CN105082453A - Technique for processing durable rubber plate - Google Patents

Technique for processing durable rubber plate Download PDF

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Publication number
CN105082453A
CN105082453A CN201510358500.7A CN201510358500A CN105082453A CN 105082453 A CN105082453 A CN 105082453A CN 201510358500 A CN201510358500 A CN 201510358500A CN 105082453 A CN105082453 A CN 105082453A
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CN
China
Prior art keywords
rubber
plate
rubber plate
durable
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510358500.7A
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Chinese (zh)
Inventor
项志才
孙宝林
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Anhui Shun Chi Cable Co Ltd
Original Assignee
Anhui Shun Chi Cable Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Shun Chi Cable Co Ltd filed Critical Anhui Shun Chi Cable Co Ltd
Priority to CN201510358500.7A priority Critical patent/CN105082453A/en
Publication of CN105082453A publication Critical patent/CN105082453A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0053Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/1418Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/02Electrophoretic coating characterised by the process with inorganic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0053Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
    • B29C2045/0079Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping applying a coating or covering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/1418Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure
    • B29C2045/14237Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure the inserts being deformed or preformed outside the mould or mould cavity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a technique for processing a durable rubber plate. The technique for processing the durable rubber plate comprises the following technological steps of nanoscale micropore surface treatment of an aluminum-manganese alloy plate, preparation of a rubber compound, injection molding, surface Teflon processing and the like. According to the technique for processing the durable rubber plate, aluminum-manganese alloy and the rubber compound are used as main materials, the aluminum-manganese alloy is used as the reinforcing material of rubber, and the bendability of the rubber plate is guaranteed through the main component which is aluminum; the hardness of the rubber plate is guaranteed by adding manganese, so that the rubber plate is more durable, and the original excellent performance of the rubber plate is not affected; the elasticity of the rubber compound obtained through a special technique is improved, the thermogenesis of the rubber compound is reduced, and the abrasion resistance of the rubber compound is improved; Teflon processing is conducted on the surface of the rubber, Teflon materials are non-viscous, slideable, and resistant to humidity and corrosion and have other excellent properties, the rubber plate also has the excellent characteristics when the Teflon materials are grafted on the rubber plate, and accordingly the performance of the rubber plate is more excellent, and the application range of the rubber plate is wider.

Description

A kind of processing technology of durable rubber plate
Technical field
The present invention relates to rubber field, be specifically related to a kind of processing technology of durable rubber plate.
Background technology
Rubber slab system is by elastomeric compound shaping or extrusion molding through calender lamination, make with vulcanizing press sulfuration or with drum vulcanizer continuous vulcanization, be widely used in the fields such as industrial and mining enterprises, traffic and transportation sector and house earth surface, as O-ring seal, rubber cushion, door and window strip of paper used for sealing and the laying aspect such as workbench and floor, therefore the performance optimizing rubber slab will benefit a lot of field, very necessary.Invention describes a kind of processing technology of durable rubber plate, main material is done with alumal and elastomeric compound, alumal is as the reinforcing material of rubber, main component aluminium ensure that the flexible of offset plate, add manganese and ensure that its hardness, its original premium properties can not be affected while making offset plate more durable, and increase with the elastomeric compound elasticity that special process obtains, heat-dissipating reduces, wearability improves, more durable than common elastomeric compound, injection moulding is carried out after nanometer level microporous surface treatment is carried out to alumal, make between aluminium alloy and rubber in conjunction with firm, not easily separated, and can realize plane between aluminium alloy and rubber to plane in conjunction with requirement, Teflon treatment process is carried out to rubber surface, Teflon material itself has not viscosity, sliding, moisture resistance, mar proof, the performance that corrosion resistance etc. are excellent, this material is grafted on rubber slab and makes rubber slab also be provided with these good characteristics, thus make rubber slab performance more excellent, the scope of application is wider.
Summary of the invention
For the deficiencies in the prior art, the object of the present invention is to provide a kind of processing technology of durable rubber plate.
The technical problem that the present invention solves can realize by the following technical solutions: a kind of processing technology of durable rubber plate, comprises following processing step:
(1) choose smooth surface, up-to-standard alumal plate, carry out nanometer level microporous surface treatment after cleaning is clean, then alloy sheets is fixed on the hanger with electrode, utilizes described hanger alloy sheets to be put into Fe (OH) 3in colloidal solution, electrolytic treatments 10 ~ 30s is carried out in energising, puts into NaOH solution immersion 20 ~ 40s that concentration is 2 ~ 8%, put into NH that concentration be 3 ~ 10% after taking out from NaOH solution again after taking-up 4100 ~ 150s is cleaned, from NH in Cl solution 4put into pure water cleaning three times after taking out in Cl solution again, in pure water after cleaning, take out alloy sheets and it is dried, namely complete alumal plate surface and carry out nanometer level microporous surface treatment;
(2) rubber compositions such as natural rubber, carbon black, white carbon, ethoxyquinoline, vulcanization accelerator, rubber filling oil, heat vulcanizate, epoxy resin are carried out one section or the mixing formation elastomeric compound of multistage, then electron irradiation is carried out to this elastomeric compound, with make in elastomeric compound in conjunction with glue content improve more than 10%, thus obtain offset plate use rubber raw materials;
(3) rubber raw materials step (2) obtained is at a certain temperature after dry certain hour, put into the barrel of rubber injection machine, then in injector, hot runner mould is installed, after injection parameters is set, utilizing injector to carry out injection moulding by carrying out the alumal plate after nanometer level microporous surface treatment with surface in step (1) after described rubber raw materials sulfuration, is the combination rubber slab of rubber parcel alumal plate structure after shaping.
(4) molded rubber plate air drying step (3) obtained, evaporation of solvent, then be the Teflon solution of 0.04 ~ 0.1g/ml to rubber surface even application concentration with flush coater, by the rubber slab after spraying, first put into hothouse natural drying, vapor away organic solvent, then put into thermostatic chamber, temperature controls at 90 DEG C ~ 110 DEG C, and time controling is at 10min ~ 10.5min, take out rubber slab after arriving setting-up time, obtain durable rubber board finished product.
Preferably, in described alumal plate, aluminium manganese ratio is 7:1.
Preferably, in described step (2), rubber composition is made up of following weight portion material: natural rubber 1000 parts, carbon black 5 ~ 15 parts, white carbon 10 ~ 20 parts, ethoxyquinoline 5 ~ 15 parts, vulcanization accelerator 5 ~ 15 parts, rubber filling oil 0 ~ 5 part, heat vulcanizate 20 ~ 30 parts, epoxy resin 10 ~ 20 parts.
Beneficial effect is: the present invention is a kind of processing technology of durable rubber plate, main material is done with alumal and elastomeric compound, alumal is as the reinforcing material of rubber, main component aluminium ensure that the flexible of offset plate, add manganese and ensure that its hardness, its original premium properties can not be affected while making offset plate more durable, and increase with the elastomeric compound elasticity that special process obtains, heat-dissipating reduces, wearability improves, more durable than common elastomeric compound, injection moulding is carried out after nanometer level microporous surface treatment is carried out to alumal, make between aluminium alloy and rubber in conjunction with firm, not easily separated, and can realize plane between aluminium alloy and rubber to plane in conjunction with requirement, Teflon treatment process is carried out to rubber surface, Teflon material itself has not viscosity, sliding, moisture resistance, mar proof, the performance that corrosion resistance etc. are excellent, this material is grafted on rubber slab and makes rubber slab also be provided with these good characteristics, thus make rubber slab performance more excellent, the scope of application is wider.
Detailed description of the invention
The following detailed description of the preferred embodiment of the present invention.
The detailed description of the invention of the processing technology of a kind of durable rubber of the present invention plate: a kind of processing technology of durable rubber plate, comprise following processing step: (1) chooses smooth surface, up-to-standard alumal plate, nanometer level microporous surface treatment is carried out after cleaning is clean, then alloy sheets is fixed on the hanger with electrode, described hanger is utilized alloy sheets to be put into Fe (OH) 3 colloidal solution, electrolytic treatments 10 ~ 30s is carried out in energising, NaOH solution immersion 20 ~ 40s that concentration is 2 ~ 8% is put into after taking-up, NH4Cl solution cleaning 100 ~ 150s that concentration is 3 ~ 10% is put into again after taking out from NaOH solution, pure water cleaning three times is put into again after taking out from NH4Cl solution, in pure water after cleaning, take out alloy sheets to dry it, namely complete alumal plate surface and carry out nanometer level microporous surface treatment, (2) rubber compositions such as natural rubber, carbon black, white carbon, ethoxyquinoline, vulcanization accelerator, rubber filling oil, heat vulcanizate, epoxy resin are carried out one section or the mixing formation elastomeric compound of multistage, then electron irradiation is carried out to this elastomeric compound, with make in elastomeric compound in conjunction with glue content improve more than 10%, thus obtain offset plate use rubber raw materials, (3) rubber raw materials step (2) obtained is at a certain temperature after dry certain hour, put into the barrel of rubber injection machine, then in injector, hot runner mould is installed, after injection parameters is set, utilizing injector to carry out injection moulding by carrying out the alumal plate after nanometer level microporous surface treatment with surface in step (1) after described rubber raw materials sulfuration, is the combination rubber slab of rubber parcel alumal plate structure after shaping.(4) molded rubber plate air drying step (3) obtained, evaporation of solvent, then be the Teflon solution of 0.04 ~ 0.1g/ml to rubber surface even application concentration with flush coater, by the rubber slab after spraying, first put into hothouse natural drying, vapor away organic solvent, then put into thermostatic chamber, temperature controls at 90 DEG C ~ 110 DEG C, and time controling is at 10min ~ 10.5min, take out rubber slab after arriving setting-up time, obtain durable rubber board finished product.In described alumal plate, aluminium manganese ratio is 7:1.In described step (2), rubber composition is made up of following weight portion material: natural rubber 1000 parts, carbon black 5 ~ 15 parts, white carbon 10 ~ 20 parts, ethoxyquinoline 5 ~ 15 parts, vulcanization accelerator 5 ~ 15 parts, rubber filling oil 0 ~ 5 part, heat vulcanizate 20 ~ 30 parts, epoxy resin 10 ~ 20 parts.
After above-mentioned processing step, obtain a kind of durable rubber plate, it does main material with alumal and elastomeric compound, alumal is as the reinforcing material of rubber, main component aluminium ensure that the flexible of offset plate, add manganese and ensure that its hardness, its original premium properties can not be affected while making offset plate more durable, and increase with the elastomeric compound elasticity that special process obtains, heat-dissipating reduces, wearability improves, more durable than common elastomeric compound, injection moulding is carried out after nanometer level microporous surface treatment is carried out to alumal, make between aluminium alloy and rubber in conjunction with firm, not easily separated, and can realize plane between aluminium alloy and rubber to plane in conjunction with requirement, Teflon treatment process is carried out to rubber surface, Teflon material itself has not viscosity, sliding, moisture resistance, mar proof, the performance that corrosion resistance etc. are excellent, this material is grafted on rubber slab and makes rubber slab also be provided with these good characteristics, thus make rubber slab performance more excellent, the scope of application is wider.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or the conversion of equivalent flow process, or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.

Claims (3)

1. a processing technology for durable rubber plate, is characterized in that, comprises following processing step:
Choose smooth surface, up-to-standard alumal plate, carry out nanometer level microporous surface treatment after cleaning is clean, then alloy sheets is fixed on the hanger with electrode, utilizes described hanger alloy sheets to be put into Fe (OH) 3in colloidal solution, electrolytic treatments 10 ~ 30s is carried out in energising, puts into NaOH solution immersion 20 ~ 40s that concentration is 2 ~ 8%, put into NH that concentration be 3 ~ 10% after taking out from NaOH solution again after taking-up 4100 ~ 150s is cleaned, from NH in Cl solution 4put into pure water cleaning three times after taking out in Cl solution again, in pure water after cleaning, take out alloy sheets and it is dried, namely complete alumal plate surface and carry out nanometer level microporous surface treatment;
The rubber compositions such as natural rubber, carbon black, white carbon, ethoxyquinoline, vulcanization accelerator, rubber filling oil, heat vulcanizate, epoxy resin are carried out one section or the mixing formation elastomeric compound of multistage, then electron irradiation is carried out to this elastomeric compound, with make in elastomeric compound in conjunction with glue content improve more than 10%, thus obtain offset plate use rubber raw materials;
Rubber raw materials step (2) obtained is at a certain temperature after dry certain hour, put into the barrel of rubber injection machine, then in injector, hot runner mould is installed, after injection parameters is set, utilizing injector to carry out injection moulding by carrying out the alumal plate after nanometer level microporous surface treatment with surface in step (1) after described rubber raw materials sulfuration, is the combination rubber slab of rubber parcel alumal plate structure after shaping;
The molded rubber plate air drying that step (3) is obtained, evaporation of solvent, then be the Teflon solution of 0.04 ~ 0.1g/ml to rubber surface even application concentration with flush coater, by the rubber slab after spraying, first put into hothouse natural drying, vapor away organic solvent, then put into thermostatic chamber, temperature controls at 90 DEG C ~ 110 DEG C, and time controling is at 10min ~ 10.5min, take out rubber slab after arriving setting-up time, obtain durable rubber board finished product.
2. the processing technology of a kind of durable rubber plate according to claim 1, is characterized in that, in described alumal plate, aluminium manganese ratio is 7:1.
3. the processing technology of a kind of durable rubber plate as claimed in claim 1, it is characterized in that, in described step (2), rubber composition is made up of following weight portion material: natural rubber 1000 parts, carbon black 5 ~ 15 parts, white carbon 10 ~ 20 parts, ethoxyquinoline 5 ~ 15 parts, vulcanization accelerator 5 ~ 15 parts, rubber filling oil 0 ~ 5 part, heat vulcanizate 20 ~ 30 parts, epoxy resin 10 ~ 20 parts.
CN201510358500.7A 2015-06-26 2015-06-26 Technique for processing durable rubber plate Pending CN105082453A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510358500.7A CN105082453A (en) 2015-06-26 2015-06-26 Technique for processing durable rubber plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510358500.7A CN105082453A (en) 2015-06-26 2015-06-26 Technique for processing durable rubber plate

Publications (1)

Publication Number Publication Date
CN105082453A true CN105082453A (en) 2015-11-25

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Country Status (1)

Country Link
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103769355A (en) * 2014-01-03 2014-05-07 安吉藤仓橡胶有限公司 Rubber surface Teflon processing technology
CN103788388A (en) * 2014-01-23 2014-05-14 怡维怡橡胶研究院有限公司 Method for improving elasticity and themogenesis performance of rubber product
CN104441406A (en) * 2014-11-28 2015-03-25 兴科电子(东莞)有限公司 In-mould injection moulding process of aluminum shell
CN104530502A (en) * 2014-12-31 2015-04-22 天津市中塘五金橡胶制品有限公司 Rubber material for shock absorbing bushing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103769355A (en) * 2014-01-03 2014-05-07 安吉藤仓橡胶有限公司 Rubber surface Teflon processing technology
CN103788388A (en) * 2014-01-23 2014-05-14 怡维怡橡胶研究院有限公司 Method for improving elasticity and themogenesis performance of rubber product
CN104441406A (en) * 2014-11-28 2015-03-25 兴科电子(东莞)有限公司 In-mould injection moulding process of aluminum shell
CN104530502A (en) * 2014-12-31 2015-04-22 天津市中塘五金橡胶制品有限公司 Rubber material for shock absorbing bushing

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Application publication date: 20151125

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