CN104891626A - Water treatment chemical for removing aniline compounds in water - Google Patents
Water treatment chemical for removing aniline compounds in water Download PDFInfo
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- CN104891626A CN104891626A CN201510355911.0A CN201510355911A CN104891626A CN 104891626 A CN104891626 A CN 104891626A CN 201510355911 A CN201510355911 A CN 201510355911A CN 104891626 A CN104891626 A CN 104891626A
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Abstract
The invention relates to water treatment chemical for removing aniline compounds in water. The water treatment chemical is made from 3, 7-dimethyl-6-octenal, 4-formylphenyl Beta-D-allopyranoside, thymopentin, aluminum sulfate, trans, trans-2, 4-nonadienal, 2-hydroxyl-4-isopropyl-2, 4, 6-cycloheptatriene-1-one, alpha-aminoisocaproic acid, potassium alginate, methylandrostenediol, (S)-2-(fmoc-amino)caproic acid, isoimperatorin, 1-pentadecanol, 3, 7, 11-trimethyl-1, 6, 10-dodecatriene-3-ol, D-acridine-2-carboxylic acid, and 2-ethyl-2, 5-dimethylhexanoic acid. The water treatment chemical has the advantages that the chemical has high ability to complex with the aniline compounds, complex precipitant forms fast, the removal rate of the aniline compounds is up to 99%, and the chemical is low in toxicity, low in use amount, free of harm to water and low in treatment cost.
Description
Technical field
The present invention relates to a kind of water conditioner removing amino benzenes compounds in water, belong to environmental protection technical field.
Background technology
Aniline is commonly called as aniline oils, and outward appearance is colourless or light yellow clear oily liquids, has strong impulse smell, and molecular formula is C
6h
7n, fusing point is-6.3 DEG C, and boiling point is 184 DEG C, and relative density is 1.0217(20/4 DEG C), refractive index is 1.5863, and flash-point is 70 DEG C, exposes in atmosphere or easily becomes brown under daylight.Aniline is slightly soluble in water, can be miscible with ethanol, ether, acetone, tetracol phenixin and benzene, also dissolves in industrial naptha.
Aniline is the most representative material of aromatic amine, be widely used in national defence, printing and dyeing, plastics, paint, agricultural chemicals and medicine industry etc., the objectionable impurities being simultaneously also serious environment pollution and being detrimental to health is that three of a kind of " carcinogenic, teratogenesis, mutagenesis " cause material.There is due to aniline the features such as extended residual, bioconcentration, carinogenicity, be classified as 129 kinds of pollutents of priority acccess control by U.S. EPA; China is by aniline, dinitraniline, p-Nitroaniline, and 2,6-Dichloran is classified as the Aniline categories of priority acccess control, requires strict control in industrial water drainage.The traditional method of process aniline waste water mainly contains the methods such as physics, chemistry, biology.
Physical comprises physisorphtion, complexing abstraction and membrane separation process; Chemical method comprises supercritical water oxidation method, sonication, wet oxidation process, electrochemical degradation method, Ozonation, Fenton oxidation method, Heterogeneous photo catalytic oxidation processes, homogeneous photochemical catalysis oxidation style and ClO 2 catalyzed oxidation method etc.; Biological process comprises anaerobic hydrolysis-biological contact oxidation process and dominant bacteria-activated sludge process.Wherein chemical method due to processing cost higher, apparatus and process is more complicated, cannot drop at present industrialization run, the such environmental effects such as biological process is subject to sewage influent concentration, temperature of reaction, reaction PH are larger, and aniline strong toxicity degradation property is poor, is very limited in actual applications.In Physical, the clearance of physisorphtion is lower, is only about 80%, organic solvent in complexing abstraction may cause the secondary pollution to environment, and membrane separation process capital cost and running expense higher, need regular soak cleaning, and its thickened waste water treatment is comparatively difficult.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of water conditioner removing amino benzenes compounds in water, it can with the amino benzenes compounds effect in water, form complex compound sediment, remove by filtering, there is low toxicity, non-environmental-pollution, clearance is high, the advantage that cost is low.
Technology contents of the present invention is: a kind of water conditioner removing amino benzenes compounds in water, comprises the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 10-20 part,
4-formylphenyl β-D-Ah coughing up pyranoside 6-12 part,
Thymopeptide-5 0.4-1.0 part,
Tai-Ace S 150 15-20 part,
Instead, trans-2,4-nonadienal 10-20 parts,
2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.5-1.2 part,
Alpha-amino group isocaproic acid 6-14 part,
Potassium alginate 10-15 part,
Anadrol 3-8 part,
Fluorenes methoxy carbonyl acyl group nor-leucine 2-6 part,
Isoimperatorin 2-5 part,
1-pentadecanol 5-10 part,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 15-30 part,
D-acridine-2-carboxylic acid 5-8 part,
2-ethyl-2,5-dimethylhexanoic acid 4-6 part.
Preferably, the raw material of the following meter of mark is by weight comprised:
3,7-dimethyl-6-octenal 15 parts,
4-formylphenyl β-D-Ah coughing up pyranoside 9 parts,
Thymopeptide-5 0.7 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 15 parts,
2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.8 part,
Alpha-amino group isocaproic acid 10 parts,
Potassium alginate 12 parts,
Anadrol 5 parts,
Fluorenes methoxy carbonyl acyl group nor-leucine 4 parts,
Isoimperatorin 3 parts,
1-pentadecanol 7 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,
D-acridine-2-carboxylic acid 6 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
The present invention has following beneficial effect:
(1) 3,7-dimethyl-6-octenal, 4-formylphenyl β-D-Ah coughing up pyranoside, thymopeptide-5, Tai-Ace S 150 four kinds of materials produce synergy, can with aniline effect, form complex compound sediment; Instead, trans-2,4-nonadienal, 2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone, alpha-amino group isocaproic acid, potassium alginate, anadrol, fluorenes methoxy carbonyl acyl group nor-leucine six kinds of materials produce synergy, can with dinitraniline and p-Nitroaniline effect, formed complex compound sediment; Isoimperatorin, 1-pentadecanol, 3,7,11-trimethylammoniums-1,6,10-12 carbon triolefin-3-alcohol, D-acridine-2-carboxylic acid, 2-ethyl-2,5-dimethylhexanoic acid five kinds of materials produce synergy, can with the effect of 2,6-Dichloran, form complex compound sediment;
(2) strong with the complex ability of amino benzenes compounds, form complex compound sediment speed fast, clearance can reach 99%;
(3) hypotoxicity, consumption is few, does not produce harm to water body;
(4) only need dosing and filtering separation device, low for equipment requirements, processing cost is low.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but the present invention's scope required for protection is not limited to the described scope of embodiment.
Embodiment 1
Remove a water conditioner for amino benzenes compounds in water, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 11 parts,
4-formylphenyl β-D-Ah coughing up pyranoside 8 parts,
Thymopeptide-5 0.5 part,
16 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 12 parts,
2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.6 part,
Alpha-amino group isocaproic acid 13 parts,
Potassium alginate 12 parts,
Anadrol 4 parts,
Fluorenes methoxy carbonyl acyl group nor-leucine 3 parts,
Isoimperatorin 4 parts,
1-pentadecanol 8 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 23 parts,
D-acridine-2-carboxylic acid 7 parts,
2-ethyl-2,5-dimethylhexanoic acid 6 parts.
Before process: containing aniline 10mg, dinitraniline 5mg, p-Nitroaniline 5mg in 1L water sample, add this water conditioner 50mg;
After process: all do not detect containing aniline 0.01mg, dinitraniline and p-Nitroaniline in 1L water sample.
Embodiment 2
Remove a water conditioner for amino benzenes compounds in water, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 16 parts,
4-formylphenyl β-D-Ah coughing up pyranoside 8 parts,
Thymopeptide-5 0.8 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 17 parts,
2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.9 part,
Alpha-amino group isocaproic acid 11 parts,
Potassium alginate 13 parts,
Anadrol 6 parts,
Fluorenes methoxy carbonyl acyl group nor-leucine 3 parts,
Isoimperatorin 4 parts,
1-pentadecanol 8 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 25 parts,
D-acridine-2-carboxylic acid 7 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
Before process: containing aniline 10mg, dinitraniline 10mg, 2,6-Dichloran 10mg in 1L water sample, add this water conditioner 50mg;
After process: all do not detect containing aniline, dinitraniline and 2,6-Dichloran in 1L water sample.
Embodiment 3
Remove a water conditioner for amino benzenes compounds in water, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 15 parts,
4-formylphenyl β-D-Ah coughing up pyranoside 9 parts,
Thymopeptide-5 0.7 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 15 parts,
2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.8 part,
Alpha-amino group isocaproic acid 10 parts,
Potassium alginate 12 parts,
Anadrol 5 parts,
Fluorenes methoxy carbonyl acyl group nor-leucine 4 parts,
Isoimperatorin 3 parts,
1-pentadecanol 7 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,
D-acridine-2-carboxylic acid 6 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
Before process: in 1L water sample containing aniline 15mg, p-Nitroaniline 15mg, 2,6-Dichloran 15mg, add this water conditioner 50mg;
After process: in 1L water sample, aniline, p-Nitroaniline and 2,6-Dichloran all do not detect.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (2)
1. remove a water conditioner for amino benzenes compounds in water, it is characterized in that, comprise following raw material by weight:
3,7-dimethyl-6-octenal 10-20 part,
4-formylphenyl β-D-Ah coughing up pyranoside 6-12 part,
Thymopeptide-5 0.4-1.0 part,
Tai-Ace S 150 15-20 part,
Instead, trans-2,4-nonadienal 10-20 parts,
2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.5-1.2 part,
Alpha-amino group isocaproic acid 6-14 part,
Potassium alginate 10-15 part,
Anadrol 3-8 part,
Fluorenes methoxy carbonyl acyl group nor-leucine 2-6 part,
Isoimperatorin 2-5 part,
1-pentadecanol 5-10 part,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 15-30 part,
D-acridine-2-carboxylic acid 5-8 part,
2-ethyl-2,5-dimethylhexanoic acid is about 4-6 part.
2. the water conditioner of amino benzenes compounds in removal water according to claim 1, is characterized in that, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 15 parts,
4-formylphenyl β-D-Ah coughing up pyranoside 9 parts,
Thymopeptide-5 0.7 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 15 parts,
2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.8 part,
Alpha-amino group isocaproic acid 10 parts,
Potassium alginate 12 parts,
Anadrol 5 parts,
Fluorenes methoxy carbonyl acyl group nor-leucine 4 parts,
Isoimperatorin 3 parts,
1-pentadecanol 7 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,
D-acridine-2-carboxylic acid 6 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510355911.0A CN104891626A (en) | 2015-06-25 | 2015-06-25 | Water treatment chemical for removing aniline compounds in water |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510355911.0A CN104891626A (en) | 2015-06-25 | 2015-06-25 | Water treatment chemical for removing aniline compounds in water |
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| CN104891626A true CN104891626A (en) | 2015-09-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510355911.0A Pending CN104891626A (en) | 2015-06-25 | 2015-06-25 | Water treatment chemical for removing aniline compounds in water |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106115806A (en) * | 2015-09-17 | 2016-11-16 | 温州泓呈祥科技有限公司 | Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003094042A (en) * | 2001-09-25 | 2003-04-02 | Kyosan Electric Mfg Co Ltd | Cleaning waste water treating system |
| CN1850643A (en) * | 2006-05-26 | 2006-10-25 | 南京大学 | Method for degrading aminobenzene or/and nitrobenzene in waste water by electrolytic process |
| CN101244878A (en) * | 2008-02-25 | 2008-08-20 | 南京大学 | Treatment for wastewater in para-nitraniline production and method for resource recovery and use |
| CN101279808A (en) * | 2008-05-28 | 2008-10-08 | 北京大学 | Method for processing nitrobenzene and aniline waste water |
| CN102464395A (en) * | 2011-10-20 | 2012-05-23 | 常州亚环环保科技有限公司 | Composite agent for treatment of aniline wastewater and application method thereof |
-
2015
- 2015-06-25 CN CN201510355911.0A patent/CN104891626A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003094042A (en) * | 2001-09-25 | 2003-04-02 | Kyosan Electric Mfg Co Ltd | Cleaning waste water treating system |
| CN1850643A (en) * | 2006-05-26 | 2006-10-25 | 南京大学 | Method for degrading aminobenzene or/and nitrobenzene in waste water by electrolytic process |
| CN101244878A (en) * | 2008-02-25 | 2008-08-20 | 南京大学 | Treatment for wastewater in para-nitraniline production and method for resource recovery and use |
| CN101279808A (en) * | 2008-05-28 | 2008-10-08 | 北京大学 | Method for processing nitrobenzene and aniline waste water |
| CN102464395A (en) * | 2011-10-20 | 2012-05-23 | 常州亚环环保科技有限公司 | Composite agent for treatment of aniline wastewater and application method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106115806A (en) * | 2015-09-17 | 2016-11-16 | 温州泓呈祥科技有限公司 | Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent |
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Application publication date: 20150909 |
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