CN1049322C - High-effective copploid liquid and preparation method thereof - Google Patents
High-effective copploid liquid and preparation method thereof Download PDFInfo
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- CN1049322C CN1049322C CN96119173A CN96119173A CN1049322C CN 1049322 C CN1049322 C CN 1049322C CN 96119173 A CN96119173 A CN 96119173A CN 96119173 A CN96119173 A CN 96119173A CN 1049322 C CN1049322 C CN 1049322C
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- disproportionated rosin
- copper
- solution
- copploid
- copploid liquid
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Abstract
The present invention discloses a copper soap solution with high efficiency, and a preparation method thereof. The copper soap solution with high efficiency is prepared by proportioning rosin or disproportionated rosin, water, strong alkali, an organic solvent, an inorganic cupric salt and an emulsifying agent. Compared with the prior art, the copper soap solution with high efficiency can be transported and stored for a long period and is safe and has no phytotoxicity to crops. Besides, the copper soap solution with high efficiency is capable of being mixed with other parasite and mite killing agents and has safety and high efficiency for preventing and curing various diseases of fruit trees and other crops.
Description
The present invention relates to a kind of copploid liquid and preparation method thereof, especially a kind of is high-effective copploid liquid of effective ingredient and preparation method thereof with copper abietinate or disproportionated rosin acid copper.
Copploid liquid is used to prevent and treat the multiple diseases of various crops by many peasants for a long time, as canker, anthracnose, grey scall and citrus eqpidemic disease etc., and the peasant in use, generally be now with the current, the local method preparation, exist the quality instability, easily produce problems such as poisoning or control efficiency be undesirable.
The object of the present invention is to provide the long-term accumulating of a kind of energy, crops are not had fully high-effective copploid liquid of poisoning and preparation method thereof.
In order to realize above-mentioned purpose, the present invention has adopted following embodiment: a kind of high-effective copploid liquid, and it is to be formed by following proportioning components:
Copper abietinate or disproportionated rosin acid copper solution: emulsifier=3～10: 0.3～1 wherein, and copper abietinate or disproportionated rosin acid copper solution are again to be formed by following proportioning components:
Rosin or disproportionated rosin: water: highly basic: organic solvent: inorganic mantoquita
＝1～5∶3～10∶0.1～2∶3～10∶0.2～4
In order to realize above-mentioned purpose, the embodiment that the present invention adopts also comprises: a kind of method for preparing high-effective copploid liquid the steps include: (1). in proportion that rosin or disproportionated rosin, water, highly basic and organic solvent stirring reaction under 50～90 ℃ of temperature is complete; (2). add the inorganic mantoquita of solubility in above-mentioned solution, insulation reacts completely under 50～80 ℃; (3). left standstill after having reacted 3～24 hours, and got upper strata copper abietinate or disproportionated rosin acid copper solution and add 0.3～1 part of emulsifier emulsification for 3～10 parts, promptly make high-effective copploid liquid.
In above-mentioned technical solution, described organic solvent is diesel oil or cyclohexanone or turpentine oil or turpentine or dipentene or benzene or dimethylbenzene or above-mentioned mixture.
In above-mentioned technical solution, described emulsifier is the mixture of anion surfactant or cationic surfactant or zwitterionic surfactant or non-ionic surface active agent or above-mentioned surfactant.
Below by concrete preparation method and embodiment the present invention is made further explanation and description:
Embodiment 1:1.30 gram rosin adds 200 ml waters, adds 300 milliliters of turpentine, adds 4 gram NaOH, is heated to 60 ℃, stirs reaction down 3 hours; 2. add 7 gram copper sulphate in the above-mentioned reactant liquor, stir reaction down 3 hours, left standstill after having reacted 6 hours, get 300 milliliters of upper strata organic liquor, add 30 milliliters of emulsifications of surfactant and promptly make high-effective copploid liquid.Embodiment 2:1.30 gram disproportionated rosin is smashed, and adds under 250 milliliters in 60 ℃ in the water, adds 4 gram NaOH, stirs reaction down 3 hours; 2. will add 300 milliliters of turpentine in the above-mentioned reactant liquor, add copper sulphate 6 grams, stir reaction down 3 hours, left standstill after having reacted 6 hours, get 300 milliliters of upper strata organic liquor, add 30 milliliters of emulsifications of surfactant and promptly make high-effective copploid liquid.
Compared with prior art, the invention provides a kind of high-effective copploid liquid and preparation method thereof, this high-efficiency copper For a long time accumulating of soap lye does not have poisoning to Crop securify, can mix with other mite and insect killing agents use. To fruit tree And the control of other crops multiple diseases is safe and efficient.
Claims (4)
1: a kind of copploid liquid, it is characterized in that it is to be formed by following composition proportion: copper abietinate or disproportionated rosin acid copper solution: emulsifier=3-10: 0.3-1, wherein copper abietinate or disproportionated rosin acid copper solution is again the upper solution that following composition proportion reaction forms, rosin or disproportionated rosin: water: highly basic: organic solvent: inorganic mantoquita=1-5: 3-10: 0.1-2: 3-10: 0.2-4.
2: a kind of method for preparing copploid liquid as claimed in claim 1 is characterized in that preparation process is:
(1) in proportion that rosin or disproportionated rosin, water, highly basic and organic solvent stirring reaction under 50-90 ℃ of temperature is complete;
(2) add the inorganic mantoquita of solubility in above-mentioned solution, insulation reacts completely under 50-80 ℃;
(3) left standstill 3-24 hour after having reacted, get upper strata copper abietinate or disproportionated rosin acid copper solution 3-10 part and add the emulsification of 0.3-1 part emulsifier, promptly make copploid liquid
3: copploid liquid according to claim 1 is characterized in that described organic solvent is diesel oil or cyclohexanone or turpentine oil or turpentine or dipentene or benzene or dimethylbenzene or above-mentioned mixture.
4: copploid liquid according to claim 1 is characterized in that described emulsifier is the mixture of anion surfactant or cationic surfactant or zwitterionic surfactant or non-ionic surface active agent or above-mentioned surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119173A CN1049322C (en) | 1996-10-16 | 1996-10-16 | High-effective copploid liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119173A CN1049322C (en) | 1996-10-16 | 1996-10-16 | High-effective copploid liquid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1161780A CN1161780A (en) | 1997-10-15 |
| CN1049322C true CN1049322C (en) | 2000-02-16 |
Family
ID=5125624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96119173A Expired - Fee Related CN1049322C (en) | 1996-10-16 | 1996-10-16 | High-effective copploid liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1049322C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1101650C (en) * | 1999-06-10 | 2003-02-19 | 黄迪辉 | Germicide composition containing organic copper |
| CN100337540C (en) * | 2000-06-06 | 2007-09-19 | 陈湖 | Synergistic liquid for dissolving rosin in water |
| CN101935275A (en) * | 2009-06-29 | 2011-01-05 | 孔波 | Preparation method and application of gum rosin acid copper |
| CN104478705B (en) * | 2014-11-11 | 2016-04-27 | 柳州市惠农化工有限公司 | The former medicine of a kind of copper rosinate, preparation method and application |
| CN112674093B (en) * | 2021-01-11 | 2022-07-08 | 青岛中达农业科技有限公司 | Environment-friendly copper abietate emulsion in water and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3262846A (en) * | 1962-11-06 | 1966-07-26 | Tennessee Corp | Stable copper emulsion for controlling plant diseases |
| GB1379440A (en) * | 1971-03-26 | 1975-01-02 | Cities Service Co | Fungicide |
-
1996
- 1996-10-16 CN CN96119173A patent/CN1049322C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3262846A (en) * | 1962-11-06 | 1966-07-26 | Tennessee Corp | Stable copper emulsion for controlling plant diseases |
| GB1379440A (en) * | 1971-03-26 | 1975-01-02 | Cities Service Co | Fungicide |
Non-Patent Citations (1)
| Title |
|---|
| FARM CHEMICALS 1964.1.1 T.M.JOHNSTON,TC-90 NEW COPPER FUNGICIDE * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1161780A (en) | 1997-10-15 |
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