CN104987231A - Production method for sludge carbonized nutrient soil - Google Patents

Production method for sludge carbonized nutrient soil Download PDF

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Publication number
CN104987231A
CN104987231A CN201510442508.1A CN201510442508A CN104987231A CN 104987231 A CN104987231 A CN 104987231A CN 201510442508 A CN201510442508 A CN 201510442508A CN 104987231 A CN104987231 A CN 104987231A
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soil
sludge carbonization
waste
sludge
water
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CN201510442508.1A
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Inventor
许庆华
金白云
许盛英
袁长兵
黄允金
陈丽萍
袁欣
蒋文兰
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

The invention discloses a production method for sludge carbonized nutrient soil. The key point of the technical scheme is that the production method comprises the steps: firstly stirring and extruding ingredients of sludge carbonized soil into sheet particles; carrying out carbonization on the sheet particles to obtain sludge carbonized soil; then granulating and sterilizing the ingredients of the sludge carbonized nutrient soil; and packaging the ingredients of the sludge carbonized nutrient soil to obtain the sludge carbonized nutrient soil. The sludge carbonized nutrient soil is composed of sludge, activated clay waste residues, attapulgite, bentonite, zeolite, smashed wastes, wastes after water retting, vermiculite, diammonium phosphate, perlite, ferrous sulfate and super absorbent resin. The sludge carbonized nutrient soil containing a lot of nitrogen, phosphorus, potassium, organic matters and microelements is excellent nutrient soil which is complete in nutrients, high in fertilizer efficiency, non-toxic, sterile, harmless, odorless and good in water retention capacity. The sludge carbonized nutrient soil is suitable for planting flowers and plants and nursery-grown plants. The production method for sludge carbonized nutrient soil is suitable for producing carbonized nutrient soil and a nutrient matrix.

Description

The production method of sludge carbonization Nutrition Soil
Technical field
The present invention relates to Nutrition Soil, be specifically related to a kind of production method of sludge carbonization Nutrition Soil.
Background technology
The Nutrition Soil raw material that existing flower plants and nursery stock uses is formulated by material mixing such as mountain mud, garden mould, pond sludge, peat soil, river sand, plant ash, wood chip, agricultural crop straw, mushroom cultivation dead meal and soil ulmin mostly, these Nutrition Soils are not through reasonably preparing burden and sterilization, preserve moisture and fertility ability, permeability is bad, easily harden, mineral matter nutritional in Nutrition Soil is difficult to be absorbed by flower plants and nursery stock, flower plants and nursery stock also can be subject to the virus and bacteria in soil and newly sprout the infringement of weeds, is unfavorable for that the normal growth of flower plants and nursery stock is grown.
Phosphorus and potassium are all that flower plants and nursery stock grows required nutritive element, although containing a certain amount of phosphorus and potassium in Nutrition Soil, but major part belongs to late effect property phosphorus and potassium, directly can not be absorbed by flower plants and nursery stock root system, cause flower plants and nursery stock poor growth, the normal growth affecting flower plants and nursery stock is grown, therefore, phosphorus in Nutrition Soil and potassium, need be converted into solubility rapid available phosphorus and potassium directly could be absorbed by plant.
Mud is the smelly paste of a kind of easy corruption that produces in sewage treatment process, it is enriched the pollutent in sewage, containing hazardous and noxious substances such as the nutritive substances such as a large amount of nitrogen, phosphorus and organism, viral micro-organisms, parasitic ovum, heavy metals, without effectively processing disposal, produce serious harm by environment.Sludge moisture content >=80% that municipal sewage plant produces, mud is mostly in alkalescence, and pH value is 8 ~ 10, the product of unsuitable direct production recycling.
Investigation display, current China has the mud of 80% not to be effectively addressed, and even has and is simply discarded in the PE such as farmland, river greatly, become new source of pollution.
At present the mud of a large amount of non-stabilizing treatment has become the heavy burden of sewage work, and mud that is how that output is huge, complicated component carries out properly processing safely, make that it is innoxious, minimizing, resource utilization, become deeply concerned key subjects.
Summary of the invention
The object of the invention is to overcome weak point in prior art, a kind of production method of sludge carbonization Nutrition Soil is provided.
The production method of sludge carbonization Nutrition Soil: first the batching of sludge carbonization soil stirred and be squeezed into platy shaped particle, charing is treated to sludge carbonization soil, then by the batching granulation of sludge carbonization Nutrition Soil and sterilizing, is packaged as the finished product of sludge carbonization Nutrition Soil.
Sludge carbonization Nutrition Soil is made up of the waste after mud, active white clay waste slag, attapulgite clay, wilkinite, zeolite, pulverizing, the waste after bubble system, vermiculite, diammonium phosphate, perlite, ferrous sulfate and High hydrophilous resin.
Containing a considerable amount of nitrogen, phosphorus, potassium and trace element in the mud of city domestic sewage treatment plant, through suitable art breading, as cultivation medium soil, soil improvement material, also can be used as the raw material making fertilizer, the mud that the present invention selects city domestic sewage treatment plant to discharge, water content≤85% of mud.
Atlapulgite is with attapulgite clay, wilkinite and gac for raw material, the sorbent material that the activity processed through acidification is higher, is widely used in grease-decolor; Atlapulgite after decolouring loses activity, can not regenerate and reuse, become a kind of auburn active white clay waste slag, in active white clay waste slag, oil length is up to 15 ~ 40%, active white clay waste slag is after again recycling, still remain the grease of 5 ~ 25%, these active white clay waste slags not only can produce spontaneous combustion, and serious environment pollution, at present, most of oil factory adopts water to spray or melt pit is buried, and as offal treatment, causes resource to waste.
Attapulgite clay has unique dispersion, high temperature resistant, anti-good colloidal property and the higher adsorptive power such as saline and alkaline, and has certain plasticity-and cohesive force.Attapulgite clay can adsorb foreign odor taste, heavy metal ion and carcinogenic substance in Nutrition Soil, the nutritive ingredient in Nutrition Soil is kept not run off, be conducive to growing of plant, the present invention selects the attapulgite clay after pulverizing, particle fineness≤0.5 millimeter of attapulgite clay.
Wilkinite is the moisture clay pit based on montmorillonite, because it has special character, as bloating tendency, cohesiveness, adsorptivity, catalytic, thixotropy, suspension and cationic exchange, wilkinite has stronger water absorbability and swelling property, adsorbable 8 ~ 15 times to the water yield of own vol, volumetric expansion can reach several times to 30 times, can be dispersed into as a form of gel and suspension in water medium, the present invention selects the wilkinite after pulverizing, bentonitic particle fineness≤0.5 millimeter.
Zeolite is the general name of a kind of moisture alkali or alkaline-earth metal rack-like aluminium silicate mineral, the internal structure of its uniqueness and crystal physico-chemical property, make it have the excellent physicochemical properties such as absorption, ion-exchange, catalyzed reaction, acidproof, heat-resisting and radiation hardness, being agriculturally used as soil improvement agent, fertilizer conservation, water conservation can being played, prevent disease and pest.The present invention selects the zeolite after pulverizing, particle fineness≤0.5 millimeter of zeolite.
The stalk of a large amount of farm crop, wood chip, bamboo bits, leaf and bark the like waste, be discarded in around farmland or roadside, mostly burned fall, severe contamination Air quality; Waste after pulverizing pulverizes after the stalk of farm crop, wood chip, bamboo bits and leaf the like waste being dried, and the present invention selects waste length≤25 millimeter after pulverizing.
Vermiculite after high-temperature roasting, its volume energy undergoes rapid expansion several times to tens times, the vermiculite after volumetric expansion, expanded vermiculite, is one of the lightest in the world mineral; Expanded vermiculite is used as soil improvement agent, can improve the structure of soil, and water storage preserves soil moisture, and improves the ventilation property of soil and aquosity, plays the multiple actions such as fertilizer conservation, water conservation, water storage, ventilative and mineral manure.The present invention selects the vermiculite after pulverizing, particle fineness≤0.5 millimeter of vermiculite.
Diammonium phosphate is a kind of readily avaiable fertilizer of high density, is applicable to various crop and soil, is specially adapted to the crop that nitrophilous needs phosphorus, makes base manure or topdress.
Perlite becomes a kind of lightweight, multifunctional novel shaped material through expansion, have the features such as apparent density is light, thermal conductivity is low, chemical stability is good, and pearlstone is fertilizer conservation, water conservation, aseptic, good permeability on agricultural, gardens.The present invention selects the pearlstone after pulverizing, particle fineness≤2.0 millimeter of pearlstone.
Ferrous sulfate is pale green crystals, the ferrous sulfate of 10% aqueous solution is acid to reindeer moss, pH value is about 3.7, in the present invention for the conditioning of mud charing pH value of Nutrition Soil and the supplement as plant ferro element, physiological disturbance is there is in control plant because of iron deficiency, make leaf look chlorosis, can also be used to kill liver moss.
The water absorbent rate of High hydrophilous resin can reach hundreds of times even thousands of times of own wt, and the present invention selects the water absorbent rate of High hydrophilous resin to be 100 ~ 300 times.
The present invention is achieved by following technical proposals:
1, the production method of sludge carbonization Nutrition Soil: (1) stir in the stirrer of the batching of sludge carbonization soil input running, be transported to after stirring in twin rollers and be squeezed into irregular platy shaped particle, thickness≤8 millimeter of platy shaped particle; By sludge carbonization soil platy shaped particle be transported in rotary type charring furnace carry out charing be treated to sludge carbonization soil work in-process, in rotary type charring furnace, carbonization temperature controls at 250 ~ 450 DEG C, and carbonization time controls at 30 ~ 90 minutes; (3) at rotary type charring furnace discharge port, a high pressure spray water xi shower nozzle is installed, adopt high pressure spray water xi, by the sludge carbonization soil work in-process extinguish fast just in anoxycausis, be the sludge carbonization soil of black after sludge carbonization soil work in-process extinguish, sludge carbonization soil water content≤25%; (4) stir in the stirrer of half-finished for sludge carbonization Nutrition Soil batching input running, inputting Squeezinggranulator granulation after stirring is sludge carbonization Nutrition Soil semi-finished granules, and particle diameter controls at 6 ~ 12 millimeters, and particle length controls at 6 ~ 20 millimeters; (5) be transported in rotary type sterilization stove by sludge carbonization Nutrition Soil semi-finished granules, carry out temperature sterilization and drying, temperature controls at 60 ~ 100 DEG C, and time controling was at 30 ~ 90 minutes; (6) sterilizing and dried sludge carbonization Nutrition Soil water content≤20%, be packaged as the finished product of sludge carbonization Nutrition Soil after cooling.
2, the batching of sludge carbonization soil is made up of following component by weight percentage: waste 5 ~ 15%, vermiculite 0.5 ~ 5% and water 0 ~ 25% after mud 45 ~ 65%, active white clay waste slag 5 ~ 25%, attapulgite clay 5 ~ 25%, wilkinite 5 ~ 20%, zeolite 2 ~ 15%, pulverizing.
3, the half-finished batching of sludge carbonization Nutrition Soil is made up of following component by weight percentage: the waste 5 ~ 25% after sludge carbonization soil 35 ~ 65%, bubble system, diammonium phosphate 0.2 ~ 10%, pearlstone 0.5 ~ 5%, ferrous sulfate 0.5 ~ 8%, High hydrophilous resin 0.1 ~ 5% and water 0 ~ 35%.
4, the batching of bubble waste is made up of following component by weight percentage: the waste 35 ~ 75% after pulverizing and water 25 ~ 65%; The method of bubble waste: first the waste after pulverizing is transported in fermentation vat, add water after again the waste after pulverizing being shakeout, waste after pulverizing is all immersed in water, and the retting in water of the waste after pulverizing 10 ~ 30 days is the waste after bubble system afterwards.
5, described in the present invention, PCm is all weight percentage.
Waste after mud in sludge carbonization soil, active white clay waste slag, mud coal, attapulgite clay, wilkinite, zeolite, pulverizing and vermiculite are after charing, phosphorus, potassium compound and the various trace elements that can will directly be able to not be absorbed by flower plants and nursery stock, be converted into the phosphorus of solubility, potassium, trace element and organic carbon.
Sludge carbonization soil after charing process, can expand attapulgite clay, wilkinite, the porosity of zeolite and adsorptive power; Active white clay waste slag is when carbonizing process, and mineral raw material and residual grease are rapidly converted into the phosphorus of solubility, potassium and trace element; Vermiculite, when 250 ~ 450 DEG C of charing process, is directly puffed to expanded vermiculite, is conducive to improving the porosity in sludge carbonization soil.
Waste after active white clay waste slag, mud coal and pulverizing is when carbonizing process, not only can be converted into the phosphorus of solubility, potassium and trace element, under anoxic condition, the heat energy of self can also be given full play to, promote that the batching of sludge carbonization soil completes charing whole process fast.
Waste is directly added to the water by employing carries out retting fermentation, to reduce the hardness of waste, improves the flexibility of fiber in waste, leaches the nutritive ingredient easily absorbed by flower plants and nursery stock and the porosity increasing sludge carbonization Nutrition Soil.
After sludge carbonization soil in sludge carbonization Nutrition Soil batching, the waste after bubble system, diammonium phosphate, pearlstone, High hydrophilous resin and the granulation of ferrous sulfate extrusion; define an overall particle; the nutritive ingredient in sludge carbonization Nutrition Soil is kept not run off; be conducive to the nitrogen in sludge carbonization Nutrition Soil, phosphorus, potassium, trace element and organism nutritive substance slow releasing, guarantee that flower plants and nursery stock grows required nutrition.
Sludge carbonization Nutrition Soil, after sterilizing and drying, can kill germ and the insect such as excrement colibacillus group, roundworm egg, nematode that in sludge carbonization Nutrition Soil, Disabled stays, weed seed can also be steamed dead, avoid the germination of weed seed.
Containing a large amount of nitrogen, phosphorus, potassium, organic matter and various trace elements in sludge carbonization Nutrition Soil, be that a kind of nutrition is complete, fertilizer efficiency is high, nontoxic, aseptic, harmless, odorless and the good high-quality Nutrition Soil of water retention property, be applicable to plant flowers and nursery stock.
Sludge carbonization Nutrition Soil uses with local mixing with soil, be conducive to the crumb structure improveing local soil, keep loosing soil, strengthen soil fertility, reduce the leaching loss of nutrient in soil, more effectively water conservation and fertilizer conservation, and can reduce because soil passes the generation of withered, the climing disease such as withered, viral, sludge carbonization Nutrition Soil is also applicable to soil improvement, desertification control and alkaline land improvement.
Adopt production method of the present invention to produce sludge carbonization Nutrition Soil, production technique is simple, does not have waste gas, dust and noise, be conducive to preserving the ecological environment, avoid and cause secondary pollution to surrounding enviroment in whole production process.
The multiple waste of a large amount of employing in the batching of sludge carbonization Nutrition Soil, is not only conducive to improving resource utilization, turns waste into wealth, can also reduce land occupation, protection and environment purification, save the energy, reduce production cost, increase economic efficiency.
The production method of sludge carbonization Nutrition Soil is applicable to charing Nutrition Soil and the nutraceutical matrix of producing different ingredients.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the production method of sludge carbonization Nutrition Soil: (1) stir in the stirrer of the batching of sludge carbonization soil input running, be transported to after stirring in twin rollers and be squeezed into irregular platy shaped particle, thickness≤6 millimeter of platy shaped particle; By sludge carbonization soil platy shaped particle be transported in rotary type charring furnace carry out charing be treated to sludge carbonization soil work in-process, in rotary type charring furnace, carbonization temperature controls at 300 ~ 400 DEG C, and carbonization time controls at 60 minutes; (3) at rotary type charring furnace discharge port, a high pressure spray water xi shower nozzle is installed, adopt high pressure spray water xi, by the sludge carbonization soil work in-process extinguish fast just in anoxycausis, be the sludge carbonization soil of black after sludge carbonization soil work in-process extinguish, sludge carbonization soil water content≤20%; (4) stir in the stirrer of half-finished for sludge carbonization Nutrition Soil batching input running, inputting Squeezinggranulator granulation after stirring is sludge carbonization Nutrition Soil semi-finished granules, and particle diameter controls at 8 millimeters, and particle length controls at 12 millimeters; (5) be transported in rotary type sterilization stove by sludge carbonization Nutrition Soil semi-finished granules, carry out temperature sterilization and drying, temperature controls at 85 ~ 95 DEG C, and time controling was at 65 minutes; (6) sterilizing and dried sludge carbonization Nutrition Soil water content≤10%, be packaged as the finished product of sludge carbonization Nutrition Soil after cooling.
2, the batching of sludge carbonization soil is made up of following component by weight percentage: waste 8%, vermiculite 1% and water 0% after mud 55%, active white clay waste slag 16%, attapulgite clay 10%, wilkinite 5%, zeolite 5%, pulverizing.
3, the half-finished batching of sludge carbonization Nutrition Soil is made up of following component by weight percentage: the waste 22% after sludge carbonization soil 52%, bubble system, diammonium phosphate 3%, pearlstone 2%, High hydrophilous resin 1%, ferrous sulfate 2% and water 18%.
4, the batching of bubble waste is made up of following component by weight percentage: the waste 52% after pulverizing and water 48%; The method of bubble waste: first the waste after pulverizing is transported in fermentation vat, add water after again the waste after pulverizing being shakeout, waste after pulverizing is all immersed in water, and the retting in water of the waste after pulverizing 18 days is the waste after bubble system afterwards.

Claims (2)

1. a production method for sludge carbonization Nutrition Soil, is characterized in that, (1) stirs in the stirrer of the batching of sludge carbonization soil input running, is transported in twin rollers and is squeezed into irregular platy shaped particle, thickness≤8 millimeter of platy shaped particle after stirring; By sludge carbonization soil platy shaped particle be transported in rotary type charring furnace carry out charing be treated to sludge carbonization soil work in-process, in rotary type charring furnace, carbonization temperature controls at 250 ~ 450 DEG C, and carbonization time controls at 30 ~ 90 minutes; (3) at rotary type charring furnace discharge port, a high pressure spray water xi shower nozzle is installed, adopt high pressure spray water xi, by the sludge carbonization soil work in-process extinguish fast just in anoxycausis, be the sludge carbonization soil of black after sludge carbonization soil work in-process extinguish, sludge carbonization soil water content≤25%; (4) stir in the stirrer of half-finished for sludge carbonization Nutrition Soil batching input running, inputting Squeezinggranulator granulation after stirring is sludge carbonization Nutrition Soil semi-finished granules, and particle diameter controls at 6 ~ 12 millimeters, and particle length controls at 6 ~ 20 millimeters; (5) be transported in rotary type sterilization stove by sludge carbonization Nutrition Soil semi-finished granules, carry out temperature sterilization and drying, temperature controls at 60 ~ 100 DEG C, and time controling was at 30 ~ 90 minutes; (6) sterilizing and dried sludge carbonization Nutrition Soil water content≤20%, be packaged as the finished product of sludge carbonization Nutrition Soil after cooling;
The batching of described sludge carbonization soil is made up of following component by weight percentage: waste 5 ~ 15%, vermiculite 0.5 ~ 5% and water 0 ~ 25% after mud 45 ~ 65%, active white clay waste slag 5 ~ 25%, attapulgite clay 5 ~ 25%, wilkinite 5 ~ 20%, zeolite 2 ~ 15%, pulverizing;
The half-finished batching of described sludge carbonization Nutrition Soil is made up of following component by weight percentage: the waste 5 ~ 25% after sludge carbonization soil 35 ~ 65%, bubble system, diammonium phosphate 0.2 ~ 10%, pearlstone 0.5 ~ 5%, ferrous sulfate 0.5 ~ 8%, High hydrophilous resin 0.1 ~ 5% and water 0 ~ 35%;
The batching of bubble waste is made up of following component by weight percentage: the waste 35 ~ 75% after pulverizing and water 25 ~ 65%; The method of bubble waste: first the waste after pulverizing is transported in fermentation vat, add water after again the waste after pulverizing being shakeout, waste after pulverizing is all immersed in water, and the retting in water of the waste after pulverizing 10 ~ 30 days is the waste after bubble system afterwards.
2. the production method of a kind of sludge carbonization Nutrition Soil according to claim 1, it is characterized in that, particle fineness≤0.5 of water content≤85% of mud, particle fineness≤0.5 of attapulgite clay millimeter, bentonitic particle fineness≤0.5 millimeter, zeolite millimeter, pulverize after waste length≤25 millimeter, particle fineness≤0.5 millimeter of vermiculite, particle fineness≤2.0 millimeter of pearlstone and the water absorbent rate of High hydrophilous resin be 100 ~ 300 times.
CN201510442508.1A 2015-07-27 2015-07-27 Production method for sludge carbonized nutrient soil Withdrawn CN104987231A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105777383A (en) * 2016-04-15 2016-07-20 李玉新 Technology for producing flower fertilizer by means of metallurgical slag
CN106116674A (en) * 2016-06-28 2016-11-16 蒋文兰 Mud lightweight through hole haydite
CN107343451A (en) * 2017-07-07 2017-11-14 王效雷 A kind of Desert of Gobi special nutritional pot, preparation method and its usage
CN112387763A (en) * 2020-10-28 2021-02-23 宁波绿宝环保科技有限公司 Treatment method of building residue soil
CN113498730A (en) * 2021-08-05 2021-10-15 中铁上海工程局集团市政环保工程有限公司 Municipal sludge-based biochar improved nutrient soil and production method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104119184A (en) * 2014-08-12 2014-10-29 许盛英 Production method of sludge compressed nutrient soil
CN104119185A (en) * 2014-08-12 2014-10-29 许盛英 Production method of bentonite compressed nutrient soil

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104119184A (en) * 2014-08-12 2014-10-29 许盛英 Production method of sludge compressed nutrient soil
CN104119185A (en) * 2014-08-12 2014-10-29 许盛英 Production method of bentonite compressed nutrient soil

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105777383A (en) * 2016-04-15 2016-07-20 李玉新 Technology for producing flower fertilizer by means of metallurgical slag
CN106116674A (en) * 2016-06-28 2016-11-16 蒋文兰 Mud lightweight through hole haydite
CN107343451A (en) * 2017-07-07 2017-11-14 王效雷 A kind of Desert of Gobi special nutritional pot, preparation method and its usage
CN107343451B (en) * 2017-07-07 2018-08-24 王效雷 A kind of Desert of Gobi special nutritional pot, preparation method and its usage
CN112387763A (en) * 2020-10-28 2021-02-23 宁波绿宝环保科技有限公司 Treatment method of building residue soil
CN113498730A (en) * 2021-08-05 2021-10-15 中铁上海工程局集团市政环保工程有限公司 Municipal sludge-based biochar improved nutrient soil and production method thereof

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