CN104909520A - MABR-MBR combined type sewage treatment device and treatment method - Google Patents
MABR-MBR combined type sewage treatment device and treatment method Download PDFInfo
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Abstract
The invention belongs to the technical field of sewage treatment, and discloses an MABR-MBR combined type sewage treatment device. The device comprises a pre-treatment unit, an MABR unit, an MBR unit and a backflushing unit matched with the MBR unit, wherein the four units are arranged along a sewage flowing direction. The invention further discloses a control method thereof. The effect of removing nitrogen and phosphorous is well realized through the sufficient combination of advantages of two membrane reactors. Since the bubbleless aeration is adopted in an MABR pond, the utilization rate of the oxygen is high and nearly can achieve 100%. Since the mass transfer range of the oxygen is small, denitrifying bacteria and denitrifying phosphate-accumulating organism are mainly existent in the water to finish denitrification and phosphorous releasing process of the nitrate, and the performance of removing nitrogen and phosphorous in the next stage is strengthened. After entering an aerobic MBR pond, the aerobic bacteria further remove residual nitrite and ammonia nitrogen, and the aerobic phosphorous-accumulating bacteria finish the phosphorous removal work. Through the previous treatment of the MABR, the volumetric loading of the MBR is reduced.
Description
Technical field
The present invention relates to technical field of sewage, particularly relate to a kind of MABR and MBR combined type waste disposal plant and treatment process.
Background technology
As shown in Figure 1, membrane aerated bioreactor (being usually called for short MABR) is a type of membrane bioreactor, this reactor is a kind of passing through to oxygenation in the hollow-fibre membrane cavity 100 of hydrophobic, air-permeability, oxygen and pollutent form concentration difference near microbial film, centered by film chamber, both respectively incorgruous diffusions with ecto-entad from inside to outside, make the organic pollutant in sewage obtain a kind of sewage disposal technology of degrading by the metabolic consumption dissolved oxygen of microorganism in microbial film.The process that MABR system removes pollutent can be divided into following four steps: first, pollutent in water body and the anerobe in current react, make that a part of phosphoric acid salt is adsorbed, itrogenous organic substance is degraded to ammonia nitrogen, second, pollutent after degraded is with current and microbial film making contact, under concentration difference drives, spread to biological face, oxygen externally spreads by film chamber simultaneously; 3rd, pollutent is degraded to nitrate NO by metabolism by the aerobic bacteria in microbial film or double oxygen bacterium further
3 -, nitrite NO
2 -deng; 4th, the pollutent after secondary degraded enters anaerobic zone again with current, and the nitrate after conversion, nitrite are reduced into N
2, release reaches efficiencies of nitrogen removal.This reactor anoxic and coexisting of anaerobic environment also make Denitrifying Phosphate Accumulating Organisms be able to enrichment, while denitrogenation, go back part that can be removed phosphorus.
When bubble-free aeration avoids traditional aeration, in sewage, volatile substances enters air as toluene, phenol with bubble and to environment, can not produce foam due to the existence of tensio-active agent simultaneously.By foamless oxygen-supplying, oxygen transfer efficiency is greatly improved, and almost can reach 100%, and working cost also can reduce.Meanwhile, gas-liquid two-phase is using film as boundary, and the control of aerating system can be more flexible.
At present this reactor Problems existing is exactly MABR when being used alone, although there are some researches show that reactor can carry out nitrification and denitrification simultaneously, phosphor-removing effect is not good.
Film-separation biological reactor (MBR) is a kind of new and effective sewage treatment process combined with membrane filtration technique by biologic treating technique.It replaces traditional biologic treating technique end second pond with membrane module, makes to keep high reactivity sludge concentration in bio-reactor, improves biological treatment organic loading, reduces surplus sludge volume by keeping low sludge loading.Under continuous aeration condition, the aerobic bacteria in active sludge is used for autophage to a pending organic pollutant part, and a part is degraded to small-molecule substance and removes.Through the wastewater effluent bacterium of membrane biological reactor process process, suspended substance and turbidity close to zero, can also retain the contaminants of biological origin such as fecal coliform, the water outlet after process can direct reuse after sterilization.
MBR technique completes roughly divides as follows to the removal of pollutent: first, the sewage entering MBR reactor directly contacts with active sludge, continuous print aeration is not only continuously aerobic bacteria oxygenation in granule sludge, also increase the contact-impact probability of pollutent and bacterium, aerobic bacteria carries out consuming using pollutent as the nutritive substance needed for own metabolism and degrades; The second, under the suction function of producing water pump, the water after process is discharged by micropore on membrane module, and granule sludge stays on and to react in pond, and this may cause the accumulation of nitrifier, makes reactor adapted process high ammonia-nitrogen wastewater.There are some researches show, at high ammonia-nitrogen wastewater process Fang Ming, MBR reactor can reach good treatment effect.
But the utilization ratio of oxygen is too low when being used alone MBR, most oxygen is diffused in air by bubble, and aerating system energy consumption is high.The oxygen of trace is only had to be utilized by Institute of Micro-biology, easily foam is produced when there being tensio-active agent in waste water, not easily remove, and due to the raising of sludge concentration in aeration tank, the problem of fouling membrane often can be there is again in actual moving process, the shortcomings such as need frequent rinsing membrane module, the life-span that therefore can there is again film is short, and maintenance cost is high.
Summary of the invention
The object of the invention is the technological deficiency for existing in prior art, and a kind of MABR and MBR combined type waste disposal plant and treatment process thereof are provided.
The technical scheme adopted for realizing object of the present invention is:
A kind of MABR and MBR combined type waste disposal plant, comprises the pretreatment unit set gradually along drainage flow direction, MABR unit and MBR unit, and with the back flushing unit of described MBR units match.
Described pretreatment unit is the grid, equalizing tank and the hair filter that set gradually, or equalizing tank and hair filter.
Described MABR unit comprises pond body, and immersion is fixedly installed on hydrophobic, air-permeability microporous membrane assembly in the body of described pond or the fine and close MABR membrane module of ventilation property, and be communicated with described MABR membrane module aerating system.
Described MBR unit comprises pond body, and immersion is arranged on the hydrophilic microporous MBR membrane module in the body of described pond, is arranged on the aeration devices bottom the body of described pond and shore pipe, and is serially connected in the water transfer pump on the water producing pipe of described MBR membrane module.
Described back flushing unit comprise be communicated with water transfer pump water outlet in order to store or buffer memory produces the water tank of water, controlled described water tank can be connected the backwash that is communicated with water transfer pump water-in to intake branch road, and can the controlled backwash branch road that water transfer pump water outlet is communicated with water producing pipe.
Described aerating system comprises air compressor machine, be communicated with described in the inlet pipe of air compressor machine air outlet to one end, film chamber of described MABR membrane module, be serially connected in the gas meter in described inlet pipe, tensimeter and air inlet electromagnetic valve, and the escape pipe be communicated with the film chamber the other end and be serially connected in pressure release valve on described escape pipe.
Adopt a treatment process for waste disposal plant, comprise the following steps:
1) waste water through pretreatment unit process is introduced in MABR reaction tank, by aerating system with the form of foamless oxygen-supplying to aeration in the film chamber of MABR membrane module, oxygen spreads from inside to outside under the driving of concentration difference, for being attached to the microorganism oxygen supply on the membranous wall of MABR membrane module, MABR membrane module and near zone are formed aerobic, double oxygen, anoxic three levels, realize aerobic bacteria, hold concurrently oxygen bacterium and anerobe and gathering denitrifying polyP bacteria coexists, also part nitric nitrogen is removed by denitrification while organics removal and ammonia nitrogen, enhance next stage MBR denitrogenation dephosphorizing performance, operationally, general aeration pressure is adjusted to below aeration film bubble point used and close to bubble point, PH controls 6.5 ~ 8.5, hydraulic detention time controls when about 8 ~ 15h, reactor for treatment effect reaches optimum regime,
2) waste water through MABR process enters MBR reaction tank, aeration is carried out at the bottom of pond, remaining organic carbon, nitre nitrogen, nitrite nitrogen and the phosphoric acid salt process of aerobic bacteria in active sludge in water is on last stage removed further, last under MBR membrane module crown_interception, sewage obtains final purification.The experiment proved that, in this stage, to make in this pond by regulating aeration control dissolved oxygen that Dissolved Oxygen concentration Control controls 7 ~ 8.5 at 3.5 ~ 5.5mg/L, PH, hydraulic detention time control 5 ~ 15h, sludge concentration at about 5000 ~ 10000mg/L time, reactor for treatment effect reaches optimum regime.
Described sewage is the high nitrogen phosphorus waste water of sanitary sewage and biochemical degradation.
Compared with prior art, the invention has the beneficial effects as follows:
1, the present invention fully combines the advantage of two kinds of membrane reactors, well can realize denitrogenation dephosphorizing.This is that the utilization ratio of oxygen is very high, almost can reach 100% owing to adopting bubble-free aeration in MABR pond.Because the mass transfer scope of oxygen is very little, in water, mainly there is denitrifying bacteria and Denitrifying Phosphate Accumulating Organisms, complete nitrate denitrification and release phosphorus process, enhancing the performance of next stage denitrogenation dephosphorizing.After entering aerobic MBR pond, aerobic bacteria removes nitrite nitrogen residual in water and ammonia nitrogen further, and aerobic phosphorous accumulating bacterium completes dephosphorization work.By the process in MABR early stage, decrease the volumetric loading of MBR, volumetric loading reduces, and corresponding energy consumption, material consumption, depreciation etc. all can correspondingly reduce, and two film processing unit substantially increases effluent quality, process water directly can carry out reuse as non-municipal usage of drinking.
2, MABR and MBR reactor coupling, the link of sludge reflux can be saved, deposit this is because the aerobic-anaerobic of MABR own is double, synchronous nitration and denitrification can be realized, and the MBR effect of damming efficiently ensure that the stable existence of high-concentration activated sludge in pond, sludge concentration can up to 12000mg/L, and this also makes the output of excess sludge little, saves sludge treatment expense.
3, eliminate multiple preprocessing unit, save floor space, save capital cost and process energy consumption.
4, can adopt Automated condtrol, operation, convenient management, working cost is low, and effluent quality is good.
Accompanying drawing explanation
Figure 1 shows that the structure function schematic diagram of MABR;
Figure 2 shows that the structural representation of MABR and MBR combined type waste disposal plant of the present invention.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
As shown in Figure 2, MABR and MBR combined type waste disposal plant of the present invention, comprises the pretreatment unit set gradually along drainage flow direction, MABR unit and MBR unit, and for the back flushing unit of MBR unit back flushing.Specifically, described pretreatment unit is the grid, equalizing tank and the hair filter that set gradually, or equalizing tank and hair filter.
Described MABR unit comprises pond body 1, and immersion is fixedly installed on hydrophobic, air-permeability micro porous hollow MABR membrane module in the body of described pond or the fine and close hollow MABR membrane module 3 of ventilation property, and the aerating system be communicated with described MABR membrane module.In the body of MABR pond, be provided with the multiple flow deflectors 5 guiding pending lower circuitous flow waterborne simultaneously, described MABR membrane module is arranged in point pond that is partitioned into by flow deflector accordingly, enter pond body in through control valve 13 through pretreated sewage under the effect of pump 7, in the production of reality, aquifer yield is general larger, when multiple MABR membrane module is set, if flow deflector there will not be slough, and microorganism is more thorough to process organic in sewage.Meanwhile, flow deflector also can be arranged in the body of MBR pond.
Described aerating system comprises air compressor machine 9, be communicated with described in the inlet pipe of air compressor machine air outlet to one end, film chamber of described MABR membrane module, be serially connected in the gas meter 11 in described inlet pipe, tensimeter 12 and air inlet electromagnetic valve 10, and the escape pipe be communicated with the film chamber the other end and be serially connected in pressure release valve 14 on described escape pipe.
Described MBR unit comprises pond body 2, immersion is arranged on the hydrophilic Breathable microporous MBR film membrane module 4 in the body of described pond, and the aeration devices be arranged on bottom the body of described pond and shore pipe, and be serially connected in the water transfer pump on the water producing pipe of described MBR membrane module.Preferably, the pond body of described MABR unit and the pond body of MBR are disposed adjacent, and the training wall 6 that passage is left in a needs bottom carries out distinguishing, be communicated with bottom the pond body of two unit, sewage case process direction unrestricted flow, effectively reduces the pump housing and uses, save electric power.
The aerated conduit as aeration devices describedly comprise air compressor machine 8 with the aeration devices of MBR pond body, being connected air compressor machine and MBR pond and go deep into the perforated pipe of MBR film unit bottom through pool wall, described perforated pipe is installed Duct fixing clamp and is communicated with aerated conduit at the bottom of pond.Described aerated conduit is provided with gas meter 17, control valve 16 and tensimeter 15.MABR and MBR arranges independent aerating system respectively, can provide separately, effectively control the maximization of integral device, break the whole up into parts and be beneficial to energy-saving and emission-reduction for each oxygen consuming amount.
Described back flushing unit comprise be communicated with water transfer pump 28 water outlet in order to store or buffer memory produces the water tank 27 of water, controlled described water tank can be communicated with the backwash be communicated with drainage pump water-in to intake branch road, and can the controlled backwash branch road that water transfer pump water outlet is communicated with water producing pipe, specifically, namely by valve 18,19,21,23,24,26,29, and vacuum breaker 22 carrys out the switching of water production control and backwash branch road, be provided with pressure warning unit 20 and 25 to carry out pressure monitor simultaneously, this no longer launches to describe at this similarly to the prior art.
MABR and MBR integral type sewage treatment unit of the present invention, achieve the efficient combination of membrane separation technique and biologic treating technique, there is good suitability to influent load change, also improve the efficiency of oxidation operation and nitrification and denitrification simultaneously, reduce power consumption.It is simple to operate, is easy to realize automatic control, manages convenient.Two kinds of films are applied to a technique, with hydrophobic hollow-fibre membrane for biofilm carrier, with the second pond in hydrophilic microfiltration membrane replacement traditional technology and conventional absorbtion filtering unit, suspended matter in waste water, colloidalmaterial, microorganism species are thoroughly separated with the water purified, high-quality is with stable more to make effluent quality, and the process of two film also ensure that the effect of water outlet.Combine simultaneously, hydraulic detention time can shorten, and while reduction energy consumption, processing efficiency is improved, and additional membrane module floor space is little, easy to operate, and the advantages such as flexible operation make this technology have good application prospect.
Adopt device water technology of the present invention as follows:
1) waste water through pretreatment unit process is introduced in MABR reaction tank, by aerating system with the form of foamless oxygen-supplying to aeration in the film chamber of MABR membrane module, oxygen spreads from inside to outside under the driving of concentration difference, for being attached to the microorganism oxygen supply on the membranous wall of MABR membrane module, MABR membrane module and near zone are formed aerobic, double oxygen, anoxic three levels, achieve aerobic bacteria, hold concurrently oxygen bacterium and anerobe and gathering denitrifying polyP bacteria coexists, also part nitric nitrogen is removed by denitrification while organics removal and ammonia nitrogen, enhance next stage MBR denitrogenation dephosphorizing performance.Operationally, generally aeration pressure is adjusted to below aeration film bubble point used and close to bubble point, when PH controls 6.5 ~ 8.5, hydraulic detention time controls at about 8 ~ 15h, reactor for treatment effect reaches optimum regime;
2) waste water through MABR process enters MBR reaction tank, aeration is carried out at the bottom of pond, remaining organic carbon, nitre nitrogen, nitrite nitrogen and the phosphoric acid salt process of aerobic bacteria in active sludge in water is on last stage removed further, last under MBR membrane module crown_interception, sewage obtains final purification.The experiment proved that, in this stage, to make in this pond by regulating aeration control dissolved oxygen that Dissolved Oxygen concentration Control controls 7 ~ 8.5 at 3.5 ~ 5.5mg/L, PH, hydraulic detention time control 5 ~ 15h, sludge concentration at about 5000 ~ 10000mg/L time, reactor for treatment effect reaches optimum regime.
Wherein, described sewage is applicable to sanitary sewage and can the waste water of biochemical treatment containing high nitrogen phosphorus etc.
Embodiment 1
Adopt the MABR-MBR Integral waste water treatment unit of structure as shown in Figure 2, pass into pretreated sanitary sewage, what sanitary sewage adopted is the shower waste of certain bath center, its water-quality guideline is: COD:140mg/L, NH3-N:42mg/L, SS:45mg/L, LAS:6.2mg/L, MABR membrane module material is polyvinylidene difluoride (PVDF) (PVDF), internal diameter 0.4mm, external diameter 0.45mm, MBR membrane module material is identical with MABR film, aperture is 0.1um, and membrane flux is 16L/ (m
2h).First utilize intake pump that pretreated water is squeezed into MABR pond, simultaneously to MABR film cavity aeration, aeration is pressed in about 0.07 ~ 0.1MPa, PH controls 7.5 ~ 8, hydraulic detention time controls at 8h, water after the process of MABR film enters MBR pond by training wall, aeration is carried out at the bottom of pond, regulate aeration rate make Dissolved Oxygen concentration Control at 3 ~ 4mg/L, PH 7 ~ 8, hydraulic detention time controls in 6h, sludge concentration at 4500 ~ 5500mg/L, shore pipe is set in the bottom of MBR reactor, by excess sludge periodic exhaustion.Water quality after water outlet is: COD:<20mg/L, NH
3-n:<3mg/L, SS:<7mg/L, LAS:<0.2mg/L, the clearance of each index is: COD:85%, NH
3-n:92%, SS:84%, LAS:96%.Water quality requirement during effluent quality reaches " urban sewage reutilization urban reclaimed water water quality " (GB/T 18920-2002).
Embodiment 2
Treatment unit is identical with embodiment 1.Water inlet adopts the Water in landscape lake that pretreated eutrophication is serious, and its water-quality guideline is COD:83mg/L, TP:0.23mg/L, TN:13mg/L, NH
3-n:0.8mg/L.Operation condition and embodiment 1 basically identical: MABR pond, aeration is pressed in about 0.07 ~ 0.1MPa, and PH controls 7.5 ~ 8.5, and hydraulic detention time controls at 8h; MBR pond, regulate aeration rate make Dissolved Oxygen concentration Control at 3.5 ~ 4.5mg/L, PH 7.5 ~ 8, hydraulic detention time controls in 6h, sludge concentration at 4000 ~ 5000mg/L.Under normal temperature, after plant running is stable, its effluent index is COD:<11mg/L, TP:<0.08mg/L, TN:<2.3mg/L, NH3-N:<0.2mg/L.
Embodiment 3
Treatment unit is identical with embodiment 1.Water inlet adopts pretreated corn starch wastewater, and its water-quality guideline is COD:8350mg/L, NH
3-n:13mg/L, TN:210mg/L, SS:2200mg/L, PO
4-: 48mg/L, PH:3.4.Operation condition is basically identical with embodiment 1 except following: MABR pond, and aeration is pressed in about 0.07 ~ 0.1MPa, and add NaOH and make PH control 7.5 ~ 8.5, hydraulic detention time controls at 12h; MBR pond, Dissolved Oxygen concentration Control at 3.5 ~ 4mg/L, PH 7.5 ~ 8, hydraulic detention time controls in 9h, sludge concentration at 6000 ~ 9000mg/L.After plant running is stable, its effluent index is COD:<50mg/L, NH3-N:<2.3mg/L, TN:<20mg/L, SS:<30mg/L, PO
4-: <2mg/L, PH:7.1.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (8)
1. a MABR and MBR combined type waste disposal plant, is characterized in that, comprises the pretreatment unit set gradually along drainage flow direction, MABR unit and MBR unit, and with the back flushing unit of described MBR units match.
2. waste disposal plant as claimed in claim 1, it is characterized in that, described pretreatment unit is the grid, equalizing tank and the hair filter that set gradually, or equalizing tank and hair filter.
3. waste disposal plant as claimed in claim 1, it is characterized in that, described MABR unit comprises pond body, and immersion is fixedly installed on hydrophobic, air-permeability microporous membrane assembly in the body of described pond or the fine and close MABR membrane module of ventilation property, and be communicated with described MABR membrane module aerating system.
4. waste disposal plant as claimed in claim 1, it is characterized in that, described MBR unit comprises pond body, immersion is arranged on the hydrophilic microporous MBR membrane module in the body of described pond, be arranged on the aeration devices bottom the body of described pond and shore pipe, and be serially connected in the water transfer pump on the water producing pipe of described MBR membrane module.
5. waste disposal plant as claimed in claim 4, it is characterized in that, described back flushing unit comprise be communicated with water transfer pump water outlet in order to store or buffer memory produces the water tank of water, controlled described water tank can be connected the backwash that is communicated with water transfer pump water-in to intake branch road, and can the controlled backwash branch road that water transfer pump water outlet is communicated with water producing pipe.
6. waste disposal plant as claimed in claim 3, it is characterized in that, described aerating system comprises air compressor machine, be communicated with described in the inlet pipe of air compressor machine air outlet to one end, film chamber of described MABR membrane module, be serially connected in the gas meter in described inlet pipe, tensimeter and air inlet electromagnetic valve, and the escape pipe be communicated with the film chamber the other end and be serially connected in pressure release valve on described escape pipe.
7. adopt a treatment process for waste disposal plant as claimed in claim 1, it is characterized in that, comprise the following steps:
1) waste water through pretreatment unit process is introduced in MABR reaction tank, by aerating system with the form of foamless oxygen-supplying to aeration in the film chamber of MABR membrane module, oxygen spreads from inside to outside under the driving of concentration difference, for being attached to the microorganism oxygen supply on the membranous wall of MABR membrane module, MABR membrane module and near zone is made to form aerobic, hold concurrently oxygen, anoxic three levels, wherein, by below aeration air pressure adjustment to aeration film bubble point used and close to bubble point, PH controls 6.5 ~ 8.5, hydraulic detention time controls at 8 ~ 15h;
2) waste water through MABR process enters MBR reaction tank, aeration is carried out bottom the body of pond, remaining organic carbon, nitre nitrogen, nitrite nitrogen and the phosphoric acid salt process of aerobic bacteria in active sludge in water is on last stage removed further, last under MBR membrane module crown_interception, sewage obtains final purification, in this stage, to make in this pond by regulating aeration control dissolved oxygen that Dissolved Oxygen concentration Control controls 7 ~ 8.5 at 3.5 ~ 5.5mg/L, PH, hydraulic detention time controls at 5 ~ 15h, sludge concentration is at 5000 ~ 10000mg/L.
8. treatment process as claimed in claim 7, is characterized in that, described sewage is the high nitrogen phosphorus waste water of sanitary sewage and biochemical degradation.
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