CN104479224A - Anti-abrasive material for automobiles - Google Patents
Anti-abrasive material for automobiles Download PDFInfo
- Publication number
- CN104479224A CN104479224A CN201410807609.XA CN201410807609A CN104479224A CN 104479224 A CN104479224 A CN 104479224A CN 201410807609 A CN201410807609 A CN 201410807609A CN 104479224 A CN104479224 A CN 104479224A
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- China
- Prior art keywords
- abrasive material
- agent
- automobile anti
- material according
- stabilizer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/10—Peculiar tacticity
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an anti-abrasive material for automobiles. The anti-abrasive material is prepared from raw materials in parts by weight as follows: isotactic polypropylene, rutile type titanium dioxide, linear low-density polyethylene, nanometer calcium sulfate, a POE elastomer, an antioxidant 1010, zinc stearate, zinc oxide, coumarone, an accelerator DM, ABS high-rubber powder, triallylisocyanurate, glycerol trioleate and an additive, wherein the additive is prepared from raw materials in parts by weight as follows: clay, an antibacterial agent, a flame retardant, a coupling agent, a heat stabilizer and a stiffening agent. The rigidity of the anti-abrasive material for the automobiles is improved, and the flame retardance and the water resistance of the anti-abrasive material are improved; meanwhile, the material has the high thermal deformation temperature, the low friction coefficient and the anti-abrasive capacity, is firm and durable, can satisfy specific use environment conditions and has a broad market application prospect.
Description
Technical field
The present invention relates to Material Field, particularly relate to a kind of automobile anti-abrasive material.
Background technology
Along with the development of automobile industry, people are to the comfortableness of automobile, security, aesthetic property, the requirement of the use propertieies such as energy saving is more and more higher, and improve orthodox car material, it is the fundamental way improving vehicle operation performance, macromolecular automobile plastic material has many outstanding advantages than orthodox car material, quality is light, mechanical property is superior, easy machine-shaping, material can reuse, also there is remarkable attractive, decorative effect, but also there are some shortcomings in these macromolecular materials, such as rigidity is poor, easy burning, non-refractory low temperature aging etc., therefore, in order to improve the performance of conventional polymer material, widen materials'use scope, need to improve original automotive plastic formula, modification is carried out to material, each position of automobile can be widely used in.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of automobile anti-abrasive material.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of automobile anti-abrasive material, comprise and being made up of the raw material of following weight part: isotatic polypropylene 80-90, Rutile type Titanium Dioxide 15-20, linear low density polyethylene 20-25, nanometer calcium sulfate 13-16, POE elastomerics 18-20, antioxidant 1010 1.5-2.5, Zinic stearas 3-4, zinc oxide 5-7, coumarone 2-3, altax 0.5-1.5, ABS high glue powder 11-14, cyanacrylate 5-6, glycerol glycerinate 13-14, auxiliary agent 8-10, described auxiliary agent is made up of the raw material of following weight part: clay 8-10, antiseptic-germicide 5-6, fire retardant 7-11, coupling agent 2-3, thermo-stabilizer 2-3 and Stiffening agent 8-12.
In a preferred embodiment of the present invention, described antiseptic-germicide is nano silver inorganic antimicrobial agent.
In a preferred embodiment of the present invention, described fire retardant is pentaerythritol bisphosphorate melamine salt.
In a preferred embodiment of the present invention, described coupling agent is silane coupling A-151.
In a preferred embodiment of the present invention, described thermo-stabilizer is liquid calcium zinc stabilizer.
In a preferred embodiment of the present invention, the main component of described liquid calcium zinc stabilizer comprises calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil and UV light absorber.
In a preferred embodiment of the present invention, described Stiffening agent is M221-series polypropylenes Stiffening agent.
The invention has the beneficial effects as follows: a kind of automobile anti-abrasive material of the present invention, this anti-abrasive material adds its rigidity, its fire-retardant and block-water performance very high, this material has that heat-drawn wire is high, frictional coefficient is low and anti abrasive ability simultaneously, durable, can meet specific environment for use condition, market application foreground is wide.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
The embodiment of the present invention comprises: a kind of automobile anti-abrasive material, comprise and being made up of the raw material of following weight part: isotatic polypropylene 85, Rutile type Titanium Dioxide 16, linear low density polyethylene 23, nanometer calcium sulfate 13, POE elastomerics 18, antioxidant 1010 2, Zinic stearas 3, zinc oxide 5, coumarone 2.5, altax 1, ABS high glue powder 12, cyanacrylate 5, glycerol glycerinate 14, auxiliary agent 10, nylon 6 has superior over-all properties, comprise physical strength, rigidity, toughness, mechanical shock absorption and wear resistance, these characteristics, add good electrical isolation capabilities and chemical resistant properties, nylon 6 is made to become a kind of " general purpose grade " material, for mechanical structure parts and can the manufacture of maintenance parts.
Described auxiliary agent is made up of the raw material of following weight part: clay 9, antiseptic-germicide 6, fire retardant 9, coupling agent 3, thermo-stabilizer 2 and Stiffening agent 10.
Described antiseptic-germicide is nano silver inorganic antimicrobial agent, but this nano silver inorganic antimicrobial agent efficiently can kill bacterium, security is high, thermotolerance is good, tool broad-spectrum antimicrobial effect, be applicable to PP, PE, PET, PPR, PET, the film of the materials such as PBT, moulding, this product silver content is 3.0%, addition is 0.5% ~ 0.7%, to all kinds of Gram-negative bacteria, gram-positive microorganism, fungi onset, to comprising intestinal bacteria, streptococcus aureus, Candida albicans, Klebsiella pneumonia, but Pseudomonas aeruginosa etc. interior to have more than 600 kinds of mushrooms excellent kill effect, there is the overlength lasting period, goods can be made to have permanent germ resistance, heat resisting temperature > 500oC.
Described fire retardant is pentaerythritol bisphosphorate melamine salt, acid source, carbon source and source of the gas are combined in a molecule by pentaerythritol bisphosphorate melamine salt, fundamentally solve each component in fire retardant material and distribute uneven problem, be more conducive to the synergistic effect playing phosphorus, nitrogen.
Described coupling agent is silane coupling A-151, and silane coupling A-151 has the effect of coupling agent and linking agent concurrently, and applicable polymer type has polyethylene, polypropylene, unsaturated polyester etc., is usually used in glass, plastics, glass, cable, pottery, rubber etc.
Described thermo-stabilizer is liquid calcium zinc stabilizer, the main component of described liquid calcium zinc stabilizer comprises calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil and UV light absorber, liquid calcium zinc stabilizer has larger solubleness usually, there is good dispersiveness, powder stablizer is far smaller than on the impact of transparency.
Described Stiffening agent is M221-series polypropylenes Stiffening agent, M221-series polypropylenes Stiffening agent can promote polyacrylic modulus in flexure (rigidity) within the specific limits, and do not affect other performances, and for client saves the cost reaching 3-12% in overall performance cost compare.
Compared with prior art, a kind of automobile anti-abrasive material of the present invention, this anti-abrasive material adds its rigidity, its fire-retardant and block-water performance very high, this material has that heat-drawn wire is high, frictional coefficient is low and anti abrasive ability simultaneously, durable, can meet specific environment for use condition, market application foreground is wide.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (7)
1. an automobile anti-abrasive material, comprise and being made up of the raw material of following weight part: isotatic polypropylene 80-90, Rutile type Titanium Dioxide 15-20, linear low density polyethylene 20-25, nanometer calcium sulfate 13-16, POE elastomerics 18-20, antioxidant 1010 1.5-2.5, Zinic stearas 3-4, zinc oxide 5-7, coumarone 2-3, altax 0.5-1.5, ABS high glue powder 11-14, cyanacrylate 5-6, glycerol glycerinate 13-14, auxiliary agent 8-10, is characterized in that:
Described auxiliary agent is made up of the raw material of following weight part: clay 8-10, antiseptic-germicide 5-6, fire retardant 7-11, coupling agent 2-3, thermo-stabilizer 2-3 and Stiffening agent 8-12.
2. a kind of automobile anti-abrasive material according to claim 1, is characterized in that: described antiseptic-germicide is nano silver inorganic antimicrobial agent.
3. a kind of automobile anti-abrasive material according to claim 1, is characterized in that: described fire retardant is pentaerythritol bisphosphorate melamine salt.
4. a kind of automobile anti-abrasive material according to claim 1, is characterized in that: described coupling agent is silane coupling A-151.
5. a kind of automobile anti-abrasive material according to claim 1, is characterized in that: described thermo-stabilizer is liquid calcium zinc stabilizer.
6. a kind of automobile anti-abrasive material according to claim 5, is characterized in that: the main component of described liquid calcium zinc stabilizer comprises calcium stearate, ricinolic acid calcium, Zinic stearas, zinc ricinate and epoxy soybean oil and UV light absorber.
7. a kind of automobile anti-abrasive material according to claim 1, is characterized in that: described Stiffening agent is M221-series polypropylenes Stiffening agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410807609.XA CN104479224A (en) | 2014-12-23 | 2014-12-23 | Anti-abrasive material for automobiles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410807609.XA CN104479224A (en) | 2014-12-23 | 2014-12-23 | Anti-abrasive material for automobiles |
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CN104479224A true CN104479224A (en) | 2015-04-01 |
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CN201410807609.XA Pending CN104479224A (en) | 2014-12-23 | 2014-12-23 | Anti-abrasive material for automobiles |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105328586A (en) * | 2015-10-09 | 2016-02-17 | 芜湖市鸿坤汽车零部件有限公司 | Composite calcium-based resin grinding wheel and manufacturing method thereof |
CN106147491A (en) * | 2016-07-11 | 2016-11-23 | 潘明华 | A kind of wear-resistant antibacterial nano paint and preparation method thereof |
CN108659350A (en) * | 2018-06-19 | 2018-10-16 | 平湖市浩鑫塑胶有限公司 | A kind of plastic bottle material and preparation method thereof |
CN109253321A (en) * | 2018-09-20 | 2019-01-22 | 重庆共启科技有限公司 | A kind of antibiotic self-cleaning PPR pipe |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103319787A (en) * | 2013-07-01 | 2013-09-25 | 南京理工大学常熟研究院有限公司 | Polypropylene (PP) material for automobile bumper |
CN103467851A (en) * | 2013-09-11 | 2013-12-25 | 成都硕屋科技有限公司 | Halogen-free flame-retardant PP (polypropylene) fiber material capable of replacing flame-retardant ABS (acrylonitrile-butadiene-styrene) and preparation method of halogen-free flame-retardant PP fiber material |
CN104109288A (en) * | 2014-07-30 | 2014-10-22 | 芜湖长鹏汽车零部件有限公司 | Automotive trim composite polypropylene material and preparation method thereof |
-
2014
- 2014-12-23 CN CN201410807609.XA patent/CN104479224A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103319787A (en) * | 2013-07-01 | 2013-09-25 | 南京理工大学常熟研究院有限公司 | Polypropylene (PP) material for automobile bumper |
CN103467851A (en) * | 2013-09-11 | 2013-12-25 | 成都硕屋科技有限公司 | Halogen-free flame-retardant PP (polypropylene) fiber material capable of replacing flame-retardant ABS (acrylonitrile-butadiene-styrene) and preparation method of halogen-free flame-retardant PP fiber material |
CN104109288A (en) * | 2014-07-30 | 2014-10-22 | 芜湖长鹏汽车零部件有限公司 | Automotive trim composite polypropylene material and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105328586A (en) * | 2015-10-09 | 2016-02-17 | 芜湖市鸿坤汽车零部件有限公司 | Composite calcium-based resin grinding wheel and manufacturing method thereof |
CN106147491A (en) * | 2016-07-11 | 2016-11-23 | 潘明华 | A kind of wear-resistant antibacterial nano paint and preparation method thereof |
CN108659350A (en) * | 2018-06-19 | 2018-10-16 | 平湖市浩鑫塑胶有限公司 | A kind of plastic bottle material and preparation method thereof |
CN109253321A (en) * | 2018-09-20 | 2019-01-22 | 重庆共启科技有限公司 | A kind of antibiotic self-cleaning PPR pipe |
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