CN105037997B - 无卤阻燃tpvc材料及其制备方法 - Google Patents
无卤阻燃tpvc材料及其制备方法 Download PDFInfo
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- CN105037997B CN105037997B CN201510403847.9A CN201510403847A CN105037997B CN 105037997 B CN105037997 B CN 105037997B CN 201510403847 A CN201510403847 A CN 201510403847A CN 105037997 B CN105037997 B CN 105037997B
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- Prior art keywords
- halogen
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- tpvc
- free flame
- magnesium hydroxide
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- 239000000463 material Substances 0.000 title claims abstract description 51
- 239000003063 flame retardant Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 11
- 229920006342 thermoplastic vulcanizate Polymers 0.000 title 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 26
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 25
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 25
- 239000004014 plasticizer Substances 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 24
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000000314 lubricant Substances 0.000 claims abstract description 12
- 239000004593 Epoxy Substances 0.000 claims abstract description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 11
- 239000003094 microcapsule Substances 0.000 claims abstract description 10
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 26
- 239000004800 polyvinyl chloride Substances 0.000 claims description 26
- 238000002156 mixing Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 13
- 229910000077 silane Inorganic materials 0.000 claims description 13
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical compound O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 10
- 150000004702 methyl esters Chemical class 0.000 claims description 10
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 9
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 9
- -1 diphenyl isooctyl phosphate Chemical compound 0.000 claims description 8
- 235000010290 biphenyl Nutrition 0.000 claims description 6
- 239000004305 biphenyl Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 238000010348 incorporation Methods 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- ZFDWSXUYIQGNHM-UHFFFAOYSA-N (6-methyl-1,1-diphenylheptyl) dihydrogen phosphate Chemical compound C=1C=CC=CC=1C(OP(O)(O)=O)(CCCCC(C)C)C1=CC=CC=C1 ZFDWSXUYIQGNHM-UHFFFAOYSA-N 0.000 abstract 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 abstract 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 8
- 235000021355 Stearic acid Nutrition 0.000 description 7
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical group [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 7
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 7
- 235000013539 calcium stearate Nutrition 0.000 description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- 239000008117 stearic acid Substances 0.000 description 7
- 239000008116 calcium stearate Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | |
PVC树脂 | SG-3型100kg | SG-3型100kg | SG-3型100kg | S-2500型100kg | S-2500型100kg | S-2500型100 kg |
DOTP | 30kg | 30kg | 30kg | 30kg | 30kg | 30kg |
环氧脂肪酸甲酯 | 4.5kg | 5kg | 4kg | 4.5kg | 6kg | 3kg |
DPOP | 22.5kg | 20kg | 25kg | 22.5kg | 15kg | 15kg |
氯化石蜡 | 3kg | 4kg | 2kg | 3kg | 4.5kg | 1.5kg |
钙锌复合稳定剂 | 6kg | 6kg | 6kg | 6kg | 6kg | 6kg |
硬脂酸钙 | 1kg | 1kg | 1kg | 1kg | 1kg | 1kg |
硬脂酸 | 1.1kg | 1.1kg | 1.1kg | 1.1kg | 1.1kg | 1.1kg |
聚乙烯蜡 | 1kg | 1kg | 1kg | 1kg | 1kg | 1kg |
活性氢氧化镁 | 50kg | 50kg | 60kg | 60kg | 60kg | 60kg |
微胶囊红磷 | 6kg | 6kg | 6kg | 9kg | 8kg | 6kg |
三氧化二锑 | 4kg | 4kg | 4kg | 8kg | 8kg | 8kg |
硼酸锌 | 5kg | 6kg | 6kg | 6kg | 8kg | 6kg |
测试性能 | 性能指标 | 测试标准 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
拉伸强度/MPa | >10.0 | GB/T1043-2006 | 12.8 | 13.1 | 12.1 | 12.5 | 12.6 | 12.5 |
断裂伸长率/% | >250 | GB/T1043-2006 | 280 | 300 | 286 | 278 | 270 | 285 |
热老化(80℃,168h)拉伸强度 | >10.0 | 11.6 | 11.7 | 11.0 | 11.4 | 11.4 | 11.3 | |
热老化(80℃,168h)拉伸强度变化率/% | ≤20 | 9.4 | 10.7 | 9.1 | 8.8 | 9.5 | 9.6 | |
邵氏硬度 | 75±5 | GB/T2411-2008 | 76 | 75 | 76 | 76 | 76 | 76 |
氧指数/% | >31 | GB/T2406.2-2009 | 31.5 | 32.0 | 33.0 | 33.1 | 33.1 | 33.0 |
垂直燃烧 | V-0 | GB/T2408-2008 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
Claims (5)
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CN201510403847.9A CN105037997B (zh) | 2015-07-10 | 2015-07-10 | 无卤阻燃tpvc材料及其制备方法 |
CN201710104650.4A CN106928590B (zh) | 2015-07-10 | 2015-07-10 | 一种无卤阻燃tpvc材料及其制备方法 |
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CN201710104650.4A Active CN106928590B (zh) | 2015-07-10 | 2015-07-10 | 一种无卤阻燃tpvc材料及其制备方法 |
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CN107778711A (zh) * | 2016-08-31 | 2018-03-09 | 苏州亨利通信材料有限公司 | 应用于高阻燃环保cmr级的pvc电缆料 |
CN108864835A (zh) * | 2018-07-21 | 2018-11-23 | 安徽启慧信息科技有限公司 | 一种耐火阻燃pvc材料的制备方法 |
CN111647237A (zh) * | 2020-05-22 | 2020-09-11 | 蒋欣雨 | 一种电缆用高导热聚氯乙烯护套材料及电缆 |
CN115806697B (zh) * | 2022-11-16 | 2024-02-02 | 浙江嘉澳环保科技股份有限公司 | 一种低成本复合型环保增塑剂及其制备方法 |
CN117757175B (zh) * | 2024-02-22 | 2024-05-10 | 河南云瀚实业有限公司 | 一种新能源车用阻燃高分子组合物及其生产工艺 |
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US4670494A (en) * | 1985-07-30 | 1987-06-02 | Gary Chemical Corp. | Flame retardant low smoke poly(vinyl chloride) thermoplastic composition |
TWI386451B (zh) * | 2009-05-12 | 2013-02-21 | Nanya Plastics Corp | 一種pvc樹脂組成物及其製品 |
CN102443226B (zh) * | 2011-09-20 | 2013-06-12 | 江苏兴华胶带股份有限公司 | 无卤阻燃pvc弹性料的生产方法 |
CN102719050B (zh) * | 2012-05-28 | 2014-01-15 | 深圳市盛嘉伦橡塑工业有限公司 | 减震用无卤阻燃热塑性弹性体材料及其制备方法 |
CN102964750A (zh) * | 2012-12-20 | 2013-03-13 | 江苏兴华胶带股份有限公司 | 无卤阻燃pvc弹性复合材料及其制备方法 |
CN105482240B (zh) * | 2013-09-29 | 2020-06-02 | 江苏理工学院 | 一种无卤阻燃线性低密度聚乙烯材料的制备方法 |
CN104194220A (zh) * | 2014-09-02 | 2014-12-10 | 中广核三角洲(中山)高聚物有限公司 | 电动汽车充电桩用pvc弹性体材料 |
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- 2015-07-10 CN CN201510403847.9A patent/CN105037997B/zh active Active
- 2015-07-10 CN CN201710104650.4A patent/CN106928590B/zh active Active
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CN105037997A (zh) | 2015-11-11 |
CN106928590A (zh) | 2017-07-07 |
CN106928590B (zh) | 2019-03-19 |
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