CN105036270A - 一种快速絮凝用水处理剂及其制备方法和水处理方法 - Google Patents
一种快速絮凝用水处理剂及其制备方法和水处理方法 Download PDFInfo
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- CN105036270A CN105036270A CN201510361052.6A CN201510361052A CN105036270A CN 105036270 A CN105036270 A CN 105036270A CN 201510361052 A CN201510361052 A CN 201510361052A CN 105036270 A CN105036270 A CN 105036270A
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- Prior art keywords
- water
- flocculation
- graphene oxide
- water treatment
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 170
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 230000003311 flocculating effect Effects 0.000 title claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 title abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 47
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 19
- -1 ferroferric oxide compound Chemical class 0.000 claims abstract description 16
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 8
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005189 flocculation Methods 0.000 claims description 107
- 230000016615 flocculation Effects 0.000 claims description 102
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 24
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000000926 separation method Methods 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 12
- KCZFLPPCFOHPNI-UHFFFAOYSA-N alumane;iron Chemical compound [AlH3].[Fe] KCZFLPPCFOHPNI-UHFFFAOYSA-N 0.000 claims description 12
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 12
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- LMDZBCPBFSXMTL-UHFFFAOYSA-N 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide Substances CCN=C=NCCCN(C)C LMDZBCPBFSXMTL-UHFFFAOYSA-N 0.000 claims description 5
- FPQQSJJWHUJYPU-UHFFFAOYSA-N 3-(dimethylamino)propyliminomethylidene-ethylazanium;chloride Chemical compound Cl.CCN=C=NCCCN(C)C FPQQSJJWHUJYPU-UHFFFAOYSA-N 0.000 claims description 5
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 5
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 4
- 229940040526 anhydrous sodium acetate Drugs 0.000 claims description 4
- 229940125782 compound 2 Drugs 0.000 claims description 4
- 229940093476 ethylene glycol Drugs 0.000 claims description 4
- 229940047670 sodium acrylate Drugs 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 150000002505 iron Chemical class 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 238000010992 reflux Methods 0.000 abstract description 5
- 230000021523 carboxylation Effects 0.000 abstract description 2
- 238000006473 carboxylation reaction Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000003541 multi-stage reaction Methods 0.000 abstract 1
- 229910000859 α-Fe Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 239000000693 micelle Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229940125773 compound 10 Drugs 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000004148 unit process Methods 0.000 description 1
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
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CN201510361052.6A CN105036270B (zh) | 2015-06-27 | 2015-06-27 | 一种快速絮凝用水处理剂及其制备方法和水处理方法 |
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CN201510361052.6A CN105036270B (zh) | 2015-06-27 | 2015-06-27 | 一种快速絮凝用水处理剂及其制备方法和水处理方法 |
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CN105036270A true CN105036270A (zh) | 2015-11-11 |
CN105036270B CN105036270B (zh) | 2017-12-05 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105776723A (zh) * | 2016-04-20 | 2016-07-20 | 张能力 | 一种污水快速絮凝的处理方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103613182A (zh) * | 2013-12-10 | 2014-03-05 | 成应向 | 一种重金属高聚絮凝剂及其应用 |
CN103613179A (zh) * | 2013-10-17 | 2014-03-05 | 昆山市奋发绝缘材料有限公司 | 一种废水处理混凝剂及其制备方法 |
CN103949218A (zh) * | 2014-04-21 | 2014-07-30 | 华南理工大学 | 一种改性石墨烯吸附剂及其制备方法与应用 |
US20150001155A1 (en) * | 2013-06-26 | 2015-01-01 | Corning Incorporated | Methods and apparatus for synthesis of stabilized zero valent nanoparticles |
-
2015
- 2015-06-27 CN CN201510361052.6A patent/CN105036270B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20150001155A1 (en) * | 2013-06-26 | 2015-01-01 | Corning Incorporated | Methods and apparatus for synthesis of stabilized zero valent nanoparticles |
CN103613179A (zh) * | 2013-10-17 | 2014-03-05 | 昆山市奋发绝缘材料有限公司 | 一种废水处理混凝剂及其制备方法 |
CN103613182A (zh) * | 2013-12-10 | 2014-03-05 | 成应向 | 一种重金属高聚絮凝剂及其应用 |
CN103949218A (zh) * | 2014-04-21 | 2014-07-30 | 华南理工大学 | 一种改性石墨烯吸附剂及其制备方法与应用 |
Non-Patent Citations (2)
Title |
---|
张慧娟等: "石墨烯基水凝胶的研究进展", 《高分子通报》 * |
李明会等: "高强度聚N’N-二甲基丙烯酰胺/氧化石墨烯复合水凝胶的制备", 《高分子材料科学与工程》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105776723A (zh) * | 2016-04-20 | 2016-07-20 | 张能力 | 一种污水快速絮凝的处理方法 |
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Inventor after: Ma Yonglin Inventor before: Li Hongliang |
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Effective date of registration: 20170808 Address after: 510665 Guangdong city of Guangzhou province Tianhe District Software Park Building No. 59 Middle East block, Grand Building Room 501 Applicant after: Ma Yonglin Address before: 100083 Haidian District, Xueyuan Road,, University of Science and Technology Beijing, No. 875, Applicant before: Li Hongliang |
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Effective date of registration: 20171010 Address after: 400056, Chongqing District, Banan City, South Village Red Star Village 12 clubs Applicant after: CHONGQING SHUOAO TECHNOLOGY CO.,LTD. Address before: 510665 Guangdong city of Guangzhou province Tianhe District Software Park Building No. 59 Middle East block, Grand Building Room 501 Applicant before: Ma Yonglin |
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Effective date of registration: 20171102 Address after: Chen Town Industrial Park 257447 Shandong city of Dongying province Lijin County Applicant after: DONGYING GUOAN CHEMICAL Co.,Ltd. Address before: 400056, Chongqing District, Banan City, South Village Red Star Village 12 clubs Applicant before: CHONGQING SHUOAO TECHNOLOGY CO.,LTD. |
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Denomination of invention: A rapid flocculation water treatment agent and its preparation method and water treatment method Effective date of registration: 20230904 Granted publication date: 20171205 Pledgee: Lijin sub branch of Dongying Bank Co.,Ltd. Pledgor: DONGYING GUOAN CHEMICAL Co.,Ltd. Registration number: Y2023980055132 |
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