CN105017984B - A kind of adhesive polymer adhesive tape, production method and its application - Google Patents
A kind of adhesive polymer adhesive tape, production method and its application Download PDFInfo
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- CN105017984B CN105017984B CN201510431562.6A CN201510431562A CN105017984B CN 105017984 B CN105017984 B CN 105017984B CN 201510431562 A CN201510431562 A CN 201510431562A CN 105017984 B CN105017984 B CN 105017984B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
Abstract
The present invention relates to a kind of adhesive polymer adhesive tape, production method and its applications, and in parts by weight, its composition of raw materials is as follows：25 ~ 50 parts of styrene-isoprene-styrene block copolymer；10 ~ 30 parts of plasticizer；First 30 ~ 60 parts of tackifying resin；3 ~ 10 parts of Nano filling；Second 10 ~ 20 parts of tackifying resin；0.02 ~ 0.05 part of ultraviolet absorber；0.02 ~ 0.05 part of antioxidant；First tackifying resin is the mixture of one or both of C 5 hydrogenated petroleum resin and terpene resin composition；Second tackifying resin is the mixture of one or more of Petropols, terpene resin and rosin resin composition.By the way that the ingredients such as the first tackifying resin, the second tackifying resin, plasticizer and Nano filling are added into styrene-isoprene-styrene block copolymer, the materials such as adhesive tape and concrete, aluminium alloy and plastic-steel obtained in this way have excellent adhesive property, but also have the characteristics that extremely soft, it is easy to implement docile and closely knit in node special-shaped part, it is adapted to various structural deformations.
Description
Technical field
The invention belongs to polymeric material fields, are related to a kind of single-coated foam, and in particular to a kind of adhesive polymer adhesive tape,
Production method and its application.
Background technology
Leakage of building is always that most one of problems is complained in architectural engineering, roof leakage, seepage in toilet, kitchen,
Exterior wall leakage, basement leakage are considered as building " cancer ".Many completion of works current years created, there have been serious leakages
The case where.Lead to leakage of building one of the major reasons：Position of joints depends merely on common water-repellent paint sealing and certainly exists waterproof defect！
It expands with heat and contract with cold since the position of joints such as negative and positive angle, Guan Gen, bearing exist, differential settlement, various combination material are because line of material is swollen
The water-repellent paint that the objective factors such as swollen coefficient difference cause elongation percentage poor is leaked by drawing crack.
If producing a kind of adhesive polymer adhesive tape, it can have excellent with materials such as concrete, aluminium alloy and plastic-steels
Different adhesive property（It just glues, hold viscous and low temperature bonding）, also have the characteristics that extremely softness, it is easy to implement in node special-shaped part
It is docile and closely knit.In the paving of the position of joints such as negative and positive angle, Guan Gen, bearing, the adhesive polymer adhesive tape is adapted to various knots in this way
Configuration becomes, to avoid leakage of building.
Invention content
A kind of adhesive polymer adhesive tape is provided the invention aims to overcome the deficiencies in the prior art.
In order to achieve the above objectives, the technical solution adopted by the present invention is：A kind of adhesive polymer adhesive tape, in parts by weight,
Its composition of raw materials is as follows：
25 ~ 50 parts of styrene-isoprene-styrene block copolymer；
10 ~ 30 parts of plasticizer；
First 30 ~ 60 parts of tackifying resin；
3 ~ 10 parts of Nano filling；
Second 10 ~ 20 parts of tackifying resin；
0.02 ~ 0.05 part of ultraviolet absorber；
0.02 ~ 0.05 part of antioxidant；
First tackifying resin is the mixing of one or both of C 5 hydrogenated petroleum resin and terpene resin composition
Object；Second tackifying resin is the mixture of one or more of Petropols, terpene resin and rosin resin composition.
Optimally, the density of the styrene-isoprene-styrene block copolymer is 0.9 ~ 0.92g/cm3, melt
Flow rate is 8.5 ~ 9.5g/10min, and the mass content of styrene is 13 ~ 18%.
Further, the volume factor of the styrene-isoprene-styrene block copolymer is 0.32 ~ 0.38, is drawn
It is 0.8 ~ 1.0Mpa to stretch stress, and stretching yield stress is 25 ~ 30 Mpa, and elongation at break is 1000 ~ 1500%, apparent viscosity 1
~1.5Pa·s。
Optimally, the plasticizer is white oil, vegetable oil, naphthenic oil, dioctyl phthalate and dioctyl adipate
One or more of composition mixture.
Optimally, the Nano filling is nano-calcium carbonate.
Optimally, content of ashes≤0.1vol% of the rosin resin, softening point be 85 ~ 90 DEG C, acid value be 7.5 ~
8mgKOH/g。
Optimally, the softening point of the terpene resin is 100 ~ 130 DEG C, acid value≤5mgKOH/g, toluene insolubles content
≤ 0.05vol%, iodine number are 10 ~ 15, saponification number≤1.5mgKOH/g.
Optimally, the softening point of the C 5 hydrogenated petroleum resin and the Petropols is 95 ~ 105 DEG C, content of ashes
≤0.02 vol%。
Another object of the present invention is to provide a kind of production method of above-mentioned adhesive polymer adhesive tape, it includes following step
Suddenly：
（a）The raw material of formula ratio is mixed to be placed on and is stored in glue groove, heating keeps storage glue groove temperature to be 145 ~ 150 DEG C, apply
Rubber roller temperature, which is 130 ~ 135 DEG C, makes raw material melt, and is subsequently agitated for；
（b）By the raw material after stirring on facing material, it is cooling after coated insulation film, then carry out cutting packaging i.e.
It can.
It is still another object of the present invention to provide a kind of applications of above-mentioned adhesive polymer adhesive tape, it includes the following steps：
（a）The adhesive polymer adhesive tape described in the paving of building node position；
（b）The brushing water-repellent paint on the adhesive polymer adhesive tape.
Since above-mentioned technical proposal is used, the present invention has following advantages compared with prior art：Macromolecule of the present invention is certainly
Adhesive tape, by be added into styrene-isoprene-styrene block copolymer the first tackifying resin, the second tackifying resin,
The ingredients such as plasticizer and Nano filling, the materials such as adhesive tape and concrete, aluminium alloy and plastic-steel obtained in this way have excellent glue
Performance is tied, is either just glued, to hold viscous and low temperature bonding performance preferable；But also have the characteristics that extremely softness, it is different in node
Shape position is easy to implement docile and closely knit, is adapted to various structural deformations.
Specific implementation mode
Adhesive polymer adhesive tape of the present invention, in parts by weight, its composition of raw materials is as follows：Styrene-isoprene-benzene second
Alkene block copolymer（SIS rubber）25 ~ 50 parts；10 ~ 30 parts of plasticizer；First 30 ~ 60 parts of tackifying resin；Nano filling 3 ~ 10
Part；Second 10 ~ 20 parts of tackifying resin；0.02 ~ 0.05 part of ultraviolet absorber；0.02 ~ 0.05 part of antioxidant；The first thickening tree
Fat is the mixture of one or both of C 5 hydrogenated petroleum resin and terpene resin composition；Second tackifying resin is stone
The mixture of one or more of oleoresin, terpene resin and rosin resin composition.Increased by the way that first is added into SIS rubber
The ingredients such as viscosity resin, the second tackifying resin, plasticizer and Nano filling, and the parts by weight of each component are accurately controlled, in this way
Configuring the materials such as the adhesive tape formed and concrete, aluminium alloy and plastic-steel has excellent adhesive property（Either just glue, hold it is viscous and
Low temperature bonding performance is preferable）；But also have the characteristics that extremely softness, it is easy to implement docile and close in node special-shaped part
It is real, it is adapted to various structural deformations.
In the present embodiment, the density of SIS rubber is 0.9 ~ 0.92g/cm3, melt flow rate (MFR) is 8.5 ~ 9.5g/
10min, the mass content of styrene are 13 ~ 18%, and corresponding SIS rubber has applicable molecular weight at this time, can well with
Other ingredients such as plasticizer carry out fully miscible, it is ensured that the stabilization of the uniform and quality of tape compositions.SIS rubber is further preferred
Volume factor be 0.32 ~ 0.38, tensile stress be 0.8 ~ 1.0Mpa, stretching yield stress is 25 ~ 30 Mpa, elongation at break is
1000 ~ 1500%, apparent viscosity is 1 ~ 1.5Pas, to be further ensured that the flexible wires of adhesive tape.Plasticizer is white oil, plants
The mixture of one or more of object oil, naphthenic oil, dioctyl phthalate and dioctyl adipate composition.Nano filling
For nano-calcium carbonate, such adhesive tape has better adhesive property with concrete.The property of above-mentioned rosin resin is：Ash content contains
Amount≤0.1vol%（Volume content）, softening point is 85 ~ 90 DEG C, and acid value is 7.5 ~ 8mgKOH/g；The property of terpene resin is：It is soft
It is 100 ~ 130 DEG C to change point, acid value≤5mgKOH/g, toluene insolubles content≤0.05vol%, and iodine number is 10 ~ 15, saponification number≤
1.5mgKOH/g；The softening point of C 5 hydrogenated petroleum resin and Petropols is 95 ~ 105 DEG C, the vol% of content of ashes≤0.02,
Tape performance is optimal made from these three resins.Ultraviolet absorber can select salicylic acid esters, benzophenone class, benzotriazole,
Group-substituted acrylonitrile, triazines and hindered amines etc., concrete model UV-P, UV531, UV-327 etc..Antioxidant is aromatic amine
Class, Hinered phenols etc., such as 1010,168, BHT, 1076.
The preferred embodiment of the invention will be described in detail below：
Embodiment 1
The present invention provides a kind of adhesive polymer adhesive tape, and in parts by weight, its composition of raw materials is as follows：
25 parts of SIS rubber（Density is 0.9g/cm3, the content of melt flow rate (MFR) 8.5g/10min, styrene is
13wt%, volume factor 0.32, tensile stress 0.8Mpa, stretching yield stress 25Mpa, elongation at break 1000%,
Apparent viscosity is 1Pas）；10 parts of white oil；First 30 parts of tackifying resin；Nano-calcium carbonate（Average grain diameter 500nm）3 parts；Second
10 parts of tackifying resin；0.02 part of ultraviolet absorber UV-P；0.02 part of antioxidant 1010；First tackifying resin is C 5 hydrogenated stone
Mixture in oleoresin and terpene resin；The softening point of terpene resin is 100 DEG C, acid value 5mgKOH/g, toluene insolubles
Content is 0.05vol%, iodine number 10, saponification number 1.5mgKOH/g；The softening point of C 5 hydrogenated petroleum resin is 95 DEG C, ash
It is 0.02 vol% to divide content.Second tackifying resin is the mixture of Petropols, terpene resin and rosin resin composition, oil
The softening point of resin is 95 DEG C, and content of ashes is 0.02 vol%；The softening point of terpene resin is 100 DEG C, acid value 5mgKOH/
G, toluene insolubles content are 0.05vol%, iodine number 10, saponification number 1.5mgKOH/g；The content of ashes of rosin resin is
0.1vol%, softening point are 85 DEG C, acid value 7.5KOH/g.
Preparation method is：
（a）The raw material of formula ratio is mixed to be placed on and is stored in glue groove, heating keeps storing glue groove temperature being 145 DEG C, glue spreader
Temperature, which is 130 DEG C, makes raw material melt, and is then stirred and evenly mixed with convention stir speed（It stirs to the property of colloid without too big shadow
It rings）；
（b）By the raw material after stirring on facing material（Need to check facing material whether there is or not breakage, such as cavity,
Scratch etc., it prevents subsequent handling from interrupting tire, influences production efficiency）, just having started speed when gluing cannot be too fast（On the left sides 1cm/s
It is right）, after waiting the honest and kind stabilization of gluings, speed is stepped up to 2 ~ 5cm/s or so；Coated insulation film after cooling, then carry out cutting packet
Dress.
Application method is:（a）The adhesive polymer adhesive tape described in the paving of building node position；
（b）The brushing water-repellent paint on the adhesive polymer adhesive tape.
Embodiment 2
The present invention provides a kind of adhesive polymer adhesive tape, and in parts by weight, its composition of raw materials is as follows：
50 parts of SIS rubber（Density is 0.9g/cm3, the content of melt flow rate (MFR) 8.5g/10min, styrene is
13wt%, volume factor 0.38, tensile stress 1.0Mpa, stretching yield stress 30Mpa, elongation at break 1500%,
Apparent viscosity is 1.5Pas）；Totally 30 parts of vegetable oil and naphthenic oil（15 parts of vegetable oil, 15 parts of naphthenic oil）；First tackifying resin
60 parts；10 parts of nano-calcium carbonate；Second 20 parts of tackifying resin；0.05 part of ultraviolet absorber UV531；0.05 part of irgasfos 168；
First tackifying resin is C 5 hydrogenated petroleum resin；The softening point of C 5 hydrogenated petroleum resin is 105 DEG C, content of ashes 0.01
vol%.Second tackifying resin is the mixture that terpene resin and rosin resin form, and the softening point of terpene resin is 130 DEG C, acid
Value is 4mgKOH/g, and toluene insolubles content is 0.03vol%, iodine number 15, saponification number 1mgKOH/g；The ash of rosin resin
It is 0.05vol% to divide content, and softening point is 90 DEG C, acid value 8KOH/g.
Preparation method is：
（a）The raw material of formula ratio is mixed to be placed on and is stored in glue groove, heating keeps storing glue groove temperature being 150 DEG C, glue spreader
Temperature, which is 135 DEG C, makes raw material melt, and is then stirred and evenly mixed with convention stir speed（It stirs to the property of colloid without too big shadow
It rings）；
（b）By the raw material after stirring on facing material（Need to check facing material whether there is or not breakage, such as cavity,
Scratch etc., it prevents subsequent handling from interrupting tire, influences production efficiency）, just having started speed when gluing cannot be too fast（On the left sides 1cm/s
It is right）, after waiting the honest and kind stabilization of gluings, step up speed；Coated insulation film after cooling, then carry out cutting packaging.
Embodiment 3
The present invention provides a kind of adhesive polymer adhesive tape, and in parts by weight, its composition of raw materials is as follows：
40 parts of SIS rubber（Density is 0.91g/cm3, the content of melt flow rate (MFR) 9g/10min, styrene is
15wt%, volume factor 0.35, tensile stress 0.9Mpa, stretching yield stress 28Mpa, elongation at break 1300%,
Apparent viscosity is 1.2Pas）；Totally 20 parts of dioctyl phthalate and dioctyl adipate（5 parts of dioctyl phthalate,
15 parts of dioctyl adipate）；First 50 parts of tackifying resin；5 parts of nano-calcium carbonate；Second 15 parts of tackifying resin；Ultraviolet absorber
0.05 part of UV-327；Antioxidant BHT and antioxidant 1076（Their weight is identical）Totally 0.05 part；First tackifying resin is terpene
Olefine resin, its softening point be 120 DEG C, acid value 4.5mgKOH/g, toluene insolubles content be 0.04vol%, iodine number 12,
Saponification number is 1.2mgKOH/g.Second tackifying resin is the mixture that terpene resin and rosin resin form, terpene resin it is soft
It is 120 DEG C, acid value 4.5mgKOH/g to change point, and toluene insolubles content is 0.04vol%, and iodine number 12, saponification number is
1.2mgKOH/g；The content of ashes of rosin resin is 0.08vol%, and softening point is 89 DEG C, acid value 7.8KOH/g.
Preparation method is：
（a）The raw material of formula ratio is mixed to be placed on and is stored in glue groove, heating keeps storing glue groove temperature being 148 DEG C, glue spreader
Temperature, which is 132 DEG C, makes raw material melt, and is then stirred and evenly mixed with convention stir speed（It stirs to the property of colloid without too big shadow
It rings）；
（b）By the raw material after stirring on facing material（Need to check facing material whether there is or not breakage, such as cavity,
Scratch etc., it prevents subsequent handling from interrupting tire, influences production efficiency）, just having started speed when gluing cannot be too fast（On the left sides 1cm/s
It is right）, after waiting the honest and kind stabilization of gluings, step up speed；Coated insulation film after cooling, then carry out cutting packaging.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention, all according to the present invention
Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of adhesive polymer adhesive tape, which is characterized in that in parts by weight, its composition of raw materials is as follows：
25 ~ 50 parts of styrene-isoprene-styrene block copolymer；
10 ~ 30 parts of plasticizer；
First 30 ~ 60 parts of tackifying resin；
3 ~ 10 parts of Nano filling；
Second 10 ~ 20 parts of tackifying resin；
0.02 ~ 0.05 part of ultraviolet absorber；
0.02 ~ 0.05 part of antioxidant；
First tackifying resin is the mixture of one or both of C 5 hydrogenated petroleum resin and terpene resin composition；Institute
State the mixture that the second tackifying resin is one or more of Petropols, terpene resin and rosin resin composition；
Content of ashes≤0.1vol% of the rosin resin, softening point are 85 ~ 90 DEG C, and acid value is 7.5 ~ 8mgKOH/g；
The softening point of the terpene resin is 100 ~ 130 DEG C, acid value≤5mgKOH/g, toluene insolubles content≤0.05vol%,
Iodine number is 10 ~ 15, saponification number≤1.5mgKOH/g；
The softening point of the C 5 hydrogenated petroleum resin and the Petropols is 95 ~ 105 DEG C, the vol% of content of ashes≤0.02.
2. adhesive polymer adhesive tape according to claim 1, it is characterised in that：The styrene-isoprene-phenylethene
The density of block copolymer is 0.9 ~ 0.92g/cm3, melt flow rate (MFR) is 8.5 ~ 9.5g/10min, the mass content of styrene
It is 13 ~ 18%.
3. adhesive polymer adhesive tape according to claim 2, it is characterised in that：The styrene-isoprene-benzene second
The volume factor of alkene block copolymer is 0.32 ~ 0.38, and tensile stress is 0.8 ~ 1.0Mpa, and stretching yield stress is 25 ~ 30
Mpa, elongation at break are 1000 ~ 1500%, and apparent viscosity is 1 ~ 1.5Pas.
4. adhesive polymer adhesive tape according to claim 1, it is characterised in that：The plasticizer is white oil, vegetable oil, ring
The mixture of one or more of alkane oil, dioctyl phthalate and dioctyl adipate composition.
5. adhesive polymer adhesive tape according to claim 1, it is characterised in that：The Nano filling is nano-calcium carbonate.
6. the production method of any adhesive polymer adhesive tape in claim 1 to 5, which is characterized in that it includes following step
Suddenly：
（a）The raw material of formula ratio is mixed to be placed on and is stored in glue groove, heating keeps storing glue groove temperature being 145 ~ 150 DEG C, glue spreader
Temperature, which is 130 ~ 135 DEG C, makes raw material melt, and is subsequently agitated for；
（b）By the raw material after stirring on facing material, it is cooling after coated insulation film, then carry out cutting packaging.
7. the application of any adhesive polymer adhesive tape in claim 1 to 5, which is characterized in that it includes the following steps：
（a）The adhesive polymer adhesive tape described in the paving of building node position；
（b）The brushing water-repellent paint on the adhesive polymer adhesive tape.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510431562.6A CN105017984B (en) | 2015-07-22 | 2015-07-22 | A kind of adhesive polymer adhesive tape, production method and its application |
| PCT/CN2015/097289 WO2017012256A1 (en) | 2015-07-22 | 2015-12-14 | High polymer self-adhesive tape, manufacturing method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510431562.6A CN105017984B (en) | 2015-07-22 | 2015-07-22 | A kind of adhesive polymer adhesive tape, production method and its application |
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| Publication Number | Publication Date |
|---|---|
| CN105017984A CN105017984A (en) | 2015-11-04 |
| CN105017984B true CN105017984B (en) | 2018-08-17 |
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| CN201510431562.6A Active CN105017984B (en) | 2015-07-22 | 2015-07-22 | A kind of adhesive polymer adhesive tape, production method and its application |
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| WO (1) | WO2017012256A1 (en) |
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| CN105017984B (en) * | 2015-07-22 | 2018-08-17 | 江苏凯伦建材股份有限公司 | A kind of adhesive polymer adhesive tape, production method and its application |
| CN105505096B (en) * | 2016-01-20 | 2017-11-21 | 河北豫源防水材料有限公司 | A kind of uncured water-repellent paint of environment-friendly type and preparation method thereof |
| CN106221629B (en) * | 2016-08-15 | 2018-10-30 | 江苏凯伦建材股份有限公司 | A kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and application |
| CN106281211A (en) * | 2016-08-22 | 2017-01-04 | 重庆中防德邦防水技术有限公司 | A kind of creep reactive polymer rubber adhesive waterproof coil and preparation method |
| CN106318292B (en) * | 2016-08-31 | 2018-08-31 | 河北方大包装股份有限公司 | A kind of removable hot-fusible pressure-sensitive adhesive and preparation method |
| CN110408341A (en) * | 2019-08-05 | 2019-11-05 | 江苏凯伦建材股份有限公司 | Macromolecule overlays waterproof roll with applying adhesive tape and its construction application |
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| CN110761663A (en) * | 2019-09-27 | 2020-02-07 | 江苏凯伦建材股份有限公司 | Anti-leakage method for window frame |
| CN112175541B (en) * | 2020-09-16 | 2022-07-19 | 广州慧谷功能材料有限公司 | Adhesive tape capable of being removed at 90 degrees, preparation method thereof and electronic product |
| CN112815153A (en) * | 2021-01-04 | 2021-05-18 | 江苏凯伦建材股份有限公司 | Waterproof treatment method for root of through-wall or floor pipeline |
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| CN105017984B (en) * | 2015-07-22 | 2018-08-17 | 江苏凯伦建材股份有限公司 | A kind of adhesive polymer adhesive tape, production method and its application |
-
2015
- 2015-07-22 CN CN201510431562.6A patent/CN105017984B/en active Active
- 2015-12-14 WO PCT/CN2015/097289 patent/WO2017012256A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102311712A (en) * | 2010-05-11 | 2012-01-11 | 博斯蒂克股份公司 | The HMPSA that is used for peelable self-adhesive label |
| CN101871248A (en) * | 2010-05-31 | 2010-10-27 | 广东科顺化工实业有限公司 | Reactive polymer waterproofing coiled material |
Also Published As
| Publication number | Publication date |
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| WO2017012256A1 (en) | 2017-01-26 |
| CN105017984A (en) | 2015-11-04 |
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