CN105002023A - Preparation of solid bottle-washing additive - Google Patents
Preparation of solid bottle-washing additive Download PDFInfo
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- CN105002023A CN105002023A CN201510452065.4A CN201510452065A CN105002023A CN 105002023 A CN105002023 A CN 105002023A CN 201510452065 A CN201510452065 A CN 201510452065A CN 105002023 A CN105002023 A CN 105002023A
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- bottle
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- surfynol
- additive
- washing
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Abstract
The invention discloses a solid bottle-washing additive. The solid bottle-washing additive comprises the main components of sodium gluconate, urea, sodium dihydrogen phosphate, sodium triphosphate, Triton DF-16, Surfynol DF-110D, Surfynol DF-220 and white carbon black. The additive finished product is good in color and luster, powder is dry, caking is not likely to occur, and the solid bottle-washing additive has good fluidity and is convenient to use and easy to add. Meanwhile, the bottle-washing additive is free of foams in the whole bottle-washing process and capable of rapidly permeating into adhesive inside bottle marking paper, in this way, the whole marking paper falls off, a washed bottle is bright and transparent without blurring, no adhesive traces are left on the exterior of the bottle, and no residues are left inside the bottle.
Description
Technical field
The present invention relates to a kind of preparation method and application of wash bottle additive, belong to returnable bottle cleaning field.
Technical background
The industry development such as beer, beverage is very fast in recent years, there is over thousands of family in current domestic large-scale beer beverage manufacturer, produce beer and beverage about 10,000 ten thousand kL per year, the indivedual brew-house of depolarization all uses outside new bottle, and all the other most of manufacturing enterprises adopt returnable bottle filling.Therefore wash bottle additive consumption in wash bottle industry is huge.Bottle washing procedure has become one of critical process in beer production, and cleaning performance directly affects quality and the outward appearance of beer product.Traditional Beer bottle washing all adopts liquid caustic soda, solid caustic soda or soda ash etc., and concentration of lye reaches more than 4%, and returnable bottle percentage of damage remains high, and clean bottle rate is no more than 94%, helpless to the dirty difficult wash bottle of weight of the dirts such as band colloid, grease, protein, wine dirt especially, and it is fuzzy to there is bottle appearance after laundering, and washing is costly, transport, store, use dangerous, easy deliquescence, perishable human body skin, easily makes equipment scaling, test bottle operative's labour intensity large, the problems such as contaminate environment.In order to solve the problem, develop a efficient wash bottle additive and necessitating.Recent domestic Jun You producer develops and production wash bottle additive, the Detergent power applied in the market, and greatly mainly with based on domestic detergent formula, improve a little it and form, conventional formulation can not meet existing processing condition.Develop a removal millimeter paper, aluminium foil is fast, cleansing power is strong, wash bottle process non-foam, and the wash bottle additive of deliquescence caking does not necessitate.
Patent CN92104136.5 provides a kind of powder industrial bottle-washing detergent, patent CN200410077723.8 provides a kind of two-pack alkalescence bottle-washing agent, the induced by alkyl hydroxybenzene tensio-active agent that these 2 patents employ the restriction of current more country or prohibit the use, big for environment pollution.And employ silicone oil defoamer, easily cause clean-out system to remain.
Patent CN92104639.1 provides a kind of powder bottle washing agent, and the bottle-washing agent foam that this patent provides is comparatively large, can not meet existing bottle-washing.
Patent CN200810111740.7 adopts washing powder to be body material, and foam is large, and cleansing power is weak, adopts normal domestic detergent use in food service industry, can not meet food service industry demand.
Patent CN98112023.7 does not have froth suppressor, and in wash bottle process, aluminium mark can not get controlling without a large amount of foams that dirt saponification produces, not competent existing bottle-washing.
Patent CN97101447.7 employs high foam surfactants, although can improve cleansing power, in wash bottle process, a large amount of foam can not get controlling, and can not meet existing bottle-washing.
Summary of the invention
The object of the invention is to the many drawbacks overcoming existing wash bottle additive, the solid wash bottle additive of a kind of highly effective and safe, low bubble, high soil removability is provided.
The present invention includes wash bottle additive, bottle washing solution and wash bottle method.The actual basic solution referring to be added in bottle washing machine of bottle washing solution, bottle washing solution is mixed by wash bottle additive, caustic alkali and water.
Generally fill a certain amount of deionized water in bottle washing machine, add bottle washing solution wherein, namely add the pressed powder wash bottle additive in sodium hydroxide and the present invention.Bottle washing solution generally comprises the water of the sodium hydroxide of 1-5 weight part and the pressed powder wash bottle additive of 0.1-1 weight part and 94-98 weight part.
A kind of pressed powder wash bottle additive, mainly comprise the raw material composition of following weight part: Sunmorl N 60S 40-60 part, urea 5-15 part, SODIUM PHOSPHATE, MONOBASIC 1-10 part, tripoly phosphate sodium STPP 5-15 part, Triton DF-161-5 part, Surfynol DF-110D 1-5 part, Surfynol DF-220 1-5 part, white carbon black 5-15 part.
The present invention introduces inlet surface promoting agent Tao Shi Triton DF-16 and air Surfynol DF-110D, Surfynol DF-220 serve outstanding effect to bottleneck aluminium mark and the foam inhibition of dirt saponification generation in wash bottle process, and low bubble can be kept while meeting high decontamination cleansing power for a long time even still.Wherein TritonDF-16 is the isomeric alcohol polyethenoxy ether class tensio-active agent of C8-C10, and on the basis ensureing raising cleansing power, perfection remains low bubble effect.Surfynol DF-110D and Surfynol DF-220 is acetylenic diols Soxylat A 25-7, and the bimolecular structure of their uniquenesses can have defoaming and out gassing in bottle washing solution, but does not have the side effect that many traditional Foam Controls have usually.Microvesicle can be eliminated, there is long-term foam control, foam and good dynamic wettability can be controlled zero defect.
The present invention introduces the white carbon black with powerful liquid adsorption performance first, can perfect absorption TritonDF-16, Surfynol DF-110D, Surfynol DF-220.Make them become solid state powder from liquid state, and firmly adsorb wherein.White carbon black has stronger dispersiveness and caking performance simultaneously, can effectively prevent solid salt moisture absorption deliquescence to lose efficacy.In addition white carbon black and relative concentration higher bottle washing alkaline solution mixing after, can produce Starso rapidly, as everyone knows, Starso has stronger synergism to cleaning, can work in coordination with other components improve cleanliness factor.Meanwhile Starso can also be got confused in cleaning process in effective inhibition vial corrosion.
Invention introduces urea and SODIUM PHOSPHATE, MONOBASIC, by practical proof, this component has special efficacy to mildew cleaning.Tripoly phosphate sodium STPP and Sunmorl N 60S raising white vase ability can be worked in coordination with.Make body clear transparent, the outer glue-free trace of bottle, noresidue in bottle.
The invention provides a kind of preparation method of pressed powder wash bottle additive, by Sunmorl N 60S, urea, SODIUM PHOSPHATE, MONOBASIC, tripoly phosphate sodium STPP, Triton DF-16, Surfynol DF-110D, Surfynol DF-220, white carbon black according to a certain percentage Homogeneous phase mixing obtains homogeneous solid powder.
The application of the acid wash bottle additive adopting above-mentioned formula and method to obtain on washing Beer Bottle.
By weight, pressed powder wash bottle additive 0.1-1 part, sodium hydroxide 1-5 part, water 94-98 part, is applied to directly adding in alkaline working fluid after this reagent mix in bottle washing machine.
The present invention, as wash bottle additive, has following remarkable advantage compared with existing commercially available bottle-washing agent:
1. this wash bottle additive is adopted new technology technology, not easily moisture absorption caking, easy to use, be easy to add.
2. this wash bottle additive is introduced inlet surface promoting agent first reach still in omnidistance wash bottle process, and do not have foam and overflow to job site, effective constituent can be present in working fluid for a long time, has the very long wash bottle life-span.
3. this wash bottle additive can make the outer paper mark of bottle come off by original state, body clear transparent, and the outer glue-free trace of bottle, noresidue in bottle, does not affect beer quality local flavor.
Embodiment
Embodiment 1
1. Sunmorl N 60S 55 parts, 12 parts, urea, SODIUM PHOSPHATE, MONOBASIC 6 parts, tripoly phosphate sodium STPP 8 parts, TritonDF-16 3 parts, Surfynol DF-110D 2 parts, Surfynol DF-220 2 parts, white carbon black 12 parts.
Embodiment 2
Sunmorl N 60S 50 parts, 10 parts, urea, SODIUM PHOSPHATE, MONOBASIC 5 parts, tripoly phosphate sodium STPP 12 parts, TritonDF-16 3 parts, Surfynol DF-110D 3 parts, Surfynol DF-220 3 parts, white carbon black 14 parts.
Embodiment 3
Sunmorl N 60S 55 parts, 8 parts, urea, SODIUM PHOSPHATE, MONOBASIC 10 parts, tripoly phosphate sodium STPP 10 parts, TritonDF-16 2 parts, Surfynol DF-110D 5 parts, Surfynol DF-220 1 part, white carbon black 9 parts.
Embodiment 4
Sunmorl N 60S 45 parts, 15 parts, urea, SODIUM PHOSPHATE, MONOBASIC 5 parts, tripoly phosphate sodium STPP 15 parts, TritonDF-16 5 parts, Surfynol DF-110D 1 part, Surfynol DF-220 4 parts, white carbon black 10 parts.
Embodiment 5
Sunmorl N 60S 60 parts, 8 parts, urea, SODIUM PHOSPHATE, MONOBASIC 5 parts, tripoly phosphate sodium STPP 8 parts, Triton DF-165 part, Surfynol DF-110D 4 parts, Surfynol DF-220 2 parts, white carbon black 8 parts.
The preparation method of above-described embodiment is: first by Sunmorl N 60S, urea, SODIUM PHOSPHATE, MONOBASIC, and tripoly phosphate sodium STPP fully mixes for subsequent use.Then by Triton DF-16, Surfynol DF-110D, Surfynol DF-220 mixes, and is sprayed onto on white carbon black, and white carbon black is fully adsorbed.Finally above-mentioned all raw materials are joined together, mix.Obtain homogeneous powder solid.
In order to verify result of use of the present invention, the wash bottle additive getting above-described embodiment 1 preparation is verified in Retrieve beer bottle Cleaning Line.
By weight, pressed powder wash bottle additive 0.3 part in embodiment 1,2.5 parts, sodium hydroxide, 97.2 parts, water, is applied to directly adding in alkaline working fluid after this reagent mix in bottle washing machine.Wash bottle temperature is 75 DEG C-85 DEG C.
| Wash bottle order of classes or grades at school | Bottle source | Wash bottle amount (individual) | Foam height | De-mark rate | White vase rate |
| 1 | Dirt bottle | 2000 | Non-foam | 99.7％ | 99.6％ |
| 2 | Mildew bottle | 2000 | Non-foam | 99.5％ | 99.3％ |
| 3 | Weathering bottle | 2000 | Non-foam | 99.6％ | 99.4％ |
| 4 | Worm's ovum bottle | 2000 | Non-foam | 99.3％ | 99.1％ |
| 5 | Greasy dirt bottle | 2000 | Non-foam | 99.8％ | 99.5％ |
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.
Claims (3)
1. a solid wash bottle additive, it is characterized in that, mainly comprise the raw material composition of following weight part: Sunmorl N 60S 40-60 part, urea 5-15 part, SODIUM PHOSPHATE, MONOBASIC 1-10 part, tripoly phosphate sodium STPP 5-15 part, Triton DF-16 1-5 part, Surfynol DF-110D 1-5 part, Surfynol DF-220 1-5 part, white carbon black 5-15 part.
2. solid wash bottle additive according to claim 1, is characterized in that: be preferably Sunmorl N 60S 55 parts, 12 parts, urea, SODIUM PHOSPHATE, MONOBASIC 6 parts, tripoly phosphate sodium STPP 8 parts, Triton DF-16 3 parts, Surfynol DF-110D 2 parts, Surfynol DF-220 2 parts, white carbon black 12 parts.
3. a preparation method for solid wash bottle additive, is characterized in that: first by Sunmorl N 60S, urea, SODIUM PHOSPHATE, MONOBASIC, tripoly phosphate sodium STPP fully mixes for subsequent use; Then by Triton DF-16, Surfynol DF-110D, Surfynol DF-220 mixes, and is sprayed onto on white carbon black, and white carbon black is fully adsorbed; Finally above-mentioned all raw materials are joined together, mix.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510452065.4A CN105002023B (en) | 2015-07-29 | 2015-07-29 | A kind of preparation of solid wash bottle additive |
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| CN201510452065.4A CN105002023B (en) | 2015-07-29 | 2015-07-29 | A kind of preparation of solid wash bottle additive |
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| CN105002023A true CN105002023A (en) | 2015-10-28 |
| CN105002023B CN105002023B (en) | 2017-08-01 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11214763B2 (en) | 2018-01-26 | 2022-01-04 | Ecolab Usa Inc. | Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a carrier |
| US11377628B2 (en) | 2018-01-26 | 2022-07-05 | Ecolab Usa Inc. | Solidifying liquid anionic surfactants |
| US11655436B2 (en) | 2018-01-26 | 2023-05-23 | Ecolab Usa Inc. | Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a binder and optional carrier |
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| CN1064307A (en) * | 1991-02-21 | 1992-09-09 | 四川省轻工业研究所 | The washing powder that contains precipitated silica |
| CN1079506A (en) * | 1992-06-05 | 1993-12-15 | 湖北省沙市市日用化工总厂 | Industrial bottle-washing detergent |
| CN1085942A (en) * | 1992-08-18 | 1994-04-27 | 普罗格特-甘布尔公司 | Detergent additives |
| CN1191893A (en) * | 1997-02-28 | 1998-09-02 | 陈又红 | Multifunctional bottle cleaning agent |
| CN1651560A (en) * | 2004-12-29 | 2005-08-10 | 广州泰成消毒洗涤用品有限公司 | Bottle cleaner for cleaning recovered bottles |
| CN103232901A (en) * | 2013-04-18 | 2013-08-07 | 衡阳市天怡化工实业有限公司 | Beverage bottle cleaning agent and preparation method thereof |
| CN105616277A (en) * | 2015-12-31 | 2016-06-01 | 罗永强 | Shampoo with moisturizing and softening functions |
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2015
- 2015-07-29 CN CN201510452065.4A patent/CN105002023B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064307A (en) * | 1991-02-21 | 1992-09-09 | 四川省轻工业研究所 | The washing powder that contains precipitated silica |
| CN1079506A (en) * | 1992-06-05 | 1993-12-15 | 湖北省沙市市日用化工总厂 | Industrial bottle-washing detergent |
| CN1085942A (en) * | 1992-08-18 | 1994-04-27 | 普罗格特-甘布尔公司 | Detergent additives |
| CN1191893A (en) * | 1997-02-28 | 1998-09-02 | 陈又红 | Multifunctional bottle cleaning agent |
| CN1651560A (en) * | 2004-12-29 | 2005-08-10 | 广州泰成消毒洗涤用品有限公司 | Bottle cleaner for cleaning recovered bottles |
| CN103232901A (en) * | 2013-04-18 | 2013-08-07 | 衡阳市天怡化工实业有限公司 | Beverage bottle cleaning agent and preparation method thereof |
| CN105616277A (en) * | 2015-12-31 | 2016-06-01 | 罗永强 | Shampoo with moisturizing and softening functions |
Non-Patent Citations (1)
| Title |
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| 黄玉媛 等: "《精细化学品实用配方手册》", 31 January 2009, 中国纺织出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11214763B2 (en) | 2018-01-26 | 2022-01-04 | Ecolab Usa Inc. | Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a carrier |
| US11377628B2 (en) | 2018-01-26 | 2022-07-05 | Ecolab Usa Inc. | Solidifying liquid anionic surfactants |
| US11655436B2 (en) | 2018-01-26 | 2023-05-23 | Ecolab Usa Inc. | Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a binder and optional carrier |
| US11834628B2 (en) | 2018-01-26 | 2023-12-05 | Ecolab Usa Inc. | Solidifying liquid anionic surfactants |
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| CN105002023B (en) | 2017-08-01 |
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