CN104448631B - High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof - Google Patents
High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof Download PDFInfo
- Publication number
- CN104448631B CN104448631B CN201410777208.4A CN201410777208A CN104448631B CN 104448631 B CN104448631 B CN 104448631B CN 201410777208 A CN201410777208 A CN 201410777208A CN 104448631 B CN104448631 B CN 104448631B
- Authority
- CN
- China
- Prior art keywords
- polyvinyl chloride
- high durable
- foam polyvinyl
- durable foam
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 38
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000004088 foaming agent Substances 0.000 claims abstract description 9
- 238000005187 foaming Methods 0.000 claims abstract description 8
- 239000003607 modifier Substances 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims abstract description 4
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 4
- 239000003999 initiator Substances 0.000 claims abstract description 4
- 239000004611 light stabiliser Substances 0.000 claims abstract description 4
- 239000000314 lubricant Substances 0.000 claims abstract description 4
- 239000000049 pigment Substances 0.000 claims abstract description 4
- 239000006260 foam Substances 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 8
- 238000007493 shaping process Methods 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000012745 toughening agent Substances 0.000 claims description 6
- 238000001802 infusion Methods 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- 239000004609 Impact Modifier Substances 0.000 claims description 3
- 238000005282 brightening Methods 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- 235000010215 titanium dioxide Nutrition 0.000 claims description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 239000001099 ammonium carbonate Substances 0.000 claims description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical group [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- 229920000578 graft copolymer Polymers 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 2
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 claims 1
- HDWLUGYOLUHEMN-UHFFFAOYSA-N Dinobuton Chemical group CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)OC(C)C HDWLUGYOLUHEMN-UHFFFAOYSA-N 0.000 claims 1
- 241000425573 Talanes Species 0.000 claims 1
- ZHHXFXQMZYLVRE-UHFFFAOYSA-N benzene butyl prop-2-enoate Chemical group C(C=C)(=O)OCCCC.C1=CC=CC=C1 ZHHXFXQMZYLVRE-UHFFFAOYSA-N 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 21
- 238000012360 testing method Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000004898 kneading Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000011056 performance test Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- 239000006084 composite stabilizer Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- QADQONZVQSTLCY-UHFFFAOYSA-N C(=CC1=CC=CC=C1)C=CC#N.C(C=C)(=O)OCCCC.C(C(=C)C)(=O)OC Chemical group C(=CC1=CC=CC=C1)C=CC#N.C(C=C)(=O)OCCCC.C(C(=C)C)(=O)OC QADQONZVQSTLCY-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical group NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an advertisement board and specifically relates to a high-weather-proof polyvinyl chloride foamed advertisement board and a preparation method thereof. The foamed advertisement board is prepared from polyvinyl chloride resin, a heat stabilizer, a light stabilizer, a processing modifier, a filler, a lubricant, a composite foaming agent, matt powder, an initiator, a cross-linking agent, a foaming stabilizer, a low-temperature flexibilizer, a brightener and a pigment. The polyvinyl chloride foamed advertisement board has the characteristics of high weather fastness and a matt surface, and is capable of improving the adhesion to inks, eliminating printing ghosting, enhancing third dimension and improving advertising effect; the preparation method is simple in process and easy to implement.
Description
Technical field
The present invention relates to a kind of billboard is and in particular to a kind of high durable foam polyvinyl chloride billboard and its preparation side
Method.
Background technology
In recent years, for the purpose kept ecological balance, various countries have formulated many preferential policies, actively push forward development to mould
Dai Mu.Wherein, polyvinyl-chloride foam material, due to have can saw as timber, can dig, can gluing, the processability such as can hole
Can, and have corrosion-resistant, do not go mouldy, Anti-moth-eating, sound insulation, heat-insulated, moistureproof the features such as, obtained good development, extensively should
For Storefront sign, exhibition booth, billboard etc..
Polyvinyl chloride of the prior art commonly foams billboard, and because weatherability is relatively low, usually the time is slightly long, just occurs
The problems such as colour fading, deformation, embrittlement, especially outdoor advertising plate is more prominent.Exposed to the weather after drenching with rain out of doors, time one long appearance
Easily there is degradation with aging, such as color occurs significant change, colour fading, surface checking, and product mechanical property is decreased obviously, and has a strong impact on
The serviceability of product, service life or life-span significantly shorten.Meanwhile, because common plate smooth surface, during use easily
It is poor to ink adhesion to occur, and easily ghost phenomena, and third dimension is poor, affects advertising results.Particularly take in computer direct
The application of print, being particularly acute of performance.Have a strong impact on the popularization in high-grade billboard field for the foam polyvinyl chloride billboard
Use.
Content of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of high durable foam polyvinyl chloride billboard, tool
There are high durable, dull surface, can increase the service life, reduce and fade, deform and embrittlement；Improve attached to ink simultaneously
Put forth effort, eliminate and print ghost image, increase third dimension, improve advertising results；Present invention simultaneously provides its preparation method.
High durable foam polyvinyl chloride billboard of the present invention, is made up of the raw material of following parts by weight:
Wherein,
Corvic is the Corvic of 700-800 for the loose type degree of polymerization.Preferably Corvic sg-
8.
Heat stabilizer is rare earth composite stabilizer；The preferred xt-1 of rare earth composite stabilizer.Light stabilizer is rutile type titanium
One of white powder or ultra-violet absorber or two kinds.Rutile type titanium white preferred tr-618 rutile type titanium white or Du Pont
r-902+.The preferred ultraviolet absorbent uv-531 of ultra-violet absorber.
Composite foamable agent is made up of yellow foaming agent and white hair infusion, and the mass ratio of yellow foaming agent and white hair infusion is 1:0.5-
1:0.05.
Yellow foaming agent is azodicarbonamide；White hair infusion is sodium acid carbonate or ammonium hydrogen carbonate.
Low temperature toughener is acr anti-impact modifier or toughener eva.Wherein, acr anti-impact modifier is preferably anti-impact
acr ls-61；In toughener eva, the molar content of va is 28%, preferably eva7470m.Matt powder is microballoon foaming agent (Shenzhen
Ying Quan Chemical Co., Ltd. of city).
Filler is calcene, and granularity is 300-1000 mesh；Lubricant is stearic acid, Tissuemat E (Qingdao
Sai Nuo Chemical Co., Ltd.) or oxidic polyethylene；Brightening agent is stilbene biphenyl fluorescent brightener；Pigment is ultramarine or charcoal
Black, carbon black is preferably carbon black n220.
Initiator is benzoyl peroxide；Crosslinking agent is dual-tert-butyl dicumyl peroxide.
Modifier is methyl methacrylate-vinyl acetate co-polymer, and inherent viscosity is 3.0-6.0；Abscess is steady
Determining agent is acrylate butyl ester-styrene-acrylonitrile-methyl methacrylate tetrabasic graft copolymer, and inherent viscosity is 11-
15.Foaming stabilizer is preferably pvc foaming control agent ls-530.Add foaming stabilizer, be mainly used to improve foamed material
Melt strength, it is ensured that material cell wall in foaming does not rupture, does not occur and steeps phenomenon.So that foaming product density is low, strong
Spend.
The preparation method of described high durable foam polyvinyl chloride billboard, first, by the material of formula ratio in 105-125
Mix at DEG C, adopt double screw extruder heating plasticizing after cooling, then through mould extrusion molding, carry out after cooling and shaping
Cutting, obtains final product high durable foam polyvinyl chloride billboard.
Described preparation method is preferably: first, the material of formula ratio is mixed all through high-speed kneading machine at 120 DEG C
Even, it is then placed in cold stirring and in machine, is cooled to less than 55 DEG C, be transported in conical double screw extruder hopper by vacuum charging system,
After extruded machine heating plasticizing, through t type extrusion die extrusion molding.Material first pre-cooled roller precooling after shaping, then through three-roller
Glazing, cooling and shaping deburring after eliminating tension force, overlay film, cuts after flattening, obtains final product high durable foam polyvinyl chloride billboard.Its
In,
The screw speed 15-20r/min of double screw extruder, barrel zone temperature is 155-175 DEG C, screw rod oil temperature 80-100
DEG C, mold temperature is 165-175 DEG C, and die lip temperature is 170-185 DEG C.
Compared with prior art, the method have the advantages that
(1) the high durable foam polyvinyl chloride billboard that the present invention prepares has the characteristics that high durable, dull surface, energy
Enough increase the service life, reduce and fade, deform and embrittlement；Improve the adhesive force to ink simultaneously, eliminate and print ghost image, increase vertical
Body-sensing, improves advertising results.
(2) present invention simultaneously provides its preparation method, process is simple, easy to operate.
Specific embodiment
With reference to embodiment, the present invention will be further described.
Embodiment 1
High durable foam polyvinyl chloride billboard described in the present embodiment, in terms of parts by weight, raw material composition is as follows:
Wherein, modifier is methyl methacrylate-vinyl acetate co-polymer, and inherent viscosity is 4.5.
Preparation method:
First, the material of formula ratio is mixed through high-speed kneading machine at 120 DEG C, be then placed in cold stirring in machine and be cooled to
55 DEG C, it is transported in conical double screw extruder hopper by vacuum charging system, after extruded machine heating plasticizing, through t type machine
Head mould has extrusion molding.First pre-cooled roller precooling, then through three-roller glazing, cooling and shaping and eliminate deburring after tension force, overlay film,
Cut after flattening, obtain final product 4mm thickness high durable foam polyvinyl chloride billboard.Wherein, the screw speed 18r/ of double screw extruder
min；It is divided into four temperature control areas, the first temperature control area temperature is: 160 DEG C, the second temperature control area temperature is: 162 DEG C, the 3rd temperature control area temperature
Spend for 164 DEG C, the 4th temperature control area temperature is: 166 DEG C；90 DEG C of screw rod oil temperature, mold temperature is 170 DEG C, and die lip temperature is 175
℃.
The high durable foam polyvinyl chloride billboard that embodiment 1 is prepared carries out performance test, test result: sheet material
Density is 0.453g/cm3, shore hardness (d) 22, glossiness (gu) 16, the ageing-resistant 800 hours time.
Ageing-resistant time test: quv (weatherability ageing oven) ageing time.
Commonly the ageing-resistant time of commercial billboard is 300-500h.
Embodiment 2
High durable foam polyvinyl chloride billboard described in the present embodiment, in terms of parts by weight, raw material composition is as follows:
Wherein, modifier is methyl methacrylate-vinyl acetate co-polymer, and inherent viscosity is 3.
Preparation method:
First, the material of formula ratio is mixed through high-speed kneading machine at 120 DEG C, be then placed in cold stirring in machine and be cooled to
50 DEG C, it is transported in conical double screw extruder hopper by vacuum charging system, after extruded machine heating plasticizing, through t type machine
Head mould has extrusion molding.First pre-cooled roller precooling, then through three-roller glazing, cooling and shaping deburring after eliminating tension force, overlay film,
Cut after flattening, obtain final product high durable foam polyvinyl chloride billboard.Wherein, the screw speed 20r/min of double screw extruder, point
For four temperature control areas, the first temperature control area temperature is: 168 DEG C, the second temperature control area temperature is: 171 DEG C, the 3rd temperature control area temperature is
173 DEG C, the 4th temperature control area temperature is: 175 DEG C；100 DEG C of screw rod oil temperature, mold temperature is 173 DEG C, and die lip temperature is 185 DEG C.
The high durable foam polyvinyl chloride billboard that embodiment 2 is prepared carries out performance test, test result: sheet material
Density is 0.481g/cm3, shore hardness (d) 24, glossiness (gu) 20, the ageing-resistant 1500 hours time.
Ageing-resistant time test: quv (weatherability ageing oven) ageing time.
Commonly the ageing-resistant time of commercial billboard is 300-500h.
Embodiment 3
High durable foam polyvinyl chloride billboard described in the present embodiment, in terms of parts by weight, raw material composition is as follows:
Wherein, modifier is methyl methacrylate-vinyl acetate co-polymer, and inherent viscosity is 6.
Preparation method:
First, the material of formula ratio is mixed through high-speed kneading machine at 120 DEG C, be then placed in cold stirring in machine and be cooled to
45 DEG C, it is transported in conical double screw extruder hopper by vacuum charging system, after extruded machine heating plasticizing, through t type machine
Head mould has extrusion molding.First pre-cooled roller precooling, then through three-roller glazing, cooling and shaping deburring after eliminating tension force, overlay film, exhibition
Cut after flat, obtain final product high durable foam polyvinyl chloride billboard.Wherein, the screw speed 15r/min of double screw extruder, is divided into
Four temperature control areas, the first temperature control area temperature is: 155 DEG C, the second temperature control area temperature is: 157 DEG C, the 3rd temperature control area temperature is 159
DEG C, the 4th temperature control area temperature is: 161 DEG C；80 DEG C of screw rod oil temperature, mold temperature is 167 DEG C, and die lip temperature is 170 DEG C.
The high durable foam polyvinyl chloride billboard that embodiment 3 is prepared carries out performance test, test result: sheet material
Density is 0.530g/cm3, shore hardness (d) 28, glossiness (gu) 6, the ageing-resistant 1200 hours time.
Ageing-resistant time test: quv (weatherability ageing oven) ageing time.
Commonly the ageing-resistant time of commercial billboard is 300-500h.
Embodiment 4
High durable foam polyvinyl chloride billboard described in the present embodiment, in terms of parts by weight, raw material composition is as follows:
Wherein, modifier is methyl methacrylate-vinyl acetate co-polymer, and inherent viscosity is 4.5.
Preparation method:
First, the material of formula ratio is mixed through high-speed kneading machine at 120 DEG C, be then placed in cold stirring in machine and be cooled to
45 DEG C, it is transported in conical double screw extruder hopper by vacuum charging system, after extruded machine heating plasticizing, through t type machine
Head mould has extrusion molding.First pre-cooled roller precooling, then through three-roller glazing, cooling and shaping deburring after eliminating tension force, overlay film, exhibition
Cut after flat, obtain final product high durable foam polyvinyl chloride billboard.Wherein, the screw speed 18r/min of double screw extruder, is divided into
Four temperature control areas, the first temperature control area temperature is: 156 DEG C, the second temperature control area temperature is: 159 DEG C, the 3rd temperature control area temperature is 161
DEG C, the 4th temperature control area temperature is: 164 DEG C；88 DEG C of screw rod oil temperature, mold temperature is 170 DEG C, and die lip temperature is 170 DEG C.
The high durable foam polyvinyl chloride billboard that embodiment 4 is prepared carries out performance test, test result: sheet material
Density is 0.60g/cm3, shore hardness (d) 30, glossiness (gu) 10, the ageing-resistant 1450 hours time.
Ageing-resistant time test: quv (weatherability ageing oven) ageing time.
Commonly the ageing-resistant time of commercial billboard is 300-500h.
Claims (10)
1. a kind of high durable foam polyvinyl chloride billboard it is characterised in that: be made up of the raw material of following parts by weight:
100 parts of Corvic；
Heat stabilizer 3-5 part；
Light stabilizer 0.1-3 part；
Modifier 1-3 part；
Filler 1-6 part；
Lubricant 0.5-2 part；
Composite foamable agent 0.3-2.0 part；
Matt powder 0.01-0.5 part；
Initiator 0.05-0.5 part；
Crosslinking agent 0.10-0.5 part；
Foaming stabilizer 5-8 part；
Low temperature toughener 5-10 part；
Brightening agent 0.02-0.2 part；
Pigment 0.03-3.0 part；
Wherein,
Composite foamable agent is made up of yellow foaming agent and white hair infusion；
Matt powder is microballoon foaming agent.
2. high durable foam polyvinyl chloride billboard according to claim 1 it is characterised in that: Corvic is thin
The easing degree of polymerization is the Corvic of 700-800.
3. high durable foam polyvinyl chloride billboard according to claim 1 it is characterised in that: heat stabilizer is multiple for rare earth
Close stabilizer；Light stabilizer is one of rutile type titanium white or ultra-violet absorber or two kinds.
4. high durable foam polyvinyl chloride billboard according to claim 1 it is characterised in that: yellow foaming agent and white hair bubble
The mass ratio of agent is 1:0.5-1:0.05.
5. high durable foam polyvinyl chloride billboard according to claim 4 it is characterised in that: yellow foaming agent be azo two
Formamide；White hair infusion is sodium acid carbonate or ammonium hydrogen carbonate.
6. high durable foam polyvinyl chloride billboard according to claim 1 it is characterised in that: low temperature toughener be acr
Anti-impact modifier or toughener eva.
7. high durable foam polyvinyl chloride billboard according to claim 1 it is characterised in that: filler be active light
Calcium carbonate, granularity is 300-1000 mesh；Lubricant is stearic acid, Tissuemat E or oxidic polyethylene；Brightening agent is talan
Biphenyl fluorescent brightener；Pigment is ultramarine or carbon black.
8. high durable foam polyvinyl chloride billboard according to claim 1 it is characterised in that: initiator be benzoyl peroxide
Formyl；Crosslinking agent is dual-tert-butyl dicumyl peroxide.
9. high durable foam polyvinyl chloride billboard according to claim 1 it is characterised in that: modifier be methyl
Methyl acrylate-vinyl acetate co-polymer, inherent viscosity is 3.0-6.0；Foaming stabilizer is acrylate butyl ester-benzene second
Alkene-acrylonitrile-methacylate methyl esters tetrabasic graft copolymer, inherent viscosity is 11-15.
10. the preparation method of the arbitrary described high durable foam polyvinyl chloride billboard of a kind of claim 1-9, its feature exists
In: first, the material of formula ratio is mixed at 105-125 DEG C, adopt double screw extruder heating plasticizing after cooling, so
By mould extrusion molding, cut after cooling and shaping, obtained final product high durable foam polyvinyl chloride billboard.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410777208.4A CN104448631B (en) | 2014-12-15 | 2014-12-15 | High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410777208.4A CN104448631B (en) | 2014-12-15 | 2014-12-15 | High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104448631A CN104448631A (en) | 2015-03-25 |
| CN104448631B true CN104448631B (en) | 2017-01-18 |
Family
ID=52895422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410777208.4A Active CN104448631B (en) | 2014-12-15 | 2014-12-15 | High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104448631B (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893156B (en) * | 2015-06-08 | 2017-10-03 | 山东汇丰木塑型材股份有限公司 | Thickness is 6 17mm foam polyvinyl chloride billboard and preparation method thereof |
| CN104893155B (en) * | 2015-06-08 | 2017-10-27 | 山东汇丰木塑型材股份有限公司 | PVC flooring base material and preparation method thereof |
| CN104910554B (en) * | 2015-06-08 | 2017-08-25 | 山东汇丰木塑型材股份有限公司 | Thickness is 3 5mm foam polyvinyl chloride billboard |
| CN105038029A (en) * | 2015-08-11 | 2015-11-11 | 绍兴市四维塑胶工程有限公司 | Modified PVC (polyvinyl chloride) foaming building material product and processing method thereof |
| CN109206771A (en) * | 2017-07-03 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of poster paper of antistatic |
| CN109206815A (en) * | 2017-07-03 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of anticorrosion poster paper |
| CN109206776A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of antistatic polyvinyl chloride foamed board |
| CN109206778A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of impact resistance foam polyvinyl chloride plate |
| CN109206775A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of anti-oxidant foam polyvinyl chloride plate |
| CN109206777A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of flame-proof polyvinyl chloride foamed board |
| CN109206773A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of foam polyvinyl chloride plate with photostability |
| CN109206774A (en) * | 2017-07-04 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of foam polyvinyl chloride plate |
| CN108517091A (en) * | 2018-04-28 | 2018-09-11 | 佛山市高明区创奇装饰材料有限公司 | A method of preparing polyvinyl chloride crust foaming plate material |
| CN109280288A (en) * | 2018-08-16 | 2019-01-29 | 温州崇奥礼品有限公司 | A kind of billboard material and preparation method thereof that uvioresistant effect is good |
| CN109535609A (en) * | 2018-12-13 | 2019-03-29 | 山东博拓塑业股份有限公司 | PVC foam profile and preparation method thereof |
| CN112592546A (en) * | 2021-02-26 | 2021-04-02 | 山东宏福化学有限公司 | Special composite ACR foaming regulator for PVC shoe material |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102358794A (en) * | 2011-08-31 | 2012-02-22 | 佛山佛塑科技集团股份有限公司 | Cross-linked polyvinyl chloride (PVC) foaming material and preparation method thereof |
| CN102492244B (en) * | 2011-12-06 | 2013-09-18 | 山东博拓塑业股份有限公司 | Polyvinyl chloride free foaming board and preparation method thereof |
| CN102942755B (en) * | 2012-12-07 | 2015-03-11 | 山东博拓塑业股份有限公司 | High-hardness polyvinyl chloride crust foaming plate material and preparation method thereof |
| CN103804820B (en) * | 2014-01-27 | 2016-04-27 | 山东博拓塑业股份有限公司 | PVC high-foaming alloy material and preparation method thereof |
-
2014
- 2014-12-15 CN CN201410777208.4A patent/CN104448631B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104448631A (en) | 2015-03-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104448631B (en) | High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof | |
| CN101168311B (en) | Composite material and preparation method thereof | |
| CN104372909A (en) | High-abrasion-resistance sound insulation wood-plastic decorative sheet and continuous manufacturing method thereof | |
| CN104387704B (en) | Weatherproof hits polyvinyl chloride wood plastic building mould and preparation method thereof | |
| WO2021121144A1 (en) | High-performance ecological spc floor board and preparation process therefor | |
| CN101941310B (en) | Plastic wood board with high weather resistance and processing method thereof | |
| CN104610631A (en) | Ultra-thin resin foamed sheet as well as production method and application thereof | |
| CN102532754A (en) | Crosslinking type polyvinyl chloride/thermoplastic polyurethane light foaming material and preparation method thereof | |
| CN103756179A (en) | Foamed plastic for making highway stand column and preparation method thereof | |
| CN110406222A (en) | A kind of weather-proof colored box material of foaming PVC co-extrusion and preparation method thereof | |
| CN102464841A (en) | Hard polyvinyl chloride foamed sheet | |
| CN103160055A (en) | Outdoor ASA / PVC-M co-extrusion pipe compositions and preparation technology thereof | |
| CN104893156A (en) | 6-17mm-thick polyvinyl chloride foamed poster board and preparation method thereof | |
| CN104004302B (en) | A kind of low density polyvinyl-chloride foam material and its preparation method | |
| CN111574781A (en) | High-weather-resistance polyvinyl chloride light-blocking foam board and preparation method thereof | |
| CN102344623A (en) | Outdoor polymeric environment-friendly floor | |
| CN107459735A (en) | Environment-protective polychloroethylene material composition and its preparation method and application | |
| CN112759857B (en) | ASA (acrylonitrile styrene acrylate) resin co-extrusion PVC (polyvinyl chloride) -based wood-plastic composite material as well as preparation method and application thereof | |
| CN106118389A (en) | A kind of sand streak pure polyester-type weather-resistant powder paint and preparation method thereof | |
| CN109181165A (en) | Low-cost polyvinyl chloride acoustic celotex board | |
| CN102729480A (en) | Method for producing low-foaming PVC (polyvinyl chloride) crust board | |
| WO2016082066A1 (en) | High-abrasion-resistance sound insulation wood-plastic decorative sheet and continuous manufacturing method therefor | |
| CN107652611A (en) | The extra-weather-proof ASA/PMMA color coextrusions material of imitation wood line and preparation method | |
| CN110483910A (en) | A kind of PVC wood plastic foamed board and preparation method thereof | |
| CN103540115A (en) | Preparation method of novel energy-saving construction material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High-weather-proof polyvinyl chloride foamed advertisement board and preparation method thereof Effective date of registration: 20190408 Granted publication date: 20170118 Pledgee: Agricultural Bank of China, Limited by Share Ltd, Yiyuan county subbranch Pledgor: Shandong Po Extension Plastics Co., Ltd. Registration number: 2019370000068 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Yue Walled Village Yiyuan County town of Shandong city of Zibo province 256102 Patentee after: Shandong Botuo New Material Technology Co., Ltd Address before: Yue Walled Village Yiyuan County town of Shandong city of Zibo province 256102 Patentee before: Shandong Po Extension Plastics Co., Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CB03 | Change of inventor or designer information |
Inventor after: Ma Jian Inventor after: Sun Feng Inventor after: Miao Wei Inventor after: Miao Xiangcheng Inventor before: Zhou Xuewei Inventor before: Sun Feng Inventor before: Wang Changming Inventor before: Miao Wei |
|
| CB03 | Change of inventor or designer information | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20211222 Granted publication date: 20170118 Pledgee: Agricultural Bank of China Limited by Share Ltd. Yiyuan county subbranch Pledgor: SHANDONG BOTUO PLASTIC INDUSTRY Co.,Ltd. Registration number: 2019370000068 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |