CN104891866A - Formula and production process of wear-resistant stone plate - Google Patents
Formula and production process of wear-resistant stone plate Download PDFInfo
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- CN104891866A CN104891866A CN201510180067.2A CN201510180067A CN104891866A CN 104891866 A CN104891866 A CN 104891866A CN 201510180067 A CN201510180067 A CN 201510180067A CN 104891866 A CN104891866 A CN 104891866A
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Abstract
The present invention belongs to the technical field of stone plates, and particularly relates to a wear-resistant stone plate, which comprises, by mass, 22-42% of an unsaturated resin, 10-20% of high white silicon micro-powder, 10-25% of aluminum hydroxide, 25-68% of a filler, 0.5-1.5% of a color paste, 1-2% of an ultraviolet absorber, 3-8% of methyl methacrylate, 0.1-0.5% of a coupling agent, 0.2-0.8% of a plasticizer, 0.2-0.4% of an accelerator, and 0.4-0.8% of a constant temperature curing agent. Compared with the formula and the production process in the prior art, the formula and the production process of the present invention have the following characteristics that the high white silicon micro-powder, the aluminum hydroxide, the filler and the like are added, such that the stone plate prepared by using the formula has advantages of high hardness and good wear resistance; the ultraviolet absorber is added, such that the good delaying and inhibition effect is provided for color changing, aging and the like during the use process so as to improve the light resistance of the stone plate; and the stone plate prepared by using the formula has advantages of no toxicity, long acting, no odor, color changing resistance, and aging resistance.
Description
Technical field
The invention belongs to stone slab technical field, particularly relate to formula and the production technique thereof of the wear-resisting stone slab of a kind of Buddha's warrior attendant.
Background technology
At present, the hardness of finishing stone slab is not high enough, and wears no resistance, and easily damaged after the use of one end time, therefore, the work-ing life of stone slab of the prior art is shorter.
In view of this, necessary formula and the production technique thereof providing the wear-resisting stone slab of a kind of Buddha's warrior attendant, adopt the stone slab of this composition and engineering to have hardness is high, wear resistance is good feature, therefore adopts the work-ing life of the stone slab of this composition and engineering longer.
Summary of the invention
The object of the invention is to: for the deficiencies in the prior art, and the formula of the wear-resisting stone slab of a kind of Buddha's warrior attendant is provided, adopt the stone slab of this formula to have hardness is high, wear resistance is good feature, therefore adopt the work-ing life of the stone slab of this composition and engineering longer.
In order to achieve the above object, the present invention adopts following technical scheme:
The formula of the wear-resisting stone slab of Buddha's warrior attendant, by mass percentage, comprises following component: unsaturated polyester 22% ~ 42%;
High white silicon powder 10% ~ 20%;
Aluminium hydroxide 10% ~ 25%;
Filler 20% ~ 68%;
Mill base 0.5% ~ 1.5%;
UV light absorber 1% ~ 2%;
Methyl methacrylate 3% ~ 8%;
Coupling agent 0.1% ~ 0.5%;
Softening agent 0.2% ~ 0.8%;
Promotor 0.2% ~ 0.4%;
Isothermal curing agent 0.4% ~ 0.8%;
Described unsaturated polyester comprises artificial unsaturated polyester resin particle (artificial UP particle), and the mass percent of described artificial unsaturated polyester resin particle is 2% ~ 10%.
Wherein, unsaturated polyester can play the effect of caking agent, and high white silicon powder is by natural quartz (SiO
2) or fused quartz (natural quartz is through high-temperature fusion, cooled amorphous Si O
2) through the micro mist of the multiple tracks processes such as broken, ball milling (or vibration, airflow milling), flotation, pickling purification, high purity water process.Silicon powder is a kind of nontoxic, tasteless, free of contamination ceramic.It has that temperature tolerance is good, acid-alkali-corrosive-resisting, poor thermal conductivity, high insulation, low bulk, stable chemical performance and the hardness excellent performance such as large.The stone slab that aluminium hydroxide is made after mixing with artificial unsaturated polyester resin particle has the texture as agate, and after toning, combinations color and lustre is bright-coloured.Unsaturated polyester aggregates into a macromolecular mass by chemical reaction, filler parcel is enlisted the services of in wherein, filler can increase product strength, regulate product texture, also can play an important role to reducing costs, aluminium hydroxide is a kind of odorless, tasteless, nontoxic white powder, molecule includes crystal water, it is fire retardant, and due to its refractive index high, thus make the stone slab made have beautiful general translucent texture.
The mass ratio of unsaturated polyester and filler (be called Jiao Ji than) is suitable could allow product density is high, bubble-free, not yielding.If Jiao Ji is than too high, then product shrinkage strain is large, and cost is also high, if Jiao Ji is than little, then bubble is difficult to discharge, and difficult forming, product scrap rate is high, increases cost equally.
Relative to prior art, the present invention is owing to adding high white silicon powder, aluminium hydroxide and filler etc., therefore the stone slab adopting this formula to prepare has the advantage that hardness is large, wear resistance is good, and its shock-resistance and mar-resistance good, resistance to deformation and quenching quenching good, and the present invention is by adding UV light absorber, good delaying and rejection ability can be had to the variable color in use procedure, aging etc., thus improve the photostabilization of stone slab.In a word, adopt stone slab non-toxic long-acting prepared by this formula, free from extraneous odour, there is Anti-tarnishing, ageing-resistant advantage.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, and by mass percentage, comprises following component:
Unsaturated polyester 23% ~ 30%;
High white silicon powder 12% ~ 17%;
Aluminium hydroxide 12% ~ 22%;
Filler 25% ~ 60%;
Mill base 0.8% ~ 1.2%;
UV light absorber 1.2% ~ 1.7%;
Methyl methacrylate 4% ~ 7%;
Coupling agent 0.2% ~ 0.4%;
Softening agent 0.3% ~ 0.6%;
Promotor 0.25% ~ 0.35%;
Isothermal curing agent 0.5% ~ 0.7%;
The mass percent of described artificial unsaturated polyester resin particle is 3% ~ 8%.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, and by mass percentage, comprises following component:
Unsaturated polyester 24%;
High white silicon powder 13%;
Aluminium hydroxide 14%;
Filler 35%;
Mill base 1%;
UV light absorber 1.4%;
Methyl methacrylate 5%;
Coupling agent 0.3%;
Softening agent 0.4%;
Promotor 0.3%;
Isothermal curing agent 0.6%;
The mass percent of described artificial unsaturated polyester resin particle is 5%.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, and described unsaturated polyester also comprises at least one in resol and epoxy resin.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, and described filler is at least one in aluminium bits, aluminium powder, aluminium borate whisker, aluminum oxide, hard coal, sodium antimonate, ANTIMONY TRIOXIDE SB 203 99.8 PCT, barium metaborate, barium sulfate, barium titanate, wilkinite, boron oxide, calcium carbonate, calcium hydroxide, calcium sulfate, ceramic microsphere, clay, diatomite, kaolin, magnesium oxide, magnesium hydroxide, silicon-dioxide, silica gel, talcum, titanium dioxide and zeolite.Adding of filler can improve processing characteristics, mechanical property, reduces the cost of stone slab simultaneously.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, described UV light absorber is salicylic acid phenyl ester, 2-(2 ˊ-hydroxyl-5 ˊ-aminomethyl phenyl) benzotriazole, 2,4-dihydroxy benaophenonel, ESCALOL 567,2-(2 '-hydroxyl-3 ', 5 '-two tertiary phenyl) at least one in-5-chlorination benzotriazole and single phenylformic acid resorcinol.UV light absorber is a kind of photostabilizer, can absorb the ultraviolet part in sunlight and fluorescence light source, and itself does not change, and it can prevent or suppress the color molecule of ultraviolet to stone slab and the Decomposition of other molecules.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, and described coupling agent is silane coupling agent or phthalate ester coupling agent.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, and described softening agent is at least one in phthalic acid two (2-ethyl hexyl) ester, dioctyl phthalate (DOP) and dibutyl phthalate.
One as the formula of the wear-resisting stone slab of Buddha's warrior attendant of the present invention is improved, and described promotor is at least one in cobalt naphthenate, cobalt iso-octoate, isocaprylic acid zinc, DMA, N, N-Diethyl Aniline and vanadium phosphate; Described isothermal curing agent is at least one in diamino-cyclohexane, isophorone diamine and methylene-bis hexamethylene alkanamine.
Another object of the present invention is the production technique providing the wear-resisting stone slab of a kind of Buddha's warrior attendant, comprises the following steps:
(1) weighing: take unsaturated polyester, high white silicon powder, aluminium hydroxide, filler, mill base, UV light absorber, methyl methacrylate, coupling agent, softening agent, promotor and isothermal curing agent by above-mentioned formula;
(2) batch mixing: white for height silicon powder, aluminium hydroxide and artificial unsaturated polyester resin particle are poured in mixing tank and stir, the time length of stirring is 60 ~ 120min; ; (3) mill base dilution: get 5% ~ 20% of mill base and remaining unsaturated polyester and add stainless steel cask high speed and stir, the speed of stirring is 200r/min ~ 500r/min, and the time length of stirring is 60 ~ 120min; (4) front stirring: the mill base diluted according to step (3) by remaining unsaturated polyester, filler, UV light absorber, methyl methacrylate, coupling agent, softening agent and promotor add agitation vat high speed and stirs, the speed stirred is 200r/min ~ 500r/min, the time length of stirring is 0.5 ~ 10min, again the batch mixing mixed according to step (2) is added this agitation vat high speed to stir, the speed stirred is 200r/min ~ 500r/min, and the time length of stirring is 0.5 ~ 10min;
(5) stir afterwards: isothermal curing agent added in this agitation vat and carry out high-speed stirring, the speed of stirring is 200r/min ~ 500r/min, and the time length of stirring is 2 ~ 10min, (6) shaping: the slurry be stirred evenly is tiled in grinding tool, send in vacuum chamber and carry out vacuum exhaust, to reach the effect of exhaust (owing to having circulated a large amount of gas in batching whipping process, if the bubble of interiors of products can not be got rid of, quality product can be affected, therefore, de-aeration is very important), after plate forming, oven for baking is sent in molding, storing temperature is 120 DEG C ~ 160 DEG C, the time length of baking is 120 ~ 180min, to realize the solidification of resin, and then the sheet material after baking is carried out pros and cons sanding and polishing rapidly, again the sheet material after sanding and polishing is sent into platform sizing, the time length of sizing is 1440 ~ 2160min, finally water mill polishing is carried out to sheet material.
Relative to prior art, present invention process is simple, is easy to realize industrialization, and the wear-resisting stone slab of Buddha's warrior attendant of preparation has that hardness is large, wear resistance good, non-toxic long-acting, free from extraneous odour, the advantage that photostabilization is good.
Embodiment
Embodiment 1
The formula of the wear-resisting stone slab of a kind of Buddha's warrior attendant that the present embodiment provides, is characterized in that, by mass percentage, comprises following component:
Epoxy resin 24%;
Artificial unsaturated polyester resin particle 5%.
High white silicon powder 13%;
Aluminium hydroxide 14%;
Aluminum oxide 35%;
Mill base 1%;
Salicylic acid phenyl ester 1.4%;
Methyl methacrylate 5%;
Silane coupling agent 0.3%;
Phthalic acid two (2-ethyl hexyl) ester 0.4%;
Cobalt naphthenate 0.3%;
Diamino-cyclohexane 0.6%;
Its production technique comprises the following steps:
(1) weighing: take epoxy resin, artificial unsaturated polyester resin particle, high white silicon powder, aluminium hydroxide, aluminum oxide, mill base, salicylic acid phenyl ester, methyl methacrylate, silane coupling agent, phthalic acid two (2-ethyl hexyl) ester, cobalt naphthenate and diamino-cyclohexane by above-mentioned formula;
(2) batch mixing: white for height silicon powder, aluminium hydroxide and artificial unsaturated polyester resin particle are poured in mixing tank and stir, the time length of stirring is 100min; (3) mill base dilution: get 15% of mill base and epoxy resin and add stainless steel cask high speed and stir, the speed of stirring is 300r/min, and the time length of stirring is 100min; (4) front stirring: the mill base diluted according to step (3) by remaining epoxy resin, aluminum oxide, salicylic acid phenyl ester, methyl methacrylate, silane coupling agent, phthalic acid two (2-ethyl hexyl) ester and cobalt naphthenate add agitation vat high speed and stir, the speed stirred is 300r/min, the time length of stirring is 1min, again the batch mixing mixed according to step (2) is added this agitation vat high speed to stir, the speed stirred is 300r/min, and the time length of stirring is 1min;
(5) stir afterwards: isothermal curing agent added in this agitation vat and carry out high-speed stirring, the speed of stirring is 300r/min, and the time length of stirring is 3min; (6) shaping: the slurry be stirred evenly is tiled in grinding tool, send in vacuum chamber and carry out vacuum exhaust, to reach the effect of exhaust, after plate forming, oven for baking is sent in molding, and storing temperature is 140 DEG C, the time length of baking is 160min, to realize the solidification of resin, and then the sheet material after baking is carried out pros and cons sanding and polishing rapidly, then the sheet material after sanding and polishing is sent into platform sizing, the time length of sizing is 2000min, finally carries out water mill polishing to sheet material.
Embodiment 2
The formula of the wear-resisting stone slab of the Buddha's warrior attendant that the present embodiment provides, by mass percentage, comprises following component: resol 26%;
Artificial unsaturated polyester resin particle 4%;
High white silicon powder 16%;
Aluminium hydroxide 12%;
Silicon-dioxide 34%;
Mill base 1.2%;
2,4 dihydroxyl benzophenone 1.5%;
Methyl methacrylate 4%;
Titanate coupling agent 0.2%;
Dioctyl phthalate (DOP) 0.35%;
Cobalt iso-octoate 0.25%;
Isophorone diamine 0.5%;
Production technique, comprises the following steps:
(1) weighing: take resol, artificial unsaturated polyester resin particle, high white silicon powder, aluminium hydroxide, silicon-dioxide, mill base, 2,4 dihydroxyl benzophenone, methyl methacrylate, titanate coupling agent, dioctyl phthalate (DOP), cobalt iso-octoate and isophorone diamine by above-mentioned formula;
(2) batch mixing: white for height silicon powder, aluminium hydroxide and artificial unsaturated polyester resin particle are poured in mixing tank and stir, the time length of stirring is 60 ~ 120min; ; (3) mill base dilution: get 10% of mill base and resol and add stainless steel cask high speed and stir, the speed of stirring is 250r/min, and the time length of stirring is 80min; (4) front stirring: mill base, silicon-dioxide, 2 that remaining resol has been diluted according to step (3), 4-dihydroxy benaophenonel, methyl methacrylate, titanate coupling agent, dioctyl phthalate (DOP) and cobalt iso-octoate add agitation vat high speed and stir, the speed stirred is 250r/min, the time length of stirring is 5min, again the batch mixing mixed according to step (2) is added this agitation vat high speed to stir, the speed stirred is 300r/min, and the time length of stirring is 4min;
(5) stir afterwards: added by isophorone diamine in this agitation vat and carry out high-speed stirring, the speed of stirring is 250r/min, and the time length of stirring is 5min; (6) shaping: the slurry be stirred evenly is tiled in grinding tool, send in vacuum chamber and carry out vacuum exhaust, to reach the effect of exhaust, after plate forming, oven for baking is sent in molding, and storing temperature is 150 DEG C, the time length of baking is 170min, to realize the solidification of resin, and then the sheet material after baking is carried out pros and cons sanding and polishing rapidly, then the sheet material after sanding and polishing is sent into platform sizing, the time length of sizing is 1500min, finally carries out water mill polishing to sheet material.
Embodiment 3
The formula of the wear-resisting stone slab of a kind of Buddha's warrior attendant that the present embodiment provides, by mass percentage, comprises following component: epoxy resin 30%;
Artificial unsaturated polyester resin particle 8%;
High white silicon powder 18%;
Aluminium hydroxide 11%;
Calcium carbonate 21%;
Mill base 1.2%;
Single phenylformic acid resorcinol 1.9%;
Methyl methacrylate 7%;
Silane coupling agent 0.4%;
Dibutyl phthalate 0.6%;
Cobalt iso-octoate 0.35%;
Methylene-bis hexamethylene alkanamine 0.55%;
Its production technique comprises the following steps:
(1) weighing: take epoxy resin, artificial unsaturated polyester resin particle, high white silicon powder, aluminium hydroxide, calcium carbonate, mill base, single phenylformic acid resorcinol, methyl methacrylate, silane coupling agent, dibutyl phthalate, cobalt iso-octoate and methylene-bis hexamethylene alkanamine by above-mentioned formula;
(2) batch mixing: white for height silicon powder, aluminium hydroxide and artificial unsaturated polyester resin particle are poured in mixing tank and stir, the time length of stirring is 70min; ; (3) mill base dilution: get 7% of mill base and epoxy resin and add stainless steel cask high speed and stir, the speed of stirring is 350r/min, and the time length of stirring is 70min; (4) front stirring: the mill base diluted according to step (3) by remaining epoxy resin, calcium carbonate, single phenylformic acid resorcinol, methyl methacrylate, silane coupling agent, dibutyl phthalate and cobalt iso-octoate add agitation vat high speed and stir, the speed stirred is 350r/min, the time length of stirring is 8min, again the batch mixing mixed according to step (2) is added this agitation vat high speed to stir, the speed stirred is 400r/min, and the time length of stirring is 6min;
(5) stir afterwards: added in this agitation vat by methylene-bis hexamethylene alkanamine and carry out high-speed stirring, the speed of stirring is 350r/min, and the time length of stirring is 7min; (6) shaping: the slurry be stirred evenly is tiled in grinding tool, send in vacuum chamber and carry out vacuum exhaust, to reach the effect of exhaust, after plate forming, oven for baking is sent in molding, and storing temperature is 145 DEG C, the time length of baking is 165min, to realize the solidification of resin, and then the sheet material after baking is carried out pros and cons sanding and polishing rapidly, then the sheet material after sanding and polishing is sent into platform sizing, the time length of sizing is 1800min, finally carries out water mill polishing to sheet material.
Embodiment 4
The formula of the wear-resisting stone slab of the Buddha's warrior attendant that the present embodiment provides, by mass percentage, comprises following component: resol 22% ~ 42%;
Artificial unsaturated polyester resin particle 6%;
High white silicon powder 11%;
Aluminium hydroxide 22%;
Kaolin 20% ~ 68%;
Mill base 0.6%;
2-(2 ˊ-hydroxyl-5 ˊ-aminomethyl phenyl) benzotriazole 1.1%;
Methyl methacrylate 3.5%;
Silane coupling agent 0.45%;
Dioctyl phthalate (DOP) 0.25%;
Vanadium phosphate 0.25%;
Diamino-cyclohexane 0.65%;
Its production technique comprises the following steps:
(1) weighing: take resol, artificial unsaturated polyester resin particle, high white silicon powder, aluminium hydroxide, kaolin, mill base, 2-(2 ˊ-hydroxyl-5 ˊ-aminomethyl phenyl by above-mentioned formula) benzotriazole, methyl methacrylate, silane coupling agent, dioctyl phthalate (DOP), vanadium phosphate and diamino-cyclohexane;
(2) batch mixing: white for height silicon powder, aluminium hydroxide and artificial unsaturated polyester resin particle are poured in mixing tank and stir, the time length of stirring is 110min; ; (3) mill base dilution: get 13% of mill base and resol and add stainless steel cask high speed and stir, the speed of stirring is 250r/min, and the time length of stirring is 80min; (4) front stirring: the mill base that remaining resol has been diluted according to step (3), kaolin, 2-(2 ˊ-hydroxyl-5 ˊ-aminomethyl phenyl) benzotriazole, methyl methacrylate, silane coupling agent, dioctyl phthalate (DOP) and vanadium phosphate add agitation vat high speed stir, the speed stirred is 400r/min, the time length of stirring is 3min, again the batch mixing mixed according to step (2) is added this agitation vat high speed to stir, the speed stirred is 400r/min, and the time length of stirring is 3min;
(5) stir afterwards: diamino-cyclohexane added in this agitation vat and carry out high-speed stirring, the speed of stirring is 350r/min, and the time length of stirring is 3min; (6) shaping: the slurry be stirred evenly is tiled in grinding tool, send in vacuum chamber and carry out vacuum exhaust, to reach the effect of exhaust, after plate forming, oven for baking is sent in molding, and storing temperature is 150 DEG C, the time length of baking is 150min, to realize the solidification of resin, and then the sheet material after baking is carried out pros and cons sanding and polishing rapidly, then the sheet material after sanding and polishing is sent into platform sizing, the time length of sizing is 1900min, finally carries out water mill polishing to sheet material.
The announcement of book and instruction according to the above description, those skilled in the art in the invention can also change above-mentioned embodiment and revise.Therefore, the present invention is not limited to embodiment disclosed and described above, also should fall in the protection domain of claim of the present invention modifications and changes more of the present invention.In addition, although employ some specific terms in this specification sheets, these terms just for convenience of description, do not form any restriction to the present invention.
Claims (10)
1. the formula of the wear-resisting stone slab of Buddha's warrior attendant, is characterized in that, by mass percentage, comprises following component: unsaturated polyester 22% ~ 42%;
High white silicon powder 10% ~ 20%;
Aluminium hydroxide 10% ~ 25%;
Filler 20% ~ 68%;
Mill base 0.5% ~ 1.5%;
UV light absorber 1% ~ 2%;
Methyl methacrylate 3% ~ 8%;
Coupling agent 0.1% ~ 0.5%;
Softening agent 0.2% ~ 0.8%;
Promotor 0.2% ~ 0.4%;
Isothermal curing agent 0.4% ~ 0.8%;
Described unsaturated polyester comprises artificial unsaturated polyester resin particle, and the mass percent of described artificial unsaturated polyester resin particle is 2% ~ 10%.
2. the formula of the wear-resisting stone slab of Buddha's warrior attendant according to claim 1, is characterized in that, by mass percentage, comprises following component:
Unsaturated polyester 23% ~ 30%;
High white silicon powder 12% ~ 17%;
Aluminium hydroxide 12% ~ 22%;
Filler 25% ~ 60%;
Mill base 0.8% ~ 1.2%;
UV light absorber 1.2% ~ 1.7%;
Methyl methacrylate 4% ~ 7%;
Coupling agent 0.2% ~ 0.4%;
Softening agent 0.3% ~ 0.6%;
Promotor 0.25% ~ 0.35%;
Isothermal curing agent 0.5% ~ 0.7%;
The mass percent of described artificial unsaturated polyester resin particle is 3% ~ 8%.
3. the formula of the wear-resisting stone slab of Buddha's warrior attendant according to claim 2, is characterized in that, by mass percentage, comprises following component:
Unsaturated polyester 24%;
High white silicon powder 13%;
Aluminium hydroxide 14%;
Filler 35%;
Mill base 1%;
UV light absorber 1.4%;
Methyl methacrylate 5%;
Coupling agent 0.3%;
Softening agent 0.4%;
Promotor 0.3%;
Isothermal curing agent 0.6%;
The mass percent of described artificial unsaturated polyester resin particle is 5%.
4. the formula of the wear-resisting stone slab of the Buddha's warrior attendant according to any one of claims 1 to 3, is characterized in that: described unsaturated polyester also comprises at least one in resol and epoxy resin.
5. the formula of the wear-resisting stone slab of the Buddha's warrior attendant according to any one of claims 1 to 3, is characterized in that: described filler is at least one in aluminium bits, aluminium powder, aluminium borate whisker, aluminum oxide, hard coal, sodium antimonate, ANTIMONY TRIOXIDE SB 203 99.8 PCT, barium metaborate, barium sulfate, barium titanate, wilkinite, boron oxide, calcium carbonate, calcium hydroxide, calcium sulfate, ceramic microsphere, clay, diatomite, kaolin, magnesium oxide, magnesium hydroxide, silicon-dioxide, silica gel, talcum, titanium dioxide and zeolite.
6. the formula of the wear-resisting stone slab of the Buddha's warrior attendant according to any one of claims 1 to 3, it is characterized in that: described UV light absorber is salicylic acid phenyl ester, 2-(2 ˊ-hydroxyl-5 ˊ-aminomethyl phenyl) benzotriazole, 2,4-dihydroxy benaophenonel, ESCALOL 567,2-(2 '-hydroxyl-3 ', 5 '-two tertiary phenyl) at least one in-5-chlorination benzotriazole and single phenylformic acid resorcinol.
7. the formula of the wear-resisting stone slab of the Buddha's warrior attendant according to any one of claims 1 to 3, is characterized in that: described coupling agent is silane coupling agent or phthalate ester coupling agent.
8. the formula of the wear-resisting stone slab of the Buddha's warrior attendant according to any one of claims 1 to 3, is characterized in that: described softening agent is at least one in phthalic acid two (2-ethyl hexyl) ester, dioctyl phthalate (DOP) and dibutyl phthalate.
9. the formula of the wear-resisting stone slab of the Buddha's warrior attendant according to any one of claims 1 to 3, is characterized in that: described promotor is at least one in cobalt naphthenate, cobalt iso-octoate, isocaprylic acid zinc, DMA, N, N-Diethyl Aniline and vanadium phosphate; Described isothermal curing agent is at least one in diamino-cyclohexane, isophorone diamine and methylene-bis hexamethylene alkanamine.
10. a production technique for the wear-resisting stone slab of Buddha's warrior attendant, is characterized in that, comprise the following steps:
(1) weighing: take unsaturated polyester, high white silicon powder, aluminium hydroxide, filler, mill base, UV light absorber, methyl methacrylate, coupling agent, softening agent, promotor and isothermal curing agent by the formula described in any one of claim 1 to 9;
(2) batch mixing: white for height silicon powder, aluminium hydroxide and artificial unsaturated polyester resin particle are poured in mixing tank and stir, the time length of stirring is 60 ~ 120min; ; (3) mill base dilution: get 5% ~ 20% of mill base and remaining unsaturated polyester and add stainless steel cask high speed and stir, the speed of stirring is 200r/min ~ 500r/min, and the time length of stirring is 60 ~ 120min; (4) front stirring: the mill base diluted according to step (3) by remaining unsaturated polyester, filler, UV light absorber, methyl methacrylate, coupling agent, softening agent and promotor add agitation vat high speed and stirs, the speed stirred is 200r/min ~ 500r/min, and the time length of stirring is 0.5 ~ 10min; The batch mixing mixed according to step (2) is added this agitation vat high speed to stir, the speed of stirring is 200r/min ~ 500r/min, and the time length of stirring is 0.5 ~ 10min again;
(5) stir afterwards: isothermal curing agent added in this agitation vat and carry out high-speed stirring, the speed of stirring is 200r/min ~ 500r/min, and the time length of stirring is 2 ~ 10min; (6) shaping: the slurry be stirred evenly is tiled in grinding tool, send in vacuum chamber and carry out vacuum exhaust, after plate forming, oven for baking is sent in molding, storing temperature is 120 DEG C ~ 160 DEG C, the time length of baking is 120 ~ 180min, and then the sheet material after baking is carried out pros and cons sanding and polishing rapidly, then the sheet material after sanding and polishing is sent into platform sizing, the time length of sizing is 1440 ~ 2160min, finally carries out water mill polishing to sheet material.
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| CN105217999A (en) * | 2015-10-14 | 2016-01-06 | 苏州法斯特信息科技有限公司 | A kind of high temperature resistant and wear-resisting composite resin material table top |
| CN106242365A (en) * | 2016-08-03 | 2016-12-21 | 广州戈兰迪新材料股份有限公司 | A kind of high intensity heavy antisepsis height anti-soil quartzite slate and preparation method thereof |
| CN108726920A (en) * | 2018-07-05 | 2018-11-02 | 珠海市盛西源机电设备有限公司 | A kind of preparation method of Z-Correct bump mapping Z-correct artificial stone |
| CN109678395A (en) * | 2019-01-22 | 2019-04-26 | 安徽唯楚新材料有限公司 | A kind of wear-resisting compound silicon aluminum plate of imitation stone and preparation method thereof |
| CN111302704A (en) * | 2020-02-25 | 2020-06-19 | 清远戈兰迪高分子材料有限公司 | Antibacterial artificial stone, preparation method thereof and building material |
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| CN108726920A (en) * | 2018-07-05 | 2018-11-02 | 珠海市盛西源机电设备有限公司 | A kind of preparation method of Z-Correct bump mapping Z-correct artificial stone |
| CN109678395A (en) * | 2019-01-22 | 2019-04-26 | 安徽唯楚新材料有限公司 | A kind of wear-resisting compound silicon aluminum plate of imitation stone and preparation method thereof |
| CN111302704A (en) * | 2020-02-25 | 2020-06-19 | 清远戈兰迪高分子材料有限公司 | Antibacterial artificial stone, preparation method thereof and building material |
| CN111302704B (en) * | 2020-02-25 | 2021-12-21 | 清远戈兰迪高分子材料有限公司 | Antibacterial artificial stone, preparation method thereof and building material |
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