CN105039757B - 一种用于生产铝合金的高含量锰添加剂及其制备方法 - Google Patents
一种用于生产铝合金的高含量锰添加剂及其制备方法 Download PDFInfo
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- CN105039757B CN105039757B CN201510541548.1A CN201510541548A CN105039757B CN 105039757 B CN105039757 B CN 105039757B CN 201510541548 A CN201510541548 A CN 201510541548A CN 105039757 B CN105039757 B CN 105039757B
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- powder
- manganese
- aluminium
- additive
- surfactant
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- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 123
- 239000011572 manganese Substances 0.000 title claims abstract description 91
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 91
- 239000000654 additive Substances 0.000 title claims abstract description 79
- 230000000996 additive effect Effects 0.000 title claims abstract description 77
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 60
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 60
- 239000004411 aluminium Substances 0.000 claims abstract description 56
- 239000000843 powder Substances 0.000 claims abstract description 55
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 239000004094 surface-active agent Substances 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000011261 inert gas Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 6
- 238000004806 packaging method and process Methods 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 18
- 239000007767 bonding agent Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 229920000447 polyanionic polymer Polymers 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 abstract description 33
- 230000008018 melting Effects 0.000 abstract description 33
- 239000007788 liquid Substances 0.000 abstract description 25
- 238000011084 recovery Methods 0.000 abstract description 16
- 229910052742 iron Inorganic materials 0.000 description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 239000000155 melt Substances 0.000 description 8
- -1 hexafluoro sodium aluminate Chemical compound 0.000 description 7
- 238000005275 alloying Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 229910001388 sodium aluminate Inorganic materials 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MKPXGEVFQSIKGE-UHFFFAOYSA-N [Mg].[Si] Chemical compound [Mg].[Si] MKPXGEVFQSIKGE-UHFFFAOYSA-N 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
Claims (6)
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CN105039757B true CN105039757B (zh) | 2017-09-29 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105734313B (zh) * | 2016-04-26 | 2018-01-23 | 沧州东盛金属添加剂制造有限公司 | 一种铝合金用锰添加剂及其制备方法 |
CN107099691A (zh) * | 2017-07-12 | 2017-08-29 | 铜山县丰华工贸有限公司 | 一种铝合金冶炼用锰剂及其制备方法 |
CN110157928A (zh) * | 2018-04-10 | 2019-08-23 | 湖南科技大学 | 一种用于铝合金的锰添加剂及其制备方法 |
CN111944949B (zh) * | 2020-07-29 | 2022-11-29 | 重庆润际远东新材料科技股份有限公司 | 锰硅复合添加剂及其制备方法 |
CN113637863A (zh) * | 2021-08-17 | 2021-11-12 | 重庆润际远东新材料科技股份有限公司 | 一种用于铝合金的锰添加剂及其制备方法 |
CN114293055A (zh) * | 2021-12-30 | 2022-04-08 | 立中四通轻合金集团股份有限公司 | 一种无氟低吸湿性锰元素添加剂 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1434932A (en) * | 1972-06-19 | 1976-05-12 | Solmet Alloys | Production of metal alloys |
US4648901A (en) * | 1981-12-23 | 1987-03-10 | Shieldalloy Corporation | Introducing one or more metals into a melt comprising aluminum |
CN1046193A (zh) * | 1989-04-03 | 1990-10-17 | 中国科学院金属研究所 | 一种熔炼铝合金用的添加剂 |
CN101381821A (zh) * | 2008-09-26 | 2009-03-11 | 北京矿冶研究总院 | 一种无熔剂铝合金添加剂及制备方法 |
-
2015
- 2015-08-28 CN CN201510541548.1A patent/CN105039757B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1434932A (en) * | 1972-06-19 | 1976-05-12 | Solmet Alloys | Production of metal alloys |
US4648901A (en) * | 1981-12-23 | 1987-03-10 | Shieldalloy Corporation | Introducing one or more metals into a melt comprising aluminum |
CN1046193A (zh) * | 1989-04-03 | 1990-10-17 | 中国科学院金属研究所 | 一种熔炼铝合金用的添加剂 |
CN101381821A (zh) * | 2008-09-26 | 2009-03-11 | 北京矿冶研究总院 | 一种无熔剂铝合金添加剂及制备方法 |
Non-Patent Citations (1)
Title |
---|
高性能锰铝合金添加剂产品及生产工艺;王国宁等;《中国锰业》;20110531;第29卷(第2期);第37页左栏第1段,第3-4段,及第38页左栏表5 * |
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Address after: 400025 area E (area a) of Tangjiatuo standard division, Gangcheng Industrial Park, Jiangbei District, Chongqing Patentee after: CHONGQING RUNJI FAR EAST NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 400025 area E (area a) of Tangjiatuo standard division, Gangcheng Industrial Park, Jiangbei District, Chongqing Patentee before: CHONGQING RUNJI YUANDONG NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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Denomination of invention: The invention relates to a high content manganese additive for producing aluminum alloy and a preparation method thereof Effective date of registration: 20220124 Granted publication date: 20170929 Pledgee: China Minsheng Banking Corp Chongqing branch Pledgor: CHONGQING RUNJI FAR EAST NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2022500000004 |
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Date of cancellation: 20230228 Granted publication date: 20170929 Pledgee: China Minsheng Banking Corp Chongqing branch Pledgor: CHONGQING RUNJI FAR EAST NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2022500000004 |
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Denomination of invention: A high content manganese additive and its preparation method for producing aluminum alloys Granted publication date: 20170929 Pledgee: Chongqing Branch of China Everbright Bank Co.,Ltd. Pledgor: CHONGQING RUNJI FAR EAST NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: Y2024500000027 |
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