CN104910708A - Antibacterial water-based gloss oil and preparation method thereof - Google Patents
Antibacterial water-based gloss oil and preparation method thereof Download PDFInfo
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- CN104910708A CN104910708A CN201510329903.9A CN201510329903A CN104910708A CN 104910708 A CN104910708 A CN 104910708A CN 201510329903 A CN201510329903 A CN 201510329903A CN 104910708 A CN104910708 A CN 104910708A
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Abstract
The invention discloses antibacterial water-based gloss oil. The antibacterial water-based gloss oil is characterized by comprising the following raw materials in parts by weight: 60 to 80 parts of modified styrene-acrylic emulsion, 0.2 to 0.4 part of carboxymethyl chitosan, 0.1 to 0.2 part of konjac glucomannan, 0.3 to 0.5 part of nano titanium dioxide, 3 to 5 parts of polyethylene wax emulsion, 1 to 2 parts of peanut proteins, 0.3 to 0.5 part of dodecyl glucoside, 1 to 2 parts of amino silicon oil and 10 to 15 parts of water. The water-based gloss oil is good in hardness, abrasion resistance and impact resistance and excellent in water resistance and corrosion resistance, has an efficient broad-spectrum antibacterial performance and is capable of improving the sanitation performance of a product and facilitating the health of a user.
Description
Technical field
The present invention relates to printing processing technology, be specifically related to a kind of antibacterial water color oil polish and preparation method thereof.
Background technology
In recent years, along with the progress of economy and living standards of the people improve constantly, the specification of quality of printed matter and the environmental requirement of Printing industry are improved constantly.On only Printing industry apply one of maximum technique, be an indispensable part in Printing industry, it is imperative to develop it and improve.Oil polish is a kind of colourless, transparent or semitransparent ink, upper smooth time by being covered with one deck oil polish at printed matter surface, form transparent optical bright layers in conjunction with subsequent technique at printed matter surface, to reach the effect of decoration and protection printed matter.Solvent evaporates not only contaminate environment in traditional solvent-borne type oil polish glazing operation; also certain infringement is produced to HUMAN HEALTH; be difficult to reach the standard-required of the health of increasingly stringent, environmental protection, labour protection; therefore environment-friendly aqueous oil polish is more and more paid attention to, and has good development prospect and market potential.The existing problem of water lustering oil mainly comprises price and the over-all properties of product, and the greatest problem that wherein product performance exist improves the weathering resistance of product, as wear resistance, water tolerance etc.
Summary of the invention
The object of this invention is to provide a kind of antibacterial water color oil polish, have good mechanical property and water tolerance, corrosion resistance nature concurrently, anti-microbial property high-efficiency broad spectrum.
The present invention is achieved by the following technical solutions:
A kind of antibacterial water color oil polish, it is obtained by the raw material of following weight parts:
Modifying cinepazid emulsion 60-80, cm-chitosan 0.2-0.4, Rhizoma amorphophalli glucomannan 0.1-0.2, nano titanium oxide 0.3-0.5, polythene wax emulsion 3-5, Semen arachidis hypogaeae protein 1-2, lauryl glucosyl 0.3-0.5, amido silicon oil 1-2, water 10-15;
Wherein modifying cinepazid emulsion is made up of the raw material of following weight part:
Vinylbenzene 40-50, butyl acrylate 40-50, vinylformic acid 3-4, methyl methacrylate 10-15, sodium lauryl sulphate 3-4, emulsifier op-10 1-1.5, titanate coupling agent TMC-311W 1-2, sodium bicarbonate 4-6, initiator A PS 3-4, water 80-100;
Wherein the preparation method of modifying cinepazid emulsion is:
By sodium lauryl sulphate and emulsifier op-10 soluble in water, obtain pre-reaction liquid; The pre-reaction liquid getting 3/5-4/5 weight part adds vinylbenzene, butyl acrylate, vinylformic acid and methyl methacrylate high-speed stirring 20-30min, obtains reaction solution A; The pre-reaction liquid of surplus is mixed with sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W and 60-70 DEG C stir 10-15min, obtain reaction solution B; Reaction solution B is slowly added dropwise to reaction solution A under 70-80 DEG C of condition, insulation reaction 2-4h, after cooling by pH regulator to 7-8, after filtration and get final product.
A preparation method for antibacterial water color oil polish, comprises the following steps:
(1) raw material is taken by weight, Rhizoma amorphophalli glucomannan and cm-chitosan are added to the water 60-80 DEG C and stir 0.5-1h, lauryl glucosyl and Semen arachidis hypogaeae protein 600-800r/min stirring 2-4h is added after cooling, filter in backward filtrate and add nano titanium oxide and ultrasonic disperse 5-10min, finally add polythene wax emulsion and amido silicon oil 1000-1500r/min stirring 15-30min, obtain aqueous promoter;
(2) aqueous promoter obtained in (1) and modifying cinepazid emulsion are jointly added in reactor, high-speed stirring 0.5-1h, filtration, packing, obtain antibacterial water color oil polish.
Advantage of the present invention is:
1. by titanate coupling agent modified benzene emulsion, improve the defect of water lustering oil mechanical property and weathering resistance, add the film-forming properties that Semen arachidis hypogaeae protein improves oil polish simultaneously, oil polish film is made both to have had good hardness, wear resistance, shock-resistance, water tolerance, corrosion resistance nature are superior, and have good tensile property and glossiness, and product has the anti-microbial property of high-efficiency broad spectrum simultaneously, the sanitation performance of goods can be promoted, be conducive to the health of user;
2. production and use procedure safety non-toxic do harm to pollution-free, environmental protection.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of antibacterial water color oil polish, is prepared from by the component raw material of following weight (kg):
Modifying cinepazid emulsion 70, cm-chitosan 0.3, Rhizoma amorphophalli glucomannan 0.15, nano titanium oxide 0.4, polythene wax emulsion 4, Semen arachidis hypogaeae protein 1.5, lauryl glucosyl 0.4, amido silicon oil 1.5, water 12;
Wherein modifying cinepazid emulsion is made up of the component raw material of following weight (kg):
Vinylbenzene 45, butyl acrylate 45, vinylformic acid 3, methyl methacrylate 12, sodium lauryl sulphate 4, emulsifier op-10 1.5, titanate coupling agent TMC-311W 1.5, sodium bicarbonate 5, initiator A PS 4, water 95;
Wherein the preparation method of modifying cinepazid emulsion is:
By sodium lauryl sulphate and emulsifier op-10 soluble in water, obtain pre-reaction liquid; The pre-reaction liquid getting 3/5 weight part adds vinylbenzene, butyl acrylate, vinylformic acid and methyl methacrylate high-speed stirring 30min, obtains reaction solution A; The pre-reaction liquid of surplus is mixed with sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W and 70 DEG C stir 10min, obtain reaction solution B; Reaction solution B is slowly added dropwise to reaction solution A under 80 DEG C of conditions, insulation reaction 2h, after cooling by pH regulator to 7-8, after filtration and get final product.
The preparation method of antibacterial water color oil polish comprises the following steps:
(1) raw material is taken by weight, Rhizoma amorphophalli glucomannan and cm-chitosan are added to the water 80 DEG C and stir 0.5h, lauryl glucosyl and Semen arachidis hypogaeae protein 800r/min stirring 4h is added after cooling, filter in backward filtrate and add nano titanium oxide and ultrasonic disperse 5min, finally add polythene wax emulsion and amido silicon oil 1500r/min stirring 15min, obtain aqueous promoter;
(2) aqueous promoter obtained in (1) and modifying cinepazid emulsion are jointly added in reactor, high-speed stirring 0.5h, filtration, packing, obtain antibacterial water color oil polish.
Through inspection, above-mentioned obtained product performance are as follows:
Glossiness: 78;
Wear resistance: 1200 times;
Water-intake rate: 12.4%;
Stability in storage: 6 months constant.
Claims (2)
1. an antibacterial water color oil polish, is characterized in that, it is obtained by the raw material of following weight parts:
Modifying cinepazid emulsion 60-80, cm-chitosan 0.2-0.4, Rhizoma amorphophalli glucomannan 0.1-0.2, nano titanium oxide 0.3-0.5, polythene wax emulsion 3-5, Semen arachidis hypogaeae protein 1-2, lauryl glucosyl 0.3-0.5, amido silicon oil 1-2, water 10-15;
Described modifying cinepazid emulsion is made up of the raw material of following weight part:
Vinylbenzene 40-50, butyl acrylate 40-50, vinylformic acid 3-4, methyl methacrylate 10-15, sodium lauryl sulphate 3-4, emulsifier op-10 1-1.5, titanate coupling agent TMC-311W 1-2, sodium bicarbonate 4-6, initiator A PS 3-4, water 80-100;
The preparation method of described modifying cinepazid emulsion is:
By sodium lauryl sulphate and emulsifier op-10 soluble in water, obtain pre-reaction liquid; The pre-reaction liquid getting 3/5-4/5 weight part adds vinylbenzene, butyl acrylate, vinylformic acid and methyl methacrylate high-speed stirring 20-30min, obtains reaction solution A; The pre-reaction liquid of surplus is mixed with sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W and 60-70 DEG C stir 10-15min, obtain reaction solution B; Reaction solution B is slowly added dropwise to reaction solution A under 70-80 DEG C of condition, insulation reaction 2-4h, after cooling by pH regulator to 7-8, after filtration and get final product.
2. the preparation method of a kind of antibacterial water color oil polish according to claim 1, is characterized in that, comprise the following steps:
(1) raw material is taken by weight, Rhizoma amorphophalli glucomannan and cm-chitosan are added to the water 60-80 DEG C and stir 0.5-1h, lauryl glucosyl and Semen arachidis hypogaeae protein 600-800r/min stirring 2-4h is added after cooling, filter in backward filtrate and add nano titanium oxide and ultrasonic disperse 5-10min, finally add polythene wax emulsion and amido silicon oil 1000-1500r/min stirring 15-30min, obtain aqueous promoter;
(2) aqueous promoter obtained in (1) and modifying cinepazid emulsion are jointly added in reactor, high-speed stirring 0.5-1h, filtration, packing, obtain antibacterial water color oil polish.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510329903.9A CN104910708A (en) | 2015-06-16 | 2015-06-16 | Antibacterial water-based gloss oil and preparation method thereof |
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| CN201510329903.9A CN104910708A (en) | 2015-06-16 | 2015-06-16 | Antibacterial water-based gloss oil and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106988156A (en) * | 2017-03-30 | 2017-07-28 | 天长市天达纸箱纸品厂 | A kind of preparation method of high-gloss water-proof corrugated case water lustering oil |
| CN107011743A (en) * | 2017-03-30 | 2017-08-04 | 天长市天达纸箱纸品厂 | A kind of preparation method of corrugated board water-repellent paint |
| CN107384201A (en) * | 2017-08-15 | 2017-11-24 | 南宁东印时代广告有限公司 | A kind of cigarette case printing oil polish and preparation method thereof |
| CN107489058A (en) * | 2017-09-21 | 2017-12-19 | 安徽宏洋包装集团有限公司 | A kind of preparation method of the nono calcium carbonate modified complex emulsions of coating for paper |
| CN108560262A (en) * | 2017-12-11 | 2018-09-21 | 江苏新瑞贝科技股份有限公司 | A kind of fastness to wet rubbing reinforcing agent and preparation method thereof |
| CN112956489A (en) * | 2020-10-30 | 2021-06-15 | 北京一撕得物流技术有限公司 | Antibacterial and antiviral water-based gloss oil and preparation method thereof |
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| CN1632022A (en) * | 2004-11-24 | 2005-06-29 | 广州电器科学研究院 | Aqueous buffing oil with shell/core structure |
| CN102943412A (en) * | 2012-11-14 | 2013-02-27 | 海南必凯水性涂料有限公司 | Wear-resistant high-gloss waterborne glazing oil and preparation method thereof |
| CN103087597A (en) * | 2013-01-21 | 2013-05-08 | 云南彩丰油墨有限公司 | Offset printing online water-based varnish applicable to UV (ultraviolet) code spraying and preparation method thereof |
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2015
- 2015-06-16 CN CN201510329903.9A patent/CN104910708A/en active Pending
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| CN103087597A (en) * | 2013-01-21 | 2013-05-08 | 云南彩丰油墨有限公司 | Offset printing online water-based varnish applicable to UV (ultraviolet) code spraying and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106988156A (en) * | 2017-03-30 | 2017-07-28 | 天长市天达纸箱纸品厂 | A kind of preparation method of high-gloss water-proof corrugated case water lustering oil |
| CN107011743A (en) * | 2017-03-30 | 2017-08-04 | 天长市天达纸箱纸品厂 | A kind of preparation method of corrugated board water-repellent paint |
| CN107384201A (en) * | 2017-08-15 | 2017-11-24 | 南宁东印时代广告有限公司 | A kind of cigarette case printing oil polish and preparation method thereof |
| CN107489058A (en) * | 2017-09-21 | 2017-12-19 | 安徽宏洋包装集团有限公司 | A kind of preparation method of the nono calcium carbonate modified complex emulsions of coating for paper |
| CN108560262A (en) * | 2017-12-11 | 2018-09-21 | 江苏新瑞贝科技股份有限公司 | A kind of fastness to wet rubbing reinforcing agent and preparation method thereof |
| CN112956489A (en) * | 2020-10-30 | 2021-06-15 | 北京一撕得物流技术有限公司 | Antibacterial and antiviral water-based gloss oil and preparation method thereof |
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Application publication date: 20150916 |