CN104973845A - Mine tailing filling gel powder and preparation method thereof - Google Patents

Mine tailing filling gel powder and preparation method thereof Download PDF

Info

Publication number
CN104973845A
CN104973845A CN201510274675.XA CN201510274675A CN104973845A CN 104973845 A CN104973845 A CN 104973845A CN 201510274675 A CN201510274675 A CN 201510274675A CN 104973845 A CN104973845 A CN 104973845A
Authority
CN
China
Prior art keywords
mine tailing
furnace slag
gel powder
granulated blast
filling gel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510274675.XA
Other languages
Chinese (zh)
Inventor
王品伦
梁影
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201510274675.XA priority Critical patent/CN104973845A/en
Publication of CN104973845A publication Critical patent/CN104973845A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses mine tailing filling gel powder and a preparation method thereof, and relates to the technical field of building materials. The mine tailing filling gel powder is prepared from raw materials of clinker, gypsum, mine tailing, granulated blast furnace slag and porcelain clay, and a chemical activator. The mass percentages of the raw materials are: clinker 15-35%, gypsum 3-10%, mine tailing 20-40%, granulated blast furnace slag 25-50%, and porcelain clay 5-20%. The dose of the chemical activator accounts for 0.05-0.15% of the total amount of the raw materials. According to the invention, the mine tailing, granulated blast furnace slag and porcelain clay are utilized; and through scientific content correction and complementation, potential activities of the mine tailing, granulated blast furnace slag and porcelain are stimulated, and wear-resistance coefficient is improved. With the method, raw resources are saved and replaced; circular economy development can be promoted; pollution can be reduced; and the ecological environment can be protected. Further pollution to the environment is not caused during a production process.

Description

A kind of mine tailing filling gel powder and preparation method thereof
Technical field
The present invention relates to gel powder preparing technical field, specifically a kind of mine tailing filling gel powder and preparation method thereof.
Background technology
Along with the process of modernization industry, human society more and more pays close attention to the research and development of Resources.The requirement of development to ecotope of society is more and more paid attention to.Backfill after mining utilizes novel material meet fortune and give birth to.
Summary of the invention
For the problems referred to above, the invention provides a kind of mine tailing filling gel powder and preparation method thereof, the gel powder that can effectively utilize a large amount of mine tailings, granulated blast-furnace slag, china clay to make is widely used in the backfill in mine.
The present invention realizes with following technical scheme: a kind of mine tailing filling gel powder, and it is that raw material adds chemical activator and makes by grog, gypsum, mine tailing, granulated blast-furnace slag, china clay, the mass percent of described each raw material
Described chemical activator raw material mass mixture ratio is:
Auxiliary agent raw material mass mixture ratio in chemical activator is:
It is further: the refuse that described mine tailing is remaining after being exploitation mineral products; Described granulated blast-furnace slag is Large Scale BF grain slag; Described china clay is china clay mineral products.
Above-mentioned gel powder specific surface area>=500m 2/ ㎏.
The making method of above-mentioned mine tailing filling gel powder, concrete steps are as follows:
(1), raw material is taken in proportion;
(2) grog, gypsum, mine tailing, granulated blast-furnace slag, china clay crusher are crushed to granularity≤10mm;
(3) iron tailings of step (2), granulated blast-furnace slag are dried to water ratio≤2%;
(4) with twin rollers, the raw material after drying is extruded further and is crushed to specific surface area>=250m 2/ ㎏;
(5) add chemical activator and be mixed into ball mill;
(6) grinding machine grinding homogenizing is to specific surface area>=500m 2/ ㎏; Be finished product.
The invention has the beneficial effects as follows: utilize mine tailing, granulated blast-furnace slag, china clay, the composition through science corrects complementary, excites the lateral reactivity of mine tailing, granulated blast-furnace slag, china clay.Improve wearing coefficient.The alternative Resources of saving, is conducive to promotion recycling economy development and decreasing pollution is preserved the ecological environment.The further pollution to environment is not produced in production process.
Embodiment
The present invention and effect is further illustrated below in conjunction with embodiment.
Embodiment 1:
Take raw material grog 20 ㎏, gypsum 3 ㎏, mine tailing 30 ㎏, granulated blast-furnace slag 40 ㎏, china clay 7 ㎏ by weight ratio, mix exciting agent 50mg outward.By grog 20 ㎏, gypsum 3 ㎏, mine tailing 30 ㎏, granulated blast-furnace slag 40 ㎏, china clay 7 ㎏, first by crusher in crushing to the particle of median size≤10mm; oven dry to water ratio is less than 2%; granulated blast-furnace slag 40 ㎏, mine tailing 30 ㎏, china clay 7 ㎏ use twin rollers grinding 50min again, mix chemical activator and are continued after grinding 25min to specific surface area>=500m by ball mill 2/ ㎏, product.
Embodiment 2:
Take raw material grog 30 ㎏, gypsum 5 ㎏, mine tailing 25 ㎏, granulated blast-furnace slag 35 ㎏, china clay 5 ㎏ by weight ratio, mix exciting agent 100mg outward.By grog 30 ㎏, gypsum 5 ㎏, mine tailing 25 ㎏, granulated blast-furnace slag 35 ㎏, china clay 5 ㎏ first by crusher in crushing to the particle of median size≤10mm; oven dry to water ratio is less than 2%; granulated blast-furnace slag 35 ㎏, mine tailing 25 ㎏, china clay 5 ㎏ use twin rollers grinding 50min again, mix chemical activator and are continued after grinding 25min to specific surface area>=500m by ball mill 2/ ㎏, product.
The product that above-mentioned 2 embodiments make, performance and technical requirements are better than GB/T3183-2003 " masonry cement " and JC/T1090-2008 " steel slag masonry cement " after testing.
Concrete outcome is in table 1, table 2.
Embodiment 1 stability 0.5mm; Sulfur trioxide content 3.01; 7 days anti-folding 4.0Mpa of embodiment 1,28 days anti-folding 6.5Mpa, 7 days resistance to compression 18.0Mpa, 28 days resistance to compression 30.8Mpa.
Embodiment 2 stability 0.56mm; Sulfur trioxide content 3.5; 7 days anti-folding 5.0Mpa of embodiment 2,28 days anti-folding 7.8Mpa, 7 days resistance to compression 19.0Mpa, 28 days resistance to compression 32.5Mpa.
The each grade strength of table 1 masonry cement and chemical index unit: Mpa
The each grade strength of table 2 steel slag masonry cement and chemical index unit: Mpa
The specific surface area produced under the power effect that Mechanical Crushing, extruding, grinding are different, granule-morphology, size distribution reach higher unification.Fiting chemical exciting agent, makes material combination material activity be not fully exerted.The activity of product and technical indicator are better than GB/T3183-2003 " masonry cement " and JC/T1090-2008 " steel slag masonry cement ".Mine tailing filling gel powder in the present invention is widely used in the backfilling material filling down-hole after replacing cement to do mineral exploration and exploitation, and alternative GB/T3183-2003 " masonry cement " and JC/T1090-2008 " steel slag masonry cement " is for masonry mortar, motar and blinding concrete, but be not suitable for structural concrete.Constant product quality of the present invention; intensity is higher than GB/T3183-2003 " masonry cement " and JC/T1090-2008 " steel slag masonry cement "; Save Resource Protect Environment, for the waste resources such as digestion process mine tailing provide wide channel, has higher technical economic benefit and social benefit.

Claims (4)

1. a mine tailing filling gel powder, is characterized in that: it is that raw material adds chemical activator and makes by a certain proportion of grog, gypsum, mine tailing, granulated blast-furnace slag, china clay, and the mass percent of above-mentioned each raw material is:
Described chemical activator raw materials quality and proportioning are:
Auxiliary agent raw materials quality in chemical activator and proportioning are:
2. a kind of mine tailing filling gel powder according to claim 1, is characterized in that: the refuse that described mine tailing is remaining after being exploitation mineral products; Described granulated blast-furnace slag is Large Scale BF grain slag; Described china clay is china clay mineral products.
3. a kind of mine tailing filling gel powder according to claim 1 and 2, is characterized in that: the specific surface area >=500 ㎡/㎏ of described mine tailing filling gel powder.
4. a making method for mine tailing filling gel powder, is characterized in that: concrete steps are as follows:
(1) raw material in claim 1 is taken in proportion;
(2) grog, gypsum, mine tailing, granulated blast-furnace slag, china clay crusher are crushed to granularity≤10mm;
(3) iron tailings of step (2), granulated blast-furnace slag are dried to water ratio≤2%;
(4) with twin rollers, the raw material after drying is extruded further and is crushed to specific surface area >=250 ㎡/㎏;
(5) add chemical activator and be mixed into ball mill;
(6) grinding machine grinding homogenizing is to specific surface area >=500 ㎡/㎏; Be finished product.
CN201510274675.XA 2015-05-26 2015-05-26 Mine tailing filling gel powder and preparation method thereof Pending CN104973845A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510274675.XA CN104973845A (en) 2015-05-26 2015-05-26 Mine tailing filling gel powder and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510274675.XA CN104973845A (en) 2015-05-26 2015-05-26 Mine tailing filling gel powder and preparation method thereof

Publications (1)

Publication Number Publication Date
CN104973845A true CN104973845A (en) 2015-10-14

Family

ID=54270871

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510274675.XA Pending CN104973845A (en) 2015-05-26 2015-05-26 Mine tailing filling gel powder and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104973845A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105541255A (en) * 2016-01-11 2016-05-04 福州大学 Copper slag-base low silicon iron tailing filling material and preparation technology thereof
CN109534705A (en) * 2019-01-25 2019-03-29 昌都龙者高新材料股份有限公司 Fine fraction metal tailings consolidated fill eco-cement and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1218777A (en) * 1997-12-02 1999-06-09 王品伦 Activating agent for mortar
JP2004075454A (en) * 2002-08-16 2004-03-11 Tetsugen Corp Blast furnace granulated slag fine aggregate and method of preventing caking of blast furnace granulated slag
KR20110053833A (en) * 2009-11-16 2011-05-24 한국지질자원연구원 Blast furnace slag cement synthetic method and blast furnace slag cement produced by this method
CN104193201A (en) * 2014-07-30 2014-12-10 南宁盈益环保建材科技有限公司 Environment-friendly and energy-saving masonry cement
CN104529198A (en) * 2014-12-26 2015-04-22 徐州市宇鑫环保建材有限公司 Silicate cement prepared from solid wastes and preparation method of silicate cement

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1218777A (en) * 1997-12-02 1999-06-09 王品伦 Activating agent for mortar
JP2004075454A (en) * 2002-08-16 2004-03-11 Tetsugen Corp Blast furnace granulated slag fine aggregate and method of preventing caking of blast furnace granulated slag
KR20110053833A (en) * 2009-11-16 2011-05-24 한국지질자원연구원 Blast furnace slag cement synthetic method and blast furnace slag cement produced by this method
CN104193201A (en) * 2014-07-30 2014-12-10 南宁盈益环保建材科技有限公司 Environment-friendly and energy-saving masonry cement
CN104529198A (en) * 2014-12-26 2015-04-22 徐州市宇鑫环保建材有限公司 Silicate cement prepared from solid wastes and preparation method of silicate cement

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105541255A (en) * 2016-01-11 2016-05-04 福州大学 Copper slag-base low silicon iron tailing filling material and preparation technology thereof
CN105541255B (en) * 2016-01-11 2017-09-22 福州大学 Copper ashes base Low-silica iron ore tailings filler and its preparation technology
CN109534705A (en) * 2019-01-25 2019-03-29 昌都龙者高新材料股份有限公司 Fine fraction metal tailings consolidated fill eco-cement and preparation method thereof

Similar Documents

Publication Publication Date Title
CN101767972B (en) Mine tailing sand brick and preparation method thereof
CN102765889B (en) Preparation method for tailing barren rock-made high-strength concrete containing coal ash
CN106007568B (en) A kind of method that coal mine filling lotion is prepared using biomass lime-ash
CN104692720B (en) A kind of copper tailing is non-burning brick and preparation method thereof
CN107244865A (en) High-strength concrete using fines molybdic tailing and barren rock and preparation method thereof
Özdemir et al. Utilization of clay wastes containing boron as cement additives
CN102320803A (en) Self-compacting concrete prepared from iron ore tailings, and preparation method thereof
CN108298898A (en) A kind of method of metal tail slag production dry-mixed mortar
CN106348712A (en) Cementing filling material for co-processing lead-containing dangerous wastes of mine and preparation method of cementing filling material
CN112374843B (en) Method for preparing mine filling concrete by utilizing wet-grinding steel slag ore pulp
CN107935487B (en) Method for producing functional material by utilizing solid waste and application
CN104876519B (en) A kind of Pb-Zn tailings and Aggregate of recycled concrete prepare autoclaved lime-sand brick method
CN106396592A (en) Mine cemented filling material for co-processing cadmium-containing hazardous wastes and preparation method of mine cemented filling material
CN101638924B (en) Limestone tailing-bricks and preparation method thereof
CN106348711A (en) Cementing filling material for co-processing mercury-containing dangerous wastes of mine and preparation method of cementing filling material
CN106045352A (en) Production process of ecological gel materials
CN106348713A (en) Cementing filling material for co-processing copper-containing dangerous waste of mine and preparation method of cementing filling material
CN106064897A (en) A kind of ecological Binder Materials
CN112897971A (en) Self-flowing cemented filling material containing superfine tail mud and preparation method and application thereof
CN107473613B (en) A kind of cement and preparation method thereof using industrial solid-state castoff production
CN104529198A (en) Silicate cement prepared from solid wastes and preparation method of silicate cement
CN101880153B (en) Method for producing baked brick by using rare-earth metal modified coal gangue
CN104876534B (en) A method of steam-pressing brisk is prepared using Tungsten tailing and tungsten ore barren rock
CN104973845A (en) Mine tailing filling gel powder and preparation method thereof
CN105198247A (en) Method for preparing full-tailing cementing material with sintering and desulfurization ash

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20151014

RJ01 Rejection of invention patent application after publication