CN105063608A - Metallic nickel-based ceramic coating for low-carbon and medium-carbon steel surfaces, and production method thereof - Google Patents
Metallic nickel-based ceramic coating for low-carbon and medium-carbon steel surfaces, and production method thereof Download PDFInfo
- Publication number
- CN105063608A CN105063608A CN201510450288.7A CN201510450288A CN105063608A CN 105063608 A CN105063608 A CN 105063608A CN 201510450288 A CN201510450288 A CN 201510450288A CN 105063608 A CN105063608 A CN 105063608A
- Authority
- CN
- China
- Prior art keywords
- ceramic coating
- metallic
- nickel
- carbon
- carbon steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
The invention discloses a metallic nickel-based ceramic coating for low-carbon and medium-carbon steel surfaces. According to the metallic nickel-based ceramic coating, metallic nickel is used as a metallic base, a ceramic coating prepared by using the refractory substances of titanium diboride, ferric oxide and the like as ceramic phases is coated on the surface of the base metal, alloy elements in the base metal diffuse towards an interface and carry out the interface reactions specified in the description with the substances of NiO and the like in the coating, and the reduced-precipitated activated nickel atoms form Ni-M metallic bonds with the base metal M, thus improving the adherence between the metallic ceramic coating and the base metal; rare-earth nanometre cerium oxide is capable of enhancing the atomic orbital interaction effect thereof among adsorbed molecules due to high activity, thus improving the wear resistance of the product; and combination of the added ferrous powder and nickel powder is capable of enhancing the permeability of the coating. The metallic ceramic coating prepared by the method disclosed by the invention has rust and corrosion resistance and oxidation resistance, and wide applications in low-carbon and medium-carbon steel surfaces.
Description
Technical field
The present invention relates to metal ceramic coating material technical field, be specifically related to a kind of metallic nickel ceramic coating for middle low carbon steel surface and preparation method thereof.
Background technology
Ceramic coating material is the stupalith being subject to extensive concern in recent years, and traditional stupalith has larger fragility, is unfavorable for the further processing of stupalith, also causes stupalith to show slightly not enough in the performance of numerous areas.Metal-ceramic coating is the obdurability that a kind of existing metal is good, has again the compound coating of the advantage such as high temperature resistant, wear-resistant, corrosion-resistant of pottery.Therefore, metal-ceramic coating obtains important application in many fields such as Aeronautics and Astronautics, such as bears at a high speed, that high-temperature fuel gas washes away etc. is complicated, the rocket engine components of bad working environments condition, can obtain effective protection by metallizing ceramic coating.There is many defects such as function singleness cost is high, toughness is little, intensity is low, coatability is poor in actual applications in the metal-ceramic coating prepared in prior art, limit use range and the Application Areas of metal-ceramic coating, be unfavorable for the realization of the target of industry energy conservation Green Development.
Summary of the invention
Object of the present invention is just to provide a kind of metallic nickel ceramic coating for middle low carbon steel surface and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of metallic nickel ceramic coating for middle low carbon steel surface, it is characterized in that, be made up of the raw material of following weight part: nano ceric oxide 14-17, nickel powder 33-45, TiB2 13-16, iron powder 15-18, ferric oxide 16-24, ferro-boron powder 12-14, butyl oleate 9-12, alum ore deposit tailings 17-27, calcium carbonate 8-10, solar oil 6-8, suitable quantity of water.
The preparation method of described a kind of metallic nickel ceramic coating for middle low carbon steel surface, is characterized in that comprising the following steps:
(1) by nano ceric oxide in 650-760 DEG C of pyroprocessing 30-50 minute, rapidly through cooled with liquid nitrogen to room temperature, add calcium carbonate ultrasonic oscillation 20-40 minute, add butyl oleate stirring and evenly mixing, under normal temperature, stir 5-8h, dry to constant weight;
(2) ferric oxide is joined in ball mill, spray into vaporific solar oil and mix thoroughly, add alum ore deposit tailings, carry out ball milling in 340-450 DEG C, mix, break up, obtained modification ferric oxide;
(3) by modification ferric oxide, TiB2 through 1560-1650 DEG C of high-temperature calcination 2-4 hour, cooling adds ferro-boron powder and is ground to 200-300 order;
(4) by step (1), (3) reaction mass stirring and evenly mixing, add nickel powder, iron powder in 1100-1200 DEG C of high-temperature calcination 3-6 hour, be cooled to room temperature, put into grinding in ball grinder 1-2 hour, add suitable quantity of water and be modulated into slip, be coated on dried sample surfaces, seasoning 24h, then 120 DEG C of dry 12h, fire 5min for last 1050 DEG C.
The present invention has following beneficial effect: the present invention selects metallic nickel to be metal matrix, adopt TiB2, the refractory compounds such as ferric oxide are coated in base metal surface as the ceramic coating that ceramic phase is obtained, alloying element in matrix metal can spread to interface, occur with materials such as the NiO in coating: the surface reactions such as NiO+M → MO+Ni, active nickel atom and the matrix metal M of precipitate reduction form Ni-M metallic bond, thus improve the adherence of metal-ceramic coating and matrix metal, and rare earth nano cerium dioxide strengthens it to the atomic orbital interaction between binding molecule due to active high energy, improve the wear resistance of product, the iron powder added is combined the perviousness that can strengthen coating with nickel powder, the metal-ceramic coating utilizing the present invention to obtain has resistant to tarnishing and oxidation-resistance, be widely used on the surface at middle low carbon steel.
Embodiment
Described a kind of metallic nickel ceramic coating for middle low carbon steel surface, it is characterized in that, be made up of the raw material of following weight part: nano ceric oxide 16, nickel powder 39, TiB2 14, iron powder 17, ferric oxide 23, ferro-boron powder 13, butyl oleate 11, alum ore deposit tailings 23, calcium carbonate 8, solar oil 6, suitable quantity of water.
Making method comprises the following steps:
(1) by nano ceric oxide in 650-760 DEG C of pyroprocessing 30-50 minute, rapidly through cooled with liquid nitrogen to room temperature, add calcium carbonate ultrasonic oscillation 20-40 minute, add butyl oleate stirring and evenly mixing, under normal temperature, stir 5-8h, dry to constant weight;
(2) ferric oxide is joined in ball mill, spray into vaporific solar oil and mix thoroughly, add alum ore deposit tailings, carry out ball milling in 340-450 DEG C, mix, break up, obtained modification ferric oxide;
(3) by modification ferric oxide, TiB2 through 1560-1650 DEG C of high-temperature calcination 2-4 hour, cooling adds ferro-boron powder and is ground to 200-300 order;
(4) by step (1), (3) reaction mass stirring and evenly mixing, add nickel powder, iron powder in 1100-1200 DEG C of high-temperature calcination 3-6 hour, be cooled to room temperature, put into grinding in ball grinder 1-2 hour, add suitable quantity of water and be modulated into slip, be coated on dried sample surfaces, seasoning 24h, then 120 DEG C of dry 12h, fire 5min for last 1050 DEG C.
The technical parameter index of the metallic nickel ceramic coating using the present invention to produce is as follows:
(1) corrosion resistant, tack is good, resistance of oxidation is good;
(2) cold-and-heat resistent circulation (room temperature-900 DEG C) ability is good;
(3) initial softening temperature improves 16.4 DEG C;
(4) coating is after tolerance 50 thermal shocks circulation, does not also have obviously peel off in the edges and corners of sample, shows excellent thermal shock resistance.
Claims (2)
1. the metallic nickel ceramic coating for middle low carbon steel surface, it is characterized in that, be made up of the raw material of following weight part: nano ceric oxide 14-17, nickel powder 33-45, TiB2 13-16, iron powder 15-18, ferric oxide 16-24, ferro-boron powder 12-14, butyl oleate 9-12, alum ore deposit tailings 17-27, calcium carbonate 8-10, solar oil 6-8, suitable quantity of water.
2. the making method of a kind of metallic nickel ceramic coating for middle low carbon steel surface according to claim 1, is characterized in that comprising the following steps:
(1) by nano ceric oxide in 650-760 DEG C of pyroprocessing 30-50 minute, rapidly through cooled with liquid nitrogen to room temperature, add calcium carbonate ultrasonic oscillation 20-40 minute, add butyl oleate stirring and evenly mixing, under normal temperature, stir 5-8h, dry to constant weight;
(2) ferric oxide is joined in ball mill, spray into vaporific solar oil and mix thoroughly, add alum ore deposit tailings, carry out ball milling in 340-450 DEG C, mix, break up, obtained modification ferric oxide;
(3) by modification ferric oxide, TiB2 through 1560-1650 DEG C of high-temperature calcination 2-4 hour, cooling adds ferro-boron powder and is ground to 200-300 order;
(4) by step (1), (3) reaction mass stirring and evenly mixing, add nickel powder, iron powder in 1100-1200 DEG C of high-temperature calcination 3-6 hour, be cooled to room temperature, put into grinding in ball grinder 1-2 hour, add suitable quantity of water and be modulated into slip, be coated on dried sample surfaces, seasoning 24h, then 120 DEG C of dry 12h, fire 5min for last 1050 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510450288.7A CN105063608A (en) | 2015-07-29 | 2015-07-29 | Metallic nickel-based ceramic coating for low-carbon and medium-carbon steel surfaces, and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510450288.7A CN105063608A (en) | 2015-07-29 | 2015-07-29 | Metallic nickel-based ceramic coating for low-carbon and medium-carbon steel surfaces, and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105063608A true CN105063608A (en) | 2015-11-18 |
Family
ID=54493105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510450288.7A Pending CN105063608A (en) | 2015-07-29 | 2015-07-29 | Metallic nickel-based ceramic coating for low-carbon and medium-carbon steel surfaces, and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105063608A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135364A (en) * | 2018-09-28 | 2019-01-04 | 桐城市明丽碳化硼制品有限公司 | A kind of blast nozzle wear-resistant coating |
-
2015
- 2015-07-29 CN CN201510450288.7A patent/CN105063608A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135364A (en) * | 2018-09-28 | 2019-01-04 | 桐城市明丽碳化硼制品有限公司 | A kind of blast nozzle wear-resistant coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2719590C (en) | High temperature resistant coating compositions | |
| CN103726009B (en) | A kind of steel surface multi-component alloy co-cementation preservative coat and co-infiltration method thereof | |
| CN105400240B (en) | A kind of phosphate coating for the protection of titanium group high temperature alloy high-temp and preparation method thereof | |
| CN103628055B (en) | A kind of at aluminum or aluminum alloy surface laser cladding Rare-Earth Ce O 2the technique of-Ni60 Alloy Composite Coating | |
| CN100460560C (en) | Process for the preparation of cubic boron nitride material | |
| CN103952661A (en) | Solid zincizing agent and preparation method thereof | |
| CN108485328A (en) | A kind of normal temperature cure inorganic coating, preparation method and coated workpieces | |
| CN103706784A (en) | Agglomerated composite powder for high-temperature abradable seal coating and preparation method thereof | |
| CN105062231A (en) | Wear-resistant metal nickel ceramic coating layer for pot and manufacture method thereof | |
| CN101082091B (en) | Ternary boride ceramet material and preparation method thereof | |
| CN107838417B (en) | A kind of iron Al-based agent diamond tool and preparation method thereof | |
| GB2278122A (en) | Phosphate-stabilised bonding solution comprising vanadium pentoxide, and, optionally, aluminium powder as a sealant | |
| CN105063608A (en) | Metallic nickel-based ceramic coating for low-carbon and medium-carbon steel surfaces, and production method thereof | |
| CN102925890A (en) | Preparation method for corrosion-resistant coating of nickel-aluminum based intermetallic compound | |
| CN108178614A (en) | A kind of preparation method of boron mud base fired brick | |
| CN107267912A (en) | Aluminising protective coating and its preparation method and application | |
| CN105039966A (en) | Anti-tensile metallic nickel ceramic coating and manufacturing method thereof | |
| CN105131657A (en) | High-film forming rate metallic nickel ceramic coating and manufacturing method thereof | |
| CN105057678A (en) | Metal nickel ceramic coating good in high-temperature-cracking-resistant peeling capacity and manufacturing method of metal nickel ceramic coating | |
| CN110306095A (en) | A kind of coating Co-based alloy powder and preparation method thereof | |
| CN105039965A (en) | Metallic nickel ceramic coating with high surface hardness and manufacturing method thereof | |
| CN105088219A (en) | Metal nickel ceramic coating with sound absorption and heat insulation functions and manufacturing method of metal nickel ceramic coating | |
| CN104451657A (en) | Preparation method of ternary boride ceramic/iron-based surface composite material | |
| CN105063610A (en) | Crack-free metal nickel ceramic coating good in coating suitability and manufacturing method thereof | |
| CN105063612A (en) | High-toughness metallic nickel ceramic coating and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151118 |
|
| RJ01 | Rejection of invention patent application after publication |