CN105040421A - Textile material and preparation method thereof - Google Patents
Textile material and preparation method thereof Download PDFInfo
- Publication number
- CN105040421A CN105040421A CN201510528124.1A CN201510528124A CN105040421A CN 105040421 A CN105040421 A CN 105040421A CN 201510528124 A CN201510528124 A CN 201510528124A CN 105040421 A CN105040421 A CN 105040421A
- Authority
- CN
- China
- Prior art keywords
- nano
- washing
- silver ion
- preparation
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a preparation method of a functional sanitary antibacterial material. The preparation method comprises the following steps: diluting 600-900ppm 12-18 nm silver ion agent by 10-12 times by adopting distilled water or purified water, thus preparing a nano-silver solution, soaking a cleaned cotton textile material into the nano-silver solution for crosslinking treatment for 32-38 min, and then taking out the cotton textile material from the solution after the crosslinking treatment, dehydrating and drying, thus preparing the functional sanitary antibacterial material. According to the preparation method, by selecting the proper concentration and grain size of anions and the proper crosslinking treatment, the washing times can be obviously improved, and a nano-antibacterial cotton textile product prepared by the functional sanitary antibacterial material has good bacteria resisting and killing effects after being washed by at least 100 times (each washing process comprises the steps of rubbing with washing powder or soap, rinsing with clean water, spin-drying and airing).
Description
Technical field
The present invention relates to a kind of textile material, be specifically related to a kind of functional sanitary anti-biotic material and preparation method thereof.
Background technology
Due to factors such as the ways of contact between the impact of natural environment and personnel or between personnel and article in daily life, cause growing and polluting of malignant bacteria unavoidably, cause human body diseases, threaten the health of the mankind.With regard to small stores, current phase people often contact the article of particularly dress use and bedding as underwear, bed clothes, the article such as sheet are mostly without sterilization antibacterial treatment, very easily make human body direct infection germ, and existing market all kinds of known living-hygienic article on sale are as sanitary paper towel, antiseptic gauze, although absorbent cotton etc. in the fabrication process will through strict sterilizing process, but in accumulating, sell and still cause unavoidably in use procedure breeding and the pollution of bacterium, therefore also fail to play most effectively antibacterial elimination virus and then ensure the effect of health.
In recent years, based on nano material and nanometer technology to receive the research and development of the modifies macromolecular material of (micro-) ground rice very prosperous, and certain achievement is achieved in the high performance, functionalization of textile product, but how it realizes more perfect combination with mankind's daily living article, be still this area scientific research personnel and need treat to excavate the problem of probing into further.
CN103147271A provides a kind of nanometer and resists antibacterial cotton spinning material and goods thereof, it adopts the product that obtains of following preparation technology: be that silver ion agent distilled water or the pure water of 10 ~ 20 nanometers of 500 ~ 1000ppm makes Nano silver solution with 10 ~ 12 times of dilutions by concentration, cotton spinning material after cleaning is immersed in Nano silver solution and is cross-linked 30 ~ 60 minutes, after crosslinked, cotton spinning material is taken out dewatered drying by solution.This invention advantage: simple science, convenient and easy, small investment, instant effect, combination property and environmental-protecting performance excellent, the release of its product has great significance to the principles and policies implementing the health strategy target of " this century, everybody enjoyed health care " that country proposes and life, medical treatment, health care combine, huge social benefit can be produced, be suitable for numerous manufacturing enterprises such as textile enterprise, knitting enterprise, paper products enterprise and apply.But, after washing 50 times, (once washing counting procedure is the nano-antibacterial cotton spinning underwear product adopting this textile material to obtain: first rub with washing powder or soap, use clear water rinsing again, then thousand are got rid of and airing), keep good antibiotic and sterilizing effect, its washing times 50 times is less, cannot meet actual operation requirements.
Summary of the invention
The object of the invention is to solve prior art Problems existing, and then provide a kind of and there is the bacterium effect of long-acting, broad-spectrum Hangzhoupro and cyclic washing nanometer Hangzhoupro bacterium cotton spinning material often and the series of commodity of sanitation utilizing this material to prepare.
To achieve these goals, present invention employs following technical scheme:
A preparation method for functional sanitary anti-biotic material, said method comprising the steps of:
Be that silver ion agent distilled water or the pure water of 12 ~ 18 nanometers of 600 ~ 900ppm makes Nano silver solution with 10 ~ 12 times of dilutions by concentration, cotton spinning material after cleaning is immersed in Nano silver solution and is cross-linked 32 ~ 38 minutes, after crosslinked, cotton spinning material is taken out dewatered drying by solution, obtain functional sanitary anti-biotic material.
Functional sanitary anti-biotic material after above preparation technology's process is compared with known various plain edition sanitary antimicrobial cotton spinning material so far, there is antibacterial high efficiency, persistence, broad spectrum activity, security, stability and the advantage such as to have no side effect, it takes full advantage of the extra-heavy antibacterial properties of inorganic nano silver ion, ionization is produced between fabric fibre or on fiber, the health of bacterial propagule and various virus is penetrated with the fineness of Nano Silver, make the bacterium of causing a disease and virus cannot produce the Hangzhoupro property of medicine, effectively can stop the flourish of microorganism on textile material, adsorb and eliminate various harmful particulate, reach " trap and go out and remove " effect to the unhelpful material of human body.Due to the cotton spinning material containing nano-silver ionic material, to have health self-cleaning, ageing-resistant, the function such as high temperature resistant, also there is obvious powerful odor-resistant result, containing nano silver ion antibiotic agent in cotton-spinning fabric, through rubbing washing, after the strong External Force Acting such as surface abrasion, the antibacterial action of fabric does not almost still decline, belong to permanent antibacterial cotton fabric material, bacterium can be prevented most effectively, the propagation of virus is infected, guarantee the safety of user or wearer, the purification health level of natural environment and the body health level of the mankind is improved by its excellent self-cleaning effect, thus product of the present invention research and development success also for this area identify take and life textiles upgrade important directions.And, the present invention is by selecting the concentration of suitable anion, particle diameter and crosslinked time, considerably improve its washing times, after washing at least 100 times, (once washing counting procedure is the nano-antibacterial cotton spinning goods adopting this textile material to obtain: first rub with washing powder or soap, use clear water rinsing again, then thousand are got rid of and airing), keep good antibiotic and sterilizing effect.
The commodity made according to above-mentioned functions sex hygiene anti-biotic material can be the various articles with people's close association in daily life, comprise the underwear product of vest, brassiere, underpants, inner shirt, interior underpants, socks, ankle socks, shoe-pad etc., quilt cover, coverlet, sheet, bed leather, cotton blanket, pillow cover, pillowcase, pillow etc. are at interior bedding, gauze, absorbent cotton, bandage, gloves, towel, mouth leather, hygienic cap, bathing cap etc. are at interior amenities, and sanitary napkin, napkin paper, face (perfume) towel paper etc. are at interior paper handkerchief articles for use and other small stores.
The concentration of described silver ion is 600 ~ 900ppm, such as 530ppm, 560ppm, 590ppm, 620ppm, 660ppm, 700ppm, 740ppm, 780ppm, 820ppm, 860ppm, preferably, the concentration of described silver ion is 650 ~ 850ppm.
The particle diameter of described silver ion is 12 ~ 18 nanometers, such as, 13 nanometers, 14 nanometers, 15 nanometers, 16 nanometers, 17 nanometers, preferably 15 ~ 18 nanometers.
The described crosslinked time is 32 ~ 38 minutes, such as 33 minutes, 34 minutes, 35 minutes, 36 minutes or 37 minutes, preferably 35 ~ 38 minutes.
Advantage of the present invention: simple science, convenient and easy, small investment, instant effect, combination property and environmental-protecting performance excellent, the release of its product has great significance to the principles and policies implementing the health strategy target of " this century, everybody enjoyed health care " that country proposes and life, medical treatment, health care combine, huge social benefit can be produced, be suitable for numerous manufacturing enterprises such as textile enterprise, knitting enterprise, paper products enterprise and apply.
In addition, the present invention is by selecting the concentration of suitable anion, particle diameter and crosslinked time, considerably improve its washing times, after washing at least 100 times, (once washing counting procedure is the nano-antibacterial cotton spinning goods adopting this textile material to obtain: first rub with washing powder or soap, use clear water rinsing again, then thousand are got rid of and airing), keep good antibiotic and sterilizing effect.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below by detailed description of the invention.
Detailed description of the invention 1
Prepare the method for nano-antibacterial cotton spinning underwear product as vest, brassiere, trousers power, inner shirt, interior underpants, socks, ankle socks etc.:
Get the silver ion agent that concentration is 12 ~ 18 nanometers of 600 ~ 900ppm, Nano silver solution is made with the distilled water of silver ion agent 10 ~ 12 times amount or pure water dilution, dry after cleaned fabric product is crossed distilled water, then the fabric product after drying is inserted in the Nano silver solution of 50 ~ 60 DEG C, soak 32 ~ 38 minutes, soak after being cross-linked and fabric product is dried by taking out in Nano silver solution, then fabric product drying plant is dried, bake out temperature is 60 ~ 80 DEG C, finally textile article is arranged inspection, packaging warehouse-in.
Detailed description of the invention 2
Prepare the cotton towel products of nano-antibacterial as the method for sanitary napkin, napkin paper, face (perfume) towel paper etc.:
Get the silver ion agent that concentration is 12 ~ 18 nanometers of 600 ~ 900ppm, Nano silver solution is made with the distilled water diluting of silver ion agent 12 times amount, towel products after cleaning to be immersed in the Nano silver solution of 60 ~ 80 DEG C 32 ~ 38 minutes, soak after being cross-linked and towel products is taken out dewatered drying by Nano silver solution, bake out temperature is 70 ~ 100 DEG C, finally sanitary antimicrobial towel products is arranged inspection, packaging warehouse-in.
Embodiment 1
Prepare the method for nano-antibacterial cotton spinning underwear product as vest, brassiere, trousers power, inner shirt, interior underpants, socks, ankle socks etc.:
Get the silver ion agent that concentration is 12 nanometers of 600ppm, Nano silver solution is made with the distilled water of silver ion agent 10 ~ 12 times amount or pure water dilution, dry after cleaned fabric product is crossed distilled water, then the fabric product after drying is inserted in the Nano silver solution of 50 ~ 60 DEG C, soak 32 minutes, soak after being cross-linked and fabric product is dried by taking out in Nano silver solution, then fabric product drying plant is dried, bake out temperature is 60 ~ 80 DEG C, finally textile article is arranged inspection, packaging warehouse-in.
Embodiment 2
Prepare the method for nano-antibacterial cotton spinning underwear product as vest, brassiere, trousers power, inner shirt, interior underpants, socks, ankle socks etc.:
Get the silver ion agent that concentration is 18 nanometers of 900ppm, Nano silver solution is made with the distilled water of silver ion agent 10 ~ 12 times amount or pure water dilution, dry after cleaned fabric product is crossed distilled water, then the fabric product after drying is inserted in the Nano silver solution of 50 ~ 60 DEG C, soak 38 minutes, soak after being cross-linked and fabric product is dried by taking out in Nano silver solution, then fabric product drying plant is dried, bake out temperature is 60 ~ 80 DEG C, finally textile article is arranged inspection, packaging warehouse-in.
Embodiment 3
Prepare the method for nano-antibacterial cotton spinning underwear product as vest, brassiere, trousers power, inner shirt, interior underpants, socks, ankle socks etc.:
Get the silver ion agent that concentration is 16 nanometers of 700ppm, Nano silver solution is made with the distilled water of silver ion agent 10 ~ 12 times amount or pure water dilution, dry after cleaned fabric product is crossed distilled water, then the fabric product after drying is inserted in the Nano silver solution of 50 ~ 60 DEG C, soak 35 minutes, soak after being cross-linked and fabric product is dried by taking out in Nano silver solution, then fabric product drying plant is dried, bake out temperature is 60 ~ 80 DEG C, finally textile article is arranged inspection, packaging warehouse-in.
The above-mentioned nano-antibacterial cotton spinning underwear product of embodiment 1 ~ 3 all has efficiently, long-acting antibiotic and sterilizing effect, product all meets the standard of national health articles for use through relevant department's Check and Inspection, it is to staphylococcus aureus, Escherichia coli, candida albicanses etc. have significantly kills inhibitory action, embodiment 1 and 2 nano-antibacterial cotton spinning underwear product is after washing 100 times, after washing 150 times, (once washing counting procedure is embodiment 3 nano-antibacterial cotton spinning underwear product: first rub with washing powder or soap, use clear water rinsing again, then thousand are got rid of and airing), still keep good antibiotic and sterilizing effect.In addition, the Clinical results through doing about medical department shows, the patient of above-mentioned nanometer Hangzhoupro bacterium cotton spinning underwear product to the disease such as skin disease, athlete's foot also has certain auxiliary therapeutic action.
Embodiment 4
Prepare the cotton towel products of nano-antibacterial as the method for sanitary napkin, napkin paper, face (perfume) towel paper etc.:
Get the silver ion agent that concentration is 12 nanometers of 600ppm, Nano silver solution is made with the distilled water diluting of silver ion agent 12 times amount, towel products after cleaning to be immersed in the Nano silver solution of 60 ~ 80 DEG C 32 minutes, soak after being cross-linked and towel products is taken out dewatered drying by Nano silver solution, bake out temperature is 70 ~ 100 DEG C, finally sanitary antimicrobial towel products is arranged inspection, packaging warehouse-in.
Embodiment 5
Prepare the cotton towel products of nano-antibacterial as the method for sanitary napkin, napkin paper, face (perfume) towel paper etc.:
Get the silver ion agent that concentration is 18 nanometers of 900ppm, Nano silver solution is made with the distilled water diluting of silver ion agent 12 times amount, towel products after cleaning to be immersed in the Nano silver solution of 60 ~ 80 DEG C 38 minutes, soak after being cross-linked and towel products is taken out dewatered drying by Nano silver solution, bake out temperature is 70 ~ 100 DEG C, finally sanitary antimicrobial towel products is arranged inspection, packaging warehouse-in.
Embodiment 6
Prepare the cotton towel products of nano-antibacterial as the method for sanitary napkin, napkin paper, face (perfume) towel paper etc.:
Get the silver ion agent that concentration is 16 nanometers of 700ppm, Nano silver solution is made with the distilled water diluting of silver ion agent 12 times amount, towel products after cleaning to be immersed in the Nano silver solution of 60 ~ 80 DEG C 35 minutes, soak after being cross-linked and towel products is taken out dewatered drying by Nano silver solution, bake out temperature is 70 ~ 100 DEG C, finally sanitary antimicrobial towel products is arranged inspection, packaging warehouse-in.
The above-mentioned nano-antibacterial cotton spinning paper handkerchief of embodiment 4 ~ 6 all has efficiently, long-acting antibiotic and sterilizing effect, product all meets the standard of national health articles for use through relevant department's Check and Inspection, it is to staphylococcus aureus, Escherichia coli, candida albicanses etc. have significantly kills inhibitory action, embodiment 4 and 5 nano-antibacterial cotton spinning towel products is after washing 100 times, after washing 150 times, (once washing counting procedure is embodiment 6 nano-antibacterial cotton spinning towel products: first rub with washing powder or soap, use clear water rinsing again, then thousand are got rid of and airing), still keep good antibiotic and sterilizing effect.In addition, the Clinical results through doing about medical department shows, the patient of above-mentioned nanometer Hangzhoupro bacterium cotton spinning towel products to the disease such as skin disease, athlete's foot also has certain auxiliary therapeutic action.
Comparative example 1
Comparative example 1 is embodiment 1 disclosed in CN103147271A.
Comparative example 2
Comparative example 2 is embodiment 2 disclosed in CN103147271A.
After goods disclosed in comparative example 1 and 2 only can ensure washing 50 times, keep good antibiotic and sterilizing effect, it is significantly lower than at least 100 times of embodiment 1 ~ 6.
Comparative example 3
All the other are identical with embodiment 1, and the concentration except silver ion is 500ppm.
Comparative example 4
All the other are identical with embodiment 1, and the concentration except anion is 1000ppm.
After goods disclosed in comparative example 3 and 4 only can ensure washing 70 times, keep good antibiotic and sterilizing effect, it is significantly lower than at least 100 times of embodiment 1 ~ 6.
Comparative example 5
All the other are identical with embodiment 1, and the particle diameter except silver ion is 10 nanometers.
Comparative example 6
All the other are identical with embodiment 1, and the particle diameter except silver ion is 20 nanometers.
After goods disclosed in comparative example 5 and 6 only can ensure washing 75 times, keep good antibiotic and sterilizing effect, it is significantly lower than at least 100 times of embodiment 1 ~ 6.
Comparative example 7
All the other are identical with embodiment 1, except crosslinking time is 28 minutes.
Comparative example 8
All the other are identical with embodiment 1, except crosslinking time is 45 minutes.
After goods disclosed in comparative example 7 and 8 only can ensure washing 80 times, keep good antibiotic and sterilizing effect, it is significantly lower than at least 100 times of embodiment 1 ~ 6.
Applicant states, the present invention illustrates method detailed of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (4)
1. a preparation method for functional sanitary anti-biotic material, is characterized in that, said method comprising the steps of:
Be that silver ion agent distilled water or the pure water of 12 ~ 18 nanometers of 600 ~ 900ppm makes Nano silver solution with 10 ~ 12 times of dilutions by concentration, cotton spinning material after cleaning is immersed in Nano silver solution and is cross-linked 32 ~ 38 minutes, after crosslinked, cotton spinning material is taken out dewatered drying by solution, obtain functional sanitary anti-biotic material.
2. the method for claim 1, is characterized in that, the concentration of described silver ion is 650 ~ 850ppm.
3. method as claimed in claim 1 or 2, it is characterized in that, the particle diameter of described silver ion is 15 ~ 18 nanometers.
4. the method as described in one of claim 1-3, is characterized in that, the described crosslinked time is 35 ~ 38 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510528124.1A CN105040421A (en) | 2015-08-25 | 2015-08-25 | Textile material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510528124.1A CN105040421A (en) | 2015-08-25 | 2015-08-25 | Textile material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105040421A true CN105040421A (en) | 2015-11-11 |
Family
ID=54447375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510528124.1A Pending CN105040421A (en) | 2015-08-25 | 2015-08-25 | Textile material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105040421A (en) |
-
2015
- 2015-08-25 CN CN201510528124.1A patent/CN105040421A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2698182C1 (en) | Polymer-based antimicrobial compositions and a method for use thereof | |
| Andra et al. | Emerging nanomaterials for antibacterial textile fabrication | |
| CN101716359B (en) | Sterilization and pasteurization material and application thereof | |
| CN102120042B (en) | Negative ion knit, textile and nonwoven fabrics and paper and products thereof and processing method | |
| CN106758180A (en) | Antibiotic fabric and preparation method thereof | |
| CA2878060A1 (en) | Physical antimicrobial method | |
| CN111226993B (en) | Long-acting antibacterial and virucidal sanitary protective product spray and application thereof | |
| CN104248776A (en) | Antibiosis solution used for dressing, antibiosis dressing and preparation method for antibiosis dressing | |
| CN103015167A (en) | Multifunctional cool shirt | |
| CN101003943A (en) | Nano antibacterial cotton textile materials, and a series of commodity of sanitation | |
| CN102978024B (en) | Mould-proof bacteriostatic traditional Chinese medicinal detergent | |
| CN103147271A (en) | Nano antibiosis and bacteriostasis cotton textile material and products thereof | |
| Goldade et al. | Antimicrobial fibers for textile clothing and medicine: current state | |
| CN102251438A (en) | Antiseptic fragrant paper towel and manufacturing method thereof | |
| CN102912632A (en) | Antibacterial functional medical textile | |
| CN111139645A (en) | High-filler antibacterial wet tissue and softening treatment process thereof | |
| CN105040421A (en) | Textile material and preparation method thereof | |
| CN102132704B (en) | Efficient sterilization crosslinking agent and method of for preparing hygienic sterilization product by using efficient sterilization crosslinking agent | |
| CN1090904C (en) | High-effective broad-spectrum fungicide and method for preparing sanitary disinfecting articles by using one | |
| Rajendran et al. | Smart textiles for infection control management | |
| CN106521933A (en) | Textile material and preparation method thereof | |
| KR100749138B1 (en) | Functional wet tissue | |
| CN108867021A (en) | A kind of Compound spinning fabric of natural degerming | |
| Toro et al. | Functional finishing of textile materials using silver-based functionalized nanoparticles: Health perspectives | |
| CN103122578A (en) | Sterilizing, nano-silver antibacterial and cool finishing type composite healthcare household article |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151111 |