficient, with weight by above Integration ofTechnology The application value wanted.
Brief description of the drawings
Fig. 1 is the planar structure schematic diagram of the present invention
Fig. 2 is the three dimensional structure diagram of impeller cone cover.
Fig. 3 is the three dimensional structure diagram of cyclone.
Fig. 4 is helical fin bobbin mouthful three dimensional structure diagram.
Fig. 5 is helical fin cylinder section view three dimensional structure diagram.
Each label is represented in figure:
A, impeller cone cover;C, cyclone;D, helical fin cylinder;1st, stirring motor;2nd, air inlet;3rd, manhole;4th, liquid feed valve;5th, change Close leaching barrel;6th, hollow shaft;7th, liquid level in chemical combination leaching barrel;8th, heating agent inlet pipe;9th, heating jacket;10th, hollow shaft axle sleeve;11、 Heating agent outlet pipe;12nd, inlet;13rd, return tube;14th, bottom valve;15th, liquid inclined tube is returned;21st, exhaust purifier;22nd, refrigerant outlet pipe; 23rd, exhaust purifier liquid level;24th, overflow pipe;25th, chuck is freezed;26th, flow spiral path;27th, filler;28th, intervalve;29、 Refrigerant inlet pipe;31st, cone cover;32nd, inlet opening;33rd, blade;37th, spinning disk;38th, axis;39th, outer barrel;40th, helical fin.
Embodiment
In conjunction with accompanying drawing, the present invention is further elaborated with.
As shown in Figure 1, Figure 2, the efficient chemical combination leaching device of the formula copper mine of ammonia No leakage shown in Fig. 3, Fig. 4 and Fig. 5, including chemical combination are leached The intervalve 28 of bucket 5 and exhaust purifier 21, chemical combination leaching barrel 5 and exhaust purifier 21 is detachably connected by flange, tail gas Clarifier 21 is by overflow pipe 24 and returns liquid inclined tube 15 and is linked back chemical combination leaching barrel 5;Chemical combination leaching barrel 5 is provided with manhole 3, liquid feed valve 4 With heating jacket 9, stirring motor 1 is by the way that in insertion chemical combination leaching barrel 5 after the connection cone of hollow shaft 6 cover 31, leaf is provided with cone cover 31 The air inlet 2 that axle circumference uniform distribution is opened is arranged at piece 33 and inlet opening 32, the top of hollow shaft 6, and hollow shaft axle sleeve 10 is arranged at the bottom of hollow shaft 6 Dynamic state limit and stable support function are played, chemical combination leaching barrel 5 is interior to pass the external bottom valve of staving provided with inlet 12 and return tube 13 On 14;The outside of exhaust purifier 21 leads to cooling water or chilled water provided with freezing chuck 25, inside provided with open intervalve 28 with The helical fin cylinder D compositions of closing are jacket structured, and helical fin cylinder D is that inwall welding helical fin 40 is formed, helical fin cylinder D Filler 27 is provided with the gap of the inwall of exhaust purifier 21, the outlet of exhaust purifier 21 is provided with cyclone C, and cyclone C is axis 38 are formed by connecting with outer barrel by spinning disk 37.
The heating jacket 9 is provided with heating agent inlet pipe 8 and heating agent outlet pipe 11.
The tail gas recycle device chuck is provided with refrigerant inlet pipe 29 and refrigerant outlet pipe 22.
The core of the design is exactly that chemical combination leaching barrel 5 is detachably connected with exhaust purifier 21 by flange.
Chemical combination leaching barrel 5 has a liquid level of heating jacket 9 and certain altitude, and the solid-phase material such as copper-sulphide ores is by opening manhole 3 removable cover is added, and the liquid phase material such as ammonia controls to add by liquid feed valve 4, and stirring motor 1 connects impeller by hollow shaft 6 The air inlet 2 that axle circumference uniform distribution is opened arranged at cone cover A, the top of hollow shaft 6, bottom have 10 dynamic state limits of hollow shaft axle sleeve with stably Supporting role, 14 discharge control actions of bottom valve.
Impeller cone cover A connections hollow shaft 6 is driven by stirring motor 1 to be rotated at a high speed, and the feed liquor of inlet opening 32 is accelerated by blade 33 Centrifugation, along cone 31 inner surface movements of cover, is thrown away by boring 31 edges of cover, high speed liquid flow can be so produced in upper speed cone cover 31 Then vacuum is produced, such large quantity of air pulls in mixed liquor stream along hollow shaft 6 by air inlet 2 by vacuum, by boring 31 sides of cover Edge is thrown away, and realizes gas liquid high-efficiency mixing and air(Oxygen)Supply.Liquid stream can be collected by inlet 12 simultaneously, by backflowing Pipe 13 is backflowed, and is formed bottom and is shoved, and effectively prevents from boring deposition and the blocking of substrate material.
Heating jacket 9 leads to steam or hot water realizes heat temperature raising, can also lead to cold water and be cooled, and the gas for overflowing liquid level is same When can carry vapor, ammonia as tail gas, gaseous mixture passes through exhaust purifier 21 is realized and reclaims and tail gas clean-up, it is to avoid ammonia is let out Leakage.
Exhaust purifier 21 has freezing chuck 25 to lead to cooling water or chilled water, intervalve 28 and helical fin cylinder D structures Into jacket structured, overflow gas and top is risen to again by the helical fin cylinder downward water conservancy diversion of D by intervalve 28, due to spiral wing There is helical fin 40 in piece cylinder D, guiding rotation can be realized to gas in interlayer, downward flow spiral path 26 is produced, leads to Cross helical fin cylinder D lower edges to overflow and pass through filler 27, overflow and rise from exhaust purifier liquid level 23, air-flow is in cyclone C Cyclone is forced by the effect of spinning disk 37, the liquid phase that may wherein carry can be effectively centrifuged, discharge gas is realized purification, Liquid phase meeting automatic dipping wall flows back downwards.
The clean-up effect of exhaust purifier 21 depends on overcoming difficulties the heat and mass transport of progress, wherein exhaust purifier liquid The controlled position of overflow pipe 24 in face 23, many rear overflow pipes 24 of condensate liquid can overflow, to return liquid inclined tube 15 can effectively prevent return slag from blocking up In plug, freezing chuck 25 in chilled water and exhaust purifier liquid phase have in very high overall heat-transfer coefficient, exhaust purifier liquid by Good automatic stirring convection circulation can be produced in temperature and gas overflowing, helical fin cylinder D has bigger gas phase side heat-transfer surface Product, while the liquid phase under exhaust purifier liquid level 23 can realize cooling ammonia condensing, tail gas clean-up to gas phase in cylinder with efficient heat transfer The cryogenic gas being partly spilled off on device liquid level 23 realizes gas phase precooling in cylinder;Swirling eddy can be effective in helical fin cylinder D Disturb air film and promote heat and mass transfer, carry out one-level cooling, condensation, gas-liquid separation, be then passed through the liquid phase of filler 27 layer and realize two The heat and mass transfer that level is directly contacted, realizes that ammonia is efficiently caught, and ascending vapor finally realizes eddy flow point once again in cyclone C From, make emission reach purification require.
Above-mentioned simply presently preferred embodiments of the present invention, not makees any formal limitation to the present invention.It is any to be familiar with sheet The technical staff in field, in the case where not departing from technical solution of the present invention scope, all using the technology contents of the disclosure above Many possible variations and modification are made to technical solution of the present invention, or is revised as the equivalent embodiment of equivalent variations.Therefore, it is all It is the content without departing from technical solution of the present invention, any is simply repaiied to made for any of the above embodiments according to the technology of the present invention essence Change, equivalent variations and modification, all should fall in the range of technical solution of the present invention protection.

Claims (3)

1. a kind of efficient chemical combination leaching device of ammonia No leakage formula copper mine, including chemical combination leaching barrel and exhaust purifier, its feature exist In:The intervalve of chemical combination leaching barrel and exhaust purifier is detachably connected by flange, and exhaust purifier is by overflow pipe and returns Liquid inclined tube is linked back chemical combination leaching barrel;Chemical combination leaching barrel is provided with manhole, liquid feed valve and heating jacket, and stirring motor is connected by hollow shaft Connect after cone cover in insertion chemical combination leaching barrel, be provided with blade and inlet opening in cone cover, hollow shaft top has what axle circumference uniform distribution was opened Air inlet, hollow shaft bottom has axle sleeve to play dynamic state limit and stable support function, and chemical combination leaching barrel is interior to be provided with inlet and backflow Pipe is passed on the external bottom valve of staving;Exhaust purifier outside leads to cooling water or chilled water provided with chuck, and inside is provided with opening Between pipe with closing helical fin cylinder constitute it is jacket structured, helical fin cylinder for inwall weld helical fin form, helical fin The gap of cylinder and exhaust purifier inwall is provided with packing layer, and exhaust purifier outlet is provided with cyclone, and cyclone is axis and outer Cylinder is formed by connecting by spinning disk.
2. the efficient chemical combination leaching device of ammonia No leakage formula copper mine according to claim 1, it is characterised in that:The heating jacket Provided with heating agent inlet pipe and outlet pipe.
3. the efficient chemical combination leaching device of ammonia No leakage formula copper mine according to claim 1 or claim 2, it is characterised in that:The tail gas Clarifier chuck is provided with refrigerant inlet pipe and outlet pipe.
CN201510637662.4A 2015-10-07 2015-10-07 The efficient chemical combination leaching device of ammonia No leakage formula copper mine Active CN105087918B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001239139A (en) * 2000-03-02 2001-09-04 Nippon Mining & Metals Co Ltd Agitation device and method for copper-removing leaching by using the same
CN200966940Y (en) * 2006-10-30 2007-10-31 大庆油田有限责任公司 Cyclonic turning back type separating apparatus
CN102961940A (en) * 2012-11-20 2013-03-13 邢学军 Gas-liquid separator combining centrifugal separation, baffle plate and filter
CN103657471A (en) * 2013-11-27 2014-03-26 江苏浩特隆搅拌设备有限公司 Special stirring machine for garbage fermentation
CN104174506A (en) * 2014-09-05 2014-12-03 吉首大学 Rotor-wing floating brush mineral flotation machine
CN203990638U (en) * 2014-08-20 2014-12-10 潍坊科技学院 Cathode electrophoresis dope reaction unit

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001239139A (en) * 2000-03-02 2001-09-04 Nippon Mining & Metals Co Ltd Agitation device and method for copper-removing leaching by using the same
CN200966940Y (en) * 2006-10-30 2007-10-31 大庆油田有限责任公司 Cyclonic turning back type separating apparatus
CN102961940A (en) * 2012-11-20 2013-03-13 邢学军 Gas-liquid separator combining centrifugal separation, baffle plate and filter
CN103657471A (en) * 2013-11-27 2014-03-26 江苏浩特隆搅拌设备有限公司 Special stirring machine for garbage fermentation
CN203990638U (en) * 2014-08-20 2014-12-10 潍坊科技学院 Cathode electrophoresis dope reaction unit
CN104174506A (en) * 2014-09-05 2014-12-03 吉首大学 Rotor-wing floating brush mineral flotation machine

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Effective date of registration: 20191105

Address after: Room 2, west of the second floor, No. 355, Huanbei West Road, Weitang street, Jiashan County, Jiaxing City, Zhejiang Province

Patentee after: Jiashan Weitang Asset Management Co.,Ltd.

Address before: 416000 Hunan, Xiangxi Tujia and Miao Autonomous Prefecture, Jishou City People's road, No. 120

Patentee before: Jishou University

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Denomination of invention: Ammonia leak free high efficiency combined leaching device for copper ore

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Pledgee: Weitang sub branch of Zhejiang Jiashan Rural Commercial Bank Co.,Ltd.

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Denomination of invention: An ammonia leak free high-efficiency copper ore leaching device

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