CN104946321A - Multifunctional diesel oil additive - Google Patents
Multifunctional diesel oil additive Download PDFInfo
- Publication number
- CN104946321A CN104946321A CN201510288743.8A CN201510288743A CN104946321A CN 104946321 A CN104946321 A CN 104946321A CN 201510288743 A CN201510288743 A CN 201510288743A CN 104946321 A CN104946321 A CN 104946321A
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- CN
- China
- Prior art keywords
- parts
- diesel oil
- oil additive
- weight part
- multifunctional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 25
- 239000000654 additive Substances 0.000 title claims abstract description 13
- 230000000996 additive effect Effects 0.000 title claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- -1 alkyl glucoside Chemical class 0.000 claims abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 9
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- 230000004224 protection Effects 0.000 abstract description 5
- 239000000779 smoke Substances 0.000 abstract description 5
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 abstract description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract description 3
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229940095102 methyl benzoate Drugs 0.000 abstract description 2
- NFWSQSCIDYBUOU-UHFFFAOYSA-N methylcyclopentadiene Chemical compound CC1=CC=CC1 NFWSQSCIDYBUOU-UHFFFAOYSA-N 0.000 abstract description 2
- DXCTUMLYTQODSP-UHFFFAOYSA-N 1-dodecoxy-2-nitrobenzene Chemical compound CCCCCCCCCCCCOC1=CC=CC=C1[N+]([O-])=O DXCTUMLYTQODSP-UHFFFAOYSA-N 0.000 abstract 1
- 238000003889 chemical engineering Methods 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 abstract 1
- 229930182478 glucoside Natural products 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000007849 Lepidium sativum Nutrition 0.000 description 2
- 244000211187 Lepidium sativum Species 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- XQEGSFGUGQAHDP-UHFFFAOYSA-N C(CCCC)[Fe]CCCCC Chemical compound C(CCCC)[Fe]CCCCC XQEGSFGUGQAHDP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The invention belongs to the technical filed of chemical engineering, and especially relates to a multifunctional diesel oil additive. The multifunctional diesel oil additive is prepared from, by weight, 20-35 parts of methylcyclopentadiene, 15-25 parts of methyl tert-butyl ether, 4-9 parts of ferrocene, 5-10 parts of methyl benzoate, 6-12 parts of ethyl acetate, 3-7 parts of o-nitrophenyl dodecyl ether, 5-10 parts of polyetheramine, 15-25 parts of alkyl glucoside, 2-7 parts of a friction modifier and 4-8 parts of an antioxidant. The multifunctional diesel oil additive can substantially improve the cetane number, the combustion-supporting metal corrosion inhibition performance, the smoke abatement performance, the oxidation resistance, the cleaning performance and the dispersion performance of diesel oil, and also has the advantages of full combustion promotion, diesel oil saving, emission reduction and environmental protection promotion.
Description
Technical field
The invention belongs to chemical technology field, particularly a kind of multifunctional diesel oil additive.
Background technology
Along with widely using of diesel engine, the consumption of diesel oil increases just year by year.But a large amount of consumption of diesel oil also will inevitably cause the further aggravation of vehicular discharge nuisance.Because discharge has a strong impact on ecotope, human health and Economic development, national governments have formulated strict emission regulation in succession, the noxious emission of restriction diesel vehicle.Therefore, the oil consumption and the pollution that reduce diesel-engine road vehicle are further current problem demanding prompt solutions.In numerous solutions, use the method for diesel-dope not changing vehicle and engine structure, under also not increasing the condition of equipment, by changing the physical property of fuel, making fuel be able to Thorough combustion, thus realizing energy-conservation and emission abatement.
Improve diesel motor fuel burning quality a lot of with the method reducing tail gas pollution, use additive to be one of economy and effective means.At present, there is the shortcomings such as function singleness, comparatively large to the corrodibility of engine interior, the reduction of exhaust emissions objectionable impurities is not obvious in diesel-dope of the prior art.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of multifunctional diesel oil additive, and it has good Cress effect, significantly reduces the discharge of black smoke and particulate matter, effectively saves diesel oil and reduces exhaust emissions.
For achieving the above object, the present invention adopts following technical scheme:
A kind of multifunctional diesel oil additive, be made up of the raw material of following weight part:
Friction improver of the present invention is the mixture of 15 ~ 25 weight part Diethylene Glycol fatty acid esters and 10 ~ 20 parts sulfuric acid Viscotrol C.Friction improver reduces friction, improves diesel oil economy, reduces discharge of poisonous waste.
Antioxidant of the present invention is the mixture of the p-di-iso-octyldiphenylamine of 12 ~ 22 weight part and the tertiary Ding-4-methylphenol of 20 ~ 30 weight parts 2,6-bis-.Add antioxidant, the usage period of diesel oil can be extended, be convenient to preserve.
Methyl cyclopentadiene and methyl tertiary butyl ether are cetane number improver, improve cetane value amplitude, make burning more stable, improve the performance of diesel oil, meanwhile, on oxygen sensor without impact, oxynitride and carbon monoxide emission can be reduced, effectively improve exhaust emissions problem.
Diamyl iron serves and reduces nozzle deposit carbon and combustion-supporting effect, strengthens keeping a public place clean, and saves gasoline.
Ethyl acetate and methyl benzoate have the effect of corrosion inhibition; the many metal protections of material to engine fuel system are had in diesel oil; copper, iron, aluminium, lead, magnesium and their many alloys can be corroded; diesel oil can absorb the moisture in air simultaneously; add corrosion inhibitor and metallic surface strong effect; produce chemistry and physisorption; form good protective membrane; isolate the contact of corrosive deposit and metalwork to a certain extent; reach the object suppressing corrosion; protection engine fuel system, increases the service life.
Ortho-nitrophenyl dodecane ether has good smoke elimination Cress effect, significantly reduces the discharge of black smoke and particulate matter, promotes environmental protection.
Alkyl glycoside is synthesized by renewable resources natural fat alcohol and glucose, be the more comprehensive new non-ionic surfactants of a kind of performance, there is good dispersiveness and emulsifying property, the stability of diesel oil can be strengthened, low-temperature phase can be resisted to be separated, to solve long storage lamination problem.
Preferably, multifunctional diesel oil additive of the present invention, be made up of the raw material of following weight part:
The multiple performances such as multifunctional diesel oil additive of the present invention significantly can improve diesel cetane-number, combustion-supporting metallic corrosion suppresses, eliminate smoke, anti-oxidant, peace and quiet and dispersion, promote Thorough combustion, save diesel oil, emissions reduction, promote environmental protection.Research shows, product of the present invention can reduce motor vehicle exhaust 48 ~ 65%, save diesel oil 25% ~ 35%, and diesel cetane-number improves 6 ~ 9 units, and the storage time can reach a year and a half more than, stablizes not stratified.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited to these embodiments.
Embodiment 1
Be in harmonious proportion by the raw material of following weight part and form:
Above-mentioned friction improver is the mixture of 15 weight part Diethylene Glycol fatty acid esters and 20 parts sulfuric acid Viscotrol C.
Above-mentioned antioxidant is the mixture of the p-di-iso-octyldiphenylamine of 12 weight part and the tertiary Ding-4-methylphenol of 30 weight parts 2,6-bis-.
Embodiment 2
Be in harmonious proportion by the raw material of following weight part and form:
Above-mentioned friction improver is the mixture of 15 weight part Diethylene Glycol fatty acid esters and 20 parts sulfuric acid Viscotrol C.
Above-mentioned antioxidant is the mixture of the p-di-iso-octyldiphenylamine of 15 weight part and the tertiary Ding-4-methylphenol of 28 weight parts 2,6-bis-.
Embodiment 3
Be in harmonious proportion by the raw material of following weight part and form:
Above-mentioned friction improver is the mixture of 20 weight part Diethylene Glycol fatty acid esters and 15 parts sulfuric acid Viscotrol C.
Above-mentioned antioxidant is the mixture of the p-di-iso-octyldiphenylamine of 17 weight part and the tertiary Ding-4-methylphenol of 25 weight parts 2,6-bis-.
Embodiment 4
Be in harmonious proportion by the raw material of following weight part and form:
Above-mentioned friction improver is the mixture of 23 weight part Diethylene Glycol fatty acid esters and 13 parts sulfuric acid Viscotrol C.
Above-mentioned antioxidant is the mixture of the p-di-iso-octyldiphenylamine of 15 weight part and the tertiary Ding-4-methylphenol of 23 weight parts 2,6-bis-.
Embodiment 5
Be in harmonious proportion by the raw material of following weight part and form:
Above-mentioned friction improver is the mixture of 25 weight part Diethylene Glycol fatty acid esters and 10 parts sulfuric acid Viscotrol C.
Above-mentioned antioxidant is the mixture of the p-di-iso-octyldiphenylamine of 12 weight part and the tertiary Ding-4-methylphenol of 20 weight parts 2,6-bis-.
Claims (2)
1. a multifunctional diesel oil additive, is characterized in that, is made up of the raw material of following weight part:
Described friction improver is the mixture of 15 ~ 25 weight part Diethylene Glycol fatty acid esters and 10 ~ 20 parts sulfuric acid Viscotrol C;
Described antioxidant is the mixture of the p-di-iso-octyldiphenylamine of 12 ~ 22 weight part and the tertiary Ding-4-methylphenol of 20 ~ 30 weight parts 2,6-bis-.
2. multifunctional diesel oil additive according to claim 1, is characterized in that, is made up of the raw material of following weight part:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510288743.8A CN104946321B (en) | 2015-05-29 | 2015-05-29 | A kind of multifunctional diesel oil additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510288743.8A CN104946321B (en) | 2015-05-29 | 2015-05-29 | A kind of multifunctional diesel oil additive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104946321A true CN104946321A (en) | 2015-09-30 |
| CN104946321B CN104946321B (en) | 2016-12-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510288743.8A Expired - Fee Related CN104946321B (en) | 2015-05-29 | 2015-05-29 | A kind of multifunctional diesel oil additive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104946321B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106367131A (en) * | 2016-09-30 | 2017-02-01 | 广西东奇能源技术有限公司 | Vehicle fuel for reducing sulfur dioxide emission |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559307A (en) * | 2012-02-29 | 2012-07-11 | 上海鑫赛孚能源科技有限公司 | Vehicle alcohol ether diesel additive and preparation method thereof |
| CN103194282A (en) * | 2013-04-08 | 2013-07-10 | 黄河三角洲京博化工研究院有限公司 | Diesel composite additive |
-
2015
- 2015-05-29 CN CN201510288743.8A patent/CN104946321B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559307A (en) * | 2012-02-29 | 2012-07-11 | 上海鑫赛孚能源科技有限公司 | Vehicle alcohol ether diesel additive and preparation method thereof |
| CN103194282A (en) * | 2013-04-08 | 2013-07-10 | 黄河三角洲京博化工研究院有限公司 | Diesel composite additive |
Non-Patent Citations (1)
| Title |
|---|
| 李和平: "《精细化工工艺学》", 31 January 2007, 科学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106367131A (en) * | 2016-09-30 | 2017-02-01 | 广西东奇能源技术有限公司 | Vehicle fuel for reducing sulfur dioxide emission |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104946321B (en) | 2016-12-28 |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20161116 Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Applicant after: Gu Yukui Address before: Room 1, unit 10, building 18, Yi Feng Road, Qixing District, Guilin, the Guangxi Zhuang Autonomous Region,, Applicant before: Ma Jian |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder |
Address after: No. 25, Xu Zhuang Street, high port district, Taizhou, Jiangsu Province Patentee after: Gu Yukui Address before: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee before: Gu Yukui |
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| CP02 | Change in the address of a patent holder | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180211 Address after: 100039 Beijing city Fengtai District new palace Sports Leisure Park No. 8 Fu No. 2 building 113 room Patentee after: Color legend (Beijing) International Daily Chemical Co.,Ltd. Address before: No. 25, Xu Zhuang Street, high port district, Taizhou, Jiangsu Province Patentee before: Gu Yukui |
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| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161228 |
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| CF01 | Termination of patent right due to non-payment of annual fee |