CN1161780A - High-effective copploid liquid and preparation method thereof - Google Patents
High-effective copploid liquid and preparation method thereof Download PDFInfo
- Publication number
- CN1161780A CN1161780A CN 96119173 CN96119173A CN1161780A CN 1161780 A CN1161780 A CN 1161780A CN 96119173 CN96119173 CN 96119173 CN 96119173 A CN96119173 A CN 96119173A CN 1161780 A CN1161780 A CN 1161780A
- Authority
- CN
- China
- Prior art keywords
- effective
- preparation
- disproportionated rosin
- copploid
- copploid liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a high efficiency copper soap solution and its preparation method. It is made up by proportioning rosin or disproportionated rosin, water, alkali, organic solvent, inorganic nantokite and emulsifying agent and mixing them. As compared with existent techniques, said invented high efficiency copper soap solution can be transported and stored for a long period, and is safe and free from insecticide burn for crops. Besides, it can be mixed with other miticide, and possesses safety and high efficiency for controlling diseases of fruit tree and crops.
Description
The present invention relates to a kind of high-effective copploid liquid and preparation method thereof, especially a kind of is high-effective copploid liquid of effective ingredient and preparation method thereof with copper abietinate or disproportionated rosin acid copper.
Copploid liquid is used to prevent and treat the multiple diseases of various crops by many peasants for a long time, as canker, anthracnose, grey scall and citrus eqpidemic disease etc., and the peasant in use, generally be now with the current, the local method preparation, exist the quality instability, easily produce problems such as poisoning or control efficiency be undesirable.
The object of the present invention is to provide the long-term accumulating of a kind of energy, crops are not had fully high-effective copploid liquid of poisoning and preparation method thereof.
In order to realize above-mentioned purpose, the present invention has adopted following embodiment: a kind of high-effective copploid liquid, and it is to be formed by following proportioning components:
Copper abietinate or disproportionated rosin acid copper solution: emulsifier=3～10: 0.3～1 wherein, and copper abietinate or disproportionated rosin acid copper solution are again to be formed by following proportioning components:
Rosin or disproportionated rosin: water: highly basic: organic solvent: inorganic mantoquita
＝1～5∶3～10∶0.1～2∶3～10∶0.2～4
In order to realize above-mentioned purpose, the embodiment that the present invention adopts also comprises: a kind of method for preparing high-effective copploid liquid the steps include:
(1). in proportion that rosin or disproportionated rosin, water, highly basic and organic solvent stirring reaction under 50～90 ℃ of temperature is complete;
(2). add the inorganic mantoquita of solubility in above-mentioned solution, insulation reacts completely under 50～80 ℃;
(3). left standstill after having reacted 3～24 hours, and got upper strata copper abietinate or disproportionated rosin acid copper solution and add 0.3～1 part of emulsifier emulsification for 3～10 parts, promptly make high-effective copploid liquid.
In above-mentioned technical solution, described organic solvent is diesel oil or cyclohexanone or turpentine oil or turpentine or dipentene or benzene or dimethylbenzene or above-mentioned mixture.
In above-mentioned technical solution, described emulsifier is the mixture of anion surfactant or cationic surfactant or zwitterionic surfactant or non-ionic surface active agent or above-mentioned surfactant.
Below by concrete preparation method and embodiment the present invention is made further explanation and description:
Embodiment 1:
1.30 gram rosin adds 200 ml waters, adds 300 milliliters of turpentine, adds 4 gram NaOH, is heated to 60 ℃, stirs reaction down 3 hours;
2. add 7 gram copper sulphate in the above-mentioned reactant liquor, stir reaction down 3 hours, left standstill after having reacted 6 hours, get 300 milliliters of upper strata organic liquor, add 30 milliliters of emulsifications of surfactant and promptly make high-effective copploid liquid.Embodiment 2:
1.30 the gram disproportionated rosin is smashed, and adds under 250 milliliters in 60 ℃ in the water, adds 4 gram NaOH, stirs reaction down 3 hours;
2. will add 300 milliliters of turpentine in the above-mentioned reactant liquor, add copper sulphate 6 grams, stir reaction down 3 hours, left standstill after having reacted 6 hours, get 300 milliliters of upper strata organic liquor, add 30 milliliters of emulsifications of surfactant and promptly make high-effective copploid liquid.
Compared with prior art, the invention provides a kind of high-effective copploid liquid and preparation method thereof, this high-efficiency copper For a long time accumulating of soap lye does not have poisoning to Crop securify, can mix with other mite and insect killing agents use. To fruit tree And the control of other crops multiple diseases is safe and efficient.
Claims (4)
1. high-effective copploid liquid is characterized in that it is to be formed by following proportioning components:
Copper abietinate or disproportionated rosin acid copper solution: emulsifier=3～10: 0.3～1 wherein, and copper abietinate or disproportionated rosin acid copper solution are again to be formed by following proportioning components:
Rosin or disproportionated rosin: water: highly basic: organic solvent: inorganic mantoquita
＝1～5∶3～10∶0.1～2∶3～10∶0.2～4
2. method for preparing high-effective copploid liquid as claimed in claim 1, it is characterized in that: preparation process is:
(1). in proportion that rosin or disproportionated rosin, water, highly basic and organic solvent stirring reaction under 50～90 ℃ of temperature is complete;
(2). add the inorganic mantoquita of solubility in above-mentioned solution, insulation reacts completely under 50～80 ℃;
(3). left standstill after having reacted 3～24 hours, and got upper strata copper abietinate or disproportionated rosin acid copper solution and add 0.3～1 part of emulsifier emulsification for 3～10 parts, promptly make high-effective copploid liquid.
3. high-effective copploid liquid according to claim 1 and 2 and preparation method thereof is characterized in that described organic solvent is diesel oil or cyclohexanone or turpentine oil or turpentine or dipentene or benzene or dimethylbenzene or above-mentioned mixture.
4. high-effective copploid liquid according to claim 1 and 2 and preparation method thereof is characterized in that described emulsifier is the mixture of anion surfactant or cationic surfactant or zwitterionic surfactant or non-ionic surface active agent or above-mentioned surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119173A CN1049322C (en) | 1996-10-16 | 1996-10-16 | High-effective copploid liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119173A CN1049322C (en) | 1996-10-16 | 1996-10-16 | High-effective copploid liquid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1161780A true CN1161780A (en) | 1997-10-15 |
| CN1049322C CN1049322C (en) | 2000-02-16 |
Family
ID=5125624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96119173A Expired - Fee Related CN1049322C (en) | 1996-10-16 | 1996-10-16 | High-effective copploid liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1049322C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1101650C (en) * | 1999-06-10 | 2003-02-19 | 黄迪辉 | Germicide composition containing organic copper |
| CN100337540C (en) * | 2000-06-06 | 2007-09-19 | 陈湖 | Synergistic liquid for dissolving rosin in water |
| CN101935275A (en) * | 2009-06-29 | 2011-01-05 | 孔波 | Preparation method and application of gum rosin acid copper |
| CN104478705A (en) * | 2014-11-11 | 2015-04-01 | 柳州市惠农化工有限公司 | Copper abietate raw drug and preparation method and application thereof |
| CN112674093A (en) * | 2021-01-11 | 2021-04-20 | 青岛中达农业科技有限公司 | Environment-friendly copper abietate emulsion in water and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3262846A (en) * | 1962-11-06 | 1966-07-26 | Tennessee Corp | Stable copper emulsion for controlling plant diseases |
| IL38796A (en) * | 1971-03-26 | 1975-06-25 | Cities Service Co | Fungicidal compositions comprising copper tallate |
-
1996
- 1996-10-16 CN CN96119173A patent/CN1049322C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1101650C (en) * | 1999-06-10 | 2003-02-19 | 黄迪辉 | Germicide composition containing organic copper |
| CN100337540C (en) * | 2000-06-06 | 2007-09-19 | 陈湖 | Synergistic liquid for dissolving rosin in water |
| CN101935275A (en) * | 2009-06-29 | 2011-01-05 | 孔波 | Preparation method and application of gum rosin acid copper |
| CN104478705A (en) * | 2014-11-11 | 2015-04-01 | 柳州市惠农化工有限公司 | Copper abietate raw drug and preparation method and application thereof |
| CN104478705B (en) * | 2014-11-11 | 2016-04-27 | 柳州市惠农化工有限公司 | The former medicine of a kind of copper rosinate, preparation method and application |
| CN112674093A (en) * | 2021-01-11 | 2021-04-20 | 青岛中达农业科技有限公司 | Environment-friendly copper abietate emulsion in water and preparation method thereof |
| CN112674093B (en) * | 2021-01-11 | 2022-07-08 | 青岛中达农业科技有限公司 | Environment-friendly copper abietate emulsion in water and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1049322C (en) | 2000-02-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE19950593A1 (en) | Process for obtaining simple fatty acid esters from fat and / or oil of biological origin | |
| CN1161780A (en) | High-effective copploid liquid and preparation method thereof | |
| CN103432165B (en) | Controlled-release multifunctional veterinary iron supplementing injection and production process thereof | |
| EP0518351B1 (en) | Process for the preparation of 2,5-di(phenylamino)terephthalic acids and their dialkylesters in high purity | |
| CN1570038A (en) | Paraffin emulsifier and its making method | |
| RU2290431C2 (en) | Easily extrudable soap blocks containing alpha-hydroxyacid salts | |
| US6699489B1 (en) | Ecologically benign product for fire ant control | |
| CN1049321C (en) | Method for preparing organic copper, a kind of broad-spectrum germicide | |
| CN1245879C (en) | Iodine water agent composite agricutural chemical and its prepn. method | |
| CN1109270A (en) | Emulsion oil of Angulatin | |
| CN1089314C (en) | Preparation of activated clay | |
| DE2535183A1 (en) | PROCESS FOR COVERING AND GRANULATING TETRAACETYLGLYCOLURIL AND TETRAACETYLAETHYLENEDIAMINE | |
| CN1229020C (en) | Suspension emulsion of nicotine microcapsule, and its prepn. method | |
| CN1028364C (en) | Process for producing highly concentrated pastes of alpha-sulfofatty acid alkyl ester alkali metal salts | |
| CN1026166C (en) | Aqueous soluble naphthenate emulsion and process for preparing thereof | |
| CN1327744A (en) | Theasaponin-chitosan compound and its preparing process and application in insecticide | |
| CN1258447A (en) | Compound raticide | |
| CN1251592C (en) | Double long chain quaternary ammonium complex iodine isothiazolinone complex antiseptic for aquatic product | |
| CN1067518C (en) | Qiangluan-compound disinfectant for silkworm | |
| JPH0645521B2 (en) | Spreading agent composition for insecticidal fungicide applied to soil | |
| CN1076080A (en) | 70% network copper-zinc-ammonia wettable germicide-acaricide and promotion plant growing compound powder and method for making thereof | |
| CN1072064A (en) | Preparing method for compound rat-killing agent | |
| CN1256025C (en) | Yin-guo microcapsule suspension emulsion, and its prepn. method | |
| CN1176740A (en) | Organic copper agent used as bactericide and acaricide, and method for preparing same | |
| CN1043600A (en) | A kind of emulsified oil of meta-tolyl-N-methyl-carbamate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |