CN104910476A - Rubber composite material, composite board prepared from material and board technique - Google Patents
Rubber composite material, composite board prepared from material and board technique Download PDFInfo
- Publication number
- CN104910476A CN104910476A CN201510369854.1A CN201510369854A CN104910476A CN 104910476 A CN104910476 A CN 104910476A CN 201510369854 A CN201510369854 A CN 201510369854A CN 104910476 A CN104910476 A CN 104910476A
- Authority
- CN
- China
- Prior art keywords
- rubber
- composite
- parts
- regenerated rubber
- reclaimed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L17/00—Compositions of reclaimed rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a rubber composite material, a composite board prepared from the material and a board technique. The rubber composite material contains the following substances in parts by weight: 100 parts of regenerated rubber, 150-300 parts of gravel and 18.5-85 parts of rubber ingredient. The regenerated rubber is any one of whole tire regenerated rubber, tire tread regenerated rubber, ethylene propylene diene monomer regenerated rubber and butyl regenerated rubber. The rubber ingredient is a combination of at least 11 of stearic acid, zinc oxide, sulfur, accelerator TT, accelerator DM, accelerator M, N330 carbon black, N220 carbon black, paraffin, coumarone indene resin, zinc borate, tritolyl phosphate, anti-aging agent 4010NA and light calcium carbonate. By using the regenerated rubber and gravel as the main raw materials, the rubber composite material has the advantages of low price and low production cost. The regenerated rubber can adopt the whole tire regenerated rubber and tire tread regenerated rubber, thereby effectively changing waste tires into valuable substances and lowering the environmental pollution caused by the waste tires.
Description
Technical field
The present invention relates to a kind of rubber composite, the invention still further relates to the complete processing of composite sheet and the sheet material be made up of rubber composite.
Background technology
Mostly existing rubber combined sheet material, be that rubber and steel wire, rubber and fiber, rubber and pulverulent filler etc. are carried out compound and be prepared from.Compound for rubber and block stone not yet has report.Stone is as large size cake mass, after rubber combined, effectively can improve compressive property and the wear resisting property of composite sheet, can be used for mat formation bridge floor, road surface, reduce the thickness of pave-load layer, reduce facing weights, effectively avoid the defect phenomenon of existing road surface low temperature brittleness, temperature flowing, extend road surface, bridge floor work-ing life.
Summary of the invention
Technical problem to be solved by this invention is the deficiency overcoming above-mentioned prior art, provides the rubber composite that a kind of tensile modulus, mechanical property and resistance to fatigue are higher.
Technical problem to be solved by this invention is the deficiency overcoming above-mentioned prior art, provides one one kinds of lightweight, cheap, good springiness, damping performance excellences, the composite sheet of long service life, antifatigue cracking.
Technical problem to be solved by this invention is the deficiency overcoming above-mentioned prior art, provides a kind of complete processing of composite sheet.
The main technical schemes adopted according to rubber composite provided by the invention is: this rubber composite contains following material and weight part:
Reclaimed rubber 100 parts;
150 ~ 300 parts, stone;
Rubber ingredients 18.5 ~ 85 parts.
Rubber composite provided by the invention also adopts following attached technical scheme:
Described reclaimed rubber is any one in whole tire reclaim, tread reclaimed rubber, Ethylene Propylene Terpolymer reclaimed rubber or butyl reclaimed rubber.
Described rubber ingredients are the combination of at least 11 kinds in stearic acid, zinc oxide, Sulfur, promotor TT, altax, captax, N330 carbon black, N220 carbon black, paraffin, coumarone indene resin, zinc borate, Tritolyl Phosphate, antioxidant 4010NA and light calcium carbonate.
Described stone is any one or multiple combination in basalt, andesite, limestone.
Described rubber composite contains following material and weight part:
Described stone grain diameter is 6 ~ 20mm.
The main technical schemes adopted according to composite sheet provided by the invention is: comprise body, and described body contains following material and weight part:
Reclaimed rubber 100 parts;
150 ~ 300 parts, stone;
Rubber ingredients 18.5 ~ 85 parts.
Composite sheet provided by the invention also adopts following attached technical scheme:
The shape of described body is square, rectangle, rhombus, isosceles trapezoid or hexagon.
The thickness of described body is 10 ~ 50mm, and area is 0.01 ~ 4m
2.
The main technical schemes adopted according to the complete processing of composite sheet provided by the invention is: after being mixed with corresponding rubber ingredients by reclaimed rubber, mix with cleaning, dried stone again, load in mould, under the condition of temperature 140 ~ 180 DEG C, more than pressure 8MPa, through 10 ~ 40min curing molding, obtained composite sheet.
According to rubber composite provided by the invention compared with prior art tool have the following advantages: main raw material of the present invention is reclaimed rubber and stone, cheap, production cost is low, reclaimed rubber can adopt whole tire reclaim and tread reclaimed rubber, effectively waste tire can be turned waste into wealth, reduce junked tire and cannot recycle and pollution to environment.
According to composite sheet provided by the invention compared with prior art tool have the following advantages: the prices of raw and semifnished materials are cheap, good springiness, damping performance are excellent, for bridge floor of mating formation, road surface, reduce the thickness of pave-load layer, reduce facing weights, extend road surface, bridge floor work-ing life.
According to composite sheet provided by the invention complete processing compared with prior art tool have the following advantages: technique is simple, and step is few, and be not subject to ambient conditions impact, the process-cycle is short, and production efficiency is high.
Embodiment
Embodiment one
According to rubber composite embodiment provided by the invention, this rubber composite contains following material and weight part:
Reclaimed rubber 100 parts;
150 ~ 300 parts, stone;
Rubber ingredients 18.5 ~ 85 parts.
Described reclaimed rubber is any one in whole tire reclaim, tread reclaimed rubber, Ethylene Propylene Terpolymer reclaimed rubber or butyl reclaimed rubber.Described rubber ingredients are the combination of at least 11 kinds in stearic acid, zinc oxide, Sulfur, promotor TT, altax, captax, N330 carbon black, N220 carbon black, paraffin, coumarone indene resin, zinc borate, Tritolyl Phosphate, antioxidant 4010NA and light calcium carbonate.Described stone is any one or multiple combination in basalt, andesite, limestone.Described stone grain diameter is 6 ~ 20mm.The present embodiment is preferably 10mm.Main raw material of the present invention is reclaimed rubber and stone, and cheap, production cost is low, and reclaimed rubber can adopt whole tire reclaim and tread reclaimed rubber, can effectively be turned waste into wealth by waste tire, reduces junked tire and cannot recycle and pollution to environment.
According to the above embodiments of the present invention, described rubber composite contains following material and weight part:
Rubber composite preparation in the present invention has the advantages such as cheap, good springiness, damping performance are excellent.
Embodiment two
The present embodiment is roughly the same with above-described embodiment one, and difference is that rubber composite described in this enforcement contains following material and weight part:
Embodiment three
The present embodiment is roughly the same with above-described embodiment one, and difference is that rubber composite described in this enforcement contains following material and weight part:
Embodiment four
The present embodiment is roughly the same with above-described embodiment three, and difference is that rubber composite described in this enforcement contains following material and weight part:
Embodiment five
The present embodiment is roughly the same with above-described embodiment one, and difference is that rubber composite described in this enforcement contains following material and weight part:
Embodiment six
The present embodiment is roughly the same with above-described embodiment five, and difference is that rubber composite described in this enforcement contains following material and weight part:
Embodiment seven
The present embodiment is roughly the same with above-described embodiment one, and difference is that rubber composite described in this enforcement contains following material and weight part:
Embodiment eight
The present embodiment is roughly the same with above-described embodiment seven, and difference is that rubber composite described in this enforcement contains following material and weight part:
The obtained matrix material of above-mentioned 8 embodiments, shown in the performance test results following table.
The performance of each embodiment bridge floor paving block
Following examples are the embodiment of composite sheet
According to composite sheet provided by the invention, comprise body, described body is made up of the rubber composite described in above-described embodiment.The prices of raw and semifnished materials of the present invention are cheap, good springiness, damping performance are excellent, for bridge floor of mating formation, road surface, reduce the thickness of pave-load layer, reduce facing weights, extend road surface, bridge floor work-ing life.
The shape of described body is square, rectangle, rhombus, isosceles trapezoid or hexagon.
The thickness of described body is 10 ~ 50mm, and the present embodiment is preferably 25mm, and area is 0.01 ~ 4m
2, the present embodiment is preferably 0.5m
2.
Following examples are the complete processing embodiment of composite sheet
Complete processing embodiment one
By whole tire reclaim and rubber ingredients according to the formula of above-mentioned rubber composite embodiment one, make uniform reclaimed rubber rubber unvulcanizate through mixing.Be the basalt of 12mm by grain diameter, after cleaning, fully dry.Then, after 148 parts of reclaimed rubber rubber unvulcanizates are mixed with 150 parts of basalt, be placed in and be of a size of thickness 20mm, area 0.01m
2square die cavity in.Temperature 140 DEG C, pressure is under the condition of 8MPa, and through 10min sulfidization molding, can obtain thickness is 10mm, and area is 0.01m
2square rubber stone composite sheet.
Complete processing embodiment two
By whole tire reclaim and rubber ingredients according to the formula of above-mentioned rubber composite embodiment two, make uniform reclaimed rubber rubber unvulcanizate through mixing.Be the andesite of 6mm by grain diameter, after cleaning, fully dry.Then, after being mixed with 300 parts of basalt by 171 parts of reclaimed rubber rubber unvulcanizates, be placed in and be of a size of thickness 10mm, area is about 4m
2rhombus die cavity in.Temperature 150 DEG C, pressure is under the condition of 8MPa, and through 20min sulfidization molding, can obtain thickness is 10mm, and area is 4m
2square rubber stone composite sheet.
Complete processing embodiment three
By tread reclaimed rubber and rubber ingredients according to the formula of above-mentioned rubber composite embodiment three, make uniform reclaimed rubber rubber unvulcanizate through mixing.Be the limestone of 8mm by grain diameter, after cleaning, fully dry.Then, by 153 parts of reclaimed rubber rubber unvulcanizates and 200 parts of basalt stone limestones, be placed in and be of a size of thickness 10mm, area 1m
2square die cavity in.Temperature 140 DEG C, pressure is under the condition of 12MPa, and through 15min sulfidization molding, can obtain thickness is 10mm, and area is 1m
2square rubber stone composite sheet.
Complete processing embodiment four
By Ethylene Propylene Terpolymer reclaimed rubber and rubber ingredients according to the formula of above-mentioned rubber composite embodiment five, make uniform reclaimed rubber rubber unvulcanizate through mixing.Be the basalt of 10mm by grain diameter, after cleaning, fully dry.Then, after 163.4 parts of reclaimed rubber rubber unvulcanizates are mixed with 250 parts of basalt, be placed in and be of a size of thickness 15mm, area 0.01m
2square die cavity in.Temperature 160 DEG C, pressure is under the condition of 10MPa, and through 30min sulfidization molding, can obtain thickness is 15mm, and area is 0.01m
2square rubber stone composite sheet.
Complete processing embodiment five
By butyl reclaimed rubber and rubber ingredients according to the formula of above-mentioned rubber composite embodiment seven, make uniform reclaimed rubber rubber unvulcanizate through mixing.Be the basalt of 20mm by grain diameter, after cleaning, fully dry.Then, after 128 parts of reclaimed rubber rubber unvulcanizates are mixed with 180 parts of basalt, be placed in and be of a size of thickness 30mm, area 0.25m
2square die cavity in.Temperature 180 DEG C, pressure is under the condition of 10MPa, and through 20min sulfidization molding, can obtain thickness is 30mm, and area is 0.25m
2square rubber stone composite sheet.
The obtained composite sheet of above-mentioned 5 embodiments, the performance test results is as shown in the table.
Although illustrate and describe embodiments of the invention, for the ordinary skill in the art, be appreciated that and can change these embodiments without departing from the principles and spirit of the present invention, scope of the present invention is by claims and equivalents thereof.
Claims (10)
1. a rubber composite, is characterized in that: this rubber composite contains following material and weight part:
Reclaimed rubber 100 parts;
150 ~ 300 parts, stone;
Rubber ingredients 18.5 ~ 85 parts.
2. rubber composite according to claim 1, is characterized in that: described reclaimed rubber is any one in whole tire reclaim, tread reclaimed rubber, Ethylene Propylene Terpolymer reclaimed rubber or butyl reclaimed rubber.
3. rubber composite according to claim 2, is characterized in that: described rubber ingredients are the combination of at least 11 kinds in stearic acid, zinc oxide, Sulfur, promotor TT, altax, captax, N330 carbon black, N220 carbon black, paraffin, coumarone indene resin, zinc borate, Tritolyl Phosphate, antioxidant 4010NA and light calcium carbonate.
4. rubber composite according to claim 1, is characterized in that: described stone is any one or multiple combination in basalt, andesite, limestone.
5. rubber composite according to claim 3, is characterized in that: described rubber composite contains following material and weight part:
6. the rubber composite according to claim 1-4 any one, is characterized in that: described stone grain diameter is 6 ~ 20mm.
7. a composite sheet, comprises body, it is characterized in that: described body is made up of the rubber composite described in above-mentioned 1-6 any one.
8. composite sheet according to claim 7, is characterized in that: the shape of described body is square, rectangle, rhombus, isosceles trapezoid or hexagon.
9. composite sheet according to claim 7, is characterized in that: the thickness of described body is 10 ~ 50mm, and area is 0.01 ~ 4m
2.
10. process the complete processing of composite sheet described in claim 7-9 any one for one kind, it is characterized in that: after reclaimed rubber is mixed with corresponding rubber ingredients, mix with cleaning, dried stone again, load in mould, under the condition of temperature 140 ~ 180 DEG C, more than pressure 8MPa, through 10 ~ 40min curing molding, obtained composite sheet.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510369854.1A CN104910476A (en) | 2015-06-29 | 2015-06-29 | Rubber composite material, composite board prepared from material and board technique |
| PCT/CN2015/000514 WO2017000088A1 (en) | 2015-06-29 | 2015-07-17 | Rubber composite material and composite panel made from said material, and panel process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510369854.1A CN104910476A (en) | 2015-06-29 | 2015-06-29 | Rubber composite material, composite board prepared from material and board technique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104910476A true CN104910476A (en) | 2015-09-16 |
Family
ID=54079951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510369854.1A Pending CN104910476A (en) | 2015-06-29 | 2015-06-29 | Rubber composite material, composite board prepared from material and board technique |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN104910476A (en) |
| WO (1) | WO2017000088A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105174848A (en) * | 2015-09-24 | 2015-12-23 | 北京大陆益通环保科技有限公司 | Rubber concrete material and composite board manufactured from same and board technology |
| CN106117817A (en) * | 2016-06-24 | 2016-11-16 | 安徽昊博健身器材有限公司 | A kind of rubber buffer for outdoor fitness equipment |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1393420A (en) * | 2001-06-27 | 2003-01-29 | 马奔 | Metal rubber concrete and its preparing process |
| CN101173069A (en) * | 2007-10-16 | 2008-05-07 | 浙江绿环橡木有限公司 | Restored rubber produced hardwood sheet material and method for producing the same |
| CN101654040A (en) * | 2009-09-21 | 2010-02-24 | 平顶山市鸿鑫达贸易有限公司 | Environmental protection inner tube and preparation method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093608B (en) * | 2010-12-30 | 2012-11-21 | 金陵科技学院 | Reclaimed rubber/coal ash composite material and preparation method thereof |
| CN104418546A (en) * | 2013-08-23 | 2015-03-18 | 张学花 | Hybrid concrete and preparation method thereof |
| CN103508705B (en) * | 2013-08-30 | 2016-05-04 | 江南大学 | A kind of ejection-type ductility PP fiber reinforced cement-based composite material and preparation method thereof |
-
2015
- 2015-06-29 CN CN201510369854.1A patent/CN104910476A/en active Pending
- 2015-07-17 WO PCT/CN2015/000514 patent/WO2017000088A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1393420A (en) * | 2001-06-27 | 2003-01-29 | 马奔 | Metal rubber concrete and its preparing process |
| CN101173069A (en) * | 2007-10-16 | 2008-05-07 | 浙江绿环橡木有限公司 | Restored rubber produced hardwood sheet material and method for producing the same |
| CN101654040A (en) * | 2009-09-21 | 2010-02-24 | 平顶山市鸿鑫达贸易有限公司 | Environmental protection inner tube and preparation method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105174848A (en) * | 2015-09-24 | 2015-12-23 | 北京大陆益通环保科技有限公司 | Rubber concrete material and composite board manufactured from same and board technology |
| CN106117817A (en) * | 2016-06-24 | 2016-11-16 | 安徽昊博健身器材有限公司 | A kind of rubber buffer for outdoor fitness equipment |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017000088A1 (en) | 2017-01-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101319061B (en) | Tire tread glue formulation adapted for various pavement conditions | |
| CN101967048A (en) | Rubber modified asphalt mixture and preparation and construction methods thereof | |
| CN107501967B (en) | Asphalt modifier, preparation method and asphalt mixture containing asphalt modifier | |
| CN101323509A (en) | Rubber modified stable grain material and preparing and construction method | |
| CN103205028A (en) | Organic clay rubber composite material for laminated rubber supporting seat and preparation process thereof | |
| CN111622043A (en) | Drainage noise reduction type asphalt pavement paving structure | |
| CN104910476A (en) | Rubber composite material, composite board prepared from material and board technique | |
| CN105601990A (en) | Modified waste tire rubber powder and preparation method thereof | |
| CN104893041A (en) | Cutting-resistant conveying belt covering glue and preparation method thereof | |
| CN102634082A (en) | Tire tread base rubber composition and preparation method | |
| CN102093608B (en) | Reclaimed rubber/coal ash composite material and preparation method thereof | |
| CN111574186B (en) | Rapid repair material for bridge expansion joint and preparation method thereof | |
| CN107141530B (en) | A kind of bionical tyre surface and preparation method thereof | |
| CN107793069A (en) | A kind of construction refuse regenerated pavior brick and preparation method thereof | |
| CN1944317A (en) | Formula for producing color tile from casting waste sand and its producing method | |
| CN103951318A (en) | Epoxy anti-skidding wearing layer structure of pavement | |
| CN102815880B (en) | A kind of technique utilizing saponified residue brickmaking | |
| CN101665599A (en) | High-strength environmentally-friendly rubber powder rubber plate and preparation method thereof | |
| CN110698869A (en) | Light durable asphalt-based composite material and preparation method thereof | |
| CN105174848A (en) | Rubber concrete material and composite board manufactured from same and board technology | |
| CN102260396A (en) | Gull rock polyvinyl chloride-flyash composite material | |
| AU2021106090A4 (en) | Rubber Concrete Material | |
| CN1225429C (en) | One-pass formed composite pulverized coal ash material and method for manufacturing the same | |
| CN112408856A (en) | Environment-friendly pavement rapid repairing material and preparation method thereof | |
| CN100590261C (en) | Construction method for highway for load bearing vehicle |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150916 |
|
| RJ01 | Rejection of invention patent application after publication |