CN104987797B - A kind of vehicle interior components with exceptional overcoat - Google Patents

A kind of vehicle interior components with exceptional overcoat Download PDF

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Publication number
CN104987797B
CN104987797B CN201510463985.6A CN201510463985A CN104987797B CN 104987797 B CN104987797 B CN 104987797B CN 201510463985 A CN201510463985 A CN 201510463985A CN 104987797 B CN104987797 B CN 104987797B
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parts
coating
vehicle interior
interior components
nsio
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CN104987797A (en
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李建
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Yancheng Chunxing Machinery Manufacturing Co., Ltd.
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Yancheng Chunxing Machinery Manufacturing Co Ltd
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Abstract

The invention provides a kind of vehicle interior components with exceptional overcoat, it is characterised in that:The coating is by the way that coating is uniformly coated on into vehicle interior components surface, is dried 25 minutes under conditions of 160 180 DEG C so that the coating weight of coating is 60 90g/m2Under conditions of obtain.The coating composition includes crosslink propylene acid esters, polyurethane, melamine, red phosphorus, ammonium dihydrogen phosphate, glycerine, ethylene glycol, butyl cellosolve, Na2O·nSiO2、TiO2And water, and in terms of the parts by weight of solid 100 of crosslink propylene acid esters, 35 parts of polyurethane, 10 15 parts of melamine, 5 10 parts of red phosphorus, 5 15 parts of ammonium dihydrogen phosphate, 5 12 parts of glycerine, 35 parts of ethylene glycol, 5 10 parts of butyl cellosolve, Na2O·nSiO25 10 parts, TiO210 20 parts, 150 180 parts of water.The vehicle interior components of the present invention have had excellent fire resistance and enough flexibilities and uniform performance concurrently.

Description

A kind of vehicle interior components with exceptional overcoat
Technical field
The present invention relates to the technical field of coating, the vehicle interior components such as especially a kind of vehicle seat, car cushion and carriage ceiling are used Coating composition and its obtained vehicle interior components of coating.
Background technology
In recent years, with the continuous development of Domestic Automotive Industry and the increasingly raising of people's living standard, for vehicle seat, car The demand of the automobile interior part such as pad and carriage ceiling is increasing, and in order to improve the overall performance of vehicle, for each of in-car Individual part is proposed higher requirement, such as the riding comfort of the flame-retarding of vehicle, vehicle, automobile interior is attractive in appearance Property and water proofing property etc., all it is the improved direction of vehicle interior appliance from now on.
In order to improve the various performances of the automobile interior parts such as vehicle seat, car cushion and carriage ceiling, most effective method is Implement one layer of coating on the surface of substrate component, then obtain corresponding performance using different coating compositions in the coating, And for the mostly important consideration of vehicle safety, widely used in the functional coating of automotive trim is fire-retardant painting Layer.The coating composition used in current most of automotive trim flame retardant coatings has mainly used the halogen systems such as deca-BDE The synthetic resin emulsion of the composition such as fire retardant and acrylic acid ester emulsion.But halogenated flame retardant smoke amount is big, the halogenation discharged Hydrogen has severe corrosive, and it is poisonous carcinogenic to produce a large amount of more bromo benzos evil English and PBDF etc. Material, influences human homergy, therefore as people are for the growing interest of environmental problem, the use of halogenated flame retardant by Increasing limitation.Particularly in terms of automobile inside components, halogenated flame retardant is easier and built-in material is widely used Polyester fiber generates halogenation pernicious gas, and urgent requirement substitutes the application of halogenated flame retardant using bittern-free flame-proof material.
Phosphorus flame retardant (including organic and inorganic system) is found to have the excellent fire-retardancy for the halogenated flame retardant that matches in excellence or beauty, from And by a lot of research and application, but serious waterproof sex chromosome mosaicism be present in phosphorus flame retardant, it is fine in vehicle seat or the polyester of car cushion The phosphorus flame retardant used in dimension fabric is even only experience warm water all can be by significant dissolution.Meanwhile phosphorus flame retardant by In the reason for the dosage and performance etc., the fabric flexibility deficiency of the built-in material after Coating is frequently resulted in, and then is made Coating easily with base material occur cracking even peel off the problems such as, both influenceed it is attractive in appearance, also cause apply layer function failure.
The purpose of the present invention is to provide a kind of Coating material composition of the vehicle interior components with excellent combination property The vehicle interior components that thing and its coating obtain, so as to obtain enough fire resistances, and can obtains enough flexibilities With uniform performance, to ensure the overall performances such as the security of vehicle interior components, comfortableness and aesthetic property.
The content of the invention
The purpose of the present invention is to provide a kind of Coating material composition of the vehicle interior components with excellent combination property The vehicle interior components that thing and its coating obtain, the coating composition is chosen by the composition of uniqueness and preferable component proportion is realized The vehicle interior components for scribbling the coating have the overall performances such as excellent security, comfortableness and aesthetic property.
To achieve the above object, present invention employs following technical scheme:
A kind of vehicle interior components with exceptional overcoat, it is characterised in that:
The coating is by the way that coating is uniformly coated on into vehicle interior components surface, is dried under conditions of 160-180 DEG C 2-5 minutes so that the coating weight of coating is 60-90g/m2Under conditions of obtain;
The coating composition includes crosslink propylene acid esters, polyurethane, melamine, red phosphorus, ammonium dihydrogen phosphate, the third three Alcohol, ethylene glycol, butyl cellosolve, Na2O·nSiO2、TiO2And water, and with the weight of solid 100 of crosslink propylene acid esters Part meter, polyurethane 3-5 parts, melamine 10-15 parts, red phosphorus 5-10 parts, ammonium dihydrogen phosphate 5-15 parts, glycerine 5-12 parts, second Glycol 3-5 parts, butyl cellosolve 5-10 parts, Na2O·nSiO25-10 parts, TiO210-20 parts, water 150-180 parts.
As preferable, the gel fraction of the crosslink propylene acid esters is 50%-70%.
As preferable, the number of the polyurethane is 4 parts.
As preferable, the number of the melamine is 12 parts.
As preferable, the weight ratio of the red phosphorus and ammonium dihydrogen phosphate is 1: 2, it is further preferred that the number of the two For 7 parts and 14 parts.
As preferable, the number of the glycerine is 10 parts.
As preferable, the number of the ethylene glycol is 4 parts, and the number of the butyl cellosolve is 8 parts.
As preferable, the Na2O·nSiO2With TiO2Weight ratio be 1: 2, it is further preferred that the number of the two For 7 parts and 14 parts.
As preferable, the Na2O·nSiO2Middle n=1.8-2.2.
As preferable, the TiO2For rutile-type, threadiness, 0.3-0.5 μm of fiber footpath, 50-80 μm of length.
The coating be by by crosslink propylene acid esters, polyurethane, melamine, red phosphorus, ammonium dihydrogen phosphate, glycerine, Ethylene glycol, butyl cellosolve, Na2O·nSiO2、TiO2Raw material is added in 35-40 DEG C of deionized water successively by proportioning, is filled Obtained after dividing stirring 2-3 hours.
The inventive method has the beneficial effect that:Chosen by the composition of uniqueness and preferable component proportion realizes and scribbles this The vehicle interior components of coating have the overall performances such as excellent security, comfortableness and aesthetic property.
Embodiment
Embodiment 1
Based on the parts by weight of solid 100 of crosslink propylene acid esters, 3 parts of polyurethane, 10 parts of melamine, 5 parts of red phosphorus, phosphoric acid 5 parts of ammonium dihydrogen, 5 parts of glycerine, 3 parts of ethylene glycol, 5 parts of butyl cellosolve, Na2O·nSiO25 parts, TiO210 parts of proportionings are accurate Standby raw material, ready raw material is added in 38 DEG C of 150 deionized waters successively, after being sufficiently stirred 2 hours, obtains the present invention The product of embodiment 1.
Wherein the gel fraction of crosslink propylene acid esters is 70%.
Wherein Na2O·nSiO2Middle n=2.0;TiO2For rutile-type, threadiness, 0.4 μm of fiber footpath, 70 μm of length.
Embodiment 2-9 is adjusted to the content of each component, and specific content ratio is listed in table 1.
Aforementioned coating composition product is uniformly coated on PET sheet surface, 3 points are dried under conditions of 170 DEG C Clock so that the coating weight of coating is 70g/m2, test sheet is obtained to test the performance of coating composition.
Embodiment 10-12 is adjusted to the coating process of the paint formulation of embodiment 1, referring specifically to table 2.
The test condition of anti-flammability is that test sheet is cut into 30mm × 30mm × 1mm in table 1, is commented using UL94 standards The fire resistance of valency coating, specially zero:V-0 and the above are quite resistance to combustion;△:The more resistance to combustion of V-1, V2;×:HB be intolerant to Combustion.
The test condition of water proofing property is in table 1, by 5mm water droplet drop coating in the surface of test sheet, checks coating surface Infiltration and the situation that becomes sticky, specially zero:Do not glue, and non-water breakthrough penetrates into coating surface;△:Do not glue, but there is water to penetrate into coating table The sign in face;×:Obvious sign that is viscous, and thering is water to penetrate into coating surface.
The test condition of flexibility is to allow 10 bit test persons to be touched with hand coating sample in table 1, passes through touching for tester Feel to confirm the soft comfortable degree of coating, soft feel number is set to soft (zero), soft feel number 5-8 people more than 8 people's Be set to relatively soft (△), being set to harder (×) below 5 people.
The test condition of even compact is that coating surface is divided into 100 1mm × 1mm lattice in table 1, then Adhesive tape is tightly adhered to thereon, then peels off adhesive tape, calculates the quantity of the intact lattice of coating, when more than 90, Think that coating uniform is fine and close, adhesiveness is excellent (zero), when for 50-90 when, it is believed that coating more even compact, adhesiveness is good (△), when less than 50, then it is assumed that coating compactness poor adhesion (×).
It is further described below for the formula of coating system of the present invention:
Crosslink propylene acid esters in coating of the present invention is a kind of heat-proof flame-proof resin with excellent fire-retardancy, and it is firing There is slow burning velocity, the main component as coating of the present invention during burning.Especially with as gel fraction 50-70% The crosslink propylene acid esters of higher degree of crosslinking can play flame retardant effect to greatest extent on the premise of control cost.
Polyurethane is extremely important for the paintability of coating as tackifier in coating of the present invention, and its content is too low to be made Coating ingredients are obtained excessively to penetrate into base material and influence coating performance, but its too high levels is also unfavorable for the uniform coating of coating, also Comfortableness can be influenceed, therefore controls its content in 3-5 parts.
Melamine has good iris action in coating of the present invention, can prevent that red phosphorus combustion inhibitor etc. is inorganic well The moisture absorption of material, so as to ensure the water proofing property of coating, but its content can not be too high, otherwise will influence coating it is fire-retardant, The whole structure of flexibility, therefore its content is controlled in 10-15 parts.
Red phosphorus and ammonium dihydrogen phosphate in coating of the present invention, red phosphorus has very excellent flame retardant effect, in order to play it Excellent effect, its content is preferably more than 5 parts, but its too high levels can then cause the coating of coating and water proofing property to become Difference, therefore its content is preferably controlled below 10 parts;Ammonium dihydrogen phosphate can cooperate with red phosphorus plays flame retardant effect, can add More than 5 parts, but too high addition influences the effect of red phosphorus and overall component proportion, therefore it is preferably controlled in less than 15 parts; Applicant is particular, it is found that the ratio of the two can play best flame retardant effect when being 1: 2.
Glycerine in coating of the present invention can aid in the fire resistance of crosslink propylene acid esters well, in order that itself and friendship Acrylate synergy is fire-retardant, and its addition at least should be 5 parts, but excessive addition can not improve the anti-flammability of system Can, the coating of coating can be caused to be deteriorated on the contrary, therefore control its content below 12 parts.
Ethylene glycol in coating of the present invention can play finely dispersed effect, more for the addition of in coating of the present invention Red phosphorus, Na2O·nSiO25 parts, TiO2Formula, its effect is particularly significant, in order to play its effect, its addition at least should For 3 parts, but excessive addition can't significantly improve the stable and uniform of coating, cause trouble on the contrary for drying etc., therefore Its content is controlled below 5 parts.
Butyl cellosolve in coating of the present invention has the function that to improve each COMPONENTS COMPATIBILITY well, particularly its with Ethylene glycol is used in conjunction with, and significantly improves the uniform and stable property of coating system, in order to play its effect, it should at least add 5 Part, but its excessive addition can't significantly improve the stable and uniform of coating, cause trouble on the contrary for drying etc., therefore control Its content is made below 10 parts.
Na in coating of the present invention2O·nSiO25 parts have extraordinary heat-proof combustion-resistant performance, and it can significantly improve painting The combustion threshold of material system, in order to play its effect, its addition at least should be 5 parts, but excessively add for heat-proof combustion-resistant Performance impact unobvious, can increase the burden of system coating on the contrary, therefore control its content below 10 parts.Meanwhile Na2O· nSiO2In n value preferably between 1.8-2.2, n values are too small to be difficult to play heat-proof combustion-resistant performance, and it is excessive to fire hot n values, general So that Na2O·nSiO2Dissolubility be deteriorated, so as to influence the paintability of coating.TiO in coating of the present invention2Itself it is A kind of inorganic fire-retarded filler, at the same its present invention coating system in can well with Na2O·nSiO2Collaboration plays carrier The effect of support, once coated component is burnt, it is able to maintain that the intensity and compactness of coating, so as to preferably play Fire resistance;And TiO2Preferably rutile-type, threadiness, 0.3-0.5 μm of fiber footpath, 50-80 μm of length, this is enabled to Coating obtains the performances such as more preferable obdurability, the sewing thread fatigue strength so as to ensure in-car part.Applicant particular, it is found that Na2O·nSiO2With TiO2Ratio be 1: 2 when can play best flame retardant effect.
In coating process in the present invention, coating coating weight can not be too low, otherwise it cannot be guaranteed that anti-flammability, the waterproof of coating The performances such as property, but can not be too high, the deterioration of the performances such as flexibility, coating, sewing thread fatigue strength otherwise can be caused, most It is controlled well in 60-90g/m2.Drying temperature during coating is preferably controlled in 160-180 DEG C, too low to be unfavorable for coating each component Cooperation and coating shaping, while influence efficiency of construction, it is too high, the timeliness of composition and the effect of coating can be caused to be deteriorated.
Table 1
1 2 3 4 5 6 7 8 9
Crosslink propylene acid esters 100 100 100 100 100 100 100 100 100
Polyurethane 3 4 4 5 5 1 4 5 3
Melamine 10 11 12 14 15 5 12 13 12
Red phosphorus 5 6 7 8 10 6 2 7 6
Ammonium dihydrogen phosphate 5 9 14 7 15 8 3 12 12
Glycerine 5 8 10 10 12 9 2 9 8
Ethylene glycol 3 4 4 5 5 4 4 1 4
Butyl cellosolve 5 7 8 9 10 7 7 1 7
Na2O·nSiO2 5 6 7 9 10 8 7 8 3
TiO2 10 12 14 16 20 18 10 13 5
Water 150 160 160 170 180 160 170 180 160
Anti-flammability × × ×
Water proofing property ×
Flexibility
Even compact × ×
The present invention coating be adapted to the surface of various vehicle interior components to coat, such as the vehicle seat of vehicle interior, car cushion and Upholstery etc..
Table 2
Coating weight (g/m2) Drying temperature (DEG C) Anti-flammability Water proofing property Flexibility Compactness
10 60 160
11 90 180
12 50 150 × × ×
13 110 200 × × ×
Although the present invention illustrates coating effect of the present invention by above-described embodiment, the invention is not limited in above-mentioned reality Apply example.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention, to each raw material of product of the present invention etc. Effect replacement and the addition of auxiliary element, the selection of concrete mode etc., within the scope of all falling within protection scope of the present invention and disclosing.

Claims (3)

  1. A kind of 1. vehicle interior components with exceptional overcoat, it is characterised in that:
    The coating is by the way that coating is uniformly coated on into vehicle interior components surface, and 2-5 points are dried under conditions of 160-180 DEG C Clock so that the coating weight of coating is 60-90g/m2Under conditions of obtain;
    The coating composition is by crosslink propylene acid esters, polyurethane, melamine, red phosphorus, ammonium dihydrogen phosphate, glycerine, second two Alcohol, butyl cellosolve, Na2O·nSiO2、TiO2Formed with water, and with the parts by weight of solid 100 of crosslink propylene acid esters Meter, polyurethane 3-5 parts, melamine 10-15 parts, red phosphorus 5-10 parts, ammonium dihydrogen phosphate 5-15 parts, glycerine 5-12 parts, second two Alcohol 3-5 parts, butyl cellosolve 5-10 parts, Na2O·nSiO25-10 parts, TiO210-20 parts, water 150-180 parts;The friendship The gel fraction of acrylate is 50%-70%;The weight ratio of the red phosphorus and ammonium dihydrogen phosphate is 1: 2;The Na2O· nSiO2With TiO2Weight ratio be 1: 2;The Na2O·nSiO2Middle n=1.8-2.2;The TiO2It is fibrous for rutile-type, 0.3-0.5 μm of fiber footpath, 50-80 μm of length.
  2. 2. vehicle interior components according to claim 1, it is characterised in that:The vehicle interior components are vehicle seat or car cushion.
  3. 3. vehicle interior components according to claim 1, it is characterised in that:The vehicle interior components are PET material.
CN201510463985.6A 2015-07-31 2015-07-31 A kind of vehicle interior components with exceptional overcoat Active CN104987797B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100498226B1 (en) * 2004-06-17 2005-07-01 진성산업(주) Fire retardant coating composition and coating method thereof
CN101712836A (en) * 2009-10-28 2010-05-26 广东省长大公路工程有限公司 Mildewproof flame-retardant tunnel decoration paint, preparation method and application thereof
JP2013049858A (en) * 2012-10-11 2013-03-14 Nisshin Chem Ind Co Ltd Coating composition for vehicular interior material, and vehicular interior material
CN103788843A (en) * 2014-02-13 2014-05-14 芜湖市宝艺游乐科技设备有限公司 High-glossiness flame-retardant UV (Ultraviolet)-curable coating material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100498226B1 (en) * 2004-06-17 2005-07-01 진성산업(주) Fire retardant coating composition and coating method thereof
CN101712836A (en) * 2009-10-28 2010-05-26 广东省长大公路工程有限公司 Mildewproof flame-retardant tunnel decoration paint, preparation method and application thereof
JP2013049858A (en) * 2012-10-11 2013-03-14 Nisshin Chem Ind Co Ltd Coating composition for vehicular interior material, and vehicular interior material
CN103788843A (en) * 2014-02-13 2014-05-14 芜湖市宝艺游乐科技设备有限公司 High-glossiness flame-retardant UV (Ultraviolet)-curable coating material and preparation method thereof

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Effective date of registration: 20171113

Address after: 400056 Chongqing Banan District South Spring Street Golden Village Fifth clubs

Applicant after: CHONGQING LONGQUAN AUTO PARTS CO., LTD.

Address before: 063021 Hebei Province, Tangshan City Kaiping District Dongcheng Green Court Building 2 105 house 2

Applicant before: Liu Shidi

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Inventor after: Li Jian

Inventor before: Liu Shidi

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Effective date of registration: 20171130

Address after: 224000 in Jiangsu province in the south of Yancheng City District New River Street Park Road No. 22, No. four standard factory (CNX)

Applicant after: Yancheng Chunxing Machinery Manufacturing Co., Ltd.

Address before: 400056 Chongqing Banan District South Spring Street Golden Village Fifth clubs

Applicant before: CHONGQING LONGQUAN AUTO PARTS CO., LTD.

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Denomination of invention: Vehicle interior component with excellent coating

Effective date of registration: 20211119

Granted publication date: 20171226

Pledgee: Bank of Jiangsu Co.,Ltd. Yancheng branch

Pledgor: YANCHENG CHUNXING MACHINERY MANUFACTURING Co.,Ltd.

Registration number: Y2021320000345