CN105071063B - A kind of soft graphite is combined earthing material anticorrosion connection method - Google Patents
A kind of soft graphite is combined earthing material anticorrosion connection method Download PDFInfo
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- CN105071063B CN105071063B CN201510247690.5A CN201510247690A CN105071063B CN 105071063 B CN105071063 B CN 105071063B CN 201510247690 A CN201510247690 A CN 201510247690A CN 105071063 B CN105071063 B CN 105071063B
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- fluid sealant
- mould
- soft graphite
- metal
- hollow mould
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000010439 graphite Substances 0.000 title claims abstract description 41
- 229910002804 graphite Inorganic materials 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 18
- 239000012530 fluid Substances 0.000 claims abstract description 31
- 239000000565 sealant Substances 0.000 claims abstract description 31
- 239000002184 metal Substances 0.000 claims abstract description 30
- 229910052751 metal Inorganic materials 0.000 claims abstract description 30
- 230000008878 coupling Effects 0.000 claims abstract description 8
- 238000010168 coupling process Methods 0.000 claims abstract description 8
- 238000005859 coupling reaction Methods 0.000 claims abstract description 8
- 229920006305 unsaturated polyester Polymers 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims description 6
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims 1
- 239000004645 polyester resin Substances 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 14
- 230000007797 corrosion Effects 0.000 abstract description 13
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 238000005253 cladding Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
- 206010063900 Steal syndrome Diseases 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- -1 graphite Compound Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Abstract
A kind of soft graphite is combined earthing material anticorrosion connection method, the coupling part of soft graphite and metal is positioned in hollow mould by methods described, fluid sealant is injected into mould cavity by the inlet above mould, and solidify, after the demoulding, the coupling part of soft graphite and metal is isolated so as to realize with external environment condition by fluid sealant tight enclosing.Hollow mould is by hollow mould top half（1）With hollow mould the latter half（2）Composition, two parts constitute complete hollow mould after merging, and form mould inside cavity（7）, wherein hollow mould top half has fluid sealant inlet（3）, fluid sealant inlet connects with mould inside cavity.The inventive method is simple and easy to operate, realize that the junction cladding of soft graphite and metal is sealed, completely cut off with corrosive environment, effectively suppress the compound corrosion between earthing material and metal of soft graphite, so as to solve bottleneck problem of the Flexible Graphite Composites in ground connection application aspect.
Description
Technical field
Earthing material anticorrosion connection method, category power ground aseptic technic neck are combined the present invention relates to a kind of soft graphite
Domain.
Background technology
For a long time, domestic and international Ground Network of Transmission Line with Renovation generally uses the metal class earthing materials such as band steel, stainless steel, copper,
And galvanized steel, stainless steel Baogang, copper covered steel metallic ground material containing electroplated metal layer, except transport and difficulty of construction are big, easy
Beyond generation steal phenomenon, the maximum bottleneck problem of metallic ground material is the corrosion of earthing material.
Soft graphite is combined earthing material, and there is acid-alkali-corrosive-resisting, non-corrosive, heavy current impact not to strike back, grounding resistance is steady
It is fixed, water-fast, high-low temperature resistant, the advantages of service life is long, connection is without electrically welding, and light weight is easy to construct and transported, therefore
Soft graphite is combined earthing material and increasingly paid attention to by engineers and technicians.However, in actual applications, soft graphite
Compound earthing material often needs segmentation to connect or need to be connected with metal material, in junction it occur frequently that serious corrosion, leads
Resistance rise even open circuit is sent a telegraph, so as to seriously limit application of the Flexible Graphite Composites in ground connection field.
The compound earthing material connection of soft graphite uses added metal sleeve pipe and crimped.It is soft under natural environment
Property graphite and metal occur galvanic corrosion, graphite is used as anode as negative electrode, metal.When galvanic corrosion occurs, metal erosion speed
Corrosion rate when rate is than metal individualism is much faster.In addition, its surface area is much larger than anode as the soft graphite of negative electrode
Metal surface area, anode and cathode area is than bigger, and galvanic corrosion is more serious.
The content of the invention
The purpose of the present invention is that being combined earthing material there is provided a kind of soft graphite for the defect that prior art is present prevents
Rotten connection method, can effectively suppress the corrosion between graphite earthing material and metal, exist so as to solve Flexible Graphite Composites
It is grounded the bottleneck problem of application aspect.
Technical scheme：
The present invention coupling part of soft graphite and metal is positioned in hollow mould, fluid sealant by mould above
Inlet is injected into mould cavity, and is solidified, after the demoulding, and the coupling part of soft graphite and metal is closely wrapped by fluid sealant
Envelope, isolates, antiseptic effect is notable so as to realize with external environment condition.
The principle of the present invention is that corrosion occurs under environmental attack, if can isolate erosion environment, corrosion will not
Can occur；The junction of soft graphite and metal is coated by encapsulating using fluid sealant, so as to isolate the corruption such as water, gas, soil
Environment is lost, etch-proof purpose is reached.
The hollow mould of the inventive method, is made up of, two parts hollow mould top half and hollow mould the latter half
Complete hollow mould is constituted after merging, and forms mould inside cavity, wherein hollow mould top half has fluid sealant injection
Mouthful, fluid sealant inlet is connected with mould inside cavity.
The coupling part of soft graphite and metal in the inventive method, refers specifically to metal connecting piece and soft graphite is combined and connect
The part of ground material connection.Soft graphite connection uses added metal sleeve pipe and crimped, and galvanic corrosion is notable herein.
Fluid sealant in the inventive method, refers to anti-corrosion fluid sealant, it is unsaturated poly- that the present invention provides two kinds of batch preparations of A, B
The method of ester fluid sealant is so as to the implementation of the present invention, and wherein A fluid sealants are with 307#（Or 306#）Unsaturated polyester (UP) and 182# are not
Saturated polyester is major ingredient, is produced by auxiliary material of reinforcing agent, initiator and accelerator, and B fluid sealants are poly- to be modified 191# unsaturations
Ester resin is major ingredient, is produced using initiator and accelerator as auxiliary material.
Brief description of the drawings
Fig. 1 is hollow mould structural representation of the present invention；
Fig. 2 is soft graphite connection diagram of the present invention；
Fig. 3 is that soft graphite of the present invention connects schematic perspective view；
Fig. 4 is hollow mould upper and lower mould matched moulds schematic diagram of the present invention；
Fig. 5 is soft graphite connection diagram of the present invention；
Fig. 6 is Fig. 5 sectional view；
In figure, 1 is hollow mould top half；2 be hollow mould the latter half；3 be fluid sealant inlet；4 be sealing
Glue；5 be metal connecting piece；6 be that soft graphite is combined earthing material；7 be mould inside cavity.
Embodiment
The present invention is described in further detail with reference to embodiment.
Hollow mould in the present embodiment is made up of hollow mould top half 1 and hollow mould the latter half 2, two parts
Complete hollow mould is constituted after merging, and forms mould inside cavity 7, wherein hollow mould top half 1 has fluid sealant note
Entrance 3, fluid sealant inlet 3 is connected with mould inside cavity 7.The coupling part of soft graphite and metal, refers specifically to metal company
Fitting 5 and soft graphite are combined the part that earthing material 6 is connected.Soft graphite connection uses added metal sleeve pipe and pressed
Connect, galvanic corrosion is notable herein.
In present embodiment, fluid sealant compounding method is as follows：
Embodiment one
The present embodiment A fluid sealants mainly include following proportionings（Pbw）；
307#（Or 306#）Unsaturated polyester (UP)：80
182# unsaturated polyester (UP)s：20
200 mesh silica flours：100~120
Cyclohexanone peroxide（Initiator）：2~4
Cobalt naphthenate（Accelerator）：2~4
Polyester, silica flour are stirred by formula, initiator is added and stirs well, finally add accelerator, side edged is stirred, until
Untill stirring.It is put into after the junction of soft graphite and metal is dried into processing with hot blast in mould, then uses F types
Clamp hollow mould, the fluid sealant prepared is injected in mould inside cavity 7 from inlet 3, can be taken off after 15 ~ 20min
Mould.
Embodiment two
The present embodiment B fluid sealants mainly include following proportionings（Volume ratio part）；
Modified 191# unsaturated polyester resins：100
Cyclohexanone peroxide（Initiator）：1~2
Cobalt naphthenate（Accelerator）：0.5~2
Initiator is added by formula and stirred well in polyester, finally adds accelerator, side edged is stirred, untill stirring.
It is put into after the junction hot blast of soft graphite and metal is dried into processing in mould, will then with F type clamp moulds
The fluid sealant prepared can be stripped from the injection mould inside of inlet 3 cavity 7 after 15 ~ 20min.
Present invention has the advantages that：The inventive method is simple and easy to operate, realizes that the junction of soft graphite and metal is wrapped
Sealing is covered, is completely cut off with corrosive environment, effectively suppresses the compound corrosion between earthing material and metal of soft graphite, so as to solve soft
Property graphite composite material ground connection application aspect bottleneck problem.
Implementation illustrating only for the embodiment of the present invention recited above, is not carried out to protection scope of the present invention
Limit, any modifications, equivalent substitutions and improvements made on the premise of design concept of the present invention is not departed from etc. should be included in
Protection scope of the present invention.
Claims (3)
1. a kind of soft graphite is combined earthing material anticorrosion connection method, it is characterised in that methods described by soft graphite with
The coupling part of metal is positioned in hollow mould, and fluid sealant is injected into mould cavity by the inlet above mould, and
Solidification, after the demoulding, the coupling part of soft graphite and metal by fluid sealant tight enclosing so that realize with external environment condition every
From；The fluid sealant includes fluid sealant A or fluid sealant B；
The preparation method of the fluid sealant A is as follows：
Prepare material by following mass ratio：
307# unsaturated polyester (UP)s：80；
182# unsaturated polyester (UP)s：20；
200 mesh silica flours：100~120；
Cyclohexanone peroxide：2~4；
Cobalt naphthenate：2~4；
Unsaturated polyester (UP), silica flour are stirred by formula, initiator cyclohexanone peroxide is added and stirs well, finally add accelerator
Cobalt naphthenate, side edged is stirred, untill stirring.
2. a kind of soft graphite is combined earthing material anticorrosion connection method according to claim 1, it is characterised in that described
Fluid sealant B preparation method is as follows：
Prepare material by following mass ratio：
Modified 191# unsaturated polyester resins：100；
Cyclohexanone peroxide：1~2；
Cobalt naphthenate：0.5~2；
Initiator cyclohexanone peroxide is added by formula and stirred well in polyester resin, finally adds accelerator cobalt naphthenate, side edged
Stir, untill stirring.
3. a kind of soft graphite is combined earthing material anticorrosion connection method according to claim 1, it is characterised in that described
The application method of fluid sealant is：It is put into after the junction hot blast of soft graphite and metal is dried into processing in mould, then
With F type clamp moulds, by the fluid sealant prepared from inlet injects mould inside cavity, it can be taken off after 15~20min
Mould.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510247690.5A CN105071063B (en) | 2015-05-15 | 2015-05-15 | A kind of soft graphite is combined earthing material anticorrosion connection method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510247690.5A CN105071063B (en) | 2015-05-15 | 2015-05-15 | A kind of soft graphite is combined earthing material anticorrosion connection method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105071063A CN105071063A (en) | 2015-11-18 |
| CN105071063B true CN105071063B (en) | 2017-08-18 |
Family
ID=54500380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510247690.5A Active CN105071063B (en) | 2015-05-15 | 2015-05-15 | A kind of soft graphite is combined earthing material anticorrosion connection method |
Country Status (1)
| Country | Link |
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| CN (1) | CN105071063B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112768969B (en) * | 2020-12-30 | 2022-06-28 | 哈尔滨工业大学 | Improved lightning protection grounding device for graphite grounding body and preparation method thereof |
| CN112688094A (en) * | 2020-12-31 | 2021-04-20 | 国网河南省电力公司南阳供电公司 | Anti-corrosion down lead structure for lightning protection grounding system |
| CN113555700B (en) * | 2021-07-28 | 2024-04-05 | 河南四达电力设备股份有限公司 | Deep vertical fast-assembled graphite grounding electrode and processing technology thereof |
| CN114300904B (en) * | 2021-12-10 | 2023-12-26 | 国网江西省电力有限公司电力科学研究院 | Corrosion-resistant connecting device for flexible graphite composite grounding material and use method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1347534A2 (en) * | 2002-03-19 | 2003-09-24 | Voest-Alpine Industrieanlagenbau GmbH & Co. | Connection terminal and grounding device |
| CN102967036A (en) * | 2012-11-22 | 2013-03-13 | 山东格瑞德集团有限公司 | Composite end enclosure and processing process |
| CN204189981U (en) * | 2014-10-28 | 2015-03-04 | 武汉大学 | A kind of flexible graphite compound earthing material connects gold utensil |
-
2015
- 2015-05-15 CN CN201510247690.5A patent/CN105071063B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1347534A2 (en) * | 2002-03-19 | 2003-09-24 | Voest-Alpine Industrieanlagenbau GmbH & Co. | Connection terminal and grounding device |
| CN102967036A (en) * | 2012-11-22 | 2013-03-13 | 山东格瑞德集团有限公司 | Composite end enclosure and processing process |
| CN204189981U (en) * | 2014-10-28 | 2015-03-04 | 武汉大学 | A kind of flexible graphite compound earthing material connects gold utensil |
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| Publication number | Publication date |
|---|---|
| CN105071063A (en) | 2015-11-18 |
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