CN104944699B - A kind of minimizing technology of grease factory waste water foul odour material - Google Patents

A kind of minimizing technology of grease factory waste water foul odour material Download PDF

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Publication number
CN104944699B
CN104944699B CN201510324670.3A CN201510324670A CN104944699B CN 104944699 B CN104944699 B CN 104944699B CN 201510324670 A CN201510324670 A CN 201510324670A CN 104944699 B CN104944699 B CN 104944699B
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bioreactor
waste water
sedimentation basin
water
inlet pipe
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CN201510324670.3A
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CN104944699A (en
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何成达
许青青
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Yangzhou University
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Yangzhou University
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Abstract

A kind of minimizing technology of grease factory waste water foul odour material, belongs to environmental protection technical field.Including:It is equipped with the equipment for removing oil wastewater foul odour material;Grease factory waste water is entered into bioreactor by closed conduit from bioreactor bottom, waste water launches nitrate into waste water while entering bioreactor, and start mixer in bioreactor and stir, carry out biological respinse processing, control below dissolved oxygen 0.2mg/L in bioreactor, bioreactor uses sludge reflux, and it is 2000 6000mg/L to control sludge concentration in bioreactor, and return sludge ratio is 50 150%;Water after processing is discharged into vertical sedimentation basin precipitation from bioreactor top, and the water of sedimentation basin is discharged into follow-up treatment facility using overflow-type and continued with.Waste water after processing is degraded containing rance material in processing procedure, is almost escaped in the waste water after processing without rancidity, protects atmospheric environment.

Description

A kind of minimizing technology of grease factory waste water foul odour material
Technical field
The present invention relates to the removal technology of sewage foul odour material, more particularly to a kind of grease factory waste water foul odour The minimizing technology of material, belongs to environmental protection technical field.
Background technology
Waste water caused by grease factory before processing rinse water, grease washes, the cleaning of job shop machine and Ground flushing water etc..Such waste component is complicated, mainly contains the materials such as gleditsia sinensis, phosphatide, protein, oil, pigment, has organic The features such as pollutant concentration is high, oil content is big, impurity is more, larger to environmental hazard, intractability is higher.In addition, such waste water Due to the volatile organic compound matter containing high concentration, there is strong pungent rancidity, severe shadow is caused to atmospheric environment Ring.The foul odour of grease factory waste water mainly by the oxidation of grease, becoming sour causes, the species of foul odour material is mainly small point The oxide such as sub- aldehyde, ketone and carboxylic acid, alcohols, peroxide.
The handling process of grease factory waste water is compared with frequently with " air supporting+anaerobic process+aerobic method " at present, and such process is useless The control aspect of water water quality has been achieved for good effect, but ignores foul odour problem caused by grease factory waste water. Oil wastewater has a strong rancidity, and it is volatile, adhesiveness is larger.Air supporting and aerobic method can make waving in oil wastewater Hair property organic substance is spilt into air, and lasting baneful influence is caused to atmospheric environment.As requirement of the people to environment is got over Come higher, how to control and handle the stink of vegetable oil mill waste water, caused the great attention of people.
The content of the invention
The purpose of the present invention is exactly to solve the technical problem that grease factory waste water foul odour material removes, there is provided a kind of oil The minimizing technology of fat factory waste water foul odour material, while grease factory's wastewater treatment water quality is well kept, it can control useless Harm of the volatile malodorous odoring substance to atmospheric environment in water.
The technical scheme is that a kind of minimizing technology of grease factory waste water foul odour material, comprises the following steps:
1)Being equipped with includes setting for the removal oil wastewater foul odour material that bioreactor and vertical sedimentation basin form It is standby;
2)Grease factory waste water is entered into bioreactor by closed conduit from bioreactor bottom, waste water enters biology Nitrate is launched while reactor into waste water, controls the COD/NO in waste water3- N=4.2-4.8, and start biological respinse Mixer stirs in device, carries out biological respinse processing, controls below dissolved oxygen 0.2mg/L in bioreactor, bioreactor Using sludge reflux, it is 2000-6000mg/L, return sludge ratio 50-150% to control sludge concentration in bioreactor;
3)By step 2)Water after processing is discharged into vertical sedimentation basin precipitation, the hydromining of sedimentation basin from bioreactor top Follow-up treatment facility is discharged into overflow-type to continue with.
Step 1)The equipment for removing oil wastewater foul odour material includes bioreactor and vertical sedimentation basin, Also include mud return line, biological respinse wall is provided with wastewater inlet pipe and overfall, and wastewater inlet pipe is arranged on biological anti- The bottom of wall is answered, overfall is arranged on the top of biological respinse wall, and wastewater inlet pipe one end is stretched into bioreactor Bottom, connection more equally distributed branch pipes of insertion are stretched on the wastewater inlet pipe in bioreactor, on every branch pipe Provided with some apopores, the wastewater inlet pipe other end stretches out connects waste water source outside bioreactor, stretches out in bioreactor Outer wastewater inlet pipe is provided with control gate valve, chemicals dosing plant, and chemicals dosing plant is provided with chemical feed pipe connection wastewater inlet pipe, biological respinse Device top is provided with bioreactor water leg along inwall, and bioreactor water leg connection overfall, bioreactor is interior to be installed There is mixer, sedimentation basin is that upper cylindrical and lower cone shape connect and compose vertical sedimentation basin, is set in sedimentation basin top wall There are sedimentation basin water inlet pipe and delivery port, sedimentation basin bottom conical end is provided with sludge outlet, central tube, discharge pipeline are provided with sedimentation basin With sedimentation basin water leg, central tube is arranged on the centre in sedimentation basin, and central tube connects biology by sedimentation basin water inlet pipe The overfall of reactor, sedimentation basin water leg are arranged in sedimentation basin upper inside wall, discharge pipeline upper end connection sedimentation basin water leg, Discharge pipeline lower end is disposed proximate at sludge outlet, and discharge pipeline is provided with three-way pipe, and discharge pipeline passes through three-way pipe and the sludge Return duct connects the wastewater inlet pipe.
Step 2)It is 24 hours that the waste water, which enters bioreactor hydraulic detention time,.
Step 2)It is described that nitrate is launched into waste water, it is that nitrate, dosing dress are launched into waste water by chemicals dosing plant Put and the bioreactor is connected by chemical feed pipe including medicament storage tank and measuring pump, medicament storage tank connection measuring pump, measuring pump Wastewater inlet pipe carry out dispensing nitrate.
Step 2)COD/NO in the control waste water3-N=4.5。
Step 2)It is described that to control sludge concentration in bioreactor be 4000mg/L.
Step 2)The return sludge ratio is 100%.
Step 3)It is described to be discharged into the vertical sedimentation basin sedimentation time as 2 hours.
Present invention process method is advanced simple, the equipment using oil wastewater foul odour material is removed, grease factory waste water Pass through closed conduit(Wastewater inlet pipe)Enter bioreactor from bottom, carry out biological respinse, mixer is installed in reactor It is stirred.Water outlet is discharged into sedimentation basin from bioreactor top, and sedimentation basin water outlet can be discharged into follow-up treatment facility and continue Processing.Process conditions are set:(1)Nitrate is added, controls the COD/NO in waste water3 N=4.5 or so;(2)Control in anoxic pond Below dissolved oxygen 0.2mg/L;(3)The sludge concentration for controlling bioreactor is 2000-6000mg/L, return sludge ratio 50- 150%.By above-mentioned processing method, waste water is degraded containing rance material in processing procedure, after the processing of the method useless Almost escaped in water without rancidity, make the unit of waste water subsequent treatment(Such as aeration)Also rance material is no longer distributed.
Beneficial effect:1st, by the implementation of the inventive method, it is degraded in waste water containing rance material, ordorless material Effusion;2nd, the subsequent processing units of waste water can use conventional treatment measure, ordorless gaseous matter effusion;3rd, process letter It is single, it is easy in the waste water disposal facility transformation of grease factory;4th, inventive process avoids due to foul odour thing in oil wastewater Atmosphere pollution caused by the volatilization of matter, protects atmospheric environment.
Brief description of the drawings
Fig. 1 is the equipment profile of the removal oil wastewater foul odour material of the present invention.
Fig. 2 is the equipment top view of the removal oil wastewater foul odour material of the present invention.
Fig. 3 is the equipment back with water inlet line layout drawing of the removal oil wastewater foul odour material of the present invention.
In figure:1 wastewater inlet pipe, 2 mixers, 3 sedimentation basin water inlet pipes, 4 central tubes, 5 reflecting plates, 6 bioreactor collection Tank, 7 baffle plates, 8 discharge pipelines, 9 sedimentation basin water legs, 10 medicament storage tanks, 11 measuring pumps, 12 chemical feed pipes, 13 mud return lines, 14 Mixer, 15 sludge reflux pumps, 16 outlet pipes, 18 branch pipes, 19 apopores.
Embodiment
For a better understanding of the present invention, technical scheme is described in detail with instantiation below, but originally Invention is not limited thereto.A kind of minimizing technology of grease factory waste water foul odour material,
Embodiment 1
1)It is equipped with the equipment for removing oil wastewater foul odour material, including bioreactor, vertical sedimentation basin, sludge Return duct, biological respinse wall are provided with wastewater inlet pipe and overfall, and wastewater inlet pipe is arranged under biological respinse wall Portion, overfall are arranged on the top of biological respinse wall, the bottom that wastewater inlet pipe one end is stretched into bioreactor, stretched into More equally distributed branch pipes of connection insertion, every branch pipe are provided with some water outlets on wastewater inlet pipe in bioreactor Hole, the wastewater inlet pipe other end stretches out connects waste water source outside bioreactor, the influent waste water stretched out outside bioreactor Pipe is provided with control gate valve, chemicals dosing plant, and chemicals dosing plant is provided with chemical feed pipe connection wastewater inlet pipe, and bioreactor top is along inwall Provided with bioreactor water leg, bioreactor water leg connects overfall, and mixer is provided with bioreactor, precipitates Pond is that upper cylindrical and lower cone shape connect and compose vertical sedimentation basin, and sedimentation basin top wall is provided with sedimentation basin water inlet pipe And delivery port, sedimentation basin bottom conical end are provided with sludge outlet, catchmented in sedimentation basin provided with central tube, discharge pipeline and sedimentation basin Groove, central tube are arranged on the centre in sedimentation basin, and central tube connects the overflow of bioreactor by sedimentation basin water inlet pipe Mouthful, sedimentation basin water leg is arranged in sedimentation basin upper inside wall, and discharge pipeline upper end connection sedimentation basin water leg, discharge pipeline lower end is set Put close at sludge outlet, discharge pipeline is provided with three-way pipe, and discharge pipeline connects institute by three-way pipe with the mud return line State wastewater inlet pipe.
2)Grease factory waste water is entered into bioreactor from bioreactor bottom by closed conduit, it is anti-to carry out biology Should, waste water index is:COD=2500.00mg/L, NO3 N=0.00mg/L, stirred using mixer is installed in bioreactor Mix, add potassium nitrate as denitrification nitrogen source, make COD/NO3 N=4.5:1.That is NO3 N=555.56mg/L, added per 1L waste water 4.01gKNO3;Hydraulic detention time is 24h, controls below dissolved oxygen 0.2mg/L in anoxic pond, return sludge ratio 150%;Sludge Concentration MLSS=5000mg/L.
3)It is small that water after bioreactor reaction treatment from bioreactor top is discharged into vertical sedimentation basin precipitation 2 When, the water of sedimentation basin is discharged into follow-up treatment facility using overflow-type and continued with.
Embodiment 2
1)It is equipped with the equipment for removing oil wastewater foul odour material, including bioreactor, vertical sedimentation basin, sludge Return duct, biological respinse wall are provided with wastewater inlet pipe and overfall, and wastewater inlet pipe is arranged under biological respinse wall Portion, overfall are arranged on the top of biological respinse wall, the bottom that wastewater inlet pipe one end is stretched into bioreactor, stretched into More equally distributed branch pipes of connection insertion, every branch pipe are provided with some water outlets on wastewater inlet pipe in bioreactor Hole, the wastewater inlet pipe other end stretches out connects waste water source outside bioreactor, the influent waste water stretched out outside bioreactor Pipe is provided with control gate valve, chemicals dosing plant, and chemicals dosing plant is provided with chemical feed pipe connection wastewater inlet pipe, and bioreactor top is along inwall Provided with bioreactor water leg, bioreactor water leg connects overfall, and mixer is provided with bioreactor, precipitates Pond is that upper cylindrical and lower cone shape connect and compose vertical sedimentation basin, and sedimentation basin top wall is provided with sedimentation basin water inlet pipe And delivery port, sedimentation basin bottom conical end are provided with sludge outlet, catchmented in sedimentation basin provided with central tube, discharge pipeline and sedimentation basin Groove, central tube are arranged on the centre in sedimentation basin, and central tube connects the overflow of bioreactor by sedimentation basin water inlet pipe Mouthful, sedimentation basin water leg is arranged in sedimentation basin upper inside wall, and discharge pipeline upper end connection sedimentation basin water leg, discharge pipeline lower end is set Put close at sludge outlet, discharge pipeline is provided with three-way pipe, and discharge pipeline connects institute by three-way pipe with the mud return line State wastewater inlet pipe.
2)Grease factory waste water is entered into bioreactor from bioreactor bottom by closed conduit, it is anti-to carry out biology Should, waste water index is:COD=2500.00mg/L, NO3 N=0.00mg/L, stirred using mixer is installed in bioreactor Mix, add potassium nitrate as denitrification nitrogen source, make COD/NO3 N=4.2:1.That is NO3 N=555.56mg/L, added per 1L waste water 4.01gKNO3;Hydraulic detention time is 24h, controls below dissolved oxygen 0.2mg/L in anoxic pond, return sludge ratio 100%;Sludge Concentration MLSS=6000mg/L.
3)It is small that water after bioreactor reaction treatment from bioreactor top is discharged into vertical sedimentation basin precipitation 2 When, the water of sedimentation basin is discharged into follow-up treatment facility using overflow-type and continued with.
Embodiment 3
1)It is equipped with the equipment for removing oil wastewater foul odour material, including bioreactor, vertical sedimentation basin, sludge Return duct, biological respinse wall are provided with wastewater inlet pipe and overfall, and wastewater inlet pipe is arranged under biological respinse wall Portion, overfall are arranged on the top of biological respinse wall, the bottom that wastewater inlet pipe one end is stretched into bioreactor, stretched into More equally distributed branch pipes of connection insertion, every branch pipe are provided with some water outlets on wastewater inlet pipe in bioreactor Hole, the wastewater inlet pipe other end stretches out connects waste water source outside bioreactor, the influent waste water stretched out outside bioreactor Pipe is provided with control gate valve, chemicals dosing plant, and chemicals dosing plant is provided with chemical feed pipe connection wastewater inlet pipe, and bioreactor top is along inwall Provided with bioreactor water leg, bioreactor water leg connects overfall, and mixer is provided with bioreactor, precipitates Pond is that upper cylindrical and lower cone shape connect and compose vertical sedimentation basin, and sedimentation basin top wall is provided with sedimentation basin water inlet pipe And delivery port, sedimentation basin bottom conical end are provided with sludge outlet, catchmented in sedimentation basin provided with central tube, discharge pipeline and sedimentation basin Groove, central tube are arranged on the centre in sedimentation basin, and central tube connects the overflow of bioreactor by sedimentation basin water inlet pipe Mouthful, sedimentation basin water leg is arranged in sedimentation basin upper inside wall, and discharge pipeline upper end connection sedimentation basin water leg, discharge pipeline lower end is set Put close at sludge outlet, discharge pipeline is provided with three-way pipe, and discharge pipeline connects institute by three-way pipe with the mud return line State wastewater inlet pipe.
2)Grease factory waste water is entered into bioreactor from bioreactor bottom by closed conduit, it is anti-to carry out biology Should, waste water index is:COD=2500.00mg/L, NO3 N=0.00mg/L, stirred using mixer is installed in bioreactor Mix, add potassium nitrate as denitrification nitrogen source, make COD/NO3 N=4.8:1.That is NO3 N=555.56mg/L, added per 1L waste water 4.01gKNO3;Hydraulic detention time is 24h, controls below dissolved oxygen 0.2mg/L in anoxic pond, return sludge ratio 50%;Sludge Concentration MLSS=2000mg/L.
3)It is small that water after bioreactor reaction treatment from bioreactor top is discharged into vertical sedimentation basin precipitation 2 When, the water of sedimentation basin is discharged into follow-up treatment facility using overflow-type and continued with.

Claims (5)

1. a kind of minimizing technology of grease factory waste water foul odour material, it is characterized in that, comprise the following steps:
1)It is equipped with the equipment for the removal oil wastewater foul odour material for including bioreactor and vertical sedimentation basin composition;
2)Grease factory waste water is entered into bioreactor by closed conduit from bioreactor bottom, waste water enters biological respinse Nitrate is launched while device into waste water, controls the COD/NO in waste water3- N=4.2-4.8, and start in bioreactor Mixer stirs, and carries out biological respinse processing, controls below dissolved oxygen 0.2mg/L in bioreactor, and bioreactor uses Sludge reflux, it is 2000-6000mg/L, return sludge ratio 50-150% to control sludge concentration in bioreactor;The waste water It it is 24 hours into bioreactor hydraulic detention time;The nitrate is potassium nitrate, and input amount is that every 1 liter of waste water adds 4.01g;
3)By step 2)Water after processing is discharged into vertical sedimentation basin precipitation from bioreactor top, and the water of sedimentation basin is using excessive Streaming is discharged into follow-up treatment facility and continued with;It is described to be discharged into the vertical sedimentation basin sedimentation time as 2 hours;
The equipment for removing oil wastewater foul odour material includes bioreactor and vertical sedimentation basin, in addition to sludge Return duct, biological respinse wall are provided with wastewater inlet pipe and overfall, and wastewater inlet pipe is arranged under biological respinse wall Portion, overfall are arranged on the top of biological respinse wall, the bottom that wastewater inlet pipe one end is stretched into bioreactor, stretched into More equally distributed branch pipes of connection insertion, every branch pipe are provided with some water outlets on wastewater inlet pipe in bioreactor Hole, the wastewater inlet pipe other end stretches out connects waste water source outside bioreactor, the influent waste water stretched out outside bioreactor Pipe is provided with control gate valve, chemicals dosing plant, and chemicals dosing plant is provided with chemical feed pipe connection wastewater inlet pipe, and bioreactor top is along inwall Provided with bioreactor water leg, bioreactor water leg connects overfall, and mixer is provided with bioreactor, precipitates Pond is that upper cylindrical and lower cone shape connect and compose vertical sedimentation basin, and sedimentation basin top wall is provided with sedimentation basin water inlet pipe And delivery port, sedimentation basin bottom conical end are provided with sludge outlet, catchmented in sedimentation basin provided with central tube, discharge pipeline and sedimentation basin Groove, central tube are arranged on the centre in sedimentation basin, and central tube connects the overflow of bioreactor by sedimentation basin water inlet pipe Mouthful, sedimentation basin water leg is arranged in sedimentation basin upper inside wall, and discharge pipeline upper end connection sedimentation basin water leg, discharge pipeline lower end is set Put close at sludge outlet, discharge pipeline is provided with three-way pipe, and discharge pipeline connects institute by three-way pipe with the mud return line State wastewater inlet pipe.
2. a kind of minimizing technology of grease factory waste water foul odour material according to claim 1, it is characterized in that, step 2) It is described that nitrate is launched into waste water, it is that nitrate is launched into waste water by chemicals dosing plant, chemicals dosing plant includes medicament storage tank And measuring pump, medicament storage tank connection measuring pump, the wastewater inlet pipe that measuring pump connects the bioreactor by chemical feed pipe enter Row launches nitrate.
3. a kind of minimizing technology of grease factory waste water foul odour material according to claim 1, it is characterized in that, step 2) COD/NO in the control waste water3-N=4.5。
4. a kind of minimizing technology of grease factory waste water foul odour material according to claim 1, it is characterized in that, step 2) It is described that to control sludge concentration in bioreactor be 4000mg/L.
5. a kind of minimizing technology of grease factory waste water foul odour material according to claim 1, it is characterized in that, step 2) The return sludge ratio is 100%.
CN201510324670.3A 2015-06-15 2015-06-15 A kind of minimizing technology of grease factory waste water foul odour material Expired - Fee Related CN104944699B (en)

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CN101318741B (en) * 2008-07-11 2011-01-05 北京城市排水集团有限责任公司 Apparatus and method for synchronous denitrification and development of sewage sludge internal carbon source of urban sewage
AU2013397276B2 (en) * 2013-06-24 2018-12-06 Biofiltro Usa, Inc. Treatment for domestic and industrial waste water
CN204111525U (en) * 2014-08-21 2015-01-21 广州嘉康环保技术有限公司 A kind of aquaculture Waste Water Treatment

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