CN104910817A

CN104910817A - Environment-friendly type composite resin and adhesive and paint based on resin

Info

Publication number: CN104910817A
Application number: CN201510112735.8A
Authority: CN
Inventors: 卢清友; 卢思竹
Original assignee: Chongqing Lierda Science And Technology Development Co Ltd
Current assignee: Chongqing Lierda Science And Technology Development Co Ltd
Priority date: 2014-03-12
Filing date: 2015-03-12
Publication date: 2015-09-16
Also published as: CN113292930A

Abstract

The invention relates to an environment-friendly type composite resin and adhesive and paint based on resin, the environment-friendly type composite resin relates to composite resin processed in composite material production used for matrix reinforcing and glass fiber reinforced plastic as well as an adhesive in building material industry, industrial and mining enterprises and daily life as well as a paint for object surface protection, especially the environment-friendly type composite resin comprises soluble glass, isocyanate and a dual-component composition of its performed polymer, a component A comprises at least soluble glass solution, and has low organic component and inorganic filling/accessory content; a component A comprises at least isocyanate and a performed polymer, and provides a soluble glass polyurethane cooperative combination for enhancing composition bonding intensity and/or composition intensity, and mass ratio of two components is about 1:1. A soluble glass mixture and isocyanate which are mutually effected and the performed polymer are subjected to a subtle reaction to form a complementation interpenetration network structure, so that large bonding intensity and better machinery performance are generated, clunging is strong, solidification time is short, surface is smooth, flame retardation and corrosion inhibition effect are excellent, no halogen is contained, safety and environmental protection performances are generated, cost is low, and production is easy.

Description

A kind of environmental-protecting composite resin and based on the tackiness agent of this resin and coating

Technical field

The present invention relates to a kind of composition that can be used for bonding between object in building materials and industrial and mining enterprises and daily life, matrix is reinforced and matrix material is produced and article surface is protected, especially comprise the cheap two-component composition of water glass, isocyanic ester and performed polymer thereof.

Background technology

The mixture of water glass or water glass and silicon sol is as the inorganic sizing material of one, there is the feature of high temperature resistant, fire-retardant, inhibition, cheapness, environmental protection, but be used as its bonding strength of sizing material of tackiness agent or dip-coating and laminates matrix material and the equal difficulty of water tolerance reaches satisfaction; And usually also can occur that halogen returns frost and strips off because of the migration of small-molecule substance and the Plant ecology effect in siliceous substrates with the coating of its preparation.As cheap environmental protection binding agent, can Sodium Silicofluoride be added in water glass and/or metal oxide is used alone, but due to the limitation of bond effect and water resistance, be difficult to use in metal and metal, metal and nonmetal and nonmetal between require higher occasion.So about the exploration of water glass sizing material modification never rests, due to water glass system true solution, in storage, in water glass component, single silicon of nano-scale and the content of oligomeric silicon itself can reduce gradually, various organic substance and inorganicly fill out adjunct ingredient complexity in modification, physico-chemical property is totally different, select or proportioning improper, the coacervate that not only in exacerbate water glass, the polycondensation of multi-silicate particle becomes can not be hydrolyzed again, in addition the short solidification of some metal and oxide compound thereof in improper component, this blend glue stuff easily in short period of time retrogradation, solidify.In water glass sizing material, add nano level fill out auxiliary material and be conducive to homogenizing of sizing material and rubber strength can be improved improving over-all properties and increasing the stability of sizing material, but cost is higher.And the blend glue stuff bonding force that it forms with isocyanic ester or its polyvalent alcohol performed polymer is weak, the induration mechanical property formed after two component effects is not good yet, is difficult to reach practical intensity.The existing tackiness agent for bonding material of construction, finishing material, door core and panel mostly is polyurethane foam glue, and its positive tensile bond strength requires to be not less than 0.5mPa.Mainly polyester polyol or polyether glycol and polyisocyanates react the base polyurethane prepolymer for use as containing remaining-NCO group formed for it; usually the organic thinner of proper catalyst and about 50% is also added with; the foamed glue thinner of industrial use is all generally methylene dichloride, will add acid or acyl chloride used as stabilizers for increase package stability extends the shelf life toward contact.The general content of domestic commercially available foamed glue-NCO is about 3%--6%, and flexible is good, and bonding strength is higher, advantage easy to use.But foamed glue price is higher, and colloid is inflammable, burning produces dense black smoke release toxic gas, and sizing material can discharge a large amount of methylene dichloride, health risk in using, and acidic component or acyl chloride material deposit potential corrosion risk, and heat-resisting and weathering resistance is bad.Although many enterprises attempt to substitute foamed glue with lower-cost inorganic sizing material or Composite rubber material, but it is weak to fail to solve initial bonding strength all the time in metal and intermetallic and metal and bonding between nonmetal and rigid material, cohesive strength is little, it is long that surface drying does solid work the time, glue-line fragility is large, the technical barrier of the water suction moisture absorption.Unsaturated polyester resin, the epoxy resin etc. such as glass fiber reinforced plastics composite material multiplex greatly 191,196,885 make tackiness agent, have the shortcoming that cost is high, inflammable, and volatile harmful solvent serious environment pollution, health risk a large amount of in resin.And existing quick drying paint is mostly solvent-borne type oil paint, inflammable and not environmentally; Water-borne coatings surface drying do solid work also easily cause corrosion of metal all comparatively slowly and oiliness membrane-forming agent water to change complex process cost high.Chinese patent CN 1993398 B discloses a kind of liquid resin mixture of the hybrid resin for the preparation of mechanical property improvement, it is characterized in that in 100 parts of described liquid mixing resins, containing 10 to 75 parts of vinyl ester and/or vibrin, 2 to 45 parts of unsaturated monomers, 2.5-45 part water glass, 2.5 to 65 parts of polymeric polyisocyanates and/or blocked polyisocyanate, and 5 to 35 parts of organophosphates and/or other softening agent.This patent inventor conducts in-depth research and fruitful exploration the mechanical property improving liquid mixing resin, but due to vinyl ester and/or vibrin larger relative to the amount of water glass, in addition all make initiator with superoxide, make promotor by phosphoric acid ester, cost is higher, although phosphoric acid ester still has fire retardation, because the little flame retardant effect of flame-retardant composition total amount is limited.Because each composition of matrix material exists reciprocal effect, the mechanism of action is complicated, the physicochemical property of material and the addition of each composition not necessarily are proportionate, Given this, inventors performed lot of experiments to workout cost and fire-retardant problem under basic environmental protection and practical prerequisite, result is encouraging, and unexpectedly.

The present invention is directed to above problem, provide one can strengthen water glass sizing material bonding strength, reduce industrial foam glue VOC amount, with low cost, bonding strength is large, the environment-friendly type water glass synergy composition that flame retardant properties is good and tackiness agent, compound resin and the coating prepared by said composition.

The present invention seeks to realize like this:

A kind of environmental-protecting composite resin, comprise water glass component A and polyurethane component B and conventional additives, it is characterized in that, A hydrated glass or modified water glass 90 ~ 100 parts, polyvalent alcohol 0 ~ 10 part, polyvalent alcohol 0 ~ 6 part, Sodium sulfate anhydrous.min(99) 0 ~ 8 part, resin liquid and/or dispersible resin-oatmeal 0 ~ 3 part, organic solvent and/or 0 ~ 6 part, softening agent, tensio-active agent and/or Sodium hexametaphosphate 99 and/or trisodium phosphate and/or tripoly phosphate sodium STPP 0 ~ 3 part, fill out auxiliary material 0 ~ 50 part; What produce containing polyester polyol and/or polyether glycol and polyisocyanates pre-polymerization in B contains the performed polymer holding NCO, its composition and each composition by weight percent are: isocyanic ester and/or blocked isocyanate 30 ~ 97%, performed polymer 0.2% ~ 30%, organic solvent and/or softening agent 0 ~ 50%, additive 0 ~ 0.5%; The weight ratio of A and B: A: B=1: 2 ~ 2: 1, described water glass is sodium silicate and/or Potassium water glass; Described modified water glass is the water glass that with the addition of a small amount of functional material or additive in water glass.

A kind of environmental-protecting composite resin and based on the tackiness agent of this resin and coating, comprise water glass component A and isocyanate component B and conventional additives, it is characterized in that, at least also containing being suitable for the vinyl ester resin preparing water glass base polyurethane prepolymer for use as compound resin in A or B, or vibrin, or acrylic resin, or epoxy resin, or organosilicon acrylic resin, or the resin liquid of styrene-acrylic resin or silica column or to dispersible in resin-oatmeal or their modification derivant one or more combination, its composition and each Composition Weight Parts are: water glass 30 ~ 100 parts, dispersion agent 0 ~ 10 part, fill out auxiliary material 0 ~ 550 part, also containing polyester and/or polyether glycol performed polymer in B, its component comprised and weight percent are: isocyanic ester and/or blocked isocyanate 30 ~ 50%, performed polymer 20% ~ 50%, organic solvent and/or softening agent 20 ~ 50%, catalyzer 0 ~ 0.3%, also resinous liquid and/or dispersible resin-oatmeal 0.3 ~ 15%, organic solvent and/or softening agent 0 ~ 50%, polyvalent alcohol 0 ~ 10%, water glass curing agent 0 ~ 10% in A or B or another component C, when being mixed to form Composite rubber material, components by weight is, A: B or (A+C): B or A: (B+C)=1 ~ 1.5: 1 ~ 1.5.Auxiliary material can not filled out add known in polyisocyanate component containing dispersible resin-oatmeal and/or the organic solvent and/or fluidizer and/or other of active group, or by the known blocked isocyanate more responsive and more stable under normality to water glass and resin and/or dispersible resin-oatmeal, organic solvent and/or fluidizer and/or other is filled out auxiliary material and mixes, the water glass amount added by aforesaid ingredients quantity relative ratio relationship determination combined amount with when using, stir, by the water glass deblocking gradually of high pH value, the adaptive phase needed by simple experiment adjustment.

A kind of environmental-protecting composite resin and based on the tackiness agent of this resin and coating, comprise water glass component A and isocyanate component B and conventional additives, it is characterized in that, described water glass is fast dissolving solid water glass, at least also containing being suitable for the vinyl ester resin preparing water glass base polyurethane prepolymer for use as compound resin in A, or vibrin, or acrylic resin, or epoxy resin, or organosilicon acrylic resin, or the resin liquid of styrene-acrylic resin or silica column or melamine resin, or to dispersible in resin-oatmeal or their modification derivant one or more combination, its composition and each Composition Weight Parts are: solid water glass 15 ~ 50 parts, resin liquid and/or dispersible resin 1 ~ 20 part, organic solvent and/or 0 ~ 40 part, softening agent, polyvalent alcohol 0 ~ 10 part, dispersion agent 0 ~ 10 part, fill out auxiliary material 0 ~ 550 part, solidifying agent 0 ~ 5, also containing polyester and/or polyether glycol performed polymer in B, isocyanic ester and/or blocked isocyanate 30 ~ 50%, performed polymer 20% ~ 50%, organic solvent and/or softening agent 20 ~ 50%, catalyzer 0 ~ 0.5%, the proportioning of A and B is (weight ratio): A: B=1 ~ 1.5: 1 ~ 1.5, A adds water before mixing with B, and amount of water is 0 of solid water glass weight, 4 ~ 1.2 times.Alleged by the present invention, fast dissolving solid water glass also claims instant powdery sodium silicate, its molecular formula Na2OmSiO2nH2O, and formula weight, generally between 280-350, is carry out the courses of processing such as material, filtration, mode transfer, spraying dry to obtain the sodium silicate such as mirabilite method, Method of Soda.

Described a kind of environmental-protecting composite resin, is characterized in that isocyanic ester and/or blocked isocyanate 30 ~ 35% in B, performed polymer 25% ~ 35%, organic solvent 25 ~ 35%, softening agent 0 ~ 10%, catalyzer 0 ~ 0.05%, described isocyanic ester is diphenylmethanediisocyanate (MDI), modification MDI, polymeric MDI/black material, poly methylene poly phenyl poly isocyanate (PAPI), different fluorine diisocyanates (IPDI), tolylene diisocyanate (TDI), hexamethylene-diisocyanate tripolymer (HDT), pentamethylene vulcabond, dicyclohexyl methane diisocyanate, two phenyl diisocyanate, phenyl diisocyanate, and one or more combination in the derivative of described isocyanic ester, the proportioning of A and B is (weight ratio)=1.2: 1.2.Described performed polymer is that polyether glycol and/or polyester polyol and polyisocyanates react obtained, containing NCO 2 ~ 20%, and preferably 8 ~ 18.Polyisocyanates to can be in different fluorine diisocyanates (IPDI), hexamethylene-diisocyanate (HDI), poly methylene poly phenyl poly isocyanate (PAPI), diphenylmethanediisocyanate (MDI), polymeric MDI, tolylene diisocyanate (TDI) and pentamethylene vulcabond, dicyclohexyl methane diisocyanate, two phenyl diisocyanate, phenyl diisocyanate one or more combination, thinner is solvent oil, acetone, benzoyl acetone, phenyl ethyl malonate, dimethyl malonate, propylene carbonate, ethyl acetate, methyl acetate, methylcarbonate, 1,1 ethylene dichloride, trichloromethane, trichlorofluoromethane, hexanaphthene, pentane, toluene, dimethylbenzene, dimethylsilane, vinyl acetate between to for plastic base class polymkeric substance refers to acetate emulsion, ethylene-vinyl acetate copolymer, vinyl acetate-acrylic multipolymer, vinyl acetate-acrylic hydroxyl methacrylate copolymers, re-dispersible glue powder, and vinyl acetate between to for plastic base class polymkeric substance and vinyl ester resin, vibrin, epoxy resin, acrylic resin or emulsion, organosilicon acrylic resin or emulsion, styrene-acrylic resin or emulsion, aldehyde ketone resin, terpolycyantoamino-formaldehyde resin, urea-formaldehyde resin, Synolac and containing thiazolinyl, hydroxyl, carboxyl and/or other band active hydrogen can with one or more combination in other active substance of-NCO group generation crosslinking reaction, described resin liquid or resin-oatmeal also comprise ACRYLIC EMULSION, organosilicon crylic acid latex, benzene emulsion, vinylchlorid-vinylidene chloride emulsion copolymer, Synolac, aldehyde ketone resin, PVC paste resin, described thinner and/or fluidizer are be one or more combination in liquid alkane, naphthenic hydrocarbon, aromatic hydrocarbon, solvent oil, whiteruss, clorafin, vinylbenzene, acrylate, ethyl acetate, phthalic ester, triethylene glycol diacetate, butyl acetic ester, methyl-monosilane, turps, vegetables oil, epoxidized vegetable oil under the normal temperature being suitable for making compound resin, described polyvalent alcohol is ethylene glycol, propylene glycol, butyleneglycol, glycol ether, neopentyl glycol, alkanediol, cyclohexanedimethanol, glycerol, triglycol, dipropylene glycol, tetramethylolmethane, D---mannitol, D---minashi sugar alcohol, Xylitol, TriMethylolPropane(TMP), 1,2,6---one or more the combination in hexanetriol, tetramethylol methane and derivative and low-molecular-weight polyester polyol and/or polyether glycol, described dispersion agent is one or more the combination in tensio-active agent, Sodium hexametaphosphate 99, trisodium phosphate, tripoly phosphate sodium STPP, described filler is one or more the combination in breeze, metal powder or metal oxide powder, fortifying fibre, expansible black lead, described auxiliary material is one or more the combination in tackifier, viscosity-depression agent, stablizer, defoamer, flow agent, pigment, described additive is one or more the combination in coupling agent, antioxidant, UV light absorber, sanitas, rust-preventive agent, fire retardant, stopper, encapsulant, water glass curing agent, anti-skinning agent, brightening agent, weight after the adding water of fast dissolving solid water glass can be equivalent to spray-dried become solid water glass before the amount of primary liquid water glass, that is solid water glass adds the water lost in drying process solid water glass is become liquid soluble glass again.

Described a kind of environmental-protecting composite resin and based on the tackiness agent of this resin and coating, it is characterized in that each Composition Weight Parts of A is: liquid soluble glass 60 ~ 85 parts, or solid water glass 20 ~ 45 parts, resin liquid and/or dispersible resin 1.5 ~ 15 parts, organic solvent and/or fluidizer 3 ~ 30 parts, ethylene glycol and/or glycerol 3 ~ 8 parts, tensio-active agent and/or Sodium hexametaphosphate 99 and/or trisodium phosphate and/or tripoly phosphate sodium STPP 0.5 ~ 8 part, fill out auxiliary material 0 ~ 20 part; Base polyurethane prepolymer for use as in B: isocyanic ester and/or blocked isocyanate: thinner and/or viscosity-depression agent=1: 1: 1, softening agent 1.5 ~ 10%, catalyzer is 0.

Further, described a kind of environmental-protecting composite resin, it is characterized in that in A, each Composition Weight Parts is: liquid soluble glass 65 ~ 85 parts or solid water glass 30 ~ 45 parts, resin liquid and/or re-dispersible glue powder 3 ~ 10 parts, organic solvent and/or phosphoric acid ester 3 ~ 10 parts, ethylene glycol 0 ~ 2 part, glycerol 4 ~ 6 parts, 0 ~ 5 part, tensio-active agent, trisodium phosphate and/or tripoly phosphate sodium STPP 1 ~ 3 part, Sodium sulfate anhydrous.min(99) 3 ~ 16 parts, talcum powder and/or sericite and/or silicon powder 0 ~ 16 part, antiaging agent and/or other additive 0 ~ 3 part; B is containing-NCO 10 ~ 20%.

Further again, described a kind of environmental protection composite adhesive and coating, it is characterized in that A composition and each Composition Weight Parts are: liquid soluble glass 75 ~ 85 parts or solid water glass 37 ~ 43 parts, unsaturated polyester resin and/or re-dispersible glue powder 3 ~ 10 parts, organic solvent and/or fluidizer 3 ~ 10 parts, polyvalent alcohol 5 ~ 7 parts, 0 ~ 5 part, tensio-active agent, tripoly phosphate sodium STPP 1 ~ 3 part, filler 15 ~ 150 parts, additive 0 ~ 10 part.

A kind of environmental-protecting composite resin and based on the tackiness agent of this resin and coating, comprise water glass component A and blocked isocyanate B component and conventional additives, it is characterized in that, at least also containing being suitable for the vinyl ester resin preparing water glass urethane compound resin in B, or vibrin, or acrylic resin, or epoxy resin, or organosilicon acrylic resin, or the resin liquid of styrene-acrylic resin or silica column or to dispersible in resin-oatmeal or their modification derivant one or more combination, in A, each Composition Weight Parts is: water glass 30 ~ 50 parts or solid water glass 15 ~ 25 parts, glycerol 5 ~ 7 parts, 0.3 ~ 5 part, tensio-active agent, tripoly phosphate sodium STPP 1 ~ 5 part, Sodium sulfate anhydrous.min(99) 5 ~ 8 parts, talcum powder and/or sericite in powder and/or silicon powder 5 ~ 30 parts, silica powder and/or other be suitable for coordinating with water glass fill out auxiliary material 0 ~ 150 part, expansible black lead 0 ~ 6 part, base polyurethane prepolymer for use as in B: methylene dichloride: solvent oil and/or methylene dichloride and/or phosphoric acid ester and/or propylene carbonate: resin liquid and/or re-dispersible glue powder: blocked isocyanate=1: 0.5: 0.5 ~ 0.8: 0.2 ~ 0.3: 1, the proportioning of A and B is: A: B=1: 1 ~ 1.3.

Described a kind of compound resin and based on the tackiness agent of this resin and coating, it is characterized in that, described water glass is one or more combination or sodium silicate and Potassium water glass and/or lithium silicate and/or silicon sol and/or organosilyl mixture in sodium silicate, Potassium water glass, lithium silicate; Described blocked isocyanate be to alkaline environment sensitivity can the blocked isocyanate of water glass deblocking and/or low temperature modification blocked isocyanate; The described resin-oatmeal that dispersibles is re-dispersible glue powder; Described organic solvent and/or softening agent be alkyl silane, phthalic ester, vegetables oil, solvent oil, methylene dichloride, phosphoric acid ester or phosphorous acid ester and/or and/or propylene carbonate in one or more combination.

Described re-dispersible glue powder is vinyl acetate and ethylene copolymer rubber powder, ethene and vinylchlorid and moon silicic acid vinyl acetate terpolymer rubber powder, vinyl acetate and ethene and higher aliphatic vinyl acetate terpolymer rubber powder, vinyl acetate and higher aliphatic vinyl acetate copolymerization rubber powder, acrylate and styrene copolymerized rubber powder, vinyl acetate and acrylate and higher aliphatic vinyl acetate terpolymer rubber powder, vinyl acetate homopolymerization rubber powder, one or more combination in vinylbenzene and butadiene copolymer rubber powder, described phthalic ester can be dioctyl phthalate (DOP), dibutyl phthalate, Dinonylphthalate, didecyl phthalate, different 11 esters of phthalic acid two, described phosphoric acid ester or phosphorous acid ester can be tris(chloroethyl)phosphate, tributyl phosphate, trimethyl phosphite 99, triethyl phosphate, tributyl phosphate (TBP), trioctyl phosphate, triphenylphosphate (TPP), Tritolyl Phosphate (TTP), described vegetables oil can be tung oil, soybean oil, sunflower seed oil, Viscotrol C, described acrylate is methyl acrylate, ethyl propenoate, butyl acrylate etc., organic solvent and/or softening agent can also be one or more combinations in Octyl adipate, benzoyl acetone, phenyl ethyl malonate, dimethyl malonate, propylene carbonate, ethylene dichloride, trichloromethane, trichlorofluoromethane, hexanaphthene, pentane, toluene, dimethylbenzene, dimethylsilane, glycidyl ether, solvent oil can be 100 ~ No. 200 solvent oils, described breeze is one or more the combination in mica powder, calcium powder, light burnt powder, Sodium sulfate anhydrous.min(99), kaolin, wilkinite, perlite powder, silica powder talcum powder, described metal powder or metal oxide powder are one or more the combination in copper powder, alloy powder, titanium dioxide, lime powder, aluminum oxide, zinc oxide, magnesium oxide, ferric oxide.One or more combination, particularly Sodium sulfate anhydrous.min(99) in the preferred mica powder of described breeze, Sodium sulfate anhydrous.min(99), silica powder, talcum powder and sericite and/or talcous combination; Dispersion agent preferred surfactant and/or tripoly phosphate sodium STPP; Tensio-active agent can be Sodium dodecylbenzene sulfonate and/or AMONYL 380LC and/or OP-10 and/or TX-10.

Described a kind of environmental-protecting composite resin and based on the tackiness agent of this resin and coating method, is characterized in that comprising following steps:

A group

1., by resin liquid and/or dispersible resin and mix with organic solvent and/or softening agent, stir, add polyvalent alcohol, after stirring or separately packaging or with fill out auxiliary material and mix rear independent packaging; Or continuation following steps;

2. add part or all of liquid soluble glass to above-mentioned adding in the mixture of polyvalent alcohol, under stirring, add tensio-active agent and/or sodium phosphate class dispersion agent, supply whole water glass in formula;

3. stir under slowly add Sodium sulfate anhydrous.min(99) and other fill out auxiliary material or stir under directly to adding Sodium sulfate anhydrous.min(99) in water glass solution and/or filling out auxiliary material and additive;

4. stirs under normal temperature or the temperature that adapts with formula material and composition stability after the mixing of above-mentioned sizing material or strong stirring, grinding until homogenize, finally to sieve or directly blowing barrelling seals;

5. add solid water glass, directly after step 1, add Sodium sulfate anhydrous.min(99), stir, then add other and fill out auxiliary material and solid water glass, stir, encapsulation; Always plant 0.4 ~ 1.2 times by compound before using add water and enter step 4; The component deposited separately mixes with the water glass comprising other composition, enters step 4.

B group

After isocyanic ester and polyester polyol and/or polyether glycol react and reach terminal, cool to lower than after 50 DEG C, thinner is added in protection atmosphere with under stirring, isocyanic ester and/or blocked isocyanate, fluidizer is added while stirring at lower than 40 DEG C, abundant mixing, nitrogen replacement barrelling seals; Or at lower than 40 DEG C, base polyurethane prepolymer for use as 25 ~ 50%, thinner 25 ~ 50 parts, softening agent and/or viscosity-depression agent 0 ~ 10% are mixed, add 30 ~ 50% isocyanic ester or black material under nitrogen protection, or directly the foamed glue containing performed polymer 30 ~ 50% is mixed by 0.5 ~ 1: 0.5 ~ 1 with black material and/or blocked isocyanate, then add softening agent and/or viscosity-depression agent 0 ~ 10%; And/or add resin liquid again and/or dispersible resin-oatmeal 0.3 ~ 15%, organic solvent and/or softening agent or softening agent 0 ~ 50%, polyvalent alcohol 0 ~ 10%, water glass curing agent 0 ~ 10%, both stir can.

A kind of with hardwood chip and/or wood chip and/or waste and old fibre as main raw material, by its water content control within 15%, through the process of defibrator process solution fibre or directly utilize two-component spray apparatus evenly to add total amount of material 10-50% the present invention with the environment protection type composite resin of A: B1-1.5 mixing or invention adhesives, insert mould or mat formation shaping after through hot pressing or cold pier or enter continuous flat press compression moulding.

Additive-package of the present invention contains component A total amount 0.5 ~ 5% coupling agent as titanate coupling agent, silane coupling agent.

In the present invention, organic sizing material organic rubber cement that especially re-dispersible glue powder and organic solvent and/or fluidizer, polyvalent alcohol fully act on the homogeneous dispersion of rear formation adds polyvalent alcohol, water glass, tripoly phosphate sodium STPP, Sodium sulfate anhydrous.min(99) and other filler again, can the synergistic effect of fortified compositions further, test finds to make the cohesive strength of many Composite rubber material larger.Composite rubber material system compound resin and based on the tackiness agent of this resin and coating general name.The formula had in the present invention was both applicable to environment-friendly resin, was also applicable to tackiness agent and coating, can be general.

For tackiness agent, in formula appropriate add solid packing especially particulate powder obviously can increase bonding strength, improve thixotropy, strengthen rigidity and the hardness of weathering resistance and colloid, but add too much, such as more than Composite rubber material 100%, most occasion affects applying glue, be not easy to big area coating, bonding strength also may be caused to reduce, mechanical property becomes bad; Can not add for the compound resin making glass fiber reinforced plastics composite material or lack filled, being beneficial to the infiltration of compound resin liquid, permeating and paste.Certainly need the occasion of strengthening material mechanical property and weather resistance, the solid packing of compound resin 2.5 ~ 10% can be added.For coating, invention adhesive and compound resin formula directly can be used according to applicable object and occasion, but in order to make performance and effect is better or cost is lower, auxiliary material filled out by can conveniently fill a prescription additives such as mixing or add appropriate coupling agent, anti UV agent, oxidation inhibitor and antisettling agent, thinner, flow agent, defoamer, solid powder, pigment etc., and can adjust to 1: 0.5-1 by A: B.

Aqueous water glass and metal oxide filler particularly part resin and/or fluidizer and/or organic solvent mix after due to organic ester under the short solidification of metal oxide and alkaline environment saponification, the organic acid produced slowly can cause the dehydration of water glass, assemble and solidification, resin liquid or resin-oatmeal, strong solvent/softening agent and polyvalent alcohol is added in isocyanate component, may react and retrogradation gradually, make much to fill a prescription the normal temperature quality guaranteed period only about one or two month, even shorter.In this case preferably do not add catalyzer, can by isocyanic ester and blocked isocyanate used in combination, adopt blocked isocyanate preservation effect best.Certainly, in water glass mixed solution, the stablizer such as sodium acrylate or inert diluent may have certain effect to prolongation storage period; Adopt solid sodium silicate, mix mixture thoroughly encapsulation, facing the used time adds water, then greatly extend the shelf life.

Compound resin of the present invention can be used for glass reinforced plastic, and especially fireproof glass steel work or other matrix material are produced; Tackiness agent can be used for antitheft door, fire prevention every core and the bonding of door body, furniture and board materials production, ceramic tile, stone material, lagging material and other building and ornament materials are bonding, body of wall, stone carving, mine, building site, crag etc. are squeegeeed, leak stopping and reinforcing, equipment is bonding, fixing with workpiece, the bonding of fire control equipment and facility and maintenance; Coating can be used for the antiseptic fire-retardation protection of building and equipment, the especially protection of bonding plane.

Be suitable for when the present invention is for making matrix material using middle alkali, especially alkali-free or alkali proof fiber as strongthener.

Positively effect of the present invention is:

1. due to resin liquid or resin-oatmeal proportion little, and the water glass proportion of cheapness is large, and production technique is simple in addition, and comparatively prior art can reduce production cost greatly, and the dispensing viscosity comparing to resin content in addition high more easily adjusts, more not easily conjunctiva peeling.

2., owing to instead of considerable part foamed glue with water glass thus the remarkable consumption reducing organic solvent, use no or little halogenide in addition, phosphoric acid ester makes fire retardant, decrease the pollution to environment and health hazard.

3. the present invention reduces resin and fluidizer consumption while raising water glass proportion, and water glass interts dehydration in configuration process and formed and be uniformly distributed in a large number and the aerosil particles of setting wherein constructing polyureas-resin compounded, thus has excellent flame retardant properties.

4. the present invention also utilizes the dispersion and emulsion of water glass and corrosion inhibitive function and base catalysis and helps deblocking effect, can make isocyanic ester and performed polymer dispersed, not having to make polyureas and interspersed crosslinking reaction complete under the induction of present composition performed polymer under conventional catalyst under normal temperature, can also contribute to blocked isocyanate deblocking; Due to the interaction of resin, performed polymer and various composition in composition and the synergistic effect of many compositions, make composition bonding strength unexpected, the glass fiber reinforced plastics composite material that compound resin makes also is tempered toughness with gentleness, and initial bonding strength is strong, time of doing solid work is short, any surface finish, waterproof.

5. due to technical scheme be on the basis of repetition test with meet basic training with, make every effort to low cost and flame-proof environmental protection is progressively formed under choice direction, there is stronger economy and practicality.

6. in the present invention, solid water glass scheme greatly can extend storage period thus improve its economy and practicality further.

Polyvalent alcohol is containing multiple hydrophilic hydroxy group, be scattered in water glass the charged corpuscle that can wrap up or isolate the ionization such as sodium sulfate, reduce ionogen to colloid equilibrium structural damage, add the solublization Buddhist monk uncomprehending reason of polyvalent alcohol to sodium sulfate etc., appropriate low molecular polylol and Sodium sulfate anhydrous.min(99) and water glass etc. act on the composition formed, objectively more stable, and obviously can improve the thixotropy of sizing material, adhesivity and toughness; Because sodium sulfate may be dissolved in water glass, obtained glue also has translucent effect to be easy to toning.In two-pack Composite rubber material, also can be cross-linked with the NCO end group in another component as the hydroxyl in the polyvalent alcohol of soft section, the interspersed structure that waterglass mixture and performed polymer are formed more firmly thus produce more excellent mechanical property and safety, environmental protection; And add in water glass/silicon sol, Sodium sulfate anhydrous.min(99), polyhydric alcohol composition again with organic rubber cement of halon and softening agent and the homogeneous dispersion of the abundant swelling rear formation of appropriate organic sizing material, the synergistic effect that can produce under the interaction of fortified compositions further, makes the cohesive strength of Composite rubber material larger.Owing to making major ingredient with water glass in sizing material, containing or only thus cost is low containing a small amount of volatile organic solvent, fire-retardant, inhibition, environmental protection, also have good heat-resisting weather resistance.Owing to very limited several industrial chemicals or work in-process can be obtained through simple agitation, be easy to produce.

Embodiment

During the embodiment of the present invention is raw materials used, base polyurethane prepolymer for use as and foamed glue are that Ba Nan Ju Cai adhensive factory, Chongqing produces, with poly methylene poly phenyl poly isocyanate (PAPI), polyether glycol and polyester polyol be raw material obtain, wherein polyether glycol molecular weight 5000, polyester polyol molecule amount 1800 ~ 2000, both weight ratios are 1 ~ 2: 1, in performed polymer-and NCO group content about 8% ~ 13%.Foamed glue is the product after performed polymer dchloromethane, and methylene dichloride accounts for 40 ~ 50%, is added with amine or tin class catalyzer 0.05 ~ 0.1%.Isocyanic ester is that the black material produced of Shenzhen Kuai Yixiu Electronic Science and Technology Co., Ltd. and ten thousand China produce polymeric MDIs (major ingredient is diphenylmethanediisocyanate and isomer thereof and oligopolymer, NCO28 ~ 32%), modification MDI (8221, NCO 31.7-32.7%) and Bayer Bitterfeld GmbH product isophorone diisocyanate (IPDI, NCO 37.5 ~ 37.8%); Blocked isocyanate is the polymeric MDI that etheric acid-ethylene glycol-methyl acrylate is closed, and prepares sample with reference to CN200580026701.1 and Hungarian patent application P0401799 and known method.Water glass, modulus 2.6 ~ 2.9, East China, Chongqing Chemical Co., Ltd. produces; Solid water glass full name fast dissolving solid water glass also claims instant powdery sodium silicate, and Yongqing County, Hebei Jing Yong Chemical Co., Ltd. produces (in embodiment, not bright Potassium water glass is sodium silicate).Epoxy resin is E-44 (6101), and Feicheng De Yuan Chemical Co., Ltd. produced.Polyamide resin (650 low molecule), Zhao Tan chemical plant, Xiangtan, Hunan Province city produces.Tripoly phosphate sodium STPP is industrial goods, and Chongqing Chuan Dong Chemical Co., Ltd. produces.Glycerol, methylene dichloride, epoxy soybean oil, Viscotrol C, dimethyl silicone oil are chemical reagent.Re-dispersible glue powder (in embodiment the equal vinyl acetate of unreceipted concrete composition and ethylene copolymer rubber powder), Vinylite, 196,885,191 resins (Jiangyin Taurus), solvent oil, Sodium sulfate anhydrous.min(99), talcum powder, phthalic ester, phosphoric acid ester, epoxy soybean oil, acrylic resin/emulsion, silica powder (800-1250 order), expansible black lead (80 ~ 100 order) and other industrial chemicals be purchased from Chongqing Shi Pingqiao Chemical market.Test cohesive strength screw used is round end, and diameter 12mm, the long 87mm of screw, be vertically bonded on the pine bar (25mm*30mm) of the surface smoothing scribbling bi-component glue of the present invention after ailhead end face flat file file finishing.After gluing, Air drying was tested after 24 ~ 48 hours, counterweight is served as with the mineral water bottle filling tap water, 580 grams every bottle, bottleneck fastens nylon ferrule, during many bottles of suspensions, running through multiple lasso system with a rope lies on screw rod, keep screw rod vertically downward, make mineral water bottle liftoff, increase progressively at every turn, drop until adhesive linkage destroys, record suspended weights; The row again that do not drop equal 30 seconds is raised the price.3 ~ 5 repetitions are established in each process, and rejecting abnormalities sample, averages.Bonding strength calculates with bound weight in average, only for referencial use.

In following comparative example and embodiment except indicating especially, for component A and the black material of 1 weight part expect to mix sample preparation with weight 1: 1 with the B that 2 weight part foamed glues (1 parts by weight of polyurethane performed polymer 1 weight parts Methylene chloride thinner) are prepared after record, surface drying time 20 ~ 60 minutes, normal temperature measures for 24 ~ 36 hours, often organizes sample and establishes 3-5 repetition (being weight part).Although nail in majority examination and occur that batten cortex is torn, fail to measure net result, in addition the residing batten position of examination nail is also because wood development process its structural strengths different from suberification degree difference to some extent, but due to examination nail stochastic distribution on batten, there is again multiple repetition, be aided with trend to observe, bonding strength and the performance of different colloid and formula should be able to be reflected from an aspect, the wetting property of this and Composite resin adhesive, to have some relations with adhesives bonding force, glue seepage force, colloid mechanical property.

Compound resin hand is stuck with paste glass reinforced plastic and is made

Prepared by compound resin:

A group: can be 100% sodium silicate or sodium silicate and Potassium water glass or/or lithium silicate and/or silicon sol and/or organosilyl mixture.Also can be following one and plurality of raw materials formulated:

1., by re-dispersible glue powder and/or resin and organic solvent and/or softening agent mix and blend, add polyvalent alcohol, stir a moment

2. in said mixture, add part or all of liquid soluble glass, under stirring, add tensio-active agent and/or sodium phosphate class dispersion agent, supply whole water glass in formula

3. stir under slowly add Sodium sulfate anhydrous.min(99) and other fill out auxiliary material or stir under directly to adding Sodium sulfate anhydrous.min(99) in water glass solution and/or filling out auxiliary material and additive

4. after the mixing of above-mentioned sizing material, under normal temperature or the temperature that adapts with formula material and composition stability, agitation grinding, until homogenize, finally sieves or directly blowing barrelling sealing;

5. add solid water glass, directly after step 1, add Sodium sulfate anhydrous.min(99), stir, then add other and fill out auxiliary material and solid water glass, stir, encapsulation; Always plant 0.4 ~ 1.2 times by compound before using add water and stir;

B component

After excessive polyisocyanates and polyester polyol and/or polyether glycol react and reach terminal, cool to lower than after 50 ~ 60 DEG C, thinner is added in protection atmosphere with under stirring, isocyanic ester and/or blocked isocyanate, fluidizer or catalyzer is added in stirring, abundant mixing, nitrogen replacement barrelling seals; Or by base polyurethane prepolymer for use as 25 ~ 50%, thinner 25 ~ 50 parts mixing at lower than 40 DEG C, add 25 ~ 50% isocyanic ester or black material under nitrogen protection, or directly foamed glue and the black material containing performed polymer 30 ~ 50% is mixed by 1: 0.5 ~ 1 and both can.

Certainly, also above step can be not limited to, take other order of addition(of ingredients) and stir with grinding technics good, result of use can be reached, just the step of the present invention's introduction is to part formulation, such as re-dispersible glue powder and phthalic ester, methyl-monosilane, Viscotrol C, methylene dichloride etc., better effects if.The ammonia ester level material composition of some not hydroxyl, active hydrogen and other active group, as phthalic ester etc. can add in B component, if isocyanic ester NCO closes completely and stablizes under normality in B, then can add more multicomponent, to water content also not so strict limiting.During use, A and B is mixed after or spraying, roller coating, blade coating, brushing, and according to fill a prescription be finished in limited time.

Raw material: A, B compound resin liquid, facing the used time mixes and stirs; Glass-fiber-fabric, selects the thick alkali-free glass fiber cloth of 0.24mm.

Following examples, adjust the even rear elder generation that is mixed to smear bottoming on mould by 1: 1 A and B, and paving layer of glass fiber fabric, repaves layer of glass fiber fabric after being coated with compound resin, then be coated with compound resin until 3 ~ 4 layers.Except indivedual, solidification in most 45 minutes, molding cutting edge finishing after 60 minutes.Examination is burnt: hand-held sample, laterally or longitudinally observes with lighter constant ignition 10 seconds turning off stove under its corner.Intensity bigness scale: with three layers of alkali-resisting glass fiber cloth, one side pattern, pastes from level to level, another side strikes off resin more than needed, the demoulding in 2 hours when making, and about 0.9mm is thick, be trimmed to wide 35mm, long 50mm, after 24 hours, light faces down, and surperficial maintenance level is unsettled, neatly clamps one end, apart from bare terminal end 10mm place extension mineral water bottle, 580 grams every bottle, have a down dip with 30 seconds specimen surfaces and be no more than miter angle and be limited, merely compare rigidity to hang bottle amount, and towards light face with relative hair side doubling to compare toughness, only for referencial use.The percentage composition of all comparative examples and embodiment, number, ratio are not particularly illustrated and are weight relationships below, and do not list B component, its B component is that 2 parts of foamed glues add a polymeric MDI, and A: B is 1: 1.

Comparative example 1

191 resin 50 promotor 1.5 solidifying agent 1.5

Namely igniting fires and produces a large amount of black smoke; 3 bottles≤hang bottle amount≤3.5 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is slight.Comparative example 2

191 resin 50 promotor 1.5 ~ 3 phosphoric acid ester (TCEP) 5 ~ 10 solidifying agent 1.5 ~ 4.5

When phosphate flame retardant add-on is resin 10%, light a fire flammable; 2 bottles≤hang bottle amount≤2.5 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is slight; When add-on is resin 20%, glass reinforced plastic is significantly clamminess deliquescing, and performance seriously becomes bad, still incendivity of lighting a fire, and produces bad smell and dense black smoke; 1 bottle≤hang bottle amount < 1.5 bottles.

Comparative example 3

Water glass 50g polyisocyanates 50g

Within 24 hours, have no solidification, within 3 days, be coated with scratch layers afterwards solid, the easy layering of glass, softer, lack rigidity, almost put and do not fire; 1 bottle≤hang bottle amount < 1.5 bottles; Phototropic face doubling, has heavier folding line, to hair side doubling, has obvious folding line.

Comparative example 4

Water glass 40 foamed glue 40

Heating, solidification in several minutes, intensity is poor.Almost put and do not fire.

Comparative example 5 (with reference to CN993398B, filling a prescription close to embodiment 25)

191 resin 60 benzoyl peroxide 1.2 polymeric MDI 18 water glass 16 triphenylphosphate fire retardants 6

Reaction is fast, within about five minutes, solidifies; Flammable; 2 bottles≤hang bottle amount≤2.5 bottle; Phototropic face doubling and to hair side doubling, folding line is all slight.

Embodiment 1

A: water glass 75 191 resin (containing 3% promotor) 4 Viscotrol C 5 glycerol 5 tripoly phosphate sodium STPP 1 gets 50g

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=1: get 50g at 0.5: 0.5: 1

Surface drying in 30 minutes; Longitudinal constant ignition, put out in fiery 20 seconds; 3.5 bottles of < hang bottle amount≤4 bottle; Phototropic face doubling, has folding line, and to hair side doubling, folding line is heavier.

Embodiment 2

A: 30g got by water glass 75 5 phosphoric acid ester (TCEP) 2 Sodium dodecylbenzene sulfonate 0.6 Sodium sulfate anhydrous.min(99) 8

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: 196 portions of resin phosphoric acid ester (TCEP): blocked polyisocyanates=1: get 35g at 0.5: 0.5: 0.15: 0.15: 1

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 4 seconds; 7 bottles of < hang bottle amount≤7.5 bottle; Phototropic face doubling, has folding line, and to hair side doubling, folding line is heavier.

Embodiment 3

A: solid water glass mixture: re-dispersible glue powder 4 Viscotrol C 4 glycerol 5 sodium lauryl sulphate 1.5 tripoly phosphate sodium STPP 1 Sodium sulfate anhydrous.min(99) 8 reinforcing body water glass 40, stirs, pack;

Get 20g, add water 12g, stirs

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=1: get 30g at 0.5: 0.5: 1

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 5 seconds; 5.5 bottles of < hang bottle amount≤6 bottle; Phototropic face doubling, has folding line, and to hair side doubling, folding line is lighter.

Embodiment 4

A: 10g got by the low sodium silicon sol 50 of water glass 50

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=1: get 10g at 0.5: 0.5: 1

Surface drying in 30 minutes; Longitudinal constant ignition, put out in fiery 13 seconds; 4.5 bottles of < hang bottle amount≤5 bottle; Phototropic face doubling slightly folding line, to hair side doubling, folding line is slightly heavy.

Embodiment 5

A: 28.2g B got by water glass 75 191 resin 5: 31.8g got by performed polymer 10 methylene dichloride 10 polymeric MDI 10 triethyl phosphate 1.8

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 8 seconds; 3 bottles of < hang bottle amount≤3.5 bottle; Phototropic face doubling, has obvious folding line, to hair side doubling, has folding line.

Embodiment 6

A: water glass 30g B: foamed glue 2 black material 1 30g (cohesive strength 0.8mpa ailhead band portion glue)

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 1 second; 2.5 bottles of < hang bottle amount≤3.5 bottle, and phototropic face doubling, has heavier folding line, to hair side doubling, has obvious folding line.

Embodiment 7

A: 30g B got by water glass: performed polymer 1 methylene dichloride 1 polymeric MDI 1 blocked isocyanate 1 rubber powder 0.1 gets 35g

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 1 second; 4 bottles of < hang bottle amount≤4.5 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is lighter.

Embodiment 8

A: 30g B got by water glass 90 re-dispersible glue powder 2.5 Viscotrol C 3 tripoly phosphate sodium STPP 2 glycerol 5 Sodium sulfate anhydrous.min(99) 8: performed polymer 1 methylene dichloride 1 polymeric MDI 1 gets 30g

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds; 5 bottles of < hang bottle amount≤6 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is lighter.

Embodiment 9

A: water glass 90 re-dispersible glue powder 1.5 Viscotrol C 3 tripoly phosphate sodium STPP 3 gets 30g B: performed polymer 1 methylene dichloride 1 polymeric MDI 1 gets 30g

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 2 seconds; 3.5 bottles of < hang bottle amount≤4 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is lighter.

Embodiment 10

A: water glass 90 re-dispersible glue powder 1 Viscotrol C 3 tripoly phosphate sodium STPP 3 glycerol 6 gets 30g B: performed polymer 1 methylene dichloride 1 polymeric MDI 1 gets 30g

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 1 second; 3 bottles of < hang bottle amount≤3.5 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is lighter.

Embodiment 11

A: water glass 90 re-dispersible glue powder 0.5 30g B: performed polymer 1 methylene dichloride 1 polymeric MDI 1 gets 30g

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds; 4 bottles of < hang bottle amount≤4.5 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is lighter.

The embodiment of the following environment protection type composite resin of the present invention can solve described technical problem equally, reaches expection technique effect.

A: water glass (modulus 2.5 ~ 2.9) 99% silane coupling agent 1%

B: the black material 25 A: B=1: 1 of catalyst-free performed polymer 5

15 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds; 3 bottles of < hang bottle amount≤4 bottle; Phototropic face doubling, has obvious folding line, and to hair side doubling, folding line is lighter.

A: water glass (modulus 2.5 ~ 2.9)

B: the black material 25 A: B=1: 1 of catalyst-free performed polymer 0.75

A: water glass (modulus 2.5 ~ 2.9)

B: the black material 100 A: B=1: 1 of catalyst-free performed polymer 0.3

15 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds, temper toughness with gentleness.

A: water glass (modulus 3.0 ~ 3.4) melamine resin 10

B: catalyst-free performed polymer 1 black material 1 methylcarbonate 0.6 methyl acetate 0.05 phosphoesterase 30 .02 A: B=1: 1

65 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds, temper toughness with gentleness.

A; Water glass (modulus 3.0 ~ 3.4) 80 benzene emulsion 8 melamine resin 5

18 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds, temper toughness with gentleness.

A: water glass (modulus 3.0 ~ 3.4) 80 benzene emulsion 4 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 4

80 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds, temper toughness with gentleness.

A: water glass (modulus 3.0 ~ 3.4) 80 fluorine carbon emulsion 6 melamine resin 20 emulsifying agent is appropriate

18 minutes surface dryings; Be difficult to light, longitudinal constant ignition, namely puts out from fire, tempers toughness with gentleness.

A: water glass (modulus 3.0 ~ 3.4) 80 acrylic resin 6 titanium dioxide 5

25 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 5 seconds, temper toughness with gentleness.

A: 30gB got by water glass 90 re-dispersible glue powder 1.5 epoxy soybean oil 4 tripoly phosphate sodium STPP 2 glycerol 5 Sodium sulfate anhydrous.min(99) 4: catalyst-free performed polymer 25 methylcarbonate 10 solvent oil 10 phosphoric acid ester 2 ritalin 3 polymeric MDI 25 gets 30g

Surface drying in 30 minutes; Be difficult to light, longitudinal constant ignition, put out in fiery 10 seconds; Temper toughness with gentleness.

A: 30g B got by water glass 80 (3.0 ~ 3.4 mould) re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 4 tripoly phosphate sodium STPP 1.5 glycerol 5 Sodium sulfate anhydrous.min(99) 4: catalyst-free performed polymer 25 methylcarbonate 10 solvent oil 10 phosphoric acid ester 2 ritalin 3 polymeric MDI 25 gets 30g

A: water glass (modulus 2.5 ~ 2.9)

B: catalyst-free performed polymer 1 black material 1 methylcarbonate 1 A: B=1: 1

15 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 10 seconds; Temper toughness with gentleness.Stick with paste with brush after 04 glass-fiber-fabric individual layer bottoming, 0.4 ~ 0.6kg/M3; Successively brush is stuck with paste to three layers of 2.2 ~ 2.9kg/M3

A: 54g got by water glass 80 re-dispersible glue powder 1 dioctyl phthalate (DOP) 4 glycerol 6 sodium polyphosphate 1.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

B: catalyst-free performed polymer 25 black material 25 methylcarbonate 8.3 methylene dichloride 4.2 solvent oil 8.3 phosphoric acid ester 2.5 ethyl acetate 3 gets 58g

50 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 5 seconds; Temper toughness with gentleness.Hand pastes version, 04 glass-fiber-fabric, 170mm*160mm, and 5 layers are just finished.

B: catalyst-free performed polymer 25 black material 25 methylcarbonate 8.3 methylene dichloride 4.2 solvent oil 8.3 phosphoric acid ester 2 methyl acetate 3 gets 58g

25 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 10 seconds; Temper toughness with gentleness

A: water glass 80 re-dispersible glue powder 1 dioctyl phthalate (DOP) 4 glycerol 6 sodium polyphosphate 1.5 Sodium sulfate anhydrous.min(99) 8 B: catalyst-free performed polymer 25 black material 25 methylcarbonate 8.3 methylene dichloride 4.2 solvent oil 8.3 phosphoric acid ester 2 methyl acetate 3

A∶B＝1∶1.5

26 minutes surface dryings; Be difficult to light, longitudinal constant ignition, put out in fiery 3 seconds; Temper toughness with gentleness

A: water glass 80 re-dispersible glue powder 1 dioctyl phthalate (DOP) 4 glycerol 6 sodium polyphosphate 1.2 Sodium sulfate anhydrous.min(99) 8 B: catalyst-free performed polymer 25 black material 25 methylcarbonate 8.3 methylene dichloride 4.2 solvent oil 8.3 phosphoric acid ester 2 methyl acetate 3

A∶B＝1.5∶1

With hardwood chip and/or wood chip and/or waste and old fibre as main raw material, water content control is within 15%, through the process of defibrator process solution fibre or directly utilize two-component spray apparatus evenly to add total amount of material 10-50% the present invention with the environment protection type composite resin of A: B1-1.5 mixing or invention adhesives, insert mould or mat formation shaping after through hot pressing or cold pier or enter continuous flat press compression moulding.Burst size of methanal does not detect by GB18580-2001 " in indoor decorating and refurnishing materials wood-based plate and goods thereof Form aldehyde release limitation " test; Described mixing material is suppressed and is prepared composite sheet in iron plate, and solidify and peel off by force after 24 hours, wood failure in mixing material, and have good flame-proof damp-proof function, cost is low.

In compound resin embodiment of the present invention, component A glass stick is mentioned after stirring, and be mostly freely drip state on liquid level 5-25cm height, viscosity is at 250 ~ 1000mpa.s; B component viscosity mostly at 200 ~ 800mpa.s, pH value > 12, adaptive phase 5-20 minute, density 1.25---1.5g/cm ³, separately get A, B two-pack compound resin 250g altogether in embodiment 8,03 ^#glass-fiber-fabric 4 layers of hand paste an edition 30*40mm ², intercept 150mm*150mm square sample block, fix two opposite side with the batten that two 100mm are high and make sample block rest part unsettled, in 2500mm eminence with 1150 grams of pebbles free-fallings impact sample blocks, have no any damage, individual layer 03 ^#glass-fiber-fabric is coated with to stick with paste after the present embodiment compound resin solidifies 72 hours and intercepts bending 180 degree of 150mm*150mm sample block (folding ridge is curved, base portion two sides distance 5mm-10mm, and large portion supports, and does not rupture), vertically lights a fire to have no for 30 seconds ignite with lighter.Through project delivery method inspection center of University Of Chongqing test (with reference to " impregnated-paper laminated wood floor " GB/T24508-2007, " underground mine use glass fiber reinforced plastics product safety performance inspection criterion " GB16413-2009), environment protection type composite resin glass reinforced plastic flexural strength: 37.5Mpa, shock resistance: 1Kg steel ball 1.02M highly falls and has no damaged, flame retardant properties: have no flame.

Binding agent method for making of the present invention:

Component A

5. add solid water glass, directly after step 1, add Sodium sulfate anhydrous.min(99), stir, then add other and fill out auxiliary material and solid water glass, stir, encapsulation; Always plant 0.4 ~ 1.2 times by compound before using add water and stir; If desired, the water glass curing agent lower than convention amount can also be added in solid water glass formula, as Sodium Silicofluoride, condensation of aluminum phosphate, metal oxide etc., have certain strengthening effect to the mechanical property of interpenetrating structure, but will be finished as early as possible after adding water.

B component

After excessive polyisocyanates and polyester polyol and/or polyether glycol react and reach terminal, cool to lower than after 50 ~ 60 DEG C, be better than most and add thinner lower than 50 DEG C in protection atmosphere with under stirring, isocyanic ester and/or blocked isocyanate, fluidizer or promotor is added in stirring, abundant mixing, nitrogen replacement barrelling seals; Or by base polyurethane prepolymer for use as 25 ~ 50%, thinner 25 ~ 50 parts mixing at lower than 40 DEG C; add 25 ~ 50% isocyanic ester or black material under nitrogen protection, or directly foamed glue and the black material containing performed polymer 30 ~ 50% is mixed by 0.5 ~ 1: 0.5 ~ 1 and both can.Certainly, also can be not limited to above step, take other rational order of addition(of ingredients) and stir to should be all right with grinding technics, can result of use be reached.The present invention introduce step to many formulas, such as re-dispersible glue powder and phthalic ester, methyl-monosilane, Viscotrol C, methylene dichloride etc., by this pre-treatment, better effects if.The urethane level material composition of some not hydroxyl, active hydrogen and other active group, as phthalic ester etc. can add in B component, if B is the mixing isocyanic ester, particularly blocked isocyanate containing blocked isocyanate over half then can add other compositions more.

During use, A and B is mixed after or spraying, roller coating, blade coating, brushing, and according to fill a prescription be finished in limited time.

Comparative example 6

Water glass 10g polymeric MDI 10g

Sample is put 85-105 DEG C of baking and is placed 36 hours (normal temperature has no solidification in lower 24 hours) after 12 hours

The thin glue of intensity (mpa) 0.7 ailhead band portion

Comparative example 2

Foamed glue 10g

The thin glue of cohesive strength (mpa) 1.1 ailhead band portion

Comparative example 7

191 resin 50 promotor 1.5 solidifying agent 1.5

The thin glue of cohesive strength (mpa) 0.5 ailhead band portion

Comparative example 8

Laminated flooring special adhesive (white glue with vinyl)

The thin glue of cohesive strength (mpa) 0.9 ailhead band portion

Comparative example 9

Cloud stone glue (glue 10 solidifying agent 0.3)

Cohesive strength (mpa) 1.8 ailhead band large stretch of glue, a small amount of wooden skin

Comparative example 10

Epoxy resin: polyamide resin=1: 1

Cohesive strength (mpa) 1.9 ailhead band portion wood skin

Following examples cohesive strength of the present invention (mpa1.0 ~ 3.5, the most half block of ailhead or nearly half block wood skin.

A: 20g got by water glass 30 191 resin 20 phosphoric acid ester (TCEP) 20 Sodium sulfate anhydrous.min(99) 6 talcum powder 6

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: get 20g at 5: 5: 10: 1

A: water glass 50 silicon sol 15 re-dispersible glue powder 8.2 glycerol 3

20g got by methylene dichloride 3 Sodium sulfate anhydrous.min(99) 10.5 talcum powder 8.2

A: 20g got by water glass 60 benzene emulsion 1 re-dispersible glue powder 1 tripoly phosphate sodium STPP 1 Sodium sulfate anhydrous.min(99) 4 light magnesium oxide 6

A: 20g got by water glass 75 re-dispersible glue powder 3 methylene dichloride 10.8 glycerol 7 tripoly phosphate sodium STPP 1 Sodium sulfate anhydrous.min(99) 8 talcum powder 15

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: get 20g at 5: 5: 10

A: water glass 75 re-dispersible glue powder 3 glycerol 7 methylene dichloride 21 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 8 Paris white 8 talcum powder 8

B: catalyst-free performed polymer: methylene dichloride: black material=1: get 20g at 1: 1

A: water glass 75 pvc sticks with paste resin 3 methylene dichloride 5 tripoly phosphate sodium STPP 1 glycerol 7 Sodium sulfate anhydrous.min(99) 9 gets 26g

B: catalyst-free performed polymer: methylene dichloride: black material=10: get 34g at 14: 10

A: water glass 75 pvc sticks with paste resin 3 dioctyl phthalate (DOP) 1.5 methylene dichloride 38 glycerol 6 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 8 density 1.35

A: water glass 75 re-dispersible glue powder 1 methylene dichloride 8 glycerol 7 tripoly phosphate sodium STPP 1.5

Sodium sulfate anhydrous.min(99) 8 talcum powder 15

30g got by A:885 resin 5 phosphoric acid ester (TTP) 5 Sodium dodecylbenzene sulfonate 0.6 water glass 75 Sodium sulfate anhydrous.min(99) 8

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: get 40g at 5: 5: 10: 1

Black material: foamed glue=1: 2 get 10g

A: water glass 75 191 resin (containing 3% promotor) 4 Viscotrol C 5 glycerol 5.5 tripoly phosphate sodium STPP 1.5

50g got by Sodium sulfate anhydrous.min(99) 9

A: 40g got by water glass 75 191 resin 5 phosphoric acid ester (TPP) 5 Sodium dodecylbenzene sulfonate 0.6 Sodium sulfate anhydrous.min(99) 8

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: get 30g at 5: 5: 10: 1

Black material: foamed glue=1: 2 get 10g

A: water glass 75 re-dispersible glue powder 3 methylene dichloride 10.8 dimethyl silicone oil 1.8 Sodium sulfate anhydrous.min(99) 8 trisodium phosphate 1 glycerol 8 talcum powder 9.5

A: water glass 75 re-dispersible glue powder 3 methylene dichloride 20 glycerol 7 acetone 2.5 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 9.5

A: water glass 75 re-dispersible glue powder 1.5 tripoly phosphate sodium STPP 1 glycerol 5 epoxy soybean oil 4

Sodium sulfate anhydrous.min(99) 8 talcum powder 15

A: 30g got by water glass 75 re-dispersible glue powder 2 mould silicone fluid 1 soybean oil 4 glycerol 5 AMONYL 380LC 1.5 tripoly phosphate sodium STPP 1.5 polyimide resin powder 1 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: water glass 75 re-dispersible glue powder 1.5 tripoly phosphate sodium STPP 1 glycerol 5 epoxy soybean oil 4 borax 0.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 15

30g got by A: water glass 75 191 resin 5 phosphoric acid ester (TCEP) 5 OP-10 0.4 butadiene-acrylonitrile rubber 0.2 Sodium dodecylbenzene sulfonate 0.6 Sodium sulfate anhydrous.min(99) 8.6

B: black material: foamed glue=1: 1 gets 10g

Catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: get 30g at 5: 5: 10: 1

Sodium sulfate anhydrous.min(99) 8 talcum powder 15

Catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: phosphoric acid ester (TPP): black material=10: get 30g at 5: 5: 1.5: 10

A: 40g got by water glass 80 re-dispersible glue powder 1.5 sunflower seed oil 4 tripoly phosphate sodium STPP 3 glycerol 6.5 Sodium sulfate anhydrous.min(99) 15

B: black material: foamed glue=1: 2 get 40g

A: water glass 80 organosilicon crylic acid latex 1.5 epoxy soybean oil 4 tripoly phosphate sodium STPP 1.5 glycerol 5 Sodium sulfate anhydrous.min(99) 8 talcum powder 10

A: water glass 80 vinyl ester resin (Fuchem 854) 1.5 dioctyl phthalate (DOP) 4 glycerol 5 tripoly phosphate sodium STPP 3 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: water glass 80 vinyl ester resin (Fuchem 820) 1 re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 4 silane coupling agent 0.3 glycerol 6 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: water glass 80 re-dispersible glue powder 10 dioctyl phthalate (DOP) 4 glycerol 5.5 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: water glass 80 re-dispersible glue powder 10 dioctyl phthalate (DOP) 4 glycerol 9 sodium polyphosphate 1.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: 20g got by water glass 80 polybutadiene epoxy resin 1.5 glycerol 9 tripoly phosphate sodium STPP 7.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

B: catalyst-free performed polymer: methylene dichloride: dioctyl phthalate (DOP): polymeric MDI=1: get 22g at 1: 0.1: 1

A: the above-mentioned sizing material of water glass 80 re-dispersible glue powder 1 tripoly phosphate sodium STPP 3 glycerol 5 ethylene glycol 2 dioctyl phthalate (DOP) 4 Sodium sulfate anhydrous.min(99) 8 talcum powder 8 gets 200, adds polyurethane foam and expects 3 in vain

A: solid water glass 40 re-dispersible glue powder 1.5 dibutyl phthalate 4 glycerol 5 ethylene glycol 2 tripoly phosphate sodium STPP 3 Sodium sulfate anhydrous.min(99) 8 talcum powder 8 cement 100, seals up for safekeeping after mixing, adds water 40 during use

A: water glass 80 re-dispersible glue powder 1 dioctyl phthalate (DOP) 4 tripoly phosphate sodium STPP 3 melamine resin 8 glycerol 5 ethylene glycol 2 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

Get above-mentioned sizing material to mix with silica powder 1: 1

A: water glass 80 re-dispersible glue powder 1 dioctyl phthalate (DOP) 4 tripoly phosphate sodium STPP 3 glycerol 5 ethylene glycol 2 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

Get above-mentioned sizing material to mix with silica powder 1: 2

A: water glass 80 re-dispersible glue powder 1 tripoly phosphate sodium STPP 3 glycerol 5 ethylene glycol 2 dioctyl phthalate (DOP) 4 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

Get above-mentioned sizing material to mix with talcum powder 2: 1

A: water glass 80 sodium methyl silicate 1 re-dispersible glue powder 2 two sodium polyphosphate 3 glycerol 5.5 talcum powder 8 200 solvent oil 4 Sodium sulfate anhydrous.min(99) 8

A: 10g got by water glass 80 tripoly phosphate sodium STPP 3 glycerol 5 titanate coupling agent 1 whiteruss 4 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

B: blocked polyisocyanate: re-dispersible glue powder: foamed glue=1: 0, get 10g at 05: 2

A: water glass 80 re-dispersible glue powder 1.5 acrylic resin 1 Viscotrol C 4 tripoly phosphate sodium STPP 1.5 glycerol 5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: 28.7g got by water glass 80 epoxy resin 3 tripoly phosphate sodium STPP 3 glycerol 5.5 Sodium sulfate anhydrous.min(99) 15

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: dioctyl phthalate (DOP): isophorone diisocyanate=1: get 24.3g at 0.5: 0.5: 0.17: 1

Black material: foamed glue=1: 2 get 7g

A: water glass 80 epoxy resin 2 dioctyl phthalate (DOP) 3 tripoly phosphate sodium STPP 1.5 glycerol 5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: water glass 80 re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 3 Viscotrol C 4 tripoly phosphate sodium STPP 1.5 glycerol 5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

A: water glass 80 benzene emulsion 1.5 re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 2 No. 200 solvent oil 2 glycerol 5.5 tripoly phosphate sodium STPP 3 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

B: catalyst-free performed polymer: methylene dichloride: modification MDI=1: 1: 1 A: B is 1: 1

30g got by A: Potassium No. 1.5 200, water glass 80 re-dispersible glue powder (Vac/VeoVa) solvent oil 4 glycerol 5.5 tripoly phosphate sodium STPP 3 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

Black material: foamed glue=1: 2 get 10g

A: 20g got by water glass 80 (sodium silicate, Potassium water glass half and half) re-dispersible glue powder (Vac/E/VeoVa) 2.5 dioctyl phthalate (DOP) 2.5 dibutyl phthalate 1.5 tripoly phosphate sodium STPP 1.5 glycerol 5.5 Sodium sulfate anhydrous.min(99) 8 sericite 5 talcum powder 5

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: isophorone diisocyanate I=1: 0.5: 0.5: 1 gets 16g

Black material: foamed glue=1: 2 get 4g

A: 20g got by water glass 85 re-dispersible glue powder 3 methylene dichloride 20 aluminium silicate wool 5 Sodium sulfate anhydrous.min(99) 8 glycerol 7 tripoly phosphate sodium STPP 1 talcum powder 15

A: get 30g after water glass 60 re-dispersible glue powder 1.5 acrylic resin 4 (oiliness) dioctyl phthalate (DOP) 2 glycerol 5 tripoly phosphate sodium STPP 1.5 stirs

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: 25g is got in modification MDI=1: 0.5: 0.5: 1

Black material: foamed glue=1: 2 get 5g

A: water glass 95 re-dispersible glue powder 15 melamine resin 5 silane coupling agent 1.2 gets 8g

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: get 10g at 5: 5: 10: 1

A: water glass 98.5 re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 4 glycerol 5.5 tripoly phosphate sodium STPP 8.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8 catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: get 10g at 5: 5: 10: 1

A: 10g got by water glass 98.5 re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 4 glycerol 5.5 tripoly phosphate sodium STPP 8.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8 light magnesium oxide 8

A: solid water glass mixture: post-reinforcing body water glass 40 mixed thoroughly by re-dispersible glue powder 4 Viscotrol C 4 glycerol 5 AMONYL 380LC 1.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8, stirs, pack

Get 20g, add water 20g, stirs

Black material: foamed glue=1: 2 get 10g

A: solid water glass mixture: post-reinforcing body water glass 40 mixed thoroughly by re-dispersible glue powder 4 Viscotrol C 4 glycerol 5 sodium lauryl sulphate 1.5 tripoly phosphate sodium STPP 1 Sodium sulfate anhydrous.min(99) 8 talcum powder 8, stirs, pack; Get 20g, add water 12g, stirs

Tackiness agent component A density about 1.25 ~ 2.25g/cm in the embodiment of the present invention ³, viscosity 380 ~ 10000mpas, pH value > 12,5 ~ 45 minutes adaptive phase, Amount of spread 800 ~ 2000g/m ².With ceramic tile one side coating 20*20mm ²to put respectively after tackiness agent in embodiment 58 in tap water and 2% aqueous sodium hydroxide solution and 1% sulphuric acid soln one month, still no abnormality seen, free-hand firmly fail to pull de-.In embodiment, quick drying paint brushing steel plate and cement plate are gone through and within 8 months, are had no cracking, variable color, get rusty and play halogen.In embodiment 51, sample boils through 4 hours tap water and 2 hours 0.5 ~ 1% sodium hydroxide solutions, and do not find the abnormal conditions such as aliquation cracking, surface luster has no considerable change.

The preparation of coating:

A preparation technology: various powder is carried out in advance grinding screening, adds the resin liquid of metering in a reservoir successively or adds glycerine again after dispersibling resin-oatmeal, softening agent stirring, adding water glass and mineral filler, obtain slurry after stirring after stirring.Slurry, after three-roll grinder one to twice grinding, adds conventional emulsions needed for reality and other auxiliary agents, stirrer with 300 ~ 800 revs/min stir 30 minutes little of mixing to 4.Coating of the present invention is not limited to aforesaid method, and various ordinary method can be adopted to prepare.

In the container of band whipping appts, the various compositions of composition component A are added with reference to tackiness agent, adjust with concrete purposes the concrete deal that auxiliary material filled out by filler, pigment, dispersion agent, flow agent and defoamer etc. routinely, vigorous stirring and/or grinding lower formation homogeneous latex emulsion are component A.Separately in the container of band whipping appts, add the various material such as catalyst-free performed polymer, organic solvent, black material of composition B component by formula and stir, obtaining B component.Add above-mentioned obtained component A, B component stirring according to A: B=0.5 ~ 1: 0.5 ~ 1 ratio, coating of the present invention can be obtained.Can directly stick with glue agent and make coating, or in compound resin/tackiness agent according to a conventional method add fill out auxiliary material and additive.

In following embodiment, coating surface drying time is all less than 2 hours, does solid work and is less than 12 hours, and oil-proofness soaks 7 days, and humidity resistance soaks 7 days, and salt tolerance soaks 3 days, and cold-hot circulates 15 times, and coating is all not wrinkling, does not come off.Be difficult to light.Coating component A density is mostly at 1.25 ~ 1.5g/cm ³, viscosity 500 ~ 3000mpas, pH value > 12,10 ~ 45 minutes adaptive phase, Amount of spread 1000 ~ 2500g/m ².Chopstick head lubricated is about 5g, and solidify and be soaked in 5% dilute hydrochloric acid solution one week after 36 hours, still glossy, attachment state is still firm.

A: water glass 80 tripoly phosphate sodium STPP 1.5 Sodium dodecylbenzene sulfonate 0.8 glycerol 5.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8 defoamer is a little

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: dioctyl phthalate (DOP): re-dispersible glue powder: black material=1: 0.5: 0.5: 0.08: 0.16: 1

Black material: foamed glue=1: 2, A: B is 1.1: 1

A: water glass 80 tripoly phosphate sodium STPP 1.5 glycerol 5 re-dispersible glue powder 1.5 Viscotrol C 4 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=1: 0.5: 0.5: 1, A: B is 1: 1

A: solid water glass mixture: post-reinforcing body water glass 40 mixed a little thoroughly by re-dispersible glue powder 4 Viscotrol C 4 glycerol 5 sodium lauryl sulphate 1.5 tripoly phosphate sodium STPP 1 Sodium sulfate anhydrous.min(99) 10 talcum powder 10 wilkinite 8 sericite 10 defoamer, stir, pack; Get 20g, add water 12g, stirs

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=10: 5: 5: 10: 1, A: B is 1.5: 1

A: water glass 80 re-dispersible glue powder 2 No. 200 solvent oil 2 dioctyl phthalate (DOP) 2 glycerol 5.5 tripoly phosphate sodium STPP 3 Sodium sulfate anhydrous.min(99) 8 talcum powder 8 expansible black leads 5

B: catalyst-free performed polymer: methylene dichloride: black material=1: 1: 1, A: B is 1: 1

A: a little flow agent of water glass 80 tripoly phosphate sodium STPP 3 glycerol 5 re-dispersible glue powder 3 dioctyl phthalate (DOP) 4 Sodium sulfate anhydrous.min(99) 8 talcum powder 20 titanium dioxide 5 light calcium carbonate 8 OP-10 1 defoamer is appropriate

B: catalyst-free performed polymer: methylene dichloride: No. 200 solvent oils: black material=1: 0.5: 0.5: 1: 1A: B is 1.2: 1

A: a little flow agent of water glass 80 re-dispersible glue powder 1.0 dimethyl silicone oil 2.5 lauryl alcohol ester 8 talcum powder 10 titanium dioxide 5 light calcium carbonate 8 OP-102 defoamer is appropriate

B: the black material 4 A: B=1: 1 of catalyst-free performed polymer 3

A: a little flow agent of water glass 100 re-dispersible glue powder 1.5 dimethyl silicone oil 1.5 lauryl alcohol ester 5 talcum powder 10 titanium dioxide 5 glycerol 2.5 ethylene glycol 2.5 tripoly phosphate sodium STPP 1.5 OP-10 2 defoamer is appropriate

B: the black material 4 A: B=1.2: 1 of catalyst-free performed polymer 4

The combination can making fiber glass resin, tackiness agent and coating in the present invention also can be:

A: water glass 80 AES3 vinylbenzene 4 re-dispersible glue powder 1.5 phosphoric acid ester 3 tripoly phosphate sodium STPP 1.5

B: catalyst-free performed polymer 1 black material 1 methylcarbonate 0.3 methyl acetate 0.3

A∶B＝1∶1

A: water glass (modulus 2.6 ~ 2.9)

B: the black material 25 A: B=1: 1 of catalyst-free performed polymer 5

A: water glass (modulus 2.6 ~ 2.9)

B: the black material 25 A: B=1: 1 of catalyst-free performed polymer 0.5

A: water glass (modulus 2.6 ~ 2.9)

B: the black material 25 A: B=1: 1 of catalyst-free performed polymer 0.75

A: water glass 80 re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 2 Viscotrol C 2 tripoly phosphate sodium STPP 1.5 glycerol 6 Sodium sulfate anhydrous.min(99) 8 talcum powder 8

B: the black material 25 A: B=1: 1 of catalyst-free performed polymer 0.75

A: water glass (modulus 2.6 ~ 2.9)

B: the black material 100 A: B=1: 1 of catalyst-free performed polymer 0.3

A: water glass (modulus 2.6 ~ 2.9) silane coupling agent 0.6

A: water glass 75 re-dispersible glue powder 1.8 dioctyl phthalate (DOP) 4 glycerol 5.5 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 4 talcum powder 4 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1

A: water glass 50 re-dispersible glue powder 1.0 epoxy soybean oil 4 glycerol 5 tripoly phosphate sodium STPP 1.5 talcum powder 16 B: the black material 1 A: B=3: 2.5 of catalyst-free performed polymer 1

A: water glass 80 re-dispersible glue powder 1.5 dibutyl phthalate 5 glycerol 5 tripoly phosphate sodium STPP 2 Sodium sulfate anhydrous.min(99) 8 titanium dioxide 50 B: the black material 1 A: B=3: 2 of catalyst-free performed polymer 1

A: water glass 30 re-dispersible glue powder 1.0 dibutyl phthalate 4 kh550 1.2

Glycerol 5 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 4 diatomite 8 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1

A: water glass 80 re-dispersible glue powder 1.5 dibutyl phthalate 4 coupling agent 1.5

Glycerol 5 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 4 mica powder 48 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1

A: water glass 80 re-dispersible glue powder 1.0 dibutyl phthalate 3

Glycerol 5 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 4 mica powder 4 B: catalyst-free performed polymer 4 black material 4 methylene dichloride 1 solvent oil 1

A∶B＝1∶1

A: water glass 80 (3.0 ~ 3.4 mould) re-dispersible glue powder 1.0 dibutyl phthalate 3

Glycerol 5 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 8 mica powder 8 B: catalyst-free performed polymer 4 black material 4 methylene dichloride 1 solvent oil 1

A∶B＝3∶2

A: water glass 30 (3.0 ~ 3.4 mould) glycerol 10 Sodium sulfate anhydrous.min(99) 8 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1

A: water glass 80 (2.1 ~ 2.5 mould) Viscotrol C 8 re-dispersible glue powder 1 tripoly phosphate sodium STPP 1 Sodium sulfate anhydrous.min(99) 4 B: the black material 1 of catalyst-free performed polymer 1

A∶B＝1∶1

A: water glass 80 (2.1 ~ 2.5 mould) Viscotrol C 6 tripoly phosphate sodium STPP 1.5 Sodium sulfate anhydrous.min(99) 5 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1

A: water glass 80 (modulus 2.6 ~ 2.9) re-dispersible glue powder 1 dimethyl silicone oil 4.8 glycerol 2.5 ethylene glycol 2.5 tripoly phosphate sodium STPP 1 Sodium sulfate anhydrous.min(99) 5 mica powder 10 vinylbenzene 8 B: catalyst-free performed polymer 2 black material 2 methylcarbonate 0.7 A: B=1: 1

A: water glass 80 re-dispersible glue powder 1 dioctyl phthalate (DOP) 4 glycerol 6 sodium polyphosphate 1.5 Sodium sulfate anhydrous.min(99) 8 talcum powder 8 B: catalyst-free performed polymer 25 black material 25 methylcarbonate 8.3 methylene dichloride 4.2 solvent oil 8.3 phosphoric acid ester 2.5 ethyl acetate 3 A: B=1: 1

A: water glass (modulus 3.0 ~ 3.4) 80 acrylic resin 5 Sodium sulfate anhydrous.min(99) 5

A: water glass (modulus 3.0 ~ 3.4) 80 Sodium dodecylbenzene sulfonate 2 epoxy resin 6 Sodium sulfate anhydrous.min(99) 5 coupling agent 2

The present invention is as environment-friendlyadhesive adhesive and multiple conventional glue Performance comparision

Normal temperature and pressure bonding strength (mpa) is with reference to (measuring after equal 48 hours)

Tai Tebang

Batten-screw 0.96 (ailhead band wood)

Ceramic tile-screw 0.97 (ailhead band glue)

Screw-screw 1.04 (ailhead band glue)

Cloud stone glue

Batten-screw 0.83 (ailhead band wood)

Ceramic tile-screw 0.95 (ailhead band glue)

Screw-screw 2.99 (ailhead band glue)

One of the present invention's series

A: water glass 80 re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 4 tripoly phosphate sodium STPP 1.5 glycerol 6 Sodium sulfate anhydrous.min(99) 8 talcum powder 80 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1 methylene dichloride 0.5 solvent oil 0.5

Cohesive strength (mpa):

Batten-screw 2.27 (ailhead band wood)

Ceramic tile-screw 1.97 (ailhead band glue)

Screw-screw 2.68 (ailhead band glue)

Two of the present invention's series

A: water glass 80 re-dispersible glue powder 1.5 epoxy soybean oil 4 tripoly phosphate sodium STPP 1.5 glycerol 6 Sodium sulfate anhydrous.min(99) 8 sericite 8 B: catalyst-free performed polymer 25 methylcarbonate 10 solvent oil 8 phosphoric acid ester 3 ritalin 4 polymeric MDI 25 A: B=1: 1

Cohesive strength (mpa):

Batten-screw 1.85 (ailhead band glue) ceramic tile-screw 1.63 (ailhead band glue)

The 3 437 battens-screw 2.51 (ailhead band glue and wood) of the present invention's series

Ceramic tile-screw 1.91 (ailhead band glue)

Screw-screw 2.93 (ailhead band glue)

Humid heat test

Tai Tebang

Ceramic tile-screw normal pressure boils and within 3 days two days, comes off nearly half, within three days, all comes off.

Screw-screw normal pressure steams and does not come off for 7 days, and ambient temperatare is put and surveyed bonding strength 0.48mpa (ailhead band glue) in 24 hours

Batten-screw is through 7 days 25 times low temperature freezing and thawing test bonding strength 1.00mpa (ailhead band glue and a small amount of wooden skin)

Cloud stone glue

Ceramic tile-screw normal pressure boils and all comes off for 3 days two days.

Batten-screw normal pressure steams and does not come off for 7 days, and ambient temperatare is put and surveyed bonding strength 0.35mpa (ailhead is glue-free black rusty stain) in 24 hours

Screw-screw normal pressure steams and closely partly comes off for 7 days, and ambient temperatare is put and surveyed bonding strength 0.30mpa (ailhead is glue-free brown-black rusty stain) in 24 hours

Batten-screw is through 7 days 25 times low temperature freezing and thawing test bonding strength 1.05mpa (ailhead band glue)

Epoxy resin (E-44 and polyamide resin 650 half and half)

Ceramic tile-screw normal pressure boils existing breach on 3 days most sample interfaces, and ambient temperatare is put and surveyed bonding strength 0.35mpa (the glue-free brown-black of ailhead) in 24 hours

Batten-screw normal pressure steams and does not come off for 7 days, and ambient temperatare is put and within 24 hours, surveyed bonding strength 0.40 ~ 1.30mpa (ailhead dark brown glue-free or be with brown glued membrane)

Screw-screw normal pressure steams existing crack on 7 days nearly half sample interfaces, and ambient temperatare is put and surveyed bonding strength 0.40 ~ 2.21mpa (ailhead band glue part has brown scales mark) in 24 hours

Batten-screw 7 days 25 times low temperature freezing and thawing test bonding strength 1.53mpa (ailhead is almost glue-free)

Four of the present invention's series

A: water glass 80 re-dispersible glue powder 1.5 epoxy soybean oil 3 dimethyl silicone oil 1 tripoly phosphate sodium STPP 1.5 glycerol 6 Sodium sulfate anhydrous.min(99) 8 sericite 100 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1 methylene dichloride 0.5 solvent oil 0.5

Cohesive strength (mpa):

Ceramic tile-screw normal pressure boils and does not all come off for 3 days, and ambient temperatare is put and surveyed bonding strength 0.63mpa (ailhead band glue) in 24 hours

Batten-screw normal pressure steams and does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 1.22mpa (ailhead dark brown glue-free or be with brown glued membrane) in 24 hours

Screw-screw normal pressure steams and does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 1.10mpa (ailhead band glue) in 24 hours

Batten-screw is through 7 days 25 times low temperature freezing and thawing test bonding strength 2.02mpa (ailhead band wood skin)

Five of the present invention's series

A: water glass 80 re-dispersible glue powder 1.5 epoxy soybean oil 2 dioctyl phthalate (DOP) 2 tripoly phosphate sodium STPP 1.5 glycerol 6 Sodium sulfate anhydrous.min(99) 8 talcum powder 80 B: the black material 1 A: B=1: 1 of catalyst-free performed polymer 1 methylcarbonate 0.5 solvent oil 0.5

Cohesive strength (mpa):

Ceramic tile-screw normal pressure boils and does not all come off for 3 days, and ambient temperatare is put and surveyed bonding strength 1.05mpa (ailhead band glue) in 24 hours

Batten-screw normal pressure steams and does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 1.31mpa (ailhead band portion glue) in 24 hours

Screw-screw normal pressure steams and does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 0.98mpa (a small amount of glue of ailhead band) in 24 hours

Batten-screw 7 days 25 times low temperature freezing and thawing test bonding strength 1.08mpa (ailhead band glue)

Dry heat test

Tai Tebang

The baking of 60 ~ 120 DEG C, ceramic tile-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 1.16mpa (ailhead band glue, Vandyke brown) in 24 hours

The baking of 60 ~ 120 DEG C, iron block-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 0.93mpa (ailhead band portion glue) in 24 hours

Cloud stone glue

The baking of 60 ~ 120 DEG C, ceramic tile-screw does not all come off for 7 days, and ambient temperatare is put and within 24 hours, surveyed bonding strength 1.47mpa (ailhead band glue or band ceramic tile fragment)

The baking of 60 ~ 120 DEG C, iron block-screw all comes off for 7 days.

Epoxy resin (E-44 and polyamide resin 650 half and half)

The baking of 60 ~ 120 DEG C, ceramic tile-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 1.76mpa (ailhead band ceramic tile fragment) in 24 hours

The baking of 60 ~ 120 DEG C, iron block-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 2.43mpa (ailhead band ceramic tile fragment) in 24 hours

Six of the present invention's series

A: water glass 80 (modulus 3.0 ~ 3.4) re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 4 tripoly phosphate sodium STPP 1.5 glycerol 6 Sodium sulfate anhydrous.min(99) 8 sericite 100 B: the black material 1 A: B=3: 2 of catalyst-free performed polymer 1

Cohesive strength (mpa):

Batten-screw normal temperature and pressure 48 hours surveys bonding strength 2.35mpa (ailhead band glue and/or wooden skin)

Ceramic tile-screw normal temperature and pressure 48 hours surveys bonding strength 2.76mpa (ailhead band glue and/or ceramic tile fragment)

The baking of 60 ~ 120 DEG C, ceramic tile-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 1.35mpa (ailhead is almost glue-free) in 24 hours

The baking of 60 ~ 120 DEG C, iron block-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 0.85mpa (ailhead is almost glue-free) in 24 hours

Seven of the present invention's series

A: water glass 80 (modulus 3.0 ~ 3.4) re-dispersible glue powder 1.5 dioctyl phthalate (DOP) 4 tripoly phosphate sodium STPP 1.5 glycerol 5 Sodium sulfate anhydrous.min(99) 8 sericite 9 B: the black material 1 A: B=1: 1 cohesive strength (mpa) of catalyst-free performed polymer 1 methylcarbonate 0.33 solvent oil 0.33 methyl acetate 0.33:

Batten-screw normal temperature and pressure 48 hours surveys bonding strength 1.98mpa (ailhead band glue and/or wooden skin)

Ceramic tile-screw normal temperature and pressure 48 hours surveys bonding strength 2.06mpa (ailhead band glue and/or ceramic tile fragment)

The baking of 60 ~ 120 DEG C, ceramic tile-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 1.46mpa (ailhead band glue) in 24 hours

The baking of 60 ~ 120 DEG C, iron block-screw does not all come off for 7 days, and ambient temperatare is put and surveyed bonding strength 2.13mpa (ailhead band glue) in 24 hours

Although the adaptive phase of compound resin, tackiness agent and coating is relevant to temperature in the present invention, can control at several minutes within the scope of a few hours according to known technologies such as formulation selection and isocyanic ester kind, closure state and thinner, catalyzer, phosphoric acid ester and other composition adjustment.

Claims

1. an environmental-protecting composite resin, comprise water glass component A and polyurethane component B and conventional additives, it is characterized in that, A hydrated glass or modified water glass 90 ~ 100 parts, polyvalent alcohol 0 ~ 10 part, polyvalent alcohol 0 ~ 6 part, Sodium sulfate anhydrous.min(99) 0 ~ 8 part, resin liquid and/or dispersible resin-oatmeal 0 ~ 3 part, organic solvent and/or 0 ~ 6 part, softening agent, tensio-active agent and/or Sodium hexametaphosphate 99 and/or trisodium phosphate and/or tripoly phosphate sodium STPP 0 ~ 3 part, fill out auxiliary material 0 ~ 50 part; What produce containing polyester polyol and/or polyether glycol and polyisocyanates pre-polymerization in B contains the performed polymer holding NCO, its composition and each composition by weight percent are: isocyanic ester and/or blocked isocyanate 30 ~ 97%, performed polymer 0.2% ~ 30%, organic solvent and/or softening agent 0 ~ 50%, additive 0 ~ 0.5%; The weight ratio of A and B: A: B=1: 2 ~ 2: 1, described water glass is sodium silicate and/or Potassium water glass; Described modified water glass is the water glass that with the addition of a small amount of functional material or additive in water glass.

2. an environmental-protecting composite resin, it is characterized in that, comprise water glass component A and polyurethane component B and conventional additives, it is characterized in that, A is water glass or modified water glass 60 ~ 100 parts, organic solvent and/or softening agent 0 ~ 30%, polyvalent alcohol 0 ~ 10 part, resin liquid and/or dispersible resin-oatmeal 0 ~ 15%, tensio-active agent and/or Sodium hexametaphosphate 99 and/or trisodium phosphate and/or tripoly phosphate sodium STPP 0 ~ 8 part, fill out auxiliary material 0 ~ 20 part; The performed polymer that polyester polyol and/or polyether glycol and polyisocyanates pre-polymerization produce also is contained in B, its composition and each composition by weight percent are: isocyanic ester and/or blocked isocyanate 30 ~ 50%, performed polymer 20 ~ 30%, organic solvent and/or softening agent 20 ~ 50%, additive 0 ~ 0.5%; The weight ratio of A and B: A: B=1: 1.5 ~ 1.5: 1, described water glass is sodium silicate and/or Potassium water glass; Described modified water glass is the water glass that with the addition of a small amount of functional material or additive in water glass.

3. an environmental-protecting composite resin and based on the tackiness agent of this resin and coating, comprise water glass component A and isocyanate component B and conventional additives, it is characterized in that, at least also containing the resin liquid or the melamine resin that are suitable for resin or epoxy resin or organosilicon acrylic resin or styrene-acrylic resin or silica column in A or B, or to dispersible in resin-oatmeal or their modification derivant one or more combination, its composition and each Composition Weight Parts are: water glass 30 ~ 100 parts, dispersion agent 0 ~ 10 part, fills out auxiliary material 0 ~ 550 part; Also containing polyester and/or polyether glycol performed polymer in B, its component comprised and weight percent are: isocyanic ester and/or blocked isocyanate 30 ~ 50%, performed polymer 20% ~ 50%, organic solvent and/or softening agent 20 ~ 50%, catalyzer 0 ~ 0.3%; Also resinous liquid and/or dispersible resin-oatmeal 0.3 ~ 15%, organic solvent and/or softening agent 0 ~ 50%, polyvalent alcohol 0 ~ 10%, water glass curing agent 0 ~ 10% in A or B or another component C; When being mixed to form Composite rubber material, components by weight is, A: B or (A+C): B or A: (B+C)=1: 1.5 ~ 1.5: 1.

4. an environmental-protecting composite resin and based on the tackiness agent of this resin and coating, comprise water glass component A and isocyanate component B and conventional additives, it is characterized in that, described water glass is fast dissolving solid water glass, at least also containing being suitable for the vinyl ester resin preparing water glass base polyurethane prepolymer for use as compound resin in A, or vibrin, or acrylic resin, or epoxy resin, or organosilicon acrylic resin, or the resin liquid of styrene-acrylic resin or silica column or melamine resin, or to dispersible in resin-oatmeal or their modification derivant one or more combination, its composition and each Composition Weight Parts are: solid water glass 15 ~ 50 parts, resin liquid or and/or re-dispersible glue powder dispersion agent 1 ~ 20 part, organic solvent and/or softening agent 0 ~ 40%, polyvalent alcohol 0 ~ 10%, tensio-active agent and/or dispersion agent 0 ~ 10%, fill out auxiliary material 0 ~ 550 part, 0 ~ 5 part, solidifying agent, A with coordinate before add water, amount of water is 0.4 ~ 1.2 times of solid water glass weight, also containing polyester and/or polyether glycol performed polymer in B, its component comprised and weight percent are: isocyanic ester and/or blocked isocyanate 30 ~ 50%, performed polymer 20% ~ 50%, organic solvent and/or softening agent 20 ~ 50%, catalyzer 0 ~ 0.5%, A: B is 1 ~ 1.5: 1 ~ 1.5.

5. according to a kind of environmental-protecting composite resin described in claim 3 or 4 with based on the tackiness agent of this resin and coating, it is characterized in that in A, each Composition Weight Parts is: liquid soluble glass 65 ~ 85 parts or solid formulation and coating, it is characterized in that in A, each Composition Weight Parts is: liquid soluble glass 65 ~ 85 parts or solid water glass 20 ~ 45 parts, resin liquid and/or dispersible resin 1.5 ~ 15 parts, organic solvent and/or 3 ~ 30 parts, softening agent, ethylene glycol and/or glycerol 3 ~ 8 parts, tensio-active agent and/or trisodium phosphate and/or tripoly phosphate sodium STPP 0.5 ~ 8 part, fill out auxiliary material 0 ~ 20 part, base polyurethane prepolymer for use as in B: isocyanic ester and/or blocked isocyanate: thinner and/or viscosity-depression agent=1: 1: 1, softening agent 1.5 ~ 10%, catalyzer is 0.

6. according to a kind of environmental-protecting composite resin described in claim 5 with based on the tackiness agent of this resin and coating, it is characterized in that in A, each Composition Weight Parts is: liquid soluble glass 65 ~ 85 parts or solid water glass 30 ~ 45 parts, resin liquid and/or re-dispersible glue powder 3 ~ 10 parts, organic solvent and/or phosphoric acid ester 3 ~ 10 parts, ethylene glycol 0 ~ 2 part, glycerol 4 ~ 6 parts, 0 ~ 5 part, tensio-active agent, trisodium phosphate and/or tripoly phosphate sodium STPP 1 ~ 3 part, Sodium sulfate anhydrous.min(99) 3 ~ 16 parts, talcum powder and/or sericite and/or silicon powder 0 ~ 16 part, antiaging agent and/or other additive 0 ~ 3 part, B contains-NCO 10 ~ 20%, its isocyanic ester and/or blocked isocyanate 30 ~ 35%, performed polymer 25% ~ 35%, organic solvent 25 ~ 35%, softening agent 0 ~ 10%, catalyzer 0 ~ 0.05%, described isocyanic ester is diphenylmethanediisocyanate (MDI), modification MDI, polymeric MDI/black material, poly methylene poly phenyl poly isocyanate (PAPI), isoflurane chalcone diisocyanate (IPDI), tolylene diisocyanate (TDI), hexamethylene-diisocyanate tripolymer (HDT), pentamethylene vulcabond, dicyclohexyl methane diisocyanate, two phenyl diisocyanate, phenyl diisocyanate, and one or more combination in the derivative of described isocyanic ester.

7. according to a kind of environmental-protecting composite resin described in claim 6 with based on the tackiness agent of this resin and coating, it is characterized in that A composition and each Composition Weight Parts are: liquid soluble glass 75 ~ 85 parts or solid water glass 37 ~ 43 parts, unsaturated polyester resin and/or re-dispersible glue powder 3 ~ 10 parts, organic solvent and/or 3 ~ 10 parts, softening agent, polyvalent alcohol 5 ~ 7 parts, 0 ~ 5 part, tensio-active agent, tripoly phosphate sodium STPP 1 ~ 3 part, filler 15 ~ 150 parts, additive 0 ~ 10 part.

8. an environmental-protecting composite resin and based on the tackiness agent of this resin and coating, comprise water glass component A and blocked isocyanate B component and conventional additives, it is characterized in that, at least also containing being suitable for the vinyl ester resin preparing water glass urethane compound resin in B, or vibrin, or acrylic resin, or epoxy resin, or organosilicon acrylic resin, or styrene-acrylic resin, or the resin liquid of silica column, or melamine resin, or to dispersible in resin-oatmeal or their modification derivant one or more combination, in A, each Composition Weight Parts is: water glass 30 ~ 50 parts or solid water glass 15 ~ 25 parts, glycerol 5 ~ 7 parts, 0.3 ~ 5 part, tensio-active agent, tripoly phosphate sodium STPP 1 ~ 5 part, Sodium sulfate anhydrous.min(99) 5 ~ 8 parts, talcum powder and/or sericite in powder and/or silicon powder 5 ~ 30 parts, silica powder and/or other be suitable for coordinating with water glass fill out auxiliary material 0 ~ 150 part, expansible black lead 0 ~ 6 part, base polyurethane prepolymer for use as in B: methylene dichloride: solvent oil and/or methylene dichloride and/or phosphoric acid ester and/or propylene carbonate: resin liquid and/or re-dispersible glue powder: blocked isocyanate=1: 0.5: 0.5 ~ 0.8: 0.2 ~ 0.3: 1, the proportioning of A and B is: A: B=1: 1 ~ 1.3.

9. according to the environment protection type composite resin described in claim 1 or 2, or the tackiness agent described in claim 7 or 8 and coating, it is characterized in that described water glass is one or more combination or sodium silicate and Potassium water glass and/or lithium silicate and/or silicon sol and/or organosilyl mixture in sodium silicate, Potassium water glass, lithium silicate; Described blocked isocyanate be to alkaline environment sensitivity can the blocked isocyanate of water glass deblocking and/or low temperature modification blocked isocyanate; The described resin-oatmeal that dispersibles is re-dispersible glue powder; Described organic solvent and/or softening agent are one or more the combination in alkyl silane, phthalic ester, vegetables oil, solvent oil, methylene dichloride, phosphoric acid ester or phosphorous acid ester and/or propylene carbonate.

10., according to a kind of environmental-protecting composite resin described in claim 1,2,3,4,6,7 or 8 with based on the tackiness agent of this resin and coating method, it is characterized in that comprising following steps:

A group

5. add solid water glass, directly after step 1, add Sodium sulfate anhydrous.min(99), stir, then add other and fill out auxiliary material and solid water glass, stir, encapsulation; Always plant 0.4 ~ 1.2 times by compound before using add water and enter step 4; The component deposited independent of water glass mixes with the water glass comprising other composition, enters step 4.

B group

After isocyanic ester and polyester polyol and/or polyether glycol react and reach terminal, cool to lower than after 50 DEG C, protection atmosphere with stir under add thinner and isocyanic ester and/or blocked isocyanate and softening agent, fully mix, nitrogen replacement barrelling seals; Or at lower than 40 DEG C, base polyurethane prepolymer for use as 35 ~ 50%, thinner 25 ~ 50%, softening agent and/or viscosity-depression agent 0 ~ 10% are mixed; add 25 ~ 50% isocyanic ester or black material under nitrogen protection; or directly the foamed glue containing performed polymer 30 ~ 50% is mixed by 0.5: 1 ~ 1: 0.5 with black material and/or blocked isocyanate; then softening agent and/or viscosity-depression agent 0 ~ 10% is added; organic solvent and/or softening agent 0 ~ 50%, both stir can.