CN103421553A - Diesel additive of energy conservation and emission reduction - Google Patents
Diesel additive of energy conservation and emission reduction Download PDFInfo
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- CN103421553A CN103421553A CN2013101239104A CN201310123910A CN103421553A CN 103421553 A CN103421553 A CN 103421553A CN 2013101239104 A CN2013101239104 A CN 2013101239104A CN 201310123910 A CN201310123910 A CN 201310123910A CN 103421553 A CN103421553 A CN 103421553A
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- diesel
- isooctyl ester
- ester nitrate
- butyl peroxide
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Abstract
A diesel additive of energy conservation and emission reduction comprises isooctyl nitrate, di-tert-butyl peroxide, aviation kerosene and amines compound, wherein the mass ratio of the isooctyl nitrate to the di-tert-butyl peroxide is 1:(0.01-100); that of isooctyl nitrate to the aviation kerosene is 1:(0.01-100), and that of the isooctyl nitrate to the amines compound is 1:(0.01-100). Compared with the prior art, the diesel additive has the advantages that based on that the isooctyl nitrate and the di-tert-butyl peroxide are different in decomposition temperature in a diesel engine, the diesel additive has a time-staggered catalysis and ignition function for the diesel oil in the engine, so as to promote efficient and stable burning of the diesel oil in the engine; by utilizing the aviation kerosene as resolvent, the performance stability of the formula is ensured; by utilizing the amines material as an engine cleaning agent, the working stability of the engine is improved.
Description
Technical field
The invention belongs to fuel oil additive, be specifically related to a kind of diesel-dope of energy-saving and emission-reduction.
Background technology
In recent years, along with being widely used of diesel engine, the positive increase year after year of the consumption of diesel oil, and limited diesel oil resource reduces increasingly, and occurred that diesel oil is under-supply, the trend of price increase.Because the alkane molecule amount of diesel component is larger, when engine operation, the rate of combustion of diesel oil is not high enough, and combustionproperty is good not, and this has not only increased oil consumption, and has deepened the pollution level of exhaust to air.According to statistics, it is the objectionable impurities of vehicular discharge that the airborne pollutent in China big city has 60%-70%, and wherein very large a part of vehicle is diesel vehicle, as vehicle for public transport and carrier vehicle etc.Smoke intensity in exhaust gas from diesel vehicle is the emphasis that air pollutant emission is controlled.Therefore the problems such as the use of diesel oil and environment protection, receive people's concern.
Diesel-dope is a kind of of fuel oil additive; it is the deficiency existed in order to make up quality problems that fuel oil self exists and the motor vehicle machinofacture limit; thereby make diesel motor can overcome after oil nozzle is difficult to mist more and produces Residual oil the problem of dripping; diesel-engine vehicles is played the protection engine behaviour, realizes that fuel oil is more perfect and burn more completely, thereby reach effects such as reducing pollutant emission, saving fuel oil, enhancing power, decarbonizing.
The numerous and confused research and development dynamics strengthened diesel-dope of fuel oil scientific and technological industry circle, to improve the combustioncharacteristics of motor spirit, reach energy-conservation and purpose environmental protection both at home and abroad.To methods such as the organic interior purification of the technological treatment of emission from vehicles nuisance, improvement fuel quality and exhaust gas purification aftertreatments.Emission controls by improving combustion need to be changed the structure of engine, is not suitable for the vehicle in use.The Diesel Engine Exhaust Purification post-processing technology, at present domestic still immature.The diesel-dope that use properties is good, the physical property of transformation fuel, be improved fuel combustion, is one of technological treatment of In-Use Motor Vehicles the best.So both need not change the structure of vehicle and engine, also need not increase equipment, can realize energy-conservation and emission abatement again.Therefore, the diesel-dope of clean environment firendly is subject to general welcome.
At present, in diesel-dope market, fuel oil additive mainly is divided into 3 large classes: energy saving additive, and its main purpose is in order to improve the power of engine, reduces oil consumption; Environment protection additive, its main purpose is the discharge of purifying engine, reduces and pollutes; Comprehensive additive, it is not only energy-conservation but also can reduce the content of objectionable impurities in engine exhaust.Use good additive, due to the structure that need not change vehicle and engine, need not increase other equipment again, as long as additive is poured in fuel tank in proportion, then refuel, just can automatically mix and come into operation, or by the deployed fuel feeding again in service station to vehicle, using method is simple, bottle packing is easy to carry, consumption is few, and expense is low.Although it is a lot of to enter in recent years the diesel-dope brand of domestic market, function singleness, can only improve a certain performance of diesel oil, and other performance of diesel oil is not improved.Some additives also can reduce other performance and the index of diesel oil when having improved a kind of performance of diesel oil, and for example: the pour point depressant that contains aromatic hydrocarbon can increase the content of benzene and toluene in diesel oil, also can reduce the capability of antidetonance of diesel oil simultaneously; The fuel catalyst that contains trichloromethane has the deep-etching effect to container made of iron, and has increased the chloride content in tail gas.And because lack synergistic effect, can not compound use to make up deficiency separately, reach the purpose of the over-all properties that improves diesel oil between existing diesel-dope.Development high-efficiency multi-function composite diesel additive just becomes an important problem.
A large amount of consumption of diesel oil cause air pollutant emission further to aggravate, and ecotope, human health and Economic development are had a strong impact on, and the Chinese government has formulated strict Abgasgesetz in succession, the noxious emission of restriction diesel vehicle.Therefore, the oil consumption and the pollution that further reduce diesel-engine road vehicle are current problem demanding prompt solutions.In numerous solutions, use the method for diesel-dope not changing vehicle and engine structure, do not increase under the condition of equipment yet, by changing the physical property of fuel, make fuel be able to abundant burning, thereby realize energy-conservation and emission abatement.Therefore, exploitation environmental protection, energy-conservation diesel-dope are very important.
Summary of the invention
The purpose of this invention is to provide a kind of discharge with pollutent in the reduction diesel motor exhaust, improve the Energy efficiency of diesel motor and the energy-saving and emission-reduction diesel-dope of operation stability.
Technical scheme of the present invention is to comprise isooctyl ester nitrate, ditertiary butyl peroxide, aviation kerosene, and wherein, isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.01-100; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.01-100.
In the present invention, isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.01-10; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.01-1.
In the present invention, isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.5; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.05;
Also comprise amine substance in the present invention, isooctyl ester nitrate: the amine substance mass ratio is 1:0.01-100.
In the present invention, isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.01-10; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.01-1; Isooctyl ester nitrate: the amine substance mass ratio is 1:0.01-1.
In the present invention, isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.5; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.05; Isooctyl ester nitrate: the amine substance mass ratio is 1:0.05.
Amine substance of the present invention is that acyl (Asia) amine, alkyl replace (many) amine, azanol and derivative thereof, polyetheramine.
Amine substance of the present invention is succimide, triethylene diamine, polyoxyethylene glycol succimide, PIBA.
The present invention adopts certain ratio allotment isooctyl ester nitrate and ditertiary butyl peroxide mixture, add again the certain proportion aviation kerosene as the formula solvent, add a certain proportion of amine substance as sedimental clean-out system in engine, finally form diesel-dope formulas stable performance, energy-saving and environmental protection.
Ratio allotment isooctyl ester nitrate and ditertiary butyl peroxide mixture that employing of the present invention is certain are to take engine rig test research as basis, in the different monooctyl ester of certain mass ratio mixed nitrate and ditertiary butyl peroxide.
When the different monooctyl ester of mixed nitrate and ditertiary butyl peroxide, must add a certain proportion of aviation kerosene to make solvent, reduce the system heat release.Must mix after three kinds of materials add, form colourless transparent solution.
During described aminated compounds adds system again after three kinds of materials form colourless transparent solution, its effect is the diesel oil settling cleaned in diesel motor.Can add the use aminated compounds according to applicable cases.
The present invention's advantage compared with prior art is.
(1) with existing formula, compare, the present invention uses isooctyl ester nitrate and the ditertiary butyl peroxide catalyzer as diesel combustion in engine.The difference of decomposition temperature in diesel motor according to isooctyl ester nitrate and ditertiary butyl peroxide, the present invention has played to in-engine diesel oil the effect that the catalysis of staggering the time is ignited, and has promoted the burning of diesel oil stability and high efficiency in engine.
(2) with existing formula, compare, the present invention uses aviation kerosene as solvent, guarantees the stability of performance formula.Use amine substance as engine cleansing agent, improve the job stability of engine.
Energy-saving and emission-reduction diesel-dope of the present invention environmental protection, energy-conservation, stable performance.Use the present invention, can obviously reduce exhaust pollutant discharge, reduction engine fuel rate of consumption, the raising engine operation stability of diesel motor.
Specific embodiments
Embodiment 1:
(1) formula, select following component by mass fraction:
Isooctyl ester nitrate 10
Ditertiary butyl peroxide 80
Aviation kerosene 5
Succimide 5
(2) each component materials is mixed to the formation clear solution, obtain additive of the present invention.
(3) by the additive of the present invention that mixes in mass ratio routine 1:500 with diesel oil, mix.
Embodiment 2:
(1) formula, select following component by mass fraction:
Isooctyl ester nitrate 30
Ditertiary butyl peroxide 40
Aviation kerosene 20
Triethylene diamine 10
(2) each component materials is mixed to the formation clear solution, obtain additive of the present invention.
(3) by the additive of the present invention that mixes in mass ratio routine 1:1000 with diesel oil, mix.
Embodiment 3:
(1) formula, select following component by mass fraction:
Isooctyl ester nitrate 70
Ditertiary butyl peroxide 10
Aviation kerosene 10
Polyoxyethylene glycol succimide 10
(2) each component materials is mixed to the formation clear solution, obtain additive of the present invention.
(3) by the additive of the present invention that mixes in mass ratio routine 1:2000 with diesel oil, mix.
Embodiment 4:
(1) formula, select following component by mass fraction:
Isooctyl ester nitrate 15
Ditertiary butyl peroxide 80
Aviation kerosene 5
(2) each component materials is mixed to the formation clear solution, obtain additive of the present invention.
(3) by the additive of the present invention that mixes in mass ratio routine 1:500 with diesel oil, mix.
Embodiment 5:
(1) formula, select following component by mass fraction:
Isooctyl ester nitrate 50
Ditertiary butyl peroxide 30
Aviation kerosene 20
(2) each component materials is mixed to the formation clear solution, obtain additive of the present invention.
(3) by the additive of the present invention that mixes in mass ratio routine 1:500 with diesel oil, mix.
Claims (8)
1. an energy-saving and emission-reduction diesel-dope, it is characterized in that: comprise isooctyl ester nitrate, ditertiary butyl peroxide, aviation kerosene, wherein, isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.01-100; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.01-100.
2. energy-saving and emission-reduction diesel-dope according to claim 1, it is characterized in that: described isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.01-10; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.01-1.
3. energy-saving and emission-reduction diesel-dope according to claim 1, it is characterized in that: described isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.5; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.05.
4. energy-saving and emission-reduction diesel-dope according to claim 1, it is characterized in that: also comprise amine substance, wherein, isooctyl ester nitrate: the amine substance mass ratio is 1:0.01-100.
5. energy-saving and emission-reduction diesel-dope according to claim 4, it is characterized in that: described isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.01-10; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.01-1; Isooctyl ester nitrate: the amine substance mass ratio is 1:0.01-1.
6. energy-saving and emission-reduction diesel-dope according to claim 4, it is characterized in that: described isooctyl ester nitrate: the ditertiary butyl peroxide mass ratio is 1:0.5; Isooctyl ester nitrate: the aviation kerosene amount is than being 1:0.05; Isooctyl ester nitrate: the amine substance mass ratio is 1:0.05.
7. energy-saving and emission-reduction diesel-dope according to claim 4 is characterized in that: described amine substance is that acyl (Asia) amine, alkyl replace (many) amine, azanol and derivative thereof, polyetheramine.
8. energy-saving and emission-reduction diesel-dope according to claim 4, it is characterized in that: described amine substance is succimide, triethylene diamine, polyoxyethylene glycol succimide, PIBA.
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CN2013101239104A CN103421553A (en) | 2013-04-11 | 2013-04-11 | Diesel additive of energy conservation and emission reduction |
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CN2013101239104A CN103421553A (en) | 2013-04-11 | 2013-04-11 | Diesel additive of energy conservation and emission reduction |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106010692A (en) * | 2016-06-21 | 2016-10-12 | 西安卓求新材料有限公司 | Composite diesel additive |
CN106118763A (en) * | 2016-07-01 | 2016-11-16 | 盛世昆仲(北京)科技发展有限公司 | A kind of composite diesel additive and preparation method |
CN106902881A (en) * | 2017-02-23 | 2017-06-30 | 上海千茂化工科技有限公司 | A kind of gasoline, diesel oil and distillate fuel oil catalyst composition peculiar to vessel |
CN107980056A (en) * | 2015-04-28 | 2018-05-01 | 联合引发剂有限公司 | Fuel additive is used for the purposes for removing deposit in diesel engine in diesel fuel |
CN110452746A (en) * | 2019-08-23 | 2019-11-15 | 章敏 | A kind of peace and quiet synergist of fuel environment protection and preparation method |
CN112812859A (en) * | 2020-12-29 | 2021-05-18 | 昆明天尔食品加工有限公司 | Energy-saving and environment-friendly diesel oil, catalyst and preparation method of energy-saving and environment-friendly diesel oil |
CN113234498A (en) * | 2021-06-07 | 2021-08-10 | 北京燧火科技有限公司 | Diesel oil additive and preparation method thereof |
CN114561234A (en) * | 2022-02-17 | 2022-05-31 | 天津大学 | Methanol fuel additive and methanol fuel for compression ignition engine blended with same |
GB2611187A (en) * | 2021-09-24 | 2023-03-29 | Innospec Ltd | Use and method |
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CN1958750A (en) * | 2005-11-01 | 2007-05-09 | 王英华 | Liquid fuel in use for diesel engine, and preparation method |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107980056A (en) * | 2015-04-28 | 2018-05-01 | 联合引发剂有限公司 | Fuel additive is used for the purposes for removing deposit in diesel engine in diesel fuel |
CN106010692A (en) * | 2016-06-21 | 2016-10-12 | 西安卓求新材料有限公司 | Composite diesel additive |
CN106118763A (en) * | 2016-07-01 | 2016-11-16 | 盛世昆仲(北京)科技发展有限公司 | A kind of composite diesel additive and preparation method |
CN106902881A (en) * | 2017-02-23 | 2017-06-30 | 上海千茂化工科技有限公司 | A kind of gasoline, diesel oil and distillate fuel oil catalyst composition peculiar to vessel |
CN106902881B (en) * | 2017-02-23 | 2017-11-07 | 上海千茂化工科技有限公司 | A kind of gasoline, diesel oil and distillate fuel oil catalyst composition peculiar to vessel |
CN110452746A (en) * | 2019-08-23 | 2019-11-15 | 章敏 | A kind of peace and quiet synergist of fuel environment protection and preparation method |
CN112812859A (en) * | 2020-12-29 | 2021-05-18 | 昆明天尔食品加工有限公司 | Energy-saving and environment-friendly diesel oil, catalyst and preparation method of energy-saving and environment-friendly diesel oil |
CN113234498A (en) * | 2021-06-07 | 2021-08-10 | 北京燧火科技有限公司 | Diesel oil additive and preparation method thereof |
CN113234498B (en) * | 2021-06-07 | 2023-05-16 | 北京燧火科技有限公司 | Diesel fuel additive and preparation method thereof |
GB2611187A (en) * | 2021-09-24 | 2023-03-29 | Innospec Ltd | Use and method |
GB2611187B (en) * | 2021-09-24 | 2024-08-28 | Innospec Ltd | Use and method |
CN114561234A (en) * | 2022-02-17 | 2022-05-31 | 天津大学 | Methanol fuel additive and methanol fuel for compression ignition engine blended with same |
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Application publication date: 20131204 |