CN104987790A - Waterproof corrosion-resistant photocuring paint - Google Patents
Waterproof corrosion-resistant photocuring paint Download PDFInfo
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- CN104987790A CN104987790A CN201510387352.1A CN201510387352A CN104987790A CN 104987790 A CN104987790 A CN 104987790A CN 201510387352 A CN201510387352 A CN 201510387352A CN 104987790 A CN104987790 A CN 104987790A
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Abstract
The invention discloses waterproof corrosion-resistant photocuring paint. The paint comprises, by weight, 15-40 parts of acrylic emulsion, 3-10 parts of polyurethane, 0.5-5 parts of rosin modified phenolic resin, 0.5-2 parts of triethoxyisobutylsilane, 0.5-1.7 parts of carboxymethylcellulose, 0.6-0.9 parts of hydroxypropyl methyl cellulose, 1-4 parts of dipropylene glycol methyl ether, 2-4 parts of potassium chromate, 4-6 parts of aluminium hydroxide, 2-6 parts of preservatives, 1-4 parts of barium sulfate, 2-5 parts of antioxidants, 6-14 parts of photoinitiators, 3-6 parts of defoaming agents, 2-7 parts of a molybdenum compound, 2-6 parts of sodium sulfate and 16-23 parts of water. The photocuring paint has the advantages of being short in curing time, low in curing temperature and low in volatile component, and meanwhile the coating is good in waterproof performance and corrosion resistance.
Description
Technical field
The present invention relates to photo-cured coating field, particularly relate to a kind of water-tight corrosion-proof photo-cured coating.
Background technology
Along with the development of coatings industry, people can note the performance of its safety and environmental protection and the problem of use cost more when using coating.All easily distribute obnoxious flavour after traditional many coating use, thus be detrimental to health; Although some coating can not give out obnoxious flavour, also have the problem of length set time, need to coordinate other instrument to accelerate solidification, thus improve use cost.
Photo-cured coating of the prior art, have short, the advantage such as solidification value is low, volatile matter is low set time, but its waterproof and antiseptic property cannot meet the demand of Vehicles Collected from Market.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes a kind of water-tight corrosion-proof photo-cured coating.Have set time short, solidification value is low, the advantage that volatile matter is low, also has good waterproof and antiseptic property simultaneously.
A kind of water-tight corrosion-proof photo-cured coating that the present invention proposes, its raw material comprises by weight: ACRYLIC EMULSION 15-40 part, urethane 3-10 part, rosin modified phenolic resin 0.5-5 part, isobutyl triethoxy silane 0.5-2 part, carboxymethyl cellulose 0.5-1.7 part, Vltra tears 0.6-0.9 part, dipropylene glycol methyl ether 1-4 part, potassiumchromate 2-4 part, aluminium hydroxide 4-6 part, sanitas 2-6 part, barium sulfate 1-4 part, oxidation inhibitor 2-5 part, light trigger 6-14 part, defoamer 3-6 part, molybdenum compound 2-7 part, sodium sulfate 2-6 part, water 16-23 part.
Preferably, rosin modified phenolic resin is prepared according to following technique: xylenol and aluminum trichloride (anhydrous) are added and mix, be warming up to 60-70 DEG C, insulation 1-3h, do not stop in the process heated up to stir, then add formaldehyde, regulate pH > 7, be warming up to 100-115 DEG C, insulation 2-4h obtains material a; In material a, add rosin, be warming up to 130-145 DEG C, insulation 3.5-5h, obtains material b; In material b, add tetramethylolmethane and metaphosphoric acid, be warming up to 180-200 DEG C, insulation 1-2h, continues to be warming up to 240-260 DEG C, and insulation 2-4h, obtains rosin modified phenolic resin.
Preferably, in the preparation technology of rosin modified phenolic resin, the mass ratio of xylenol, aluminum trichloride (anhydrous) and formaldehyde is 80-120:2-5:30-40.
Preferably, in the preparation technology of rosin modified phenolic resin, the mass ratio of rosin, tetramethylolmethane and metaphosphoric acid is 150-250:20-40:2-7.
Preferably, sanitas is in CMIT and/or MIT.
Preferably, oxidation inhibitor is one or more compositions in pentanoic, Ursol D and dihydroquinoline.
Preferably, light trigger is 1-hydroxy-cyciohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, one or more compositions in TMDPO.
Preferably, defoamer is one in n-Octanol, tributyl phosphate, triphenylphosphate, emulsification methyl-silicone oil, emulsification polymethylphenyl siloxane fluid or two or more composition.
Preferably, its raw material comprises by weight: ACRYLIC EMULSION 17-38 part, urethane 5-8 part, rosin modified phenolic resin 1.5-4 part, isobutyl triethoxy silane 1.0-1.5 part, carboxymethyl cellulose 0.7-1.5 part, Vltra tears 0.7-0.8 part, dipropylene glycol methyl ether 2-3 part, potassiumchromate 2.5-3.5 part, aluminium hydroxide 4.5-5.5 part, sanitas 3-5 part, barium sulfate 2-3 part, oxidation inhibitor 2.5-4.5 part, light trigger 7-13 part, defoamer 4-5 part, molybdenum compound 3-6 part, sodium sulfate 3-5 part, water 18-21 part.
Preferably, its raw material comprises by weight: ACRYLIC EMULSION 27.5 parts, urethane 6.5 parts, rosin modified phenolic resin 2.75 parts, isobutyl triethoxy silane 1.25 parts, carboxymethyl cellulose 1.1 parts, Vltra tears 0.75 part, dipropylene glycol methyl ether 2.5 parts, potassiumchromate 3 parts, 5 parts, aluminium hydroxide, sanitas 4 parts, 2.5 parts, barium sulfate, 3.5 parts, oxidation inhibitor, light trigger 10 parts, defoamer 4.5 parts, molybdenum compound 4.5 parts, 4 parts, sodium sulfate, 19.5 parts, water.
Preparation method of the present invention, comprises the steps:
S1, ACRYLIC EMULSION, urethane, rosin modified phenolic resin, isobutyl triethoxy silane and water are joined reactor, carboxymethyl cellulose and Vltra tears is added successively under the whipped state of limit, be warming up to 30-45 DEG C, first stir 10-15 minute with the speed of 300-400r/min, and then stir 15-20 minute with the speed of 500-800r/min;
S2, in reactor, add dipropylene glycol methyl ether, potassiumchromate, aluminium hydroxide, sanitas, barium sulfate, oxidation inhibitor, light trigger, defoamer, molybdenum compound and sodium sulfate successively, 20-25 minute is stirred with the speed of 800-1000r/min, then drop in sand mill and grind, filter with 500 order filter cloths again.
In the present invention, with ACRYLIC EMULSION, urethane and rosin modified phenolic resin for prepolymer, and ratio is coordinated mutually between composition, also the antiseptic property of prepolymer is improve to a certain extent by Abietyl modified resol, mutually promote with ACRYLIC EMULSION and urethane simultaneously, effectively improve the integral waterproofing antiseptic property of prepolymer; The isobutyl triethoxy silane added, its small molecule structure had can penetrate cementing properties surface, penetrate into inside concrete and be exposed to the air in acidity or alkaline environment and the water molecules generation chemical reaction in substrate, form permanent firmly high-environmental waterproof layer, percdation, suppress moisture absorption, produce waterproof, anti-Cl
-, anti-ultraviolet performance and there is ventilation property; The carboxymethyl cellulose added, Vltra tears and dipropylene glycol methyl ether are as sizing agent, both are used in combination make the dilution of protective system and plybonding effect better, film thin and thick is even, level and smooth film can be formed, potassiumchromate, aluminium hydroxide and sanitas is added and the proportional range of conservative control between them in above-mentioned coating, not only can strengthen the antiseptic property of above-mentioned coating, and greatly strengthen the wear resisting property of coating, significant prolongation work-ing life of above-mentioned coating.In the present invention, it is short that described water-tight corrosion-proof photo-cured coating has set time, and solidification value is low, and the advantage that volatile matter is low also has good waterproof and antiseptic property simultaneously.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In embodiment, the weight part of ACRYLIC EMULSION can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 27.5,28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, the weight part of urethane can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts, 10 parts, the weight part of rosin modified phenolic resin can be 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1.0 part, 1.1 part, 1.2 part, 1.3 part, 1.4 part, 1.5 part, 1.6 part, 1.7 part, 1.8 part, 1.9 part, 2.0 part, 2.1 part, 2.2 part, 2.3 part, 2.4 part, 2.5 part, 2.6 part, 2.7 part, 2.75 part, 2.8 part, 2.9 part, 3.0 part, 3.1 part, 3.2 part, 3.3 part, 3.4 part, 3.5 part, 3.6 part, 3.7 part, 3.8 part, 3.9 part, 4.0 part, 4.1 part, 4.2 part, 4.3 part, 4.4 part, 4.5 part, 4.6 part, 4.7 part, 4.8 part, 4.9 part, 5 parts, the weight part of isobutyl triethoxy silane can be 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1.0 parts, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, 2 parts, the weight part of carboxymethyl cellulose can be 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 1.0 parts, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, the weight part of Vltra tears can be 0.6 part, 0.7 part, 0.8 part, 0.9 part, the weight part of dipropylene glycol methyl ether can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, the weight part of potassiumchromate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, the weight part of aluminium hydroxide can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, the weight part of sanitas can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, the weight part of barium sulfate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, the weight part of oxidation inhibitor can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, the weight part of light trigger can be 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, the weight part of defoamer can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, the weight part of molybdenum compound can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, the weight part of sodium sulfate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, the weight part of water can be 16 parts, 16.5 parts, 17 parts, 17.5 parts, 18 parts, 18.5 parts, 19 parts, 19.5 parts, 20 parts, 20.5 parts, 21 parts, 21.5 parts, 22 parts, 22.5 parts, 23 parts.
Embodiment 1
A kind of water-tight corrosion-proof photo-cured coating that the present invention proposes, its raw material comprises by weight: ACRYLIC EMULSION 27.5 parts, urethane 6.5 parts, rosin modified phenolic resin 2.75 parts, isobutyl triethoxy silane 1.25 parts, carboxymethyl cellulose 1.1 parts, Vltra tears 0.75 part, dipropylene glycol methyl ether 2.5 parts, potassiumchromate 3 parts, 5 parts, aluminium hydroxide, CMIT 4 parts, 2.5 parts, barium sulfate, pentanoic 3.5 parts, 1-hydroxy-cyciohexyl phenyl ketone 10 parts, n-Octanol 4.5 parts, molybdenum compound 4.5 parts, 4 parts, sodium sulfate, 19.5 parts, water.
Wherein, rosin modified phenolic resin is prepared according to following technique: 100 parts of xylenols and 3.5 parts of aluminum trichloride (anhydrous)s are added by weight and mix, be warming up to 65 DEG C, insulation 2h, do not stop in the process heated up to stir, then pass into 35 parts of formaldehyde, regulate pH > 7, be warming up to 107.5 DEG C, insulation 3h obtains material a; In material a, add 200 parts of rosin, be warming up to 137.5 DEG C, insulation 4.25h, obtains material b; In material b, add 30 parts of tetramethylolmethanes and 4.5 parts of metaphosphoric acids, be warming up to 190 DEG C, insulation 1.5h, continues to be warming up to 250 DEG C, and insulation 3h, obtains rosin modified phenolic resin.
Embodiment 2
A kind of water-tight corrosion-proof photo-cured coating that the present invention proposes, its raw material comprises by weight: ACRYLIC EMULSION 15 parts, urethane 10 parts, rosin modified phenolic resin 0.5 part, isobutyl triethoxy silane 2 parts, carboxymethyl cellulose 0.5 part, Vltra tears 0.9 part, dipropylene glycol methyl ether 1 part, potassiumchromate 4 parts, 4 parts, aluminium hydroxide, MIT 6 parts, 1 part, barium sulfate, Ursol D 5 parts, 6 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone, tributyl phosphate 6 parts, molybdenum compound 2 parts, 6 parts, sodium sulfate, 16 parts, water.
Described rosin modified phenolic resin is prepared according to following technique: 80 parts of xylenols and 5 parts of aluminum trichloride (anhydrous)s are added by weight and mix, be warming up to 60 DEG C, insulation 1h, do not stop in the process heated up to stir, then 40 parts of formaldehyde are passed into, regulate pH > 7, be warming up to 100 DEG C, insulation 4h obtains material a; In material a, add 150 parts of rosin, be warming up to 145 DEG C, insulation 3.5h, obtains material b; In material b, add 40 parts of tetramethylolmethanes and 2 parts of metaphosphoric acids, be warming up to 200 DEG C, insulation 1h, continues to be warming up to 260 DEG C, and insulation 2h, obtains rosin modified phenolic resin.
Embodiment 3
A kind of water-tight corrosion-proof photo-cured coating that the present invention proposes, its raw material comprises by weight: ACRYLIC EMULSION 40 parts, urethane 3 parts, rosin modified phenolic resin 5 parts, isobutyl triethoxy silane 0.5 part, carboxymethyl cellulose 1.7 parts, Vltra tears 0.6 part, dipropylene glycol methyl ether 4 parts, potassiumchromate 2 parts, 6 parts, aluminium hydroxide, CMIT 2 parts, 4 parts, barium sulfate, dihydroquinoline 2 parts, 2, 4, 6-trimethyl benzoyl diphenyl base phosphine oxide 14 parts, triphenylphosphate 3 parts, molybdenum compound 7 parts, 2 parts, sodium sulfate, 23 parts, water.
Wherein, rosin modified phenolic resin is prepared according to following technique: 120 parts of xylenols and 2 parts of aluminum trichloride (anhydrous)s are added by weight and mix, be warming up to 70 DEG C, insulation 3h, do not stop in the process heated up to stir, then pass into 30 parts of formaldehyde, regulate pH > 7, be warming up to 115 DEG C, insulation 2h obtains material a; In material a, add 250 parts of rosin, be warming up to 130 DEG C, insulation 5h, obtains material b; In material b, add 20 parts of tetramethylolmethanes and 7 parts of metaphosphoric acids, be warming up to 180 DEG C, insulation 2h, continues to be warming up to 240 DEG C, and insulation 4h, obtains rosin modified phenolic resin.
Embodiment 4
A kind of water-tight corrosion-proof photo-cured coating that the present invention proposes, its raw material comprises by weight: ACRYLIC EMULSION 17 parts, urethane 8 parts, rosin modified phenolic resin 1.5 parts, isobutyl triethoxy silane 1.5 parts, carboxymethyl cellulose 0.7 part, Vltra tears 0.8 part, dipropylene glycol methyl ether 2 parts, potassiumchromate 3.5 parts, 4.5 parts, aluminium hydroxide, sanitas 5 parts, 2 parts, barium sulfate, 4.5 parts, oxidation inhibitor, light trigger 7 parts, emulsification methyl-silicone oil 5 parts, molybdenum compound 3 parts, 5 parts, sodium sulfate, 18 parts, water.
Wherein, sanitas is the constituent in CMIT and MIT.Oxidation inhibitor is the composition in pentanoic, Ursol D and dihydroquinoline.Light trigger is the composition in 1-hydroxy-cyciohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone and TMDPO.
Wherein, rosin modified phenolic resin is prepared according to following technique: 88 parts of xylenols and 4.8 parts of aluminum trichloride (anhydrous)s are added by weight and mix, be warming up to 62 DEG C, insulation 1.2h, do not stop in the process heated up to stir, then pass into 39 parts of formaldehyde, regulate pH > 7, be warming up to 105 DEG C, insulation 3.8h obtains material a; In material a, add 158 parts of rosin, be warming up to 142 DEG C, insulation 3.8h, obtains material b; In material b, add 38 parts of tetramethylolmethanes and 3 parts of metaphosphoric acids, be warming up to 185 DEG C, insulation 1.5h, continues to be warming up to 258 DEG C, and insulation 2.5h, obtains rosin modified phenolic resin.
Embodiment 5
A kind of water-tight corrosion-proof photo-cured coating that the present invention proposes, its raw material comprises by weight: ACRYLIC EMULSION 38 parts, urethane 5 parts, rosin modified phenolic resin 4 parts, isobutyl triethoxy silane 1.0 parts, carboxymethyl cellulose 1.5 parts, Vltra tears 0.7 part, dipropylene glycol methyl ether 3 parts, potassiumchromate 2.5 parts, 5.5 parts, aluminium hydroxide, sanitas 3 parts, 3 parts, barium sulfate, 2.5 parts, oxidation inhibitor, light trigger 13 parts, emulsification polymethylphenyl siloxane fluid 5 parts, molybdenum compound 3 parts, 5 parts, sodium sulfate, 18 parts, water.
Wherein, sanitas is the constituent in CMIT and MIT.Oxidation inhibitor is the composition of pentanoic and Ursol D.Light trigger is the composition of 1-hydroxy-cyciohexyl phenyl ketone and 2-hydroxy-2-methyl-1-phenyl-1-acetone.
Wherein, rosin modified phenolic resin is prepared according to following technique: 118 parts of xylenols and 2.5 parts of aluminum trichloride (anhydrous)s are added by weight and mix, be warming up to 68 DEG C, insulation 2.8h, do not stop in the process heated up to stir, then pass into 32 parts of formaldehyde, regulate pH > 7, be warming up to 112 DEG C, insulation 3.5h obtains material a; In material a, add 240 parts of rosin, be warming up to 133 DEG C, insulation 4.8h, obtains material b; In material b, add 22 parts of tetramethylolmethanes and 6.8 parts of metaphosphoric acids, be warming up to 183 DEG C, insulation 1.8h, continues to be warming up to 243 DEG C, and insulation 3.6h, obtains rosin modified phenolic resin.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (10)
1. a water-tight corrosion-proof photo-cured coating, it is characterized in that, its raw material comprises by weight: ACRYLIC EMULSION 15-40 part, urethane 3-10 part, rosin modified phenolic resin 0.5-5 part, isobutyl triethoxy silane 0.5-2 part, carboxymethyl cellulose 0.5-1.7 part, Vltra tears 0.6-0.9 part, dipropylene glycol methyl ether 1-4 part, potassiumchromate 2-4 part, aluminium hydroxide 4-6 part, sanitas 2-6 part, barium sulfate 1-4 part, oxidation inhibitor 2-5 part, light trigger 6-14 part, defoamer 3-6 part, molybdenum compound 2-7 part, sodium sulfate 2-6 part, water 16-23 part.
2. water-tight corrosion-proof photo-cured coating according to claim 1, it is characterized in that, rosin modified phenolic resin is prepared according to following technique: xylenol and aluminum trichloride (anhydrous) are added and mix, be warming up to 60-70 DEG C, insulation 1-3h, do not stop in the process of intensification to stir, then formaldehyde is passed into, regulate pH > 7, be warming up to 100-115 DEG C, insulation 2-4h obtains material a; In material a, add rosin, be warming up to 130-145 DEG C, insulation 3.5-5h, obtains material b; In material b, add tetramethylolmethane and metaphosphoric acid, be warming up to 180-200 DEG C, insulation 1-2h, continues to be warming up to 240-260 DEG C, and insulation 2-4h, obtains rosin modified phenolic resin.
3. water-tight corrosion-proof photo-cured coating according to claim 1 and 2, is characterized in that, in the preparation technology of rosin modified phenolic resin, the mass ratio of xylenol, aluminum trichloride (anhydrous) and formaldehyde is 80-120:2-5:30-40.
4. the water-tight corrosion-proof photo-cured coating according to any one of claim 1-3, is characterized in that, in the preparation technology of rosin modified phenolic resin, the mass ratio of rosin, tetramethylolmethane and metaphosphoric acid is 150-250:20-40:2-7.
5. the water-tight corrosion-proof photo-cured coating according to any one of claim 1-4, is characterized in that, sanitas is CMIT and/or MIT.
6. the water-tight corrosion-proof photo-cured coating according to any one of claim 1-5, is characterized in that, oxidation inhibitor is one or more compositions in pentanoic, Ursol D and dihydroquinoline.
7. the water-tight corrosion-proof photo-cured coating according to any one of claim 1-6; it is characterized in that; light trigger is one or more compositions in 1-hydroxy-cyciohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, TMDPO.
8. the water-tight corrosion-proof photo-cured coating according to any one of claim 1-7, is characterized in that, defoamer is one in n-Octanol, tributyl phosphate, triphenylphosphate, emulsification methyl-silicone oil, emulsification polymethylphenyl siloxane fluid or two or more composition.
9. the water-tight corrosion-proof photo-cured coating according to any one of claim 1-8, it is characterized in that, its raw material comprises by weight: ACRYLIC EMULSION 17-38 part, urethane 5-8 part, rosin modified phenolic resin 1.5-4 part, isobutyl triethoxy silane 1.0-1.5 part, carboxymethyl cellulose 0.7-1.5 part, Vltra tears 0.7-0.8 part, dipropylene glycol methyl ether 2-3 part, potassiumchromate 2.5-3.5 part, aluminium hydroxide 4.5-5.5 part, sanitas 3-5 part, barium sulfate 2-3 part, oxidation inhibitor 2.5-4.5 part, light trigger 7-13 part, defoamer 4-5 part, molybdenum compound 3-6 part, sodium sulfate 3-5 part, water 18-21 part.
10. the water-tight corrosion-proof photo-cured coating according to any one of claim 1-9, it is characterized in that, its raw material comprises by weight: ACRYLIC EMULSION 27.5 parts, urethane 6.5 parts, rosin modified phenolic resin 2.75 parts, isobutyl triethoxy silane 1.25 parts, carboxymethyl cellulose 1.1 parts, Vltra tears 0.75 part, dipropylene glycol methyl ether 2.5 parts, potassiumchromate 3 parts, 5 parts, aluminium hydroxide, sanitas 4 parts, 2.5 parts, barium sulfate, 3.5 parts, oxidation inhibitor, light trigger 10 parts, defoamer 4.5 parts, molybdenum compound 4.5 parts, 4 parts, sodium sulfate, 19.5 parts, water.
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| CN201510387352.1A CN104987790A (en) | 2015-06-30 | 2015-06-30 | Waterproof corrosion-resistant photocuring paint |
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| CN106118439A (en) * | 2016-06-30 | 2016-11-16 | 成都华聚杨武家具有限公司 | A kind of metal furniture coating |
| CN106243955A (en) * | 2016-08-01 | 2016-12-21 | 安庆瑞泰化工有限公司 | A kind of ageing-resistant water paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106118439A (en) * | 2016-06-30 | 2016-11-16 | 成都华聚杨武家具有限公司 | A kind of metal furniture coating |
| CN106243955A (en) * | 2016-08-01 | 2016-12-21 | 安庆瑞泰化工有限公司 | A kind of ageing-resistant water paint and preparation method thereof |
| CN106318176A (en) * | 2016-08-14 | 2017-01-11 | 安庆市沁之源电器有限公司 | Anti-scratch paint for dust collector and preparation method of paint |
| CN109439140A (en) * | 2018-10-31 | 2019-03-08 | 福州盛世凌云环保科技有限公司 | A kind of ion implanting composite coating anti-bacteria stainless steel water pipe |
| CN109439140B (en) * | 2018-10-31 | 2021-12-14 | 福州盛世凌云环保科技有限公司 | Ion implantation composite coating antibacterial stainless steel water pipe |
| CN111100555A (en) * | 2019-12-30 | 2020-05-05 | 苏州佳固士新材料科技有限公司 | Water-based penetration self-healing high polymer modified asphalt waterproof coating with hydrophobic surface and preparation method and application thereof |
| CN111621231A (en) * | 2020-03-12 | 2020-09-04 | 苏州佳固士新材料科技有限公司 | Waterproof material for back surface with soft outer surface and rigid inner surface as well as preparation method and application of waterproof material |
| CN113405880A (en) * | 2021-05-21 | 2021-09-17 | 刘济忠 | Pathological specimen sealing liquid and preparation and sealing methods thereof |
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