CN104919034B - Dress material powder detergent composition - Google Patents
Dress material powder detergent composition Download PDFInfo
- Publication number
- CN104919034B CN104919034B CN201380068824.6A CN201380068824A CN104919034B CN 104919034 B CN104919034 B CN 104919034B CN 201380068824 A CN201380068824 A CN 201380068824A CN 104919034 B CN104919034 B CN 104919034B
- Authority
- CN
- China
- Prior art keywords
- ingredient
- mass
- dress material
- detergent composition
- powder detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims abstract description 209
- 239000003599 detergent Substances 0.000 title claims abstract description 189
- 239000000843 powder Substances 0.000 title claims abstract description 171
- 239000000463 material Substances 0.000 title claims abstract description 157
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 103
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract description 51
- 235000019341 magnesium sulphate Nutrition 0.000 claims abstract description 51
- 239000010457 zeolite Substances 0.000 claims abstract description 39
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 26
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 24
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims abstract description 23
- 150000008064 anhydrides Chemical class 0.000 claims abstract description 18
- 150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000004615 ingredient Substances 0.000 claims description 291
- 238000000034 method Methods 0.000 claims description 94
- 238000004140 cleaning Methods 0.000 claims description 91
- 238000005406 washing Methods 0.000 claims description 91
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 75
- -1 alkali metal salt Chemical class 0.000 claims description 40
- 239000002002 slurry Substances 0.000 claims description 39
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 35
- 125000000217 alkyl group Chemical group 0.000 claims description 35
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 32
- 238000004519 manufacturing process Methods 0.000 claims description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 19
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 claims description 18
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 17
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 16
- 235000011152 sodium sulphate Nutrition 0.000 claims description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 14
- 239000003513 alkali Substances 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 9
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 229910052936 alkali metal sulfate Inorganic materials 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000001447 alkali salts Chemical class 0.000 claims 1
- 239000006260 foam Substances 0.000 description 35
- 239000004744 fabric Substances 0.000 description 30
- 239000007864 aqueous solution Substances 0.000 description 27
- 239000000243 solution Substances 0.000 description 27
- 238000005187 foaming Methods 0.000 description 20
- 210000002374 sebum Anatomy 0.000 description 20
- 229910052708 sodium Inorganic materials 0.000 description 18
- 239000011734 sodium Substances 0.000 description 18
- 238000001694 spray drying Methods 0.000 description 15
- 239000004115 Sodium Silicate Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 14
- 229910052911 sodium silicate Inorganic materials 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 12
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 12
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 12
- 229910052709 silver Inorganic materials 0.000 description 12
- 239000004332 silver Substances 0.000 description 12
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 12
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 125000005702 oxyalkylene group Chemical group 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- BXSBGUZTAOTBBS-UHFFFAOYSA-N O.O.O.O.O.O.O.[Mg] Chemical compound O.O.O.O.O.O.O.[Mg] BXSBGUZTAOTBBS-UHFFFAOYSA-N 0.000 description 5
- 238000002310 reflectometry Methods 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
- 235000011180 diphosphates Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004688 heptahydrates Chemical class 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- QBRPIXOGXMPIMA-UHFFFAOYSA-N [Mg].S(O)(O)(=O)=O.O.O.O.O.O.O.O Chemical compound [Mg].S(O)(O)(=O)=O.O.O.O.O.O.O.O QBRPIXOGXMPIMA-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 241000894007 species Species 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- PLJXBUQESSWMNC-UHFFFAOYSA-N CCCCCCCCCCCCCCCC.CCCCCCCCCCCCCCCC(O)=O Chemical compound CCCCCCCCCCCCCCCC.CCCCCCCCCCCCCCCC(O)=O PLJXBUQESSWMNC-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
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- 241000723346 Cinnamomum camphora Species 0.000 description 1
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- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- OVBJJZOQPCKUOR-UHFFFAOYSA-L EDTA disodium salt dihydrate Chemical compound O.O.[Na+].[Na+].[O-]C(=O)C[NH+](CC([O-])=O)CC[NH+](CC([O-])=O)CC([O-])=O OVBJJZOQPCKUOR-UHFFFAOYSA-L 0.000 description 1
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- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of dress material powder detergent composition, is contained respectively with particular range：(A) surfactant, (B) comprising (a1) alkylbenzenesulfonate and (a2) alkyl sulfate are selected from the compound of one or more of the anhydride of magnesium sulfate and the hydrate of magnesium sulfate and (C) is selected from the compound of one or more of zeolite and tripolyphosphate, (a1)/(a2) mass ratio is more than 1 and less than 5, and adds up in (A) and contain more than (a1) and (a2) 60 mass % and below 100 mass %.
Description
Technical field
The present invention relates to dress material powder detergent composition and the washing methods of dress material.
Background technology
In dress material detergent, as cleansing, mostly with the anion surfactant of alkyl benzene sulphonate (salt) etc.
For main base.It it is known that anion surfactant can influence cleaning force because of the hardness components of the water used in cleaning.Cause
This, in order to remove hardness components from water, it will usually and with the builder of zeolite or tripolyphosphate etc..
In the 85th page table 11 of Japanese Unexamined Patent Publication 2005-160476 or the table 28 of page 102, disclose containing alkylbenzene
The anion surfactant of sodium sulfonate or sodium alkyl sulfate etc. and the high density detergent detergent composition of anhydrous magnesium sulfate.
In these specific example, the phosphoric acid class builder of tripolyphosphate etc. is largely coordinated.
In Japanese Unexamined Patent Application Publication 2009-504871, disclose is increasing skill containing anionic clean surface activating agent, calcium
Art, and the solid of the content of zeolite builders or phosphate builder down to the particle shape less than 5 mass % washs washing
In agent composition, magnesium sulfate etc. can be used as dehydrating agent.
In Japanese Unexamined Patent Application Publication 2009-504836, disclose containing alkylbenzenesulfonate, hydrability substance, and zeolite
The content of builder or phosphate builder washs detergent down to the solid less than 5 mass %.As hydrability substance, special
Sodium carbonate and/or magnesium sulfate are listed in the claim 4 of sharp document 3.In the Japanese Unexamined Patent Application Publication paragraph 0016 of No. 2009-504836
In, the purpose of usage for disclosing hydrability substance is to inhibit to generate when reducing the content of zeolite builders or phosphate builder
Solid washing detergent physical stability, especially into the deterioration of cake intensity.The hydration that Japanese Unexamined Patent Application Publication 2009-504836
Property substance preferably has defined hydration index, and it is without watery to suggest hydrability substance by the 0024th section record etc..
It is disclosed in Japanese Unexamined Patent Publication 2012-236978 containing being more than 2 selected from menthol and camphor and logPow
And the detergent ingredients of one or more of less than 7 fragrance component, surfactant, alkaline agent and metal ion chelation agent, and
And the hand washing detergent composition for laundering of refrigerant sense can be felt in hand washing.
In Japanese Unexamined Patent Application Publication 2012-500306, disclose containing nonionic surface active agent, the work of anionic surface
Property agent and cold water dispersing aid, and there is the super concentrated liquid detergent composition of excellent water dispersible at low temperature.
In claim 11 and 12, magnesium sulfate 7 hydrate is described as cold water dispersing aid.
Recorded in U.S. Patent No. 5013486 alkylbenzenesulfonate containing 2.9 weight %, alkyl sulfate with
And the detergent bar (detergent bar) of 25 weight % aqueous solutions of magnesium sulfate.Detergent bar can be become by describing magnesium sulfate
Firmly.
The content of the invention
The present invention relates to a kind of dress material powder detergent composition, wherein, contain：Following (A) ingredients, content 10
More than quality % and below 30 mass %；(B) ingredient, the value as the anhydride for being converted into magnesium sulfate are more than 1.5 mass %
And 10 below mass %；And (C) ingredient, content are below 8 mass %,
(a1) mass ratio (a1) ingredient/(a2) ingredient of ingredient and (a2) ingredient is more than 0.5 and less than 5, in (A) ingredient
In add up to containing more than (a1) ingredient and 60 mass % of (a2) ingredient and below 100 mass %,
(A) ingredient：Surfactant comprising following (a1) ingredients He (a2) ingredient,
(a1) ingredient：Alkylbenzenesulfonate,
(a2) ingredient：Alkyl sulfate；
(B) ingredient：The compound of one or more of the hydrate of anhydride and magnesium sulfate selected from magnesium sulfate；
(C) ingredient：Compound selected from one or more of zeolite and tripolyphosphate.
Moreover, it relates to a kind of washing methods of dress material, wherein, by the invention described above of more than 1g and below 10g
Dress material powder detergent composition and 1L Deutschland hardness be 5 ° of more than DH and 30 ° of below DH water mix, with mixing
Cleaning solution by dress material hand-wash wash.
Specific embodiment
Hand washing washing also is carried out to the dress material of fashion clothing etc. in Japan.Further, it is known that connect routine use in Southeast Asia
Dress material also have hand washing wash custom.
It is the environment of high temperature and humidity in south east asia, hand operation spends the time, and largely adheres to skin on clothes
The oily dirt of fat dirt etc..Hardness additionally, there are water is more than the area of the high rigidity of 5 ° of DH (especially 8 ° of DH).It is known such as
Largely there are sebum dirt in cleaning solution, the dirt removal there will be dress material reduces or since sebum dirt causes fruit
Be difficult to blister during cleaning, and foam not continue the technical issues of.Clearly seek (1) for used detergent and be not only clothing
The soil release of material newly seeks largely to blister during (2) hand washing washing, and the foam duration, in addition hand does not overheat during (3) hand washing washing
(hot) sense of touch is good.In addition, dirt is to be difficult to one of dirt removed, so as to seek higher cleaning force.For above-mentioned
" the dirt removal of (1) dress material " also clearly seeks the dirt removal of dirt.
In order to reduce the hardness components in water, and inhibit the reduction of the cleaning force of anion surfactant, reduce water
The ingredient of hardness can use zeolite or tripolyphosphate.
If however, largely coordinate these ingredients, not only economically not preferably, but also when being clearly present hand washing washing
Foaming characteristic and the foam become difficult to continue the technical issues of.
That is, in the detergent composition for hand washing washing, it is desirable to：It largely blisters during hand washing cleaning, the foam duration,
In addition the sense of touch of cleaning solution is good, and even if reducing the content of zeolite or tripolyphosphate, the also table in the water of high rigidity
Existing high oiliness soil cleaning power and the cleaning force to particulate foulings such as mud.
The present invention provides a kind of dress material powder detergent composition, even if the dress material powder detergent composition is with firmly
It spends high water, and the cleaning solution cleaning more than sebum dirt amount, is also able to maintain that high cleaning force to oily dirt, hand washing are clear
The continuation of the foam after foaming characteristic and hand washing cleaning when clean, and when hand-washing cleaning, hand does not overheat the sense of touch of (hot)
Well.Further, even if providing using water with high hardness, to being attached to the cleaning force of the dirt on dress material, also excellent dress material is used
Powder detergent composition.
According to the present invention it is possible to provide a kind of dress material powder detergent composition, which is combined with powder detergent
Even if object water with high hardness, and the cleaning solution cleaning more than sebum dirt amount, are also able to maintain that high to the clear of oily dirt
The continuation of the foam after foaming characteristic and hand washing cleaning when clean power, hand washing cleaning, and when hand washing is cleaned, hand is felt
It is good not overheat the sense of touch of (hot), and suitable for hand washing washing.Further, even if providing using water with high hardness, to being attached to clothing
The cleaning force of dirt on material also excellent dress material powder detergent composition.
Embodiments of the present invention include a kind of dress material powder detergent composition, wherein, contain：Following (A) ingredients
More than 10 mass % and below 30 mass %；(B) ingredient is more than 1.5 mass % and below 10 mass % as magnesium sulfate；With
And below 8 mass % of (C) ingredient, mass ratio (a1) ingredient/(a2) ingredient of (a1) ingredient and (a2) ingredient is more than 0.5 and 5
Hereinafter, add up in (A) ingredient containing more than (a1) ingredient and 60 mass % of (a2) ingredient and below 100 mass %,
(A) ingredient：Surfactant comprising following (a1) ingredients He (a2) ingredient,
(a1) ingredient：Alkylbenzenesulfonate,
(a2) ingredient：Alkyl sulfate；
(B) ingredient：Magnesium sulfate 7 hydrate；
(C) ingredient：Compound selected from one or more of zeolite and tripolyphosphate.
In addition, embodiments of the present invention are related to a kind of washing methods of dress material, wherein, by more than 1g and below 10g
The dress material powder detergent composition of the invention described above embodiment is 5 ° of more than DH and 30 ° of below DH with 1L Deutschland hardness
Water mixes, with the cleaning solution hand washing washing dress material mixed.
<(A) ingredient>
(A) ingredient is the surfactant for containing following (a1) ingredients and (a2) ingredient under prescribed conditions.
(a1) ingredient：Alkylbenzenesulfonate
(a2) ingredient：Alkyl sulfate
[(a1) ingredient]
As the alkylbenzenesulfonate of (a1) ingredient, be not particularly limited, for example, can enumerate with carbon number for 8 with
On, it is preferably more than 10, further preferably more than 12, and be less than 20, it is preferably less than 16 alkyl, is preferably straight chain
The alkylbenzenesulfonate of alkyl.
From the perspective of the storage stability of spatter property or composition, alkylbenzenesulfonate can enumerate sodium, potassium etc.
Alkali metal salt, alkanolamine etc..In the case of the composition of the modulation present invention, alkyl benzene sulphonate can be added into composition
(acid type), and be allowed in the mixed system of powder constituents with alkali progress neutralization reaction as alkylbenzenesulfonate, it can also be pre-
It is added to after first neutralizing in composition.In alkyl benzene sulphonate in, sodium hydroxide, potassium hydroxide, hydrogen-oxygen can be used
Change the alkali of lithium, ammonium hydroxide etc..The salt for forming (a1) ingredient is preferably the alkali metal salt of sodium, potassium etc., further preferably sodium salt.
[(a2) ingredient]
(a2) ingredient of the present invention is alkyl sulfate, and the carbon number of alkyl is preferably more than 10 and less than 16.That is,
(a) ingredient be preferably with carbon number be more than 10 and be less than 16 alkyl, be preferably straight chained alkyl alkylsurfuric acid
Salt.(a2) ingredient is preferably that the ratio for the straight chained alkyl that the carbon number in whole alkyl is more than 12 and less than 16 is 50 matter
Measure the alkyl sulfate of more than %.It is preferably whole alkane from the perspective of foaming characteristic during cleaning and the continuation of foam
The ratio for the straight chained alkyl that carbon number is 12 is more than 40 mass % further preferably more than 50 mass % in base, more
The preferably alkyl sulfate of more than 60 mass %.(a2) it is more than 12 and 16 that ingredient, which is more preferably carbon number in whole alkyl,
The ratio of following straight chained alkyl is more than 50 mass %, and all in alkyl the straight chained alkyl that carbon number is 12 ratio
Preferably more than 40 mass %, further preferably more than 50 mass % are more preferably the alkylsurfuric acid of more than 60 mass %
Salt.In addition, from the perspective of carrying capacity of environment is reduced by using renewable raw materials, it is straight in whole alkyl in (a2) ingredient
The ratio of alkyl group is preferably more than 50 mass % further preferably more than 70 mass %, be more preferably 90 mass % with
On, it is still more preferably more than 99 mass %, further more preferably 100 mass %, i.e. (a2) ingredient is straight chained alkyl
Sulfate.
The alkaline earth of alkali metal salt, alkanolamine and the magnesium of sodium, potassium etc., calcium etc. can be enumerated by forming the salt of (a2) ingredient
Metal salt etc. is preferably alkali metal salt, further preferably sodium salt from the perspective of clean-up performance, foaming characteristic, dissolubility.
In the present invention, mass ratio (a1) ingredient/(a2) ingredient of (a1) ingredient and (a2) ingredient for more than 0.5 and 5 with
Under.
Even if the dress material powder detergent composition of the present invention largely containing (B) ingredient, from being able to maintain that the clear of dirt
From the perspective of clean power, the mass ratio of (a1) ingredient/(a2) ingredient is also less than 5, is preferably less than 4.8, further preferably
Less than 4.6, it is more preferably less than 4.3, is still more preferably less than 4.0, more further preferably less than 3.5, into one
Step more preferably less than 2.5, further more preferably less than 2.4, and then preferably less than 2.2, and then more preferably 2.0
Below.
Even if the dress material powder detergent composition of the present invention largely contains magnesium sulfate 7 hydrate, from being able to maintain that oil
From the perspective of dirty cleaning force, the mass ratio of (a1) ingredient/(a2) ingredient is also less than 5, is preferably less than 4.8, further
Preferably less than 4.6, be more preferably less than 4.3, be even more preferably less than 2.5, further more preferably 2.4 with
Under, and then preferably less than 2.2, and then more preferably less than 2.0, more further preferably less than 1.8.
Even if the dress material powder detergent composition of the present invention is largely containing the magnesium sulfate beyond magnesium sulfate 7 hydrate
Hydrate or anhydride, from the perspective of the cleaning force for being able to maintain that greasy dirt, the mass ratio of (a1) ingredient/(a2) ingredient
Be preferably less than 4.8 for less than 5.0, further preferably less than 4.6, be more preferably less than 4.3, even more preferably for
Less than 2.5, further more preferably less than 2.4, and then preferably less than 2.2, and then more preferably less than 2.0, more
Further preferably less than 1.8.
From the perspective of the foam duration during cleaning under the conditions of high rigidity, the quality of (a1) ingredient/(a2) ingredient
Than for more than 0.5, being preferably more than 0.6, further preferably more than 0.7, it is more preferably more than 0.9.
From the perspective of the foam duration when cleaning force and cleaning that can take into account greasy dirt, (a1) ingredient/(a2) into
The mass ratio divided is preferably more than 0.9 and less than 1.8.
From the perspective of the foam duration when cleaning force and cleaning that can take into account greasy dirt and dirt, (a1) ingredient/
(a2) mass ratio of ingredient is preferably more than 0.9, and further preferably more than 1.1, it is more preferably more than 1.2, further
Preferably more than 1.4, more further preferably more than 1.5, and preferably less than 6.0, further preferably less than 5.0,
More preferably less than 4.8, more further preferably less than 4.6 are still more preferably less than 4.3, and then preferably 2.5
Hereinafter, and then more preferably less than 2.4, it is and then still more preferably less than 2.2, and then is more more preferably 2.0
Below.
In addition, in the present invention, add up in (A) ingredient containing more than (a1) ingredient and 60 mass % of (a2) ingredient and
Below 100 mass %.From the perspective of foaming characteristic during hand washing cleaning and the continuation of foam, in (A) ingredient preferably
Total to contain more than (a1) ingredient and 70 mass % of (a2) ingredient, further preferably more than 80 mass % are more preferably 90
More than quality % is still more preferably 100 mass %.
As (A) ingredient, the surfactant beyond (a1) ingredient and (a2) ingredient can be contained.As (a1) ingredient and
(a2) surfactant beyond ingredient, for example, can enumerate selected from polyoxyalkylene alkyl sulfate [for polyoxyalkylenes,
The degree of polymerization of oxyalkylene group is more than 1 and less than 10, and the carbon number of alkyl is more than 12 and less than 16.], alpha-sulfo-fatty acid
Alkyl ester salt, alpha-alkene sulfonate [carbon number of alpha-olefin is more than 12 and less than 18] and carbon number are more than 12
And the anion surfactant in less than 18 soap.
In addition, as (A) ingredient, can enumerate selected from polyoxyalkene sorbitan aliphatic ester, polyoxyalkylene fatty
Acid esters, polyoxyalkylene alkyl, polyoxyalkylene alkyl phenyl ether, sucrose fatty ester, sorbitan fatty acid ester, aliphatic acid
Nonionic surfactant in alkanolamide and alkyl-glucoside；Add selected from list or dialkylamine and its polyoxyethylene
Cationic surfactant into object and single or double long chain alkyl ammonium salt；Selected from carbobetaine, sulfobetaines,
And the amphoteric surfactant in hydroxy sulfo lycine.Above-mentioned nonionic surfactant, cationic surfactant and
The alkyl of amphoteric surfactant is preferably the primary alkyl or secondary alkyl that carbon number is more than 12 and less than 16.Preferred fatty acid
Carbon number be more than 12 and less than 16.Oxyalkylene group is preferably the oxyalkylene group that carbon number is more than 2 and less than 4, is made
For oxyalkylene group further preferably oxyethylene group.Polyoxyalkylenes are preferably that the repetitive unit of above-mentioned oxyalkylene group is 2
Above and less than 40 group.That is, in the case where being represented with the average addition molal quantity of oxyalkylene, preferably averagely addition
Molal quantity is more than 2 and less than 40.Silane alcohol base is preferably ethyl alcohol base (hydroxyethyl).
(A) in ingredient, the content of the surfactant beyond (a1) ingredient and (a2) ingredient, from the cleaning force of greasy dirt and clear
From the perspective of foam duration when clean, to be less than 40 mass %, preferably smaller than 30 mass % are further preferably no larger than 20 matter
%, more preferably less than 10 mass % are measured, is still more preferably 0 mass %, i.e. do not contain.
Modulation the present invention dress material powder detergent composition when, (A) ingredient can be used as containing (a1) ingredient,
(a2) mixture of ingredient and other surfactants coordinates.In addition, in the dress material powder detergent of the modulation present invention
During composition, (a1) ingredient, (a2) ingredient and other surfactants can also be respectively cooperating with.
[(B) ingredient]
(B) ingredient is anhydride and the compound of one or more of the hydrate of magnesium sulfate selected from magnesium sulfate.(B)
Ingredient, even if water with high hardness is used as clean water, is also able to maintain that skin by being used in combination with above-mentioned (a1) ingredient and (a2) ingredient
The continuation of the foam after foaming characteristic, hand washing cleaning when the cleaning force of fat dirt, hand washing are cleaned.
In addition, the dress material powder detergent composition of the present invention, by (B) ingredient containing specified quantitative, for using
It is excellent to the spatter property of dirt in the case of in water with high hardness, such as the cleaning for the water that hardness is 8 ° of more than DH.The present invention's
(B) it is said that the magnesium contained by ingredient is changed with the anion surfactant foam (scum) as the cleansing in cleaning solution,
And reduce the hardness components of cleaning effect.If distinguished into water with high hardness, such as the water of 8 ° of more than DH by (B) into
Divide and supplied magnesium, then unexpectedly the spatter property of dirt is improved.
In addition, if (B) ingredient is the hydrate of magnesium sulfate, then sense of touch when hand-washing becomes better.
(B) ingredient is preferably the hydrate of magnesium sulfate, specifically, can enumerate monohydrate, the magnesium sulfate of magnesium sulfate
Hexahydrate, heptahydrate, the dodecahydrate of magnesium sulfate of magnesium sulfate.Further preferably magnesium sulfate 7 hydrate.Sulphur
Sour magnesium heptahydrate in the case where water with high hardness is used as clean water to the cleaning force of sebum dirt and dirt,
The sense of touch when continuation of the foam after foaming characteristic, hand washing cleaning when being cleaned during hand washing, hand washing are cleaned is excellent, therefore preferably.
In addition, storage stability from dress material powder detergent composition, being particularly difficult to cause cured viewpoint during preservation to go out
The heptahydrate of hair, preferably also magnesium sulfate.Magnesium sulfate 7 hydrate can use powdery or granular.
[(C) ingredient]
(C) ingredient is the compound selected from one or more of zeolite and tripolyphosphate.
Zeolite is also referred to as crystallinity aluminosilicate.Specifically, A types, X-type, P type zeolite etc. can be contained as zeolite
Crystallinity aluminosilicate.Its average primary particle diameter is preferably 0.1 μm or more, further preferably 1 μm or more, additionally, it is preferred that being
Less than 10 μm, further preferably less than 5 μm.As the preferred substance of crystallinity aluminosilicate, be preferably type A zeolite (for example,
Trade name " Toyobuilder "：TOSOH CORPORATION are manufactured, and the oil suction measured by 5101 methods of JIS K can be
More than 40mL/100g).In addition, as preferred product, can also enumerate p-type (for example, trade name " Doucil A24 ",
" ZSEO64 " etc.；All it is the manufacture of Crosfield companies；Oil suction can be 60~150mL/100g), X-type is (for example, trade name
" WessalithXD ", the manufacture of Degussa companies, oil suction can be 80~100mL/100g), International Publication No. 9842622 records
Mixed zeolite.
Be preferably alkali metal ion as the counter ion in tripolyphosphate, further preferably selected from sodium ion and
Ion in potassium ion.In whole counter ions, the mass ratio of sodium ion and potassium ion is preferably more than 70 mass %, into one
Step is preferably more than 85 mass %.It is used in combination with tripolyphosphate, orthophosphates, pyrophosphate can be used.Tripolyphosphate, just
The mass ratio of phosphatic amount and pyrophosphate is preferably tripolyphosphate/orthophosphates/pyrophosphate=(80 mass parts
Above and 97 is below mass part)/(more than 1 mass parts and 10 is below mass part)/(more than 2 mass parts and 10 is below mass part)
(amount be as anhydride to calculate).
In the dress material powder detergent composition of the present invention, zeolite is preferably comprised as (C) ingredient.It is in addition, of the invention
Dress material powder detergent composition in, as (C) ingredient, tripolyphosphate can also be contained.
[dress material powder detergent composition]
The dress material powder detergent composition of the present invention is used preferably as hand washing washing.In detail as described later, preferably make
To be used to modulate the powder detergent composition of the cleaning solution used in hand washing washing.In addition, it is also adaptable as while this is sent out
Bright dress material is sprinkled upon with powder detergent composition in a part for the dress material in the water for being impregnated in and being used in washing, while being allowed to
It is contacted with water and rubs detergent used in the washing of washing.In addition, be suitable as by by the present invention powder detergent
Composition is taken in right amount with hand, and the hand is impregnated in the water used in washing, is next stirred while being mixed with water
So as to modulate cleaning solution, and dress material is impregnated in the detergent that rubbing washing is carried out in the cleaning solution.
The content of (A) ingredient in the dress material powder detergent composition of the present invention is more than 10 mass % and 30 matter
Below % is measured, from the perspective of foaming characteristic when spatter property, hand washing cleaning and the continuation of foam, the content of (A) ingredient
Preferably more than 12 mass %, further preferably more than 14 mass % are more preferably more than 16 mass %.The clothing of the present invention
The content of (A) ingredient in material powder detergent composition is preferably below 25 mass % from the viewpoint of economy,
Further preferably below 23 mass % are more preferably below 21 mass %, are still more preferably below 20 mass %, more
Add further preferably below 19 mass %.
In addition, the content of (B) ingredient in the dress material powder detergent composition of the present invention, as being converted into magnesium sulfate
Anhydride value, i.e., be scaled with anhydrous more than 1.5 mass % and below 10 mass %, from hand washing clean when foaming characteristic with
It is preferably more than 1.6 mass % and from the perspective of the continuation of foam, further preferably more than 1.8 mass % are more excellent
It elects as more than 2 mass %, is still more preferably more than 2.2 mass %, more further preferably more than 2.5 mass %, into
One step is more preferably more than 3 mass %.From the perspective of sense of touch when economy, cleaning force and hand washing cleaning, (B) ingredient
Value of the content as the anhydride for being scaled magnesium sulfate, preferably below 8 mass %, further preferably 7 in the composition
Below quality % is more preferably below 6 mass %.
From the perspective of the spatter property of sebum dirt, (B) in dress material powder detergent composition of the invention into
Point content, the value as the anhydride for being converted into magnesium sulfate is preferably below 8 mass %, further preferably 7 mass % with
Under, be more preferably below 6 mass %, be still more preferably below 5 mass %, more further preferably 4 mass % with
Under, it is even more preferably below 3 mass %, further more preferably below 2.5 mass %.
From the perspective of the spatter property of dirt, (B) ingredient in dress material powder detergent composition of the invention
Content is more than 1.5 mass % as the value for the anhydride for being scaled magnesium sulfate, is preferably more than 1.6 mass %, further
Preferably more than 1.8 mass % are more preferably more than 2.0 mass %, are still more preferably more than 2.5 mass %, into one
Step be more preferably more than 3.0 mass %, further more preferably more than 4.0 mass %, and then preferably 5.0 mass % with
On, and preferably below 8.0 mass %, further preferably below 7.0 mass %.
In addition, the content of (C) ingredient in the dress material powder detergent composition of the present invention is below 8 mass %, from
It is preferably below 7 mass % from the perspective of economy, further preferably below 6.5 mass %, are still more preferably 6
Below quality %.From the perspective of the spatter property of dirt, the content of (C) ingredient is in the composition below 8 mass %, preferably
It is more preferably below 7.0 mass % for below 7.5 mass %, further preferably below 7.0 mass %, more preferably 6.5
Below quality % is even more preferably below 6.0 mass %, further more preferably below 5.5 mass %, further
Preferably below 5.0 mass %.From the perspective of spatter property, the powder of sebum dirt dry loose easily metering, zeolite
Content is preferably more than 3 mass %, further preferably more than 4 mass % in the composition.From cleaning when foaming characteristic and
From the perspective of the continuation of foam, preferably the content of tripolyphosphate is more few better, in the composition preferably 3 mass % with
Under, further preferably below 2 mass % are not contained more preferably, i.e. 0 mass %.In addition, in (C) ingredient, tripolyphosphate
Content be scaled it is anhydrous.
In the dress material powder detergent composition of the present invention, as (D) ingredient, it can contain selected from alkali metal carbonic acid
The compound of one or more of salt (d1), alkali metal chloride (d2) and alkali metal sulfates (d3).
Alkali carbonate (d1) is matched with by being used as alkaline agent in the dress material powder detergent composition of the present invention, from
And with the effect for improving cleaning force.Specific compound is not particularly limited, for example, can enumerate selected from sodium carbonate and carbon
The compound of one or more of sour potassium.
Alkali metal chloride (d2), alkali metal sulfates (d3) are by being matched with dress material powder detergent group of the invention
It closes in object, so as to improve the ionic strength in cleaning solution, and foaming characteristic and the continuation of foam when improving cleaning.Make
It for the specific compound of alkali metal chloride (d2), is not particularly limited, can enumerate in sodium chloride and potassium chloride
1 kind or more of compound.In addition, the particular compound as alkali metal sulphuric acid sodium (d3), is not particularly limited, it can enumerate and be selected from
The compound of one or more of potassium sulfate and sodium sulphate.
As (D) ingredient, from the perspective of foaming characteristic during cleaning and the continuation of foam, alkali is preferably selected from
The compound of one or more of metal carbonate (d1) and alkali metal sulfates (d3).From the sight of the spatter property of sebum dirt
Point sets out, and alkali carbonate (d1), especially more than 20 mass % of sodium carbonate is preferably comprised in (D) ingredient, further preferably
For more than 25 mass %, more preferably more than 30 mass %.From the perspective of the foaming characteristic and continuation during cleaning, (D)
It is preferably comprised in ingredient below 100 mass % of alkali carbonate (d1), further preferably below 90 mass %, it is more excellent
Choosing contains below 80 mass %, further preferably below 70 mass %.In addition, the content of (D) ingredient is anhydrous conversion.
In addition, the dress material of the present invention with the content of (D) ingredient in powder detergent composition be preferably 40 mass % with
Upper and below 70 mass %.From under the conditions of high rigidity spatter property, hand washing cleaning when foaming characteristic, the viewpoint of the continuation of foam
Set out, the content of (D) ingredient is more preferably more than 50 mass % in the composition, further preferably 55 mass % with
On, it is more preferably below 65 mass % from the viewpoint of economy.
The dress material powder detergent composition of the present invention can contain following ingredient.(i) from the stream of detergent particles
Dynamic property and not from the perspective of caking capacity, can also contain surface modifier.Covering is modified as surface, such as can be arranged
Lift aluminosilicate, calcium silicates, silica, the silicate compound of crystalline silicate compound etc., bentonite, talcum, viscous
The clay minerals such as soil, carboxymethyl cellulose, polyethylene glycol, polyacrylic acid or its salt, acrylic acid and maleic acid copolymer or
The water-soluble polymer of the polycarboxylate of its salt etc. etc..The content of surface modifier is from the perspective of storage stability, preferably
For below the 20 mass % in the dress material powder detergent composition of the present invention, further preferably below 15 mass %.Separately
Outside, it is preferably more than the 1 mass % in detergent composition of the invention, further preferably from the perspective of being modified from surface
It is more preferably more than 5 mass % for more than 3 mass %；
(ii) the gamut preventing agent of polyvinylpyrrolidone etc.；
(iii) enzyme of cellulase, amylase, pectase, protease, lipase etc.；
(iv) fluorescent dye, such as Tinopal CBS (trade name, Ciba Specialty Chemicals Inc.
Manufacture) or the fluorescent dyes sold of WHITEX SA (trade name, Sumitomo Chemical Co manufacture)；
(v) antioxidant of butylated hydroxytoluene, distyrenated cresols, sodium sulfite and sodium hydrogensulfite etc.；
(vii) antifoaming agent of pigment, fragrance, antibiotic antiseptic, silicone etc.；
(viii) ion exchange water, tap water, in ion exchange water to add compared with the quality of water as 0.1~5mg/kg
The water of the water of sodium hypochlorite etc. is added.
From the perspective of dissolution in low temperature, stability, according to JIS K3362：2008 (the chapter Section 1 of page 58 the 8th) are recorded
The average grain diameter of detergent composition of the present invention acquired with screening machinery by the granularity that method for sieving measures be preferably
150 μm or more and less than 1000 μm, further preferably more than 200 μm and less than 900 μm, more preferably 250 μm or more and
Less than 800 μm.
From the perspective of dissolution in low temperature, stability, pass through JIS K3362:2008 (the chapter Section 2 of page 59 the 8th) are recorded
The apparent density (g/ml) of detergent composition of the present invention that measures of method be preferably more than 0.15 and less than 1.2, into one
Step is preferably more than 0.2 and less than 1.1, is more preferably more than 0.25 and less than 1.0, still more preferably for more than 0.3 and
Less than 0.98.
From the perspective of clean-up performance and bubble amount and foam duration, the JIS of detergent composition of the invention
K3362:2008 (the chapter Section 3 of page 60 the 8th) record the 1.0 mass % measured at 25 DEG C aqueous solution pH be preferably 8 with
Upper and less than 12, further preferably more than 9 and less than 11.5, are more preferably more than 9.5 and less than 11, still more preferably
For more than 10 and less than 11.
The manufacturing method of the detergent composition of the present invention is not particularly limited, and can be manufactured with well known method.Example
Such as, spray drying process, dry type neutralisation, drying-granulating method, dry-mix process, fluidized bed seasoning, film drying can be passed through
Method, extruding pelletization method, rotation comminution granulation, stirring-granulating method, densification comminution granulation, surfactant support method and combination thereof is come
It is manufactured.
In the detergent composition of the manufacture present invention, (B) ingredient can also be mixed with the slurry containing (A) ingredient and water
It closes, even if from the powder detergent composition for preserving the present invention, is also able to maintain that from the perspective of more good mobility, it is excellent
Spray drying was gated to manufacture containing (A) ingredient and the few blapharoplast of moisture, and by (B) ingredient and the matrix
Particle mixes.
From the perspective of foaming characteristic during washing is good, preferably by spray drying, manufacture contains (A) ingredient and 10 matter
The blapharoplast of the water of below % is measured, and (B) ingredient is mixed with the blapharoplast.(B) ingredient can also be in blapharoplast
Cooperation is less than the amount of 10 mass % of whole use levels.There is mobility from the dress material powder detergent of the present invention
(fluidity) from the perspective of, the moisture in the blapharoplast containing (A) ingredient be more preferably 9 mass % with
Under, further preferably below 8 mass % are more preferably below 7 mass %, are still more preferably below 6 mass %.
The dress material powder detergent composition of the present invention, from sebum dirt or the spatter property of dirt, foaming characteristic, foam
Continuation raising from the perspective of, preferably with dress material use obtained from including the manufacturing method of following 1~processes of process 3
Powder detergent composition.
Process 1：(A) ingredient and water are mixed, so as to obtain moisture as more than 30 mass % and below 70 mass %
The process of slurry；
Process 2：The slurry obtained in process 1 is spray-dried, obtains the matrix that moisture is below 10 mass %
The process of grain；
Process 3：The process that the blapharoplast obtained in process 2 is mixed with (B) ingredient, (C) ingredient.
(B) ingredient can also use the 10 mass % for being less than whole use levels in process 1.It is held from foam is further improved
From the perspective of continuous property, (B) ingredient is using more than the 93 mass % of whole use levels preferably in process 3, and surplus is in process 1
It uses, using more than the 95 mass % of whole use levels in process 3, surplus makes further preferred (B) ingredient in process 1
With more preferred (B) ingredient uses whole use levels in process 3.
From the perspective of the easiness of manufacture, the moisture in the slurry obtained in above-mentioned operation 1 is preferably 35 matter
Measure more than %, further preferably more than 40 mass %, and preferably below 65 mass %, further preferably 60 mass %
Below.
From the perspective of the dress material of the present invention has mobility (fluidity) with powder detergent composition, above-mentioned work
Moisture in the blapharoplast obtained in sequence 2 is more preferably below 9 mass %, is more preferably below 8 mass %,
Further preferably below 7 mass % are more preferably below 6 mass %.
Blapharoplast and (B) ingredient and (C) ingredient can also simultaneously be mixed in above-mentioned operation 3.Alternatively, it is also possible to
The 2 kinds of ingredients that will be selected from blapharoplast and (B) ingredient and (C) ingredient mix, then are mixed with remaining ingredient.
In the case where using (D) ingredient or any ingredient, can be used in the arbitrary process of 1~process of process 3.
From the perspective of the easiness of manufacture, (D) ingredient is used preferably in process 1.Therefore, in the case of containing (D) ingredient,
The dress material of the present invention is preferably to be obtained with the manufacturing method including following processes 1 '~process 3 ' with powder detergent composition
Dress material powder detergent composition.
Process 1 '：(A) ingredient, (D) ingredient and water are mixed, so as to obtain moisture as more than 30 mass % and 70 matter
The process for measuring the slurry of below %.
Process 2 '：The slurry obtained in process 1 is spray-dried, obtains the matrix that moisture is below 10 mass %
The process of grain.
Process 3 '：The process that the blapharoplast obtained in process 2 and (B) ingredient, (C) ingredient are mixed.
[hand washing washing methods]
The dress material powder detergent composition of the present invention is used preferably as hand washing washing.The dress material of the present invention is washed with powder
Agent composition is washed as the cleaning solution mixed with water, is preferably supplied in hand washing washing.As the dress material for having used the present invention
With the washing methods of powder detergent composition, the dress material that can enumerate the present invention by more than 1g and below 10g is washed with powder
The water mixing of agent composition and 1L Deutschland hardness for 5 ° of more than DH and 30 ° of below DH is washed, is washed with the cleaning solution mixed
Wash the washing methods of the dress material of dress material.
In above-mentioned washing methods, from the perspective of spatter property, powder detergent composition of the invention is in cleaning solution
In concentration be preferably more than 2.5g/L, further preferably more than 3g/L, be more preferably more than 3.5g/L.On the other hand,
It is below 10g/L from the perspective of rinsability, is preferably below 8g/L, further preferably below 6g/L.More preferably
It is used with the concentration of more than 3.5g/L and below 5g/L.
In cleaning solution, the dress material powder detergent composition of the present invention is preferably contained with the concentration of more than 0.03 mass %
In (A) ingredient, further preferably more than 0.06 mass %, also, from the viewpoint of economy, preferably with 0.12 matter
The concentration of amount below % contains, and is further preferably contained with the concentration of below 0.09 mass %.
In above-mentioned washing methods, the hardness of the water used in the modulation of cleaning solution with Deutschland hardness be calculated as 5 ° of more than DH and
30 ° of below DH.It is real from being easier in terms of foaming characteristic, the continuation of foam in spatter property, the cleaning of excellent sebum dirt
It is preferably 6 ° of more than DH from the perspective of the effect of the present invention is felt on border, further preferably 8 ° of more than DH are more preferably
10 ° of more than DH.From during cleaning foaming characteristic, be preferably 30 ° of below DH, further preferably from the perspective of the continuation of foam
It is more preferably 20 ° of below DH for 25 ° of below DH.Hardness is represented with the chelatometric titration for having used disodium EDTA
The total hardness that method acquires.
Therefore, can be preferably more than 2.5g by more than 1g in the washing methods of the dress material of the present invention, it is further excellent
It elects more than 3g as, is more preferably more than 3.5g, and be below 10g, be preferably below 8g, further preferably below 6g,
The dress material powder detergent composition of the present invention and the Deutschland hardness of 1L of more preferably below 5g/L is 5 ° of more than DH, excellent
It elects 6 ° of more than DH as, further preferably 8 ° of more than DH, is more preferably 10 ° of more than DH, and be 30 ° of below DH, further
Preferably 25 ° of below DH are more preferably the water mixing of 20 ° of below DH, washing dress material are hand-washed with the cleaning solution being mixed to get.
In above-mentioned washing methods, from the perspective of the easiness of washing when being cleaned from hand washing, the clothing containing the present invention
The ratio between the capacity (L) of the cleaning solution of material powder detergent composition and the quality (kg) of dress material (hereinafter referred to as bath raio) are with [clear
The capacity (L) of clean liquid]/[quality (kg) of dress material] meter preferably more than 3, further preferably more than 5.From spatter property, cleaning
When foaming characteristic, from the perspective of the continuation of foam, bath raio is preferably less than 20, further preferably less than 10.
In addition, other specific application methods of the powder detergent composition as the present invention, can also enumerate on one side
The detergent composition of the present invention is sprinkled upon in a part for the dress material being impregnated in washing in the water that uses, while being allowed to and water
Contact, and the method for rubbing washing.In addition, by the way that the powder detergent composition of the present invention is taken in right amount with hand, by the hand
It is impregnated in washing in the water that uses, next stirs while mixed with water so as to modulate cleaning solution, dress material is impregnated in
The method that rubbing washing is carried out in the cleaning solution can further be actually perceived the effect of the present invention.
On above-mentioned embodiment, the present invention further discloses following dress material powder detergent composition and
The washing methods of dress material.
<1>A kind of dress material powder detergent composition, wherein, contain：Following more than 10 mass % of (A) ingredient and 30 matter
Measure below %；(B) ingredient, the value for being converted into the anhydride of magnesium sulfate are more than 1.5 mass % and below 10 mass %；And
(C) below 8 mass % of ingredient, mass ratio (a1) ingredient/(a2) ingredient of (a1) ingredient and (a2) ingredient for more than 0.5 and 5 with
Under, add up in (A) ingredient containing more than (a1) ingredient and 60 mass % of (a2) ingredient and below 100 mass %,
(A) ingredient：Surfactant comprising following (a1) ingredients He (a2) ingredient,
(a1) ingredient：Alkylbenzenesulfonate,
(a2) ingredient：Alkyl sulfate；
(B) ingredient：The compound of one or more of the heptahydrate of anhydride and magnesium sulfate selected from magnesium sulfate；
(C) ingredient：Compound selected from one or more of zeolite and tripolyphosphate.
<2>Such as<1>The dress material powder detergent composition, wherein, (B) ingredient is the hydrate of magnesium sulfate.
<3>Such as<2>The dress material powder detergent composition, wherein, contain：Following 10 mass % of (A) ingredient with
Upper and below 30 mass %；(B) ingredient, be converted into magnesium sulfate anhydride value for more than 1.5 mass % and 10 mass % with
Under；And below 8 mass % of (C) ingredient, mass ratio (a1) ingredient/(a2) ingredient of (a1) ingredient and (a2) ingredient for 0.5 with
It is upper and less than 5, add up in (A) ingredient containing more than (a1) ingredient and 60 mass % of (a2) ingredient and below 100 mass %,
(A) ingredient：Surfactant comprising following (a1) ingredients He (a2) ingredient,
(a1) ingredient：Alkylbenzenesulfonate,
(a2) ingredient：Alkyl sulfate；
(B) ingredient：Magnesium sulfate 7 hydrate；
(C) ingredient：Compound selected from one or more of zeolite and tripolyphosphate.
<4>Such as<1>~<3>Any one of dress material powder detergent composition, wherein, (a1) ingredient be with
Carbon number is more than 8, is preferably more than 10, further preferably more than 12, and be less than 20, it is preferably less than 16 alkane
Base is preferably the alkylbenzenesulfonate of straight chained alkyl.
<5>Such as<1>~<4>Any one of dress material powder detergent composition, wherein, (a2) ingredient be with
Carbon number be more than 10 and be less than 16 alkyl, be preferably straight chained alkyl alkyl sulfate.
<6>Such as<1>~<5>Any one of dress material powder detergent composition, wherein, for (a2) ingredient,
The ratio of straight chained alkyl in whole alkyl is more than 50 mass %, is preferably more than 70 mass %, is more preferably 90 matter
More than % is measured, is still more preferably more than 99 mass %, further more preferably 100 mass %, i.e. (a2) ingredient is straight
Alkyl group sulfate.
<7>Such as<1>~<6>Any one of dress material powder detergent composition, wherein, (a2) ingredient for all
Carbon number in alkyl is that the ratio of more than 12 and less than 16 straight chained alkyl is more than 50 mass %, and all in alkyl
Carbon number be 12 the ratio of straight chained alkyl be preferably more than 40 mass % further preferably more than 50 mass %, more
Add the alkyl sulfate of preferably more than 60 mass %.
<8>Such as<1>~<7>Any one of dress material powder detergent composition, wherein, (a1) ingredient and (a2)
Mass ratio (a1) ingredient/(a2) ingredient of ingredient is more than 0.5, is preferably more than 0.6, further preferably more than 0.7, more
Preferably more than 0.9, and be preferably less than 4.8 for less than 5, further preferably less than 4.6, be more preferably 4.3 with
Under, it is even more preferably less than 2.5, more further preferably less than 1.8.
<9>Such as<1>~<8>Any one of dress material powder detergent composition, wherein, closed in (A) ingredient
Meter containing more than (a1) ingredient and 60 mass % of (a2) ingredient, preferably more than 70 mass %, further preferably 80 mass % with
On, it is more preferably more than 90 mass %, and be below 100 mass %, it is preferably 100 mass %.
<10>Such as<1>~<9>Any one of dress material powder detergent composition, wherein, contain (A) ingredient 10
More than quality %, be preferably more than 12 mass %, further preferably more than 14 mass %, be more preferably 16 mass % with
On, and be below 30 mass %, it is preferably below 25 mass %, further preferably below 23 mass %, more further
Preferably below 19 mass %.
<11>Such as<1>~<10>Any one of dress material powder detergent composition, wherein, magnesium sulfate seven is hydrated
Object is powdery or granular.
<12>Such as<1>~<11>Any one of dress material powder detergent composition, wherein, as being converted into sulphur
The value of the anhydride of sour magnesium is preferably more than 1.6 mass % containing more than 1.5 mass % of (B) ingredient, and further preferably 1.8
More than quality %, be more preferably more than 2 mass %, more further preferably more than 2.5 mass %, even more preferably for
More than 3 mass %, and be below 10 mass %, it is preferably below 8 mass %, further preferably below 7 mass %, more
Preferably below 6 mass %.
<13>Such as<1>~<12>Any one of dress material powder detergent composition, wherein, as (C) ingredient
Contain zeolite.
<14>Such as<1>~<13>Any one of dress material powder detergent composition, wherein, as (C) ingredient
Contain tripolyphosphate.
<15>Such as<1>~<14>Any one of dress material powder detergent composition, wherein, contain (C) ingredient 7
Below quality %, further preferably below 6.5 mass % are more preferably below 6 mass %.
<16>Such as<1>~<15>Any one of dress material powder detergent composition, wherein, as (C) ingredient
Zeolite content in the composition for more than 3 mass %, be preferably more than 4 mass %.
<17>Such as<1>~<16>Any one of dress material powder detergent composition, wherein, as (C) ingredient
Tripolyphosphate content in the composition for below 3 mass %, be preferably below 2 mass %, further preferably 0 matter
Measure %.
<18>Such as<1>~<17>Any one of dress material powder detergent composition, wherein, be further used as
(D) ingredient contains in the composition selected from alkali carbonate (d1), alkali metal chloride (d2) and alkali metal sulfates
One or more of (d3) more than 40 mass % of compound and below 70 mass %.
<19>Such as<18>The dress material powder detergent composition, wherein, alkali carbonate (d1) is selected from carbon
The compound of one or more of sour sodium and potassium carbonate.
<20>Such as<18>Or<19>The dress material powder detergent composition, wherein, alkali metal chloride (d2) is
Compound selected from one or more of sodium chloride and potassium chloride.
<21>Such as<18>~<20>Any one of dress material powder detergent composition, wherein, alkali metal sulphuric acid
Salt (d3) is the compound selected from one or more of potassium sulfate and sodium sulphate.
<22>Such as<18>~<21>Any one of dress material powder detergent composition, wherein, in the composition
It is preferably more than 50 mass % containing more than 40 mass % of (D) ingredient, further preferably more than 55 mass %, and be 70
Below quality % is preferably below 65 mass %.
<23>Such as<1>~<22>Any one of dress material powder detergent composition, wherein, for hand washing wash
With.
<24>A kind of washing methods of dress material, wherein, be preferably more than 2.5g by more than 1g, further preferably 3g with
On, it is more preferably more than 3.5g, and be below 10g, it is preferably below 8g, further preferably below 6g, more preferably
For below 5g/L's<1>~<23>Any one of dress material powder detergent composition and 1L Deutschland hardness be 5 ° of DH
More than, it is preferably 6 ° of more than DH, further preferably 8 ° of more than DH are more preferably 10 ° of more than DH, and are 30 ° of below DH,
Preferably 25 ° of below DH are more preferably the water mixing of 20 ° of below DH, washing dress material are hand-washed with the cleaning solution being mixed to get.
<25>Such as<1>~<17>Any one of dress material powder detergent composition, wherein, the dress material powder
Last detergent composition is obtained by including the manufacturing method of following 1~processes of process 3.
Process 1：(A) ingredient and water are mixed, so as to obtain moisture as more than 30 mass % and below 70 mass %
The process of slurry；
Process 2：The slurry obtained in process 1 is spray-dried, obtains the matrix that moisture is below 10 mass %
The process of grain；
Process 3：The process that the blapharoplast obtained in process 2 and (B) ingredient, (C) ingredient are mixed.
<26>Such as<18>~<22>Any one of dress material powder detergent composition, wherein, the dress material is used
Powder detergent composition is obtained by including the manufacturing method of following processes 1 '~process 3 '.
Process 1 '：(A) ingredient, (D) ingredient and water are mixed, so as to obtain moisture as more than 30 mass % and 70 matter
The process for measuring the slurry of below %；
Process 2 '：The slurry obtained in process 1 is spray-dried, obtains the matrix that moisture is below 10 mass %
The process of grain；
Process 3 '：The process that the blapharoplast obtained in process 2 and (B) ingredient, (C) ingredient are mixed.
Embodiment
Following embodiment is illustrated for the implementation of the present invention.Embodiment is illustrated for example of the invention
, it is not configured to limit the present invention.
The ingredient used in embodiment is illustrated below.
[(A) ingredient]
(a1-1)：Neopelex [(a1) ingredient]
(a2-1)：Sodium alkyl sulfate [(a2) ingredient, the composition of alkyl：Lauryl/myristyl/palmityl=67/28/5
(mass ratio)]
(a3-1)：Polyoxyethylene (ethylene oxide be averaged addition molal quantity for 21) lauryl ether
[(B) ingredient]
Digital representation in table is converted into the quality % of the anhydride of magnesium sulfate.
(b-1)：Magnesium sulfate 7 hydrate
(b-2)：The anhydride of magnesium sulfate
[(C) ingredient]
(c-1)：Zeolite [4A type zeolites, average grain diameter are 3 μm] (TOSOH CORPORATION manufactures)
(c-2)：Sodium tripolyphosphate
[(D) ingredient]
(d1-1)：Sodium carbonate
(d3-1)：Sodium sulphate
[any ingredient]
(e-1)：No. 2 sodium metasilicate：(TOKUYAMA SIAM SILICA CO.LTD. are manufactured sodium metasilicate (40 mass %), table
The middle quality % for representing active ingredient.)
(e-2)：Polyacrylic acid sodium salt (40 mass % aqueous solutions, weight average molecular weight 8000, represent in table effectively into
The quality % divided.)
<Embodiment 1>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 18.62kg concentration is 65 mass %, 22.00kg concentration
Sodium alkyl sulfate paste, 30.25kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 22.00kg sodium carbonate,
44.00kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.1kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 2.5 mass %).Further, by the obtained particle of 90.9 parts by weight and 5 parts by weight zeolites, 4.1 parts sulfuric acid magnesium
Heptahydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder detergent group
Close object.The average grain diameter of the powder detergent composition is 262 μm, the apparent density of JIS K3362 is 0.37g/mL.It is acquired
The composition of powder detergent composition be recorded in table 1.
<Embodiment 2>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 19.97kg concentration is 65 mass %, 23.60kg concentration
Sodium alkyl sulfate paste, 32.44kg concentration be 40 mass % No. 2 sodium silicate aqueous solutions, 24kg sodium carbonate, 47.19kg
Sodium sulphate, the Sodium Polyacrylate saline solution that 1.18kg concentration is 40 mass % and water mixing, have modulated moisture as 50 matter
Measure the uniform slurry of %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
For 2.36 mass %).Further, by the obtained blapharoplast of 84.76 parts by weight and 5 parts by weight zeolites, 10.24 parts by weight sulphur
Sour magnesium heptahydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder washing
Agent composition.The average grain diameter of the powder detergent composition is 261 μm, the apparent density of JIS K3362 is 0.36g/mL.Institute
The composition of obtained powder detergent composition is recorded in table 1.
<Embodiment 3>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 20.46kg concentration is 65 mass %, 24.18kg concentration
Sodium alkyl sulfate paste, 33.25kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 24.18kg sodium carbonate,
48.36kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.21kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 0.31 mass %).Further, by the obtained blapharoplast of 82.71 parts by weight and 5 parts by weight zeolites, 12.3 weight
Part magnesium sulfate 7 hydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder
Detergent composition.The average grain diameter of the powder detergent composition is 265 μm, the apparent density of JIS K3362 is 0.38g/
mL.The composition of obtained powder detergent composition is recorded in table 1.
<Embodiment 4>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 14.39kg concentration is 65 mass %, 31.17kg concentration
Sodium alkyl sulfate paste, 30.25kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 22.00kg sodium carbonate,
44.00kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.1kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 2.5 mass %).Further, by the obtained blapharoplast of 90.9 parts by weight and 5 parts by weight zeolites, 4.1 parts by weight sulphur
Sour magnesium heptahydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder washing
Agent composition.The average grain diameter of the powder detergent composition is 290 μm, the apparent density of JIS K3362 is 0.37g/mL.Institute
The composition of obtained powder detergent composition is recorded in table 1.
<Embodiment 5>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 15.43kg concentration is 65 mass %, 33.43kg concentration
Sodium alkyl sulfate paste, 32.44kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 23.60kg sodium carbonate,
47.19kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.18kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 2.36 mass %).Further, by the obtained blapharoplast of 84.76 parts by weight and 5 parts by weight zeolites, 10.24 weight
Part magnesium sulfate 7 hydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder
Detergent composition.The average grain diameter of the powder detergent composition is 289 μm, the apparent density of JIS K3362 is 0.38g/
mL.The composition of obtained powder detergent composition is recorded in table 1.
<Embodiment 6>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 25.30kg concentration is 65 mass %, 18.33kg concentration
Sodium alkyl sulfate paste, 30.25kg concentration be 40 mass % No. 2 sodium silicate aqueous solutions, 22.00kg sodium carbonate, 44kg
Sodium sulphate, the Sodium Polyacrylate saline solution that 1.1kg concentration is 40 mass % and water mixing, have modulated moisture as 50 mass %
Uniform slurry.Next, this slurry is dried by spray drying, blapharoplast (moisture 5.5 has been obtained
Quality %).Further, by the obtained blapharoplast of 90.9 parts by weight and 5 parts by weight zeolites, 4.1 parts sulfuric acid magnesium, seven water
It closes object to be mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder detergent combination
Object.The average grain diameter of the powder detergent composition is 267 μm, the apparent density of JIS K3362 is 0.34g/mL.It is obtained
The composition of powder detergent composition is recorded in table 1.
<Embodiment 7>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 16.92kg concentration is 65 mass %, 36.67kg concentration
Sodium alkyl sulfate paste, 30.25kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 22.00kg sodium carbonate,
44.00kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.1kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 5.5 mass %).Further, by the obtained blapharoplast of 90.9 parts by weight and 5 parts by weight zeolites, 4.1 parts by weight sulphur
Sour magnesium heptahydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder washing
Agent composition.The average grain diameter of the powder detergent composition is 290 μm, the apparent density of JIS K3362 is 0.35g/mL.Institute
The composition of obtained powder detergent composition is recorded in table 1.
<Embodiment 8>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 18.20kg concentration is 65 mass %, 21.51kg concentration
Sodium alkyl sulfate paste, 29.57kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 21.51kg sodium carbonate,
43.01kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.08kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 10.60 mass %).Further, it is the obtained blapharoplast of 93 parts by weight and 5 parts by weight zeolites, 2 parts by weight is anhydrous
Magnesium sulfate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder detergent combination
Object.The average grain diameter of the powder detergent composition is 275 μm, the apparent density of JIS K3362 is 0.32g/mL.It is obtained
The composition of powder detergent composition is recorded in table 1.
<Embodiment 9~18>
In embodiment 1, suitably change species or the dosage of each ingredient to become table 2 or forming described in table 3, manufacture
The dress material powder detergent composition of the present invention.At this point, in embodiment 18, coordinate in slurry before spray drying
(being used in process 1) magnesium sulfate 7 hydrate.
In addition, in embodiment 1~18, detergent combination has been modulated with the manufacturing method including 1~process of above-mentioned operation 3
Object.In embodiment 1~17, (B) ingredient has been used in process 3, in embodiment 18, used in process 1 (B) into
Point.
<Comparative example 1>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 17.81kg concentration is 65 mass %, 21.05kg concentration
Sodium alkyl sulfate paste, 28.95kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 21.05kg sodium carbonate,
42.11kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.05kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 12.6 mass %).Further, the obtained blapharoplast of 95 parts by weight and 5 parts by weight zeolites are stirred using concrete
It mixes machine (manufacture of silver dollar mechanical industry Co., Ltd.) to be mixed, has obtained powder detergent composition.The powder detergent group
The average grain diameter for closing object is 263 μm, the apparent density of JIS K3362 is 0.39g/mL.Obtained powder detergent composition
Composition be recorded in table 1.
<Comparative example 2>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 17.99kg concentration is 65 mass %, 21.26kg concentration
Sodium alkyl sulfate paste, 29.23kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 21.26kg sodium carbonate,
42.52kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.06kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 11.68 mass %).Further, by the obtained blapharoplast of 94.08 parts by weight, 5 parts by weight zeolites and 0.92 weight
Part magnesium sulfate 7 hydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder
Detergent composition.The average grain diameter of the powder detergent composition is 292 μm, the apparent density of JIS K3362 is 0.35g/
mL.The composition of obtained powder detergent composition is recorded in table 1.
<Comparative example 3>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 27.08kg concentration is 65 mass %, 3.67kg concentration
Sodium alkyl sulfate paste, 30.25kg concentration be No. 2 sodium silicate aqueous solutions of 40 mass %, 22.00kg sodium carbonate,
44.00kg sodium sulphate, the Sodium Polyacrylate saline solution that 1.1kg concentration is 40 mass % and water mixing, having modulated moisture is
The uniform slurry of 50 mass %.Next, this slurry is dried by spray drying, blapharoplast (moisture has been obtained
Content is 8.5 mass %).Further, by the obtained blapharoplast of 90.9 parts by weight, 5 parts by weight zeolites and 4.1 parts by weight sulphur
Sour magnesium heptahydrate is mixed using concrete mixer (manufacture of silver dollar mechanical industry Co., Ltd.), has obtained powder washing
Agent composition.The average grain diameter of the powder detergent composition is 278 μm, the apparent density of JIS K3362 is 0.39g/mL.Institute
The composition of obtained powder detergent composition is recorded in table 1.
<Comparative example 4>
It is 30 mass % by sodium dodecyl benzene sulfonate aqueous solution that 10.15kg concentration is 65 mass %, 11.00kg concentration
Sodium alkyl sulfate paste, 8.8kg polyoxyethylene lauryl ethers (EO=21.0), 30.25kg concentration be No. 2 of 40 mass %
Sodium silicate aqueous solution, 22.00kg sodium carbonate, 44.00kg sodium sulphate, the Sodium Polyacrylate brine that 1.1kg concentration is 40 mass %
Solution and water mixing, have modulated the uniform slurry that moisture is 50 mass %.Next, by this slurry by be spray-dried into
Row drying has obtained blapharoplast (moisture is 8.5 mass %).Further, by the obtained matrix of 90.9 parts by weight
Grain, 5 parts by weight zeolites and 4.1 parts sulfuric acid magnesium heptahydrates use concrete mixer (silver dollar mechanical industry Co., Ltd.
Manufacture) it is mixed, obtain powder detergent composition.The average grain diameter of the powder detergent composition is 285 μm, JIS
The apparent density of K3362 is 0.38g/mL.The composition of obtained powder detergent composition is recorded in table 1.
<Comparative example 5~10>
In comparative example 1, suitably change species or the dosage of each ingredient to become forming described in table 2, so as to make
The dress material powder detergent composition of the present invention is made.
In addition, in comparative example 1~10, detergent combination has been modulated with the manufacturing method including 1~process of above-mentioned operation 3
Object.In a comparative example, the situation for coordinating (B) ingredient is used in process 3.
<Performance evaluation>
For the powder detergent composition obtained in embodiment and comparative example, following evaluation has been carried out.Result is shown
In table 1~3.In following evaluation methods, the powder detergent composition that can obtain meeting the performance of criterion of acceptability is
It is suitable for the dress material powder detergent composition of the hand washing of the present invention.
(1) cleaning force is evaluated
The cleaning force evaluation of (1-1) sebum dirt
<The making of artificial contamination's cloth>
Used artificial contamination's cloth be 6cm × 6cm the thin plain weave blending dyeing painting cloth of cotton polyester (cotton polyester ratio=
35/65, it is bought from valley head shop.Hereinafter referred to as " former cloth ") in a manner of every 1 piece of 100mg intaglio plate coating structure consisting of the following
Into model sebum dirt form.
Model sebum dirt
The model sebum dirt with consisting of is used.
0.44 mass % of lauric acid, 3.15 mass % of myristic acid, 2.35 mass % of pentadecanoic acid, 6.31 matter of palmitic acid
Measure %, 0.44 mass % of Heptadecanoic acide, 1.6 mass % of stearic acid, 7.91 mass % of oleic acid, 13.33 matter of olein
Measure %, 2.22 mass % of palmitic acid hexadecane base ester, 6.66 mass % of squalene
<Clean conditions>
0.2g model sebums dirt, 0.3ml are added in water to 1L hardness for 10 ° of DH (Ca/Mg=6/4, mass ratio)
In cleaning solution (30 DEG C) obtained from powder detergent composition described in glacial acetic acid, 3.5g tables 1~3,5 pieces have been put into manually
Model sebum dirt immune cloth.Next, the thin plain weave blending dyeing painting cloth of the cotton polyester for having put into 6cm × 12cm, and by bath raio tune
It saves to 20.It is cleaned with Terg-O-Tometer under conditions of 180 turns, 3 minutes.
Cleaning force is the original before measuring pollution with colour examining colour-difference-metre (electricity Se Industrial Co., Ltd of Japan system makes, Z-300A)
The reflectivity under 550nm before and after the cleaning of cloth and model sebum dirt immune cloth, acquires clean rate (%) according to the following formula.
It is measured respectively for 5 pieces of pollution cloth and acquires average value.It more than 60% is acceptance line that clean rate, which is, and numerical value is more high the more preferred.
Clean rate (%)=100 × [(the model skin before reflectivity-cleaning of the model sebum dirt immune cloth after cleaning
The reflectivity of fat dirt immune cloth)/(reflectivity of the model sebum dirt immune cloth before reflectivity-cleaning of former cloth)]
(1-2) dirt cleaning force is evaluated
<The modulation that dirt is dyed cloth>
The artificial contamination's cloth used is to use the weaved cotton cloth of 10cm × 10cm (cotton 100% is bought by valley head shop.Hereinafter,
Referred to as " former cloth ".), by the preparation method described in the 0030th~0038 section of Japanese Unexamined Patent Publication 10-204769, modulate dirt
It dyes cloth.
<Cleaning force test operation>
The water that 5L temperature is 30 DEG C and hardness is 10 ° of DH (Ca/Mg=6/4, mass ratio) is put into a diameter of 36cm, depth
It spends in the polypropylene washbowl for being 11L for 13cm, capacity.In water into washbowl, input 17.5g dress materials are washed with powder
Agent composition.It is stirred with hand in a manner that water will not disperse from washbowl, and is allowed to homodisperse or dissolves, modulation
Cleaning solution.1 piece of dirt is dyed cloth and is sewn on the GUNZE YG undershirts of 1 L dimension.By 5, the undershirt is impregnated in above-mentioned cleaning solution
In 30 minutes.After dipping, the dirt being sewn on undershirt is dyed cloth and rubbed each other by washing person, and with hand rubbing 50 times.At this time
Frictional force be using comparative example 1 dress material with powder detergent composition and similarly rubs mutually when dirt dye cloth it is clear
Clean power becomes 45% frictional force.Afterwards, undershirt is put into 5L temperature is 30 DEG C and hardness is 10 ° of DH (Ca/Mg=6/4, quality
Than) water in.Catch the neck portion of 1 undershirt, the operation that is put into 10 times is taken out from water.5 undershirts are carried out respectively
Aforesaid operations.It after hand coil buckling undershirt, from undershirt removes dirt and dyes cloth, after being dried with extruding drying machine, survey
The cleaning force that dirt is dyed cloth is determined.
Cleaning force is the original before measuring pollution with colour examining colour-difference-metre (electricity Se Industrial Co., Ltd of Japan system makes, Z-300A)
The reflectivity under 550nm before and after the cleaning that cloth and dirt are dyed cloth has acquired clean rate (%) according to the following formula.Clean rate is
50% the above are acceptance line, and numerical value is more high the more preferred.
Clean rate (%)=100 × [(reflection that the dirt before reflectivity-cleaning that the dirt after cleaning is dyed cloth is dyed cloth
Rate)/(reflectivity that the dirt before reflectivity-cleaning of former cloth is dyed cloth)]
(2) evaluation of foam duration
Cloth is all taken out after being tested in the cleaning force evaluation of above-mentioned (1-1) sebum dirt and obtains cleaning solution, it will
The 200mL cleaning solutions (30 DEG C of temperature) were injected into 30 seconds in columned glass tube (diameter 5cm, height 90cm), were determined
Foam height (cm) after standing 5 minutes.
Using the foam height 9.3cm of comparative example 1 as standard, the embodiment or comparative example of comparison are calculated according to following formulas
Foam duration relative value.It more than 1.1 is qualified that foam duration relative value, which is, and numerical value is more high the more preferred.
Foam duration relative value=[embodiment of comparison or the foam height (cm) of comparative example]/[1 (standard of comparative example
Composition) foam height (cm)]
(3) evaluation of sense of touch when hand-washing
Sense of touch evaluation during hand washing carries out the sensory evaluation with palm by the following method.It shows the result in table 1~3.
Evaluation method
18g detergent compositions are gently held with one hand, and it is 30 DEG C to be slowly put into 5L temperature in such a state
In water (hardness is 10 ° of DH (Ca/Mg=6/4, mass ratio)).In the state of detergent composition is maintained just into the water it
Afterwards by 1 minutes, by the skilled special evaluation group member of the evaluation of the sense of touch of 5 opponents (30~40 years old, 2 people of women,
3 people of male) according to the sense of touch of following standards evaluation palm, and acquire average value.It more than 0.8 is qualified that average value, which is,.
* criterion
0：The sense of touch of palm feels (hot) hotter than the powder detergent composition of embodiment 8.
1：The sense of touch of palm is felt slightly to generate heat (hot), but feels to be far from the powder detergent combination of embodiment 8
Object heat (hot).
[table 1]
[table 2]
[table 3]
In table, (B) ingredient, the quality % of (D) ingredient are the amounts based on anhydrous conversion.
Claims (32)
1. a kind of dress material powder detergent composition, wherein,
Contain：
Following (A) ingredients, content are more than 10 mass % and below 30 mass %；
(B) ingredient, the value for being converted into the anhydride of magnesium sulfate are more than 1.5 mass % and below 10 mass %；And
(C) ingredient, content are below 8 mass %,
(a1) mass ratio (a1) ingredient/(a2) ingredient of ingredient and (a2) ingredient is more than 0.5 and less than 5, is closed in (A) ingredient
Meter contains more than (a1) ingredient and 60 mass % of (a2) ingredient and below 100 mass %,
(A) ingredient：Surfactant comprising following (a1) ingredients He (a2) ingredient,
(a1) ingredient：Alkylbenzenesulfonate,
(a2) ingredient：Alkyl sulfate with the straight chained alkyl that carbon number is more than 10 and less than 16；
(B) ingredient：The compound of one or more of the hydrate of anhydride and magnesium sulfate selected from magnesium sulfate；
(C) ingredient：Compound selected from one or more of zeolite and tripolyphosphate.
2. dress material powder detergent composition as described in claim 1, wherein,
(B) ingredient is the hydrate of magnesium sulfate.
3. dress material powder detergent composition as claimed in claim 2, wherein,
Contain：Following more than 10 mass % of (A) ingredient and below 30 mass %；(B) ingredient is converted into the anhydride of magnesium sulfate
It is worth for more than 1.5 mass % and below 10 mass %；And below 8 mass % of (C) ingredient, the matter of (a1) ingredient and (a2) ingredient
Amount is more than 0.5 and less than 5 than (a1) ingredient/(a2) ingredient, is added up in (A) ingredient containing (a1) ingredient and (a2) ingredient 60
More than quality % and below 100 mass %,
(A) ingredient：Surfactant comprising following (a1) ingredients He (a2) ingredient,
(a1) ingredient：Alkylbenzenesulfonate,
(a2) ingredient：Alkyl sulfate with the straight chained alkyl that carbon number is more than 10 and less than 16；
(B) ingredient：Magnesium sulfate 7 hydrate；
(C) ingredient：Compound selected from one or more of zeolite and tripolyphosphate.
4. dress material powder detergent composition as claimed in claim 3, wherein,
Magnesium sulfate 7 hydrate is powdery or granular.
5. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
(a1) ingredient is the alkylbenzenesulfonate with the alkyl that carbon number is more than 8 and less than 20.
6. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Alkylbenzenesulfonate as (a1) ingredient is alkali metal salt or alkanolamine.
7. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
(a2) ingredient is that the ratio for the straight chained alkyl that the carbon number in whole alkyl is more than 12 and less than 16 is 50 mass %
More than, and all the ratio for the straight chained alkyl that the carbon number in alkyl is 12 is alkyl sulfate more than 40 mass %.
8. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Alkyl sulfate as (a2) ingredient is alkali metal salt or alkali salt.
9. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
(a1) mass ratio (a1) ingredient/(a2) ingredient of ingredient and (a2) ingredient is more than 0.6 and less than 4.8.
10. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
It is aggregated in (A) ingredient containing more than (a1) ingredient and 80 mass % of (a2) ingredient and below 100 mass %.
11. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Contain more than 12 mass % of (A) ingredient and below 25 mass %.
12. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
As the value for the anhydride for being converted into magnesium sulfate, contain more than 1.5 mass % of (B) ingredient and below 8 mass %.
13. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Contain zeolite and be used as (C) ingredient.
14. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Contain tripolyphosphate and be used as (C) ingredient.
15. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
(C) ingredient is zeolite.
16. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Contain below 7 mass % of (C) ingredient.
17. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
The content of zeolite as (C) ingredient is more than 3 mass % in the composition.
18. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
The content of tripolyphosphate as (C) ingredient is below 3 mass % in the composition.
19. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Be further used as (D) ingredient, in the composition contain selected from alkali carbonate (d1), alkali metal chloride (d2), with
And more than the 40 mass % of compound and below 70 mass % of one or more of alkali metal sulfates (d3).
20. dress material powder detergent composition as claimed in claim 19, wherein,
Contain more than 20 mass % of alkali carbonate (d1) and below 100 mass % in (D) ingredient.
21. dress material powder detergent composition as claimed in claim 19, wherein,
Alkali carbonate (d1) is the compound selected from one or more of sodium carbonate and potassium carbonate.
22. dress material powder detergent composition as claimed in claim 19, wherein,
Alkali metal chloride (d2) is the compound selected from one or more of sodium chloride and potassium chloride.
23. dress material powder detergent composition as claimed in claim 19, wherein,
Alkali metal sulfates (d3) are the compound selected from one or more of potassium sulfate and sodium sulphate.
24. dress material powder detergent composition as claimed in claim 19, wherein,
Contain more than 50 mass % of (D) ingredient and below 65 mass % in the composition.
25. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
According to JIS K3362：The granularity measured with screening machinery by method for sieving that 2008 chapter Section 1 of page 58 the 8th is recorded
The average grain diameter of the dress material powder detergent composition acquired is 150 μm or more and less than 900 μm.
26. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
Pass through JIS K3362：The apparent density that the method that 2008 chapter Section 2 of page 59 the 8th is recorded measures is more than 0.15g/ml
And below 1.2g/ml.
27. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
The dress material is that hand washing washing is used with powder detergent composition.
28. a kind of washing methods of dress material, wherein,
By the dress material powder detergent composition and 1L any one of the claim 1~27 of more than 1g and below 10g
Deutschland hardness is the water mixing of 5 ° of more than DH and 30 ° of below DH, hand-washes dress material with the cleaning solution mixed and washs.
29. the washing methods of dress material as claimed in claim 28, wherein,
The capacity and dress material of cleaning solution containing the dress material powder detergent composition any one of claim 1~27
Mass ratio be calculated as more than 3 and less than 20 with [capacity of cleaning solution]/[quality of dress material], the list of the capacity of the cleaning solution
To rise, the unit of the quality of the dress material is kg for position.
30. the washing methods of the dress material as described in claim 28 or 29, wherein,
The washing methods of the dress material combines the dress material any one of claim 1~27 with powder detergent for one side
Object is sprinkled upon in a part for the dress material in the water for being impregnated in and being used in washing, while being allowed to contact with water, and rubs the side of washing
Method；Dress material any one of claim 1~27 with powder detergent composition with hand is taken in right amount, which is impregnated
In the water used in washing, next stir while being mixed with water so as to modulate cleaning solution, it is clear that dress material is impregnated in this
The method that rubbing washing is carried out in clean liquid.
31. such as dress material powder detergent composition according to any one of claims 1 to 4, wherein,
The dress material powder detergent composition is obtained by including the manufacturing method of following 1~processes of process 3,
Process 1：(A) ingredient and water are mixed, so as to obtain moisture as more than 30 mass % and the slurry of below 70 mass %
Process；
Process 2：The slurry obtained in process 1 is spray-dried, obtains the blapharoplast that moisture is below 10 mass %
Process；
Process 3：The process that the blapharoplast obtained in process 2 and (B) ingredient, (C) ingredient are mixed.
32. dress material powder detergent composition as claimed in claim 19, wherein,
The dress material powder detergent composition is obtained by including the manufacturing method of following processes 1 '~process 3 ',
Process 1 '：(A) ingredient, (D) ingredient and water are mixed, so as to obtain moisture as more than 30 mass % and 70 mass %
The process of following slurry；
Process 2 '：The slurry obtained in process 1 is spray-dried, obtains the blapharoplast that moisture is below 10 mass %
Process；
Process 3 '：The process that the blapharoplast obtained in process 2 and (B) ingredient, (C) ingredient are mixed.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-287040 | 2012-12-28 | ||
| JP2012287040 | 2012-12-28 | ||
| PCT/JP2013/083015 WO2014103690A1 (en) | 2012-12-28 | 2013-12-10 | Washing powder composition for clothes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104919034A CN104919034A (en) | 2015-09-16 |
| CN104919034B true CN104919034B (en) | 2018-05-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380068824.6A Expired - Fee Related CN104919034B (en) | 2012-12-28 | 2013-12-10 | Dress material powder detergent composition |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5700469B2 (en) |
| CN (1) | CN104919034B (en) |
| SG (1) | SG11201504268SA (en) |
| WO (1) | WO2014103690A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6219246B2 (en) * | 2014-04-23 | 2017-10-25 | 花王株式会社 | Powder detergent composition for clothing |
| JP6407682B2 (en) * | 2014-11-27 | 2018-10-17 | 花王株式会社 | Method for producing powder detergent composition for clothing |
| JP6249424B2 (en) * | 2015-06-30 | 2017-12-20 | 花王株式会社 | Powder cleaning composition for clothing |
| JP6242440B2 (en) * | 2015-06-30 | 2017-12-06 | 花王株式会社 | Powder cleaning composition for clothing |
| WO2017002759A1 (en) * | 2015-06-30 | 2017-01-05 | 花王株式会社 | Powder detergent composition for clothing |
| WO2019144372A1 (en) * | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Detergent granules with high anionic surfactant content |
| JP6633123B2 (en) * | 2018-04-24 | 2020-01-22 | 花王株式会社 | Powder detergent composition for clothing |
| JP7422004B2 (en) * | 2020-05-18 | 2024-01-25 | 花王株式会社 | Powder cleaning composition for clothing |
| JP7422003B2 (en) * | 2020-05-18 | 2024-01-25 | 花王株式会社 | Powder cleaning composition for clothing |
| CN117736811B (en) * | 2024-02-21 | 2024-05-10 | 特丝丽化工有限公司 | Washing composition and preparation method thereof |
Citations (8)
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|---|---|---|---|---|
| US5013486A (en) * | 1989-04-28 | 1991-05-07 | Colgate-Palmolive Company | Detergent bar with improved stain removing and antibacterial properties |
| CN1155295A (en) * | 1994-06-17 | 1997-07-23 | 普罗格特-甘布尔公司 | Hand wash laundry compositions |
| CN1182122A (en) * | 1996-06-14 | 1998-05-20 | 普罗格特-甘布尔公司 | Laundry detergent bar containing magnesium sulfate with improved physical properties |
| CN1233274A (en) * | 1996-07-08 | 1999-10-27 | 普罗格特-甘布尔公司 | Hand wash laundry detergent compositions containing a combination of surfactants |
| CN1281496A (en) * | 1997-10-10 | 2001-01-24 | 普罗格特-甘布尔公司 | Detergent composition containing mid-chain branched surfactants and electrolyte for improved performance |
| CN1281498A (en) * | 1997-10-10 | 2001-01-24 | 普罗格特-甘布尔公司 | Surfactant detergent composition containing mid-chain branched surfactants |
| CN101243172A (en) * | 2005-08-19 | 2008-08-13 | 宝洁公司 | A solid laundry detergent composition comprising anionic detersive surfactant and a calcium-augmented technology |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2353800A (en) * | 1999-09-02 | 2001-03-07 | Procter & Gamble | Antibacterial detergent compositions |
| GB2356201A (en) * | 1999-11-13 | 2001-05-16 | Procter & Gamble | Detergent compositions |
| GB2361930A (en) * | 2000-05-05 | 2001-11-07 | Procter & Gamble | Process for making solid cleaning components |
| EP1754780B1 (en) * | 2005-08-19 | 2010-04-21 | The Procter and Gamble Company | A solid laundry detergent composition comprising alkyl benzene sulphonate and a hydratable material |
-
2013
- 2013-11-22 JP JP2013241505A patent/JP5700469B2/en active Active
- 2013-12-10 WO PCT/JP2013/083015 patent/WO2014103690A1/en active Application Filing
- 2013-12-10 SG SG11201504268SA patent/SG11201504268SA/en unknown
- 2013-12-10 CN CN201380068824.6A patent/CN104919034B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5013486A (en) * | 1989-04-28 | 1991-05-07 | Colgate-Palmolive Company | Detergent bar with improved stain removing and antibacterial properties |
| CN1155295A (en) * | 1994-06-17 | 1997-07-23 | 普罗格特-甘布尔公司 | Hand wash laundry compositions |
| CN1182122A (en) * | 1996-06-14 | 1998-05-20 | 普罗格特-甘布尔公司 | Laundry detergent bar containing magnesium sulfate with improved physical properties |
| CN1233274A (en) * | 1996-07-08 | 1999-10-27 | 普罗格特-甘布尔公司 | Hand wash laundry detergent compositions containing a combination of surfactants |
| CN1281496A (en) * | 1997-10-10 | 2001-01-24 | 普罗格特-甘布尔公司 | Detergent composition containing mid-chain branched surfactants and electrolyte for improved performance |
| CN1281498A (en) * | 1997-10-10 | 2001-01-24 | 普罗格特-甘布尔公司 | Surfactant detergent composition containing mid-chain branched surfactants |
| CN101243172A (en) * | 2005-08-19 | 2008-08-13 | 宝洁公司 | A solid laundry detergent composition comprising anionic detersive surfactant and a calcium-augmented technology |
| CN102159692A (en) * | 2008-08-14 | 2011-08-17 | 麦莱琉卡有限公司 | Ultra concentrated liquid laundry detergent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5700469B2 (en) | 2015-04-15 |
| JP2014141641A (en) | 2014-08-07 |
| SG11201504268SA (en) | 2015-07-30 |
| WO2014103690A1 (en) | 2014-07-03 |
| CN104919034A (en) | 2015-09-16 |
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