CN104909470A - Pre-treatment device and treatment method of dilute water - Google Patents

Pre-treatment device and treatment method of dilute water Download PDF

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Publication number
CN104909470A
CN104909470A CN201510313529.3A CN201510313529A CN104909470A CN 104909470 A CN104909470 A CN 104909470A CN 201510313529 A CN201510313529 A CN 201510313529A CN 104909470 A CN104909470 A CN 104909470A
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CN
China
Prior art keywords
staving
dilution water
lime
liming
pretreatment unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510313529.3A
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Chinese (zh)
Inventor
江迎春
徐军
杨越峰
陈志明
王永丰
柯丞东
沈剑锋
傅阿二
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SHAOXING WATER MAKING CO Ltd
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SHAOXING WATER MAKING CO Ltd
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Application filed by SHAOXING WATER MAKING CO Ltd filed Critical SHAOXING WATER MAKING CO Ltd
Priority to CN201510313529.3A priority Critical patent/CN104909470A/en
Publication of CN104909470A publication Critical patent/CN104909470A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a pre-treatment device and a treatment method of dilute water, and relates to the technical field of water treatment. The pre-treatment device of the dilute water comprises a barrel body, the barrel body is provided with a dilute water inlet, a lime inlet, a lime water outlet, and a wastewater discharge outlet, a mixing shaft driven by a motor is arranged in the barrel body, and a mixing paddle is arranged on the mixing shaft. The dilute water in a lime system is pre-treated through the treatment device, and the trace carbonate contained in the dilute water is removed in advance in coordination with the specific mixing speed and reaction time in the treatment process, the environment of producing calcium carbonate in the pipe wall is blocked, and the problems of pipeline scaling and blocking are solved from the source; and the pretreatment device is simple in structure, reasonable in design, low in investment cost, and easy to popularize and use.

Description

The pretreatment unit of dilution water and treatment process
technical field:
The present invention relates to water-treatment technology field, relating in particular in the lime system of water treatment for dissolving pretreatment unit and the pretreatment process of the dilution water of lime.
background technology:
At water treatment field, source water mostly is reservoir water or underground water, due to the most slant acidity of carbonate containing trace in water, in order to regulate the pH value of water, makes it reach the standard of tap water, and the general mode of feeding lime breast that adopts adjusts pH value.In existing milk of lime preparation system, first hydrated lime feed is added in lime dissolving vessel, then according to proportioning continuous supplementation dilution water, being mixed with certain density lime milk solution after mixing in dissolving vessel, stirring, finally by adding pump, lime milk solution being got to each toss area.
Due to dilution water generally direct employing source water, and each toss area is apart from each other, need the pipeline connecting hundreds of rice long to carry from lime dissolving vessel to toss area, transport pipe is after 1 ~ 2 month (about 45 days) are run, carbonate in course of conveying in dilution water and the calcium ion in milk of lime slowly react and form calcium carbonate and be attached to inner-walls of duct, the accumulation inner-walls of duct in elapsed time easily forms one deck white, hard calcium carbonate scaling and the settling of calcium hydroxide, pipeline undergauge is made after pipeline scale, actual internal area diminishes, build-up of pressure loss and line clogging, reduce the transport capacity of pipeline.Existing descaling method is mostly by human at periodic intervals's dredging, and hard scale difficulty is dredged, and January once, workload is large, not only time-consuming, effort, operational difficulty, and causes certain physical abuse to pipeline, shorten the working life of pipeline, add maintenance and the replacement charge of tubing.
summary of the invention:
For in the lime system existed in above-mentioned prior art, the easy fouling of milk of lime transport pipe, the technical problems such as difficult cleaning, the object of the present invention is to provide a kind of pretreatment unit and treatment process thereof of dilution water, effectively the trace carbonate in dilution water can be got rid of in advance, carry out preparing lime milk solution with this through pretreated dilution water again, blocked the environment generating calcium carbonate in tube wall, solved the problem of pipeline scale and blocking from source.This pretreatment unit structure is simple, and reasonable in design, input cost is low, is easy to promote the use of.
To achieve these goals, the technical solution used in the present invention is as follows:
A pretreatment unit for dilution water, is characterized in that: comprise staving, and staving is provided with dilution water import, lime import, liming outlet, discharge of wastewater mouth, and be provided with in staving by motor-driven stir shaft, stir shaft is provided with stirring rake.
The further setting of the present invention is:
Described dilution water import, lime import are arranged on staving top, and liming outlet, discharge of wastewater mouth are arranged on staving bottom, and the level height of described liming outlet is on discharge of wastewater mouth.
Described stir shaft is by Bracket setting on staving, and described stir shaft is provided with 1 or 2 layer of stirring rake, preferred stir shaft is arranged upper and lower two-layer stirring rake.Stirring rake is set by height suitable in staving, coordinates specific rotating speed, form suitable axial liquid Flow Velocity, ensure that the calcium carbonate formed sinks, and excessive calcium hydroxide is in suspended state, thus makes reaction in staving more complete.
Described stirrer rotating speed is 100 ~ 200 revs/min, and power is 2.2KW.
Described staving is also provided with liquidometer and detects mouth, liquidometer is arranged on staving by anchor, and to detect mouth position corresponding with liquidometer.Be convenient to the amount accurately controlling to add each liquid in staving, thus effectively control the concentration of solution in staving.
Described liquid level counts called putting-into-type liquid level meter or ultrasonic level gage, preferred ultrasonic level gage.
Described staving being also provided with acid-adding port, for adding organic acid or mineral acid in staving, the calcium carbonate hard scale at the bottom of bucket being removed.
Described staving is also provided with overflow port, and described overflow port is apart from staving distance from top within 5cm, and overflow port carries out flow control by coupled surplus valve.
A kind of pretreatment process of dilution water, dilution water and milk of lime strong solution are pumped in staving from dilution water entrance and lime inlet according to setting ratio respectively, being mixed with lime weight percent is 1% ~ 4% liming dilute solution, charging rear stirrer is with the rotating speed rapid stirring 10 ~ 15 minutes of 110 ~ 150rpm/min, the a small amount of carbonate in dilution water and the calcium ion in milk of lime is made fully to react generation calcium carbonate, impurity particle small in liming flocculates into oarse-grained contamination precipitation thing, more than 30 minutes are left standstill after stirring completes, calcium carbonate and impurity particle are sunk to bottom staving under gravity, with the rotating speed low rate mixing of 60 ~ 85rpm/min during discharging, liming dilute solution after carbon elimination hydrochlorate is discharged from liming outlet.
In the above-mentioned methods preferably, charging rear stirrer carries out rapid stirring 15 minutes with the rotating speed of 120rpm/min, and having stirred rear time of repose is 120 ~ 155 minutes.
Beneficial effect of the present invention is as follows:
1, dilution water pretreatment unit of the present invention, structure is simple, reasonable in design, only need increase the preposition operation of a step in lime system, effectively trace carbonate contained in dilution water can be removed, block the environment generating calcium carbonate in milk of lime carrier wall, solved the problem of pipeline scale and blocking from source, and this covering device input cost is low, is easy to promote the use of.
2, dilution water pretreatment process of the present invention, utilize chemical precipitation principle, remove the carbonate in dilution water, because carbonate in dilution water is micro-, by adding excessive calcium ion, conservative control stirring velocity and the reaction times again, increase probability and the reaction times of carbonate and calcium ion reaction in staving, in advance the calcium carbonate scaling generated in transport pipe is formed in staving, and at the bottom of being sunk to barrel by rational time of repose, periodic exhaustion or focus on, not only avoid later stage pipeline scale, and process is convenient.
3, dilution water pretreatment unit of the present invention, by the impurity in separation, purification liming and foulant, reduces the wearing and tearing of lime pump seal, extends the working time of pump.
4, dilution water pretreatment process of the present invention, can reduce and even eliminate ducted lime scale formation, the effluent water quality fluctuation avoiding line clogging to cause.
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
accompanying drawing illustrates:
Fig. 1 is the dilution water pretreatment unit structural representation of the embodiment of the present invention;
Fig. 2 is the dilution water pretreatment unit vertical view of the embodiment of the present invention.
Embodiment
As shown in Figure 1 and Figure 2, the pretreatment unit of dilution water of the present invention, comprise staving 1, stirrer 2 is provided with in staving 1, described stirrer 2 is by motor-driven stir shaft 3, and stir shaft 3 is provided with 1 or 2 layer of stirring rake 4, and described stirrer 2 is fixed on staving 1 by support, be respectively equipped with dilution water import 5, lime import 6 on staving 1 top, be provided with liming outlet 8 in staving bottom, discharge of wastewater mouth 9.
Wherein, pending dilution water adds in staving 1 by dilution water import 5, controls flooding quantity by the opening and closing of water intaking valve; Lime adds in staving 1 by lime import 6, lime can be unslaked lime or white lime, can add in powder form, also can add with the form of milk of lime, finally dissolve in water with the form of calcium hydroxide, in the present embodiment, lime adds with milk of lime form, controlled the add-on of milk of lime by the opening and closing of feed valve;
Dilution water and milk of lime through mixing, stir after, the trace carbonate in dilution water and the calcium ion in milk of lime react, and reaction formula is as follows:
CO 3 2-+Ca 2+→CaCO 3
HCO 3 -+ Ca 2+→ CaCO 3↓ (calcium hydroxide is excessive)
After abundant reaction, the precipitation of calcium carbonate of generation and contamination precipitation sink to bottom staving 1 under gravity, for carbonate is after treatment by the rare milk of lime mixed solution got rid of in advance in staving 1.
Liming outlet 8, for rare milk of lime mixed solution after process is discharged stand-by or be directly connected with the water inlet pipe in lime system participate in next step lime system in.
Discharge of wastewater mouth 9, for regularly discharging the precipitation of calcium carbonate and contamination precipitation that are accumulated in bottom staving 1.
Be more than the basic element of character of dilution water pretreatment unit of the present invention, but, in order to optimize the present invention, in preferred embodiments, next or several associated components can also be configured to.
In order to better control the amount adding liquid in staving 1, described staving 1 is also provided with liquidometer and detects mouth 10, liquidometer is arranged on staving 1 by anchor, and with liquidometer, to detect mouth 10 position corresponding, for detecting the height of liquid in staving 1, described liquidometer can select called putting-into-type liquid level meter or ultrasonic level gage, preferred ultrasonic level gage, its precision is high, install and easy to use.
Described staving is also provided with acid-adding port 11, for to acid adding in staving 1, because carbonate deposit is the most easily dissolved in diluted acid, common are mineral acid and organic acid all can be dissolved, the most frequently used as dilute hydrochloric acid, can regularly be got rid of by the calcium carbonate hard scale at the bottom of sinking to barrel, the waste water after cleaning is discharged from discharge of wastewater mouth 9.
Described staving 1 is also provided with overflow port 7, and described overflow port 7 is apart from staving 1 distance from top within 5cm, and overflow port 7 is controlled by coupled surplus valve, for level pressure overflow, and the safe operation of securing system.
Above-mentioned dilution water pretreatment unit is adopted to carry out pretreated method to dilution water as follows:
Dilution water and milk of lime strong solution are pumped in staving 1 from dilution water entrance 5 and lime inlet 6 according to setting ratio respectively, be configured to liming dilute solution, in described liming dilute solution, the weight percent of lime is 1%-4%, charging rear stirrer 2 is with the rotating speed rapid stirring 10 ~ 15 minutes of 110 ~ 150rpm/min, the a small amount of carbonate in dilution water and the calcium ion in milk of lime is made fully to react generation calcium carbonate, impurity particle small in liming flocculates into oarse-grained contamination precipitation thing, more than 30 minutes are left standstill after stirring completes, calcium carbonate and impurity particle is made to sink to bottom staving 1 under gravity, with the rotating speed low rate mixing of 60 ~ 85rpm/min during discharging, the liming dilute solution on top is stirred from liming outlet 8 and discharge.
The ratio that dilution water and milk of lime strong solution add is not particularly limited, specifically can regulate according to the concentration of milk of lime strong solution, when milk of lime strong solution concentration is larger, the dilution water ratio added increases, when the concentration of milk of lime strong solution is less, the dilution water ratio added reduces, and ensures that the liming dilute solution concentration be configured to is in 1% ~ 4% scope generally.
After charging, dissolve further for making milk of lime strong solution, and make undissolved calcium hydroxide be in suspended state, increase the reaction probabilities of calcium ion and carbanion in the aqueous solution, find through applicant's test of many times, adopt stirrer with the rotating speed rapid stirring 10 ~ 15 minutes of 110 ~ 150rpm/min, reaction can be made more complete.Because the milk of lime dilute solution of configuration is supersaturated solution, if the rotating speed of stirrer is too slow, the axial liquid Flow Velocity formed in staving 1 is little, excessive calcium hydroxide can not be made to be in suspended state, and sedimentation gradually, affect speed of response, if the rotating speed of stirrer is too fast, the axial liquid Flow Velocity formed in staving 1 is large, the precipitation of calcium carbonate that reaction generates is heavy again does not go down, when the stirring velocity of stirrer is at 110 ~ 150rpm/min, the axial liquid Flow Velocity formed can just ensure that oversaturated calcium hydroxide is in suspended state, the calcium carbonate of generation can be made again to sink gradually under gravity, reach the object of carbonate in removing dilution water.
During discharging, because after leaving standstill, calcium carbonate and excessive calcium hydroxide are all lowered into bottom staving 1, adopt stirrer with the rotating speed low rate mixing of 60 ~ 85rpm/min, excessive calcium hydroxide suspends again and dissolves in water, and the impurity such as calcium carbonate are still deposited in bottom of the barrel, form calcium hydroxide suspension emulsion and be separated with lime deposit.
Through test, after adopting above-mentioned dilution water pretreatment process to process dilution water, re-use hose pump to add pipeline and be added in next step lime system, after carrying out proportioning with lime, obtained milk of lime is transported to each toss area through transport pipe, and after running 40 days continuously, inner-walls of duct does not occur hard scale; And do not adopt the dilution water through pre-treatment, namely directly adopt the former water containing carbonate to be added in lime system, after running 40 days equally continuously there is white hard scale in conveying pipeline inner wall.
Embodiment 1:
As shown in Figure 1, a kind of dilution water pretreatment unit, comprises staving 1, and the shape of staving 1 is cylindrical, and the net capacity of staving 1 is more than 5 cubes, and bucket inner cylinder bottom surface is greater than 1.8 meters to end face vertical height; Bucket top is respectively equipped with dilution water import 5, lime import 6, liquidometer detection mouth 10 and acid-adding port 11, liming outlet 8 is provided with in staving bottom, discharge of wastewater mouth 9, described liming outlet 8 is arranged to go out apart from 10cm bottom staving, more than the beds of precipitation at the bottom of being positioned at barrel, be convenient to avoid settling region the liming dilute solution after treatment on upper strata is all discharged, described discharge of wastewater mouth 9 is arranged at bottom staving 1 or 0 ~ 5cm place at the bottom of distance bucket, and the waste liquid be convenient to after the precipitation at the bottom of by bucket, impurity or cleaning staving is discharged.Described staving 1 is also provided with overflow port 7, and described overflow port 7 is 5cm apart from staving 1 distance from top.
Stirrer 2 is provided with in staving 1, described stirrer 2 is by motor-driven stir shaft 3, stir shaft 3 is provided with 2 layers of stirring rake 4, the stirring rake 4 of lower floor is arranged at more than the beds of precipitation, 8 are exported to flat position with liming, the stirring rake 4 on upper strata is arranged in the middle part of staving 1, and two-layer stirring rake stirs, and mixing effect is better.Described stirrer 2 is fixed on staving 1 by support, and welds a liquidometer static shelving on support, and liquidometer is arranged on staving by anchor, and to detect mouth 10 position corresponding with liquidometer.
The equipment such as described staving, stirrer, liquidometer all can meet the corrosion of 4% lime.
Described stirrer rotating speed is 100 ~ 200 revs/min, and power is 2.2KW.
Above-mentioned dilution water pretreatment unit is adopted to carry out pretreated method to dilution water as follows:
Dilution water and milk of lime strong solution are pumped in staving 1 from dilution water entrance 5 and lime inlet 6 according to the ratio of 1:1 respectively, be configured to liming dilute solution, in described liming dilute solution, the weight percent of lime is 2%, charging rear stirrer 2 is with the rotating speed rapid stirring 15 minutes of 120rpm/min, the a small amount of carbonate in dilution water and the calcium ion in milk of lime is made fully to react generation calcium carbonate, impurity particle small in liming flocculates into oarse-grained contamination precipitation thing, 120 minutes are left standstill after stirring completes, calcium carbonate and impurity particle is made to sink to bottom staving 1 under gravity, with the rotating speed low rate mixing of 85rpm/min during discharging, the liming dilute solution on top is stirred from liming outlet 8 and discharge.
Embodiment 2:
The basic structure of dilution water pretreatment unit is with embodiment 1, and difference is, the pretreatment process of dilution water is as follows:
Dilution water and milk of lime strong solution are pumped in staving 1 from dilution water entrance 5 and lime inlet 6 according to the ratio of 1:1.5 respectively, be configured to liming dilute solution, in described liming dilute solution, the weight percent of lime is 1.6%, charging rear stirrer 2 is with the rotating speed rapid stirring 10 minutes of 150rpm/min, the a small amount of carbonate in dilution water and the calcium ion in milk of lime is made fully to react generation calcium carbonate, impurity particle small in liming flocculates into oarse-grained contamination precipitation thing, 155 minutes are left standstill after stirring completes, calcium carbonate and impurity particle is made to sink to bottom staving 1 under gravity, with the rotating speed low rate mixing of 60rpm/min during discharging, the liming dilute solution on top is stirred from liming outlet 8 and discharge.
Due to the carbonate of content trace in pending dilution water, dilution water mixes in staving 1 with milk of lime strong solution, stir the dilute solution forming milk of lime, the described lime percentage composition contained by milk of lime dilute solution is 1%-4%, be mainly oversaturated calcium hydroxide suspension, be dissolved in the excessive calcium ion in dilution water and trace carbonate, under the effect of stirrer, by controlling specific stirring velocity and reaction times, make fully contacting of the carbonate in dilution water and calcium ion in lime, generate precipitation of calcium carbonate, in advance by the carbonate removal in dilution water, at the bottom of the lime deposit generated sinks to barrel, discharge or periodic cleaning can be concentrated to remove, save time, laborsaving, simple.Dilution water after pretreatment becomes the dilute solution of liming, the percentage composition of lime in the liming that need be added by calculating, at lime system call interception lime adding amount, is configured to milk of lime is added to each toss area by the liming dilute solution after process and lime.
By the test of half a year, applicant finds the lime system after using dilution water pretreatment unit of the present invention and disposal methods, not there is scale formation in transport pipe, efficiently solve the easy fouling of original milk of lime transport pipe, the technical problems such as difficult cleaning.
Above content is the further description done provided technical scheme in conjunction with the preferred embodiment of the present invention; can not assert that the present invention specifically implements to be confined to these explanations above-mentioned; for general technical staff of the technical field of the invention; without departing from the inventive concept of the premise; some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.

Claims (10)

1. a pretreatment unit for dilution water, is characterized in that: comprise staving, and staving is provided with dilution water import, lime import, liming outlet, discharge of wastewater mouth, and be provided with in staving by motor-driven stir shaft, stir shaft is provided with stirring rake.
2. the pretreatment unit of a kind of dilution water according to claim 1, it is characterized in that: described dilution water import, lime import are arranged on staving top, liming outlet, discharge of wastewater mouth are arranged on staving bottom, and the level height of described liming outlet is on discharge of wastewater mouth.
3. the water pre-treatment means of a kind of dilution according to claim 1, is characterized in that: described stir shaft is by Bracket setting on staving, and described stir shaft is provided with 1 or 2 layer of stirring rake.
4. the pretreatment unit of a kind of dilution water according to claim 1, is characterized in that: described stirrer rotating speed is 100 ~ 200 revs/min, and power is 2.2KW.
5. according to the pretreatment unit of a kind of dilution water one of claim 1-4 Suo Shu, it is characterized in that: described staving is also provided with liquidometer and detects mouth, liquidometer is arranged on staving by anchor, and to detect mouth position corresponding with liquidometer.
6. the pretreatment unit of a kind of dilution water according to claim 5, is characterized in that: described liquid level counts ultrasonic level gage.
7. the pretreatment unit of a kind of dilution water according to claim 6, is characterized in that: described staving is also provided with acid-adding port, for adding organic acid or mineral acid in staving, is removed by the calcium carbonate hard scale at the bottom of bucket.
8. the pretreatment unit of a kind of dilution water according to claim 7, is characterized in that: described staving is also provided with overflow port, and overflow port is apart from staving distance from top within 5cm, and overflow port carries out flow control by coupled surplus valve.
9. according to claim 1-4, the pretreatment unit of the dilution water of one of 6-8 carries out the pretreated method of dilution water, it is characterized in that: dilution water and milk of lime strong solution are pumped in staving from dilution water entrance and lime inlet according to setting ratio respectively, being mixed with lime weight percent is 1% ~ 4% liming dilute solution, charging rear stirrer is with the rotating speed rapid stirring 10 ~ 15 minutes of 110 ~ 150rpm/min, the a small amount of carbonate in dilution water and the calcium ion in milk of lime is made fully to react generation calcium carbonate, impurity particle small in liming flocculates into oarse-grained contamination precipitation thing, more than 30 minutes are left standstill after stirring completes, calcium carbonate and impurity particle are sunk to bottom staving under gravity, with the rotating speed low rate mixing of 60 ~ 85rpm/min during discharging, liming dilute solution after carbon elimination hydrochlorate is discharged from liming outlet.
10. the water pretreatment process of a kind of dilution according to claim 9, is characterized in that: charging rear stirrer carries out rapid stirring 15 minutes with the rotating speed of 120rpm/min, and having stirred rear time of repose is 120 ~ 155 minutes.
CN201510313529.3A 2015-06-10 2015-06-10 Pre-treatment device and treatment method of dilute water Pending CN104909470A (en)

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Application Number Priority Date Filing Date Title
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2774371A1 (en) * 1998-02-03 1999-08-06 Atochem Elf Sa Synergistic descaling composition for removing lime scale from cooling circuits, boilers and domestic appliances
JP2005239457A (en) * 2004-02-25 2005-09-08 Ebara Corp Method and apparatus for preparation of slaked lime aqueous solution
CN201148384Y (en) * 2008-01-18 2008-11-12 上海德源水处理工程有限公司 Powdery lime automatic metering and preparing apparatus
CN201495126U (en) * 2009-09-23 2010-06-02 上海东振环保工程技术有限公司 Lime cream preparing and adding device
CN102718294A (en) * 2011-03-29 2012-10-10 深圳市水务(集团)有限公司 Limewater-clarifying method used for processing drinking water
US20130187087A1 (en) * 2012-01-23 2013-07-25 Applied Specialties, Inc. Process for lime slurry production
CN204051572U (en) * 2014-08-28 2014-12-31 武汉江扬环境科技股份有限公司 Full-automatic lime chemicals dosing plant

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2774371A1 (en) * 1998-02-03 1999-08-06 Atochem Elf Sa Synergistic descaling composition for removing lime scale from cooling circuits, boilers and domestic appliances
JP2005239457A (en) * 2004-02-25 2005-09-08 Ebara Corp Method and apparatus for preparation of slaked lime aqueous solution
CN201148384Y (en) * 2008-01-18 2008-11-12 上海德源水处理工程有限公司 Powdery lime automatic metering and preparing apparatus
CN201495126U (en) * 2009-09-23 2010-06-02 上海东振环保工程技术有限公司 Lime cream preparing and adding device
CN102718294A (en) * 2011-03-29 2012-10-10 深圳市水务(集团)有限公司 Limewater-clarifying method used for processing drinking water
US20130187087A1 (en) * 2012-01-23 2013-07-25 Applied Specialties, Inc. Process for lime slurry production
CN204051572U (en) * 2014-08-28 2014-12-31 武汉江扬环境科技股份有限公司 Full-automatic lime chemicals dosing plant

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Application publication date: 20150916