CN104893155B - PVC flooring base material and preparation method thereof - Google Patents

PVC flooring base material and preparation method thereof Download PDF

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Publication number
CN104893155B
CN104893155B CN201510306513.XA CN201510306513A CN104893155B CN 104893155 B CN104893155 B CN 104893155B CN 201510306513 A CN201510306513 A CN 201510306513A CN 104893155 B CN104893155 B CN 104893155B
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parts
foaming
temperature
base material
preparation
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CN104893155A (en
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高炳坤
段培彩
孙凯
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Shandong Gibbs New Materials Co ltd
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SHANDONG HUIFENG WOOD PLASTIC PROFILE Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The invention discloses a kind of PVC flooring base material and preparation method thereof, belong to polyvinyl-chloride plate material technical field.Solve that existing product cost is high, ropy problem, be made up of following raw material:80 100 parts of polyvinyl chloride SG8 types resin, 100 120 parts of coarse whiting, 50 parts of floor base material template reclaimed materials, 903 78 parts of foaming control agent, 902 23 parts of foaming control agent, 2.8 4.9 parts of compound stabilizer, 60 0.6 1.2 parts of in-lubricant ZB, 0.35 0.7 parts of Tissuemat E PE waxes, 0.2 0.5 parts of AP, 0.5 0.8 parts of plasticiser OA3,0.3 0.4 parts of heat release type AC foaming agents, triumphant 1.4 1.6 parts of 2 foaming agents of c, 25 parts of iron oxide yellow powder, 24 parts of CPE in heat absorbing type;Preparation method includes batch mixing, and finished product is extruded in plasticizing foaming.Product of the present invention can be widely applied to the places such as office building, market, school, gymnasium, hospital.

Description

PVC flooring base material and preparation method thereof
Technical field
The present invention relates to a kind of PVC flooring base material and preparation method thereof, belong to polyvinyl-chloride plate material technical field.
Background technology
PVC flooring is called plastic floor, is emerging high-tech pavement in current world's building material industry, existing Generally used in decorative engineering abroad.PVC flooring is widelyd popularize from the eighties into domestic market, now The industries such as office building, market, airport, school, library, gymnasium, pharmaceutical factory, hospital, factory are widely used, and obtain satisfaction Effect.PVC flooring has environmentally friendly formaldehydeless, fire-retardant, waterproof, mothproof, moistureproof, noise-proofing, cost as ecological floor It is low the advantages of can be recycled, received by increasing people.
Prior art production PVC flooring is usually that related auxiliaries are added in Corvic, is mixed i.e. through too high Extrusion molding base material, is then packaging listing, existing formula and production method by following process such as sanding, pad pasting, UV processing Not only production cost is high for the product of acquisition, and product deposits that heat distortion temperature is low, and sanding bending, thick floor is uneven whole The problems such as.
The content of the invention
It is an object of the invention to provide a kind of PVC flooring base material, with cost is low, quality is good, high temperature is constant The advantages of shape, smooth surface-brightening.
The present invention also aims to provide a kind of preparation method of PVC flooring base material.
Described PVC flooring base material, is made up of the raw material of following parts by weight:Polyvinyl chloride SG8 type resins 80-100 Part, 100-120 parts of coarse whiting, 50 parts of floor base material template reclaimed materials, 9037-8 parts of foaming control agent, foaming control agent 9022-3 Part, 2.8-4.9 parts of compound stabilizer, ZB-600.6-1.2 parts of in-lubricant, 0.35-0.7 parts of Tissuemat E, AP 0.2-0.5 Part, OA30.5-0.8 parts of plasticiser, 0.3-0.4 parts of heat release type AC foaming agents, triumphant 1.4-1.6 parts of c-2 foaming agents, iron in heat absorbing type 2-5 parts of bloom, 2-4 parts of CPE.
The preparation method of described PVC flooring base material, comprises the following steps:
(1) batch mixing:
First by 80-100 parts of polyvinyl chloride SG8 type resins, 100-120 parts of coarse whiting, 2.8-4.9 parts of compound stabilizer is put 0.3-0.4 parts of heat type AC foaming agents, triumphant 1.4-1.6 parts of c-2 foaming agents in heat absorbing type, ZB-600.6-1.2 parts of in-lubricant gathers 0.35-0.7 parts of ethylene waxes, 0.2-0.5 parts of AP, OA30.5-0.8 parts of plasticiser, 2-4 parts of CPE, 2-5 parts of iron oxide yellow powder, foaming is adjusted 9037-8 parts of agent, 9022-3 parts of foaming control agent are saved, 50 parts of floor base material template reclaimed materials is sequentially added in the mixed pot of heat, and stirring rises Compound is put into stirring in cold mixing pot rapidly to 110-120 DEG C, then and is cooled to 40-60 DEG C by temperature;
(2) plasticizing foaming:
Cooling material is delivered to the extruder that temperature is set as 150-200 DEG C, makes it through seven sections of twin-screw heating of barrel Plasticizing foaming;
(3) finished product is extruded:
The material plastified after foaming is delivered into the mould that temperature is 160-190 DEG C, die lip is extruded, cools down and presses via shaping platform Sizing is closed, hauling machine excision forming of moving out obtains finished product;Oil temperature machine temperature is set at 175-190 DEG C, die lip wherein at mould Water temperature machine is set in 15-30 DEG C, and shaping platform cooling water temperature is 17-30 DEG C.
The batch mixing of the present invention is simple to operate, and the setting range of technological temperature is relatively wide relatively reasonable, reduces in production due to temperature A variety of operation difficulties that degree setting range is smaller and brings.
PVC flooring matrix density prepared by the present invention is 0.7-0.9g/cm3, thickness is 4.2-5mm.
Compared with prior art, the beneficial effects of the invention are as follows:
Inventive formulation advantages of simple, production cost is low, by adding appropriate calcium powder on the basis of panel density is improved It ensure that plate surface finish.
Add polymeric plasticizer CPE be haloflex, due to the presence of chlorine atom make CPE turn into polar polymer and There is identical polar group with polyvinyl chloride, enhance the compatibility with polyvinyl chloride, because that can keep larger between its macromolecular chain Van der Waals force, therefore the impact resistance of polyvinyl chloride is substantially increased, play good toughening effect.
CPE of the present invention addition maintains 2-4 parts, and CPE consumption is very few, in order to reach good modeling during production sheet material Change effect, barrel temperature can be greatly improved, and high temperature thickener is easily caused, while product embrittlement, quality dissatisfaction;Consumption conference makes Too, extrusion is difficult to control to material plasticizing in sheet material production, has considerable influence simultaneously for plate surface hardness.
Because the proportion of calcium powder is larger, the consumption of lubricant is increased, it is to avoid due to lack of lubrication, friction increase, material The too poor caused a variety of adverse consequences of mobility, the increasing of lubricant quantity also substantially prolongs the production time;But too many Lubricant can cause material plasticizing impacted again, and mobility causes by force discharging unstable very much, and sheet metal thickness is unstable, and production is difficult to control System.
The regulation space of temperature control, die orifice regulation, the speed of production of the present invention etc. is larger, is conducive to the stabilization of production to hold It is continuous.
Product of the present invention is also with high temperature is indeformable, environment friendly and pollution-free, renewable, elastic big, anti-impact force is strong, noise-proofing With meet water be puckery anti-skidding effect the advantages of.
Product quality of the present invention is light, and density is small, has in skyscraper for building body load-bearing and saving space without comparable The advantage of plan.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
The preparation method of described PVC flooring base material, comprises the following steps:
(1) batch mixing:
First by 80 parts of polyvinyl chloride SG8 types resin, 100 parts of coarse whiting, 2.8 parts of compound stabilizer, heat release type AC foaming agents 0.3 part, triumphant 1.4 parts of c-2 foaming agents in heat absorbing type, ZB-600.6 parts of in-lubricant, 0.35 part of Tissuemat E, 0.2 part of AP, modeling OA30.5 parts of agent, 2 parts of CPE, 2 parts of iron oxide yellow powder, 9037 parts of foaming control agent, 9022 parts of foaming control agent, floor base material template 50 parts of reclaimed materials is sequentially added in the mixed pot of heat, and stirring is warming up to 110 DEG C, then is put into stir in cold mixing pot by compound rapidly and is dropped Temperature is to 40 DEG C;
(2) plasticizing foaming:
Cooling material is delivered to the extruder that temperature is set as 150-200 DEG C, makes it through seven sections of twin-screw heating of barrel Plasticizing foaming;
(3) finished product is extruded:
The material plastified after foaming is delivered into the mould that temperature is 160 DEG C, die lip is extruded, it is fixed via shaping platform cooling pressing Type, hauling machine excision forming of moving out obtains finished product;Oil temperature machine temperature is set in 175 DEG C wherein at mould, and water temperature machine is set at die lip 15 DEG C are scheduled on, shaping platform cooling water temperature is 17 DEG C.
Embodiment 2
The preparation method of described PVC flooring base material, comprises the following steps:
(1) batch mixing:
First by 100 parts of polyvinyl chloride SG8 types resin, 120 parts of coarse whiting, 4.9 parts of compound stabilizer, heat release type AC foaming agents 0.4 part, triumphant 1.6 parts of c-2 foaming agents in heat absorbing type, ZB-601.2 parts of in-lubricant, 0.7 part of Tissuemat E, 0.5 part of AP, plasticizing OA30.8 parts of agent, 4 parts of CPE, 5 parts of iron oxide yellow powder, 9038 parts of foaming control agent, 9023 parts of foaming control agent, floor base material template is returned 50 parts of rewinding is sequentially added in the mixed pot of heat, and stirring is warming up to 120 DEG C, and compound then is put into stirring in cold mixing pot rapidly cools To 60 DEG C;
(2) plasticizing foaming:
Cooling material is delivered to the extruder that temperature is set as 150-200 DEG C, makes it through seven sections of twin-screw heating of barrel Plasticizing foaming;
(3) finished product is extruded:
The material plastified after foaming is delivered into the mould that temperature is 190 DEG C, die lip is extruded, it is fixed via shaping platform cooling pressing Type, hauling machine excision forming of moving out obtains finished product;Oil temperature machine temperature is set in 190 DEG C wherein at mould, and water temperature machine is set at die lip 30 DEG C are scheduled on, shaping platform cooling water temperature is 30 DEG C.
Embodiment 3
The preparation method of described PVC flooring base material, comprises the following steps:
(1) batch mixing:
First by 90 parts of polyvinyl chloride SG8 types resin, 110 parts of coarse whiting, 3.5 parts of compound stabilizer, heat release type AC foaming agents 0.35 part, triumphant 1.5 parts of c-2 foaming agents in heat absorbing type, ZB-600.8 parts of in-lubricant, 0.5 part of Tissuemat E, 0.3 part of AP, modeling OA30.65 parts of agent, 3 parts of CPE, 3 parts of iron oxide yellow powder, 9037.5 parts of foaming control agent, 9022.5 parts of foaming control agent, floor base 50 parts of material template reclaimed materials is sequentially added in the mixed pot of heat, and stirring is warming up to 115 DEG C, and then compound is put into cold mixing pot rapidly Stirring is cooled to 50 DEG C;
(2) plasticizing foaming:
Cooling material is delivered to the extruder that temperature is set as 150-200 DEG C, makes it through seven sections of twin-screw heating of barrel Plasticizing foaming;
(3) finished product is extruded:
The material plastified after foaming is delivered into the mould that temperature is 180 DEG C, die lip is extruded, it is fixed via shaping platform cooling pressing Type, hauling machine excision forming of moving out obtains finished product;Oil temperature machine temperature is set in 180 DEG C wherein at mould, and water temperature machine is set at die lip 20 DEG C are scheduled on, shaping platform cooling water temperature is 25 DEG C.
Wherein:Foaming control agent 903 is polyacrylate;
In-lubricant ZB-60 is polyol fatty acid ester;
AP is micronized polyethylene wax;
OA3 is micronizing OPE;
Heat release type AC foaming agents are azodicarbonamides;
CPE is haloflex.

Claims (1)

1. a kind of preparation method of PVC flooring base material, it is characterised in that comprise the following steps:
(1) batch mixing:
First by 80-100 parts of polyvinyl chloride SG8 type resins, 100-120 parts of coarse whiting, 2.8-4.9 parts of compound stabilizer, heat release type 0.3-0.4 parts of AC foaming agents, triumphant 1.4-1.6 parts of c-2 foaming agents, 0.6-1.2 parts of in-lubricant ZB-60, polyethylene in heat absorbing type 0.35-0.7 parts of wax PE waxes, 0.2-0.5 parts of AP, 0.5-0.8 parts of plasticiser OA3,2-4 parts of CPE, 2-5 parts of iron oxide yellow powder, foaming 7-8 parts of conditioning agent 903,2-3 parts of foaming control agent 902,50 parts of floor base material template reclaimed materials is sequentially added in the mixed pot of heat, is stirred Mix and be warming up to 110-120 DEG C, compound then is put into stirring in cold mixing pot rapidly is cooled to 40-60 DEG C;
(2) plasticizing foaming:
Cooling material is delivered to the extruder that temperature is set as 150-200 DEG C, it is plastified through seven sections of twin-screw heating of barrel Foaming;
(3) finished product is extruded:
The material plastified after foaming is delivered into the mould that temperature is 160-190 DEG C, die lip is extruded, it is fixed via shaping platform cooling pressing Type, hauling machine excision forming of moving out obtains finished product;Oil temperature machine temperature is set in water temperature at 175-190 DEG C, die lip wherein at mould Machine is set in 15-30 DEG C, and shaping platform cooling water temperature is 17-30 DEG C.
CN201510306513.XA 2015-06-08 2015-06-08 PVC flooring base material and preparation method thereof Active CN104893155B (en)

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Publication number Priority date Publication date Assignee Title
CN106167591A (en) * 2016-08-15 2016-11-30 太仓力九和塑胶工业有限公司 A kind of PVC foam body and manufacture method
CN107082982A (en) * 2017-05-10 2017-08-22 安徽森泰木塑集团股份有限公司 A kind of online three rollers laminating big flooring method of belt lock catch
CN110951193A (en) * 2019-12-20 2020-04-03 山东汇丰新材料科技股份有限公司 Low-density UV special plate and preparation method thereof
CN110885521A (en) * 2019-12-20 2020-03-17 山东汇丰新材料科技股份有限公司 Odorless embossed furniture board with thickness of 16mm-18mm
CN111705513A (en) * 2020-05-19 2020-09-25 佛山市高明亿阳塑胶有限公司 PVC foaming floor
CN115975307A (en) * 2022-12-30 2023-04-18 常州市贝美家居科技有限公司 Floor base material, preparation method thereof and floor
CN116948322A (en) * 2023-08-04 2023-10-27 常州市贝美家居科技有限公司 Physical foaming floor

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CN103059474B (en) * 2013-01-23 2015-04-15 成都缘丰科技材料有限公司 Wood-plastic composite foaming plate and preparation method thereof
CN103788543B (en) * 2014-01-22 2016-03-30 山东汇丰木塑型材股份有限公司 Novel foaming wood plastic template in use for architecture and production technique thereof
CN104448631B (en) * 2014-12-15 2017-01-18 山东博拓塑业股份有限公司 High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof

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Address after: 273300 Wenshui Park, Pingyi County Economic Development Zone, Linyi City, Shandong Province, to the north of National Highway 327, west of Fengshan Road

Patentee after: Shandong Huifeng New Material Science and Technology Co.,Ltd.

Address before: 273300 Wenshui Park, Pingyi Economic Development Zone, Linyi City, Shandong Province

Patentee before: SHANDONG HUIFENG WOOD PLASTIC PROFILE Co.,Ltd.

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Address after: 273300 North Road, 10 meters west of the intersection of Huangjin Road and Jinshan Road in Pingyi Street, Pingyi County, Linyi City, Shandong Province

Patentee after: Shandong Gibbs New Materials Co.,Ltd.

Address before: 273300 west of Fengshan Road, Wenshui Park, Pingyi Economic Development Zone, Linyi City, Shandong Province, north of national highway 327

Patentee before: Shandong Huifeng New Material Science and Technology Co.,Ltd.