CN106115806A - Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent - Google Patents
Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent Download PDFInfo
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- CN106115806A CN106115806A CN201510590382.2A CN201510590382A CN106115806A CN 106115806 A CN106115806 A CN 106115806A CN 201510590382 A CN201510590382 A CN 201510590382A CN 106115806 A CN106115806 A CN 106115806A
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- methyl
- dimethylbenzene
- xylol
- meta
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- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 title claims abstract description 77
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229920000180 alkyd Polymers 0.000 title claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 15
- KMAKOBLIOCQGJP-UHFFFAOYSA-N indole-3-carboxylic acid Chemical class C1=CC=C2C(C(=O)O)=CNC2=C1 KMAKOBLIOCQGJP-UHFFFAOYSA-N 0.000 claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 9
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 9
- 239000011976 maleic acid Substances 0.000 claims abstract description 9
- 150000003431 steroids Chemical class 0.000 claims abstract description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 16
- 229910052708 sodium Inorganic materials 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 16
- MECHNRXZTMCUDQ-RKHKHRCZSA-N vitamin D2 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)/C=C/[C@H](C)C(C)C)=C\C=C1\C[C@@H](O)CCC1=C MECHNRXZTMCUDQ-RKHKHRCZSA-N 0.000 claims description 16
- OENHQHLEOONYIE-UKMVMLAPSA-N all-trans beta-carotene Natural products CC=1CCCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C OENHQHLEOONYIE-UKMVMLAPSA-N 0.000 claims description 8
- OGLDWXZKYODSOB-SNVBAGLBSA-N alpha-phellandrene Natural products CC(C)[C@H]1CC=C(C)C=C1 OGLDWXZKYODSOB-SNVBAGLBSA-N 0.000 claims description 8
- TUPZEYHYWIEDIH-WAIFQNFQSA-N beta-carotene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2=CCCCC2(C)C TUPZEYHYWIEDIH-WAIFQNFQSA-N 0.000 claims description 8
- 235000013734 beta-carotene Nutrition 0.000 claims description 8
- 239000011648 beta-carotene Substances 0.000 claims description 8
- 229960002747 betacarotene Drugs 0.000 claims description 8
- 229930182470 glycoside Natural products 0.000 claims description 8
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 8
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 8
- OGLDWXZKYODSOB-UHFFFAOYSA-N α-phellandrene Chemical compound CC(C)C1CC=C(C)C=C1 OGLDWXZKYODSOB-UHFFFAOYSA-N 0.000 claims description 8
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 claims description 8
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 claims description 7
- WWXBHTZSYYGCSG-UHFFFAOYSA-N [4-(carbamoylamino)phenyl]arsonic acid Chemical compound NC(=O)NC1=CC=C([As](O)(O)=O)C=C1 WWXBHTZSYYGCSG-UHFFFAOYSA-N 0.000 claims description 7
- 229950000776 carbarsone Drugs 0.000 claims description 7
- 150000002338 glycosides Chemical class 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 9
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 239000013049 sediment Substances 0.000 abstract description 6
- -1 hydroxyl 3 methyl 4 pentenyl Chemical group 0.000 abstract description 4
- 230000000536 complexating effect Effects 0.000 abstract description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 125000003302 alkenyloxy group Chemical group 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 235000010378 sodium ascorbate Nutrition 0.000 abstract 1
- 229960005055 sodium ascorbate Drugs 0.000 abstract 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 abstract 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 abstract 1
- 239000013076 target substance Substances 0.000 abstract 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000000034 method Methods 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000003851 biochemical process Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000035943 smell Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229940000635 beta-alanine Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- OHFDBBFDFZXHJQ-UHFFFAOYSA-N phenylarsane Chemical compound [AsH2]C1=CC=CC=C1 OHFDBBFDFZXHJQ-UHFFFAOYSA-N 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Treatment Of Liquids With Adsorbents In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention relates to xylol in a kind of removal alkyd resin plant effluent, o-Dimethylbenzene and the inorganic agent of meta-xylene, formed by following components is compounding: (1R, 2R, 8aS) decahydro 1 (3 hydroxyl 3 methyl 4 pentenyl) 2, 5, 5, 8a tetramethyl 2 naphthalene alcohol, poly-maleic acid, bata-carotene, (25R) 5 α spiral shell steroid (alkane) 3 β alcohol, 3 indolecarboxylic acids, 4 acetoxyl group 3 methoxyl group (2 acrylic) benzene, L sodium ascorbate, 4 (3 methyl fourth 2 alkenyloxy group) furo [3, 2 g] .alpha.-5:6-benzopyran 7 ketone, Glycocoll betaine etc..This inorganic agent is strong with the complexing power of target substance, forms complex compound sediment speed fast, and clearance is up to 99.9%, and consumption is few, and water body does not produce harm.
Description
Technical field
The present invention relates to a kind of remove the process of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent
Agent, belongs to environmental protection technical field.
Background technology
Alkyd resin synthesis is main uses solvent method to produce.In solvent method, the evaporator strip of conventional dimethylbenzene goes out esterification water, warp
Again flow back to reactor after crossing the oil-water separation of water knockout drum, the most repeatedly, promote the carrying out of polyesterification reaction, generate alkyd tree
Fat.Therefore alkyd resin plant effluent is mixed with a large amount of benzene kind solvent, predominantly dimethylbenzene.Dimethylbenzene can quite be permanently present in
In drinking-water.When in tap water, the concentration of dimethylbenzene is 5mg/L, its odour intensity is equivalent to 5 grades, and the distinctive smell of dimethylbenzene is then wanted
Spending 7 to 8 days could disappear;Then need 4 to 5 days when odour intensity is 3 grades.The time that in river, the abnormal smells from the patient of dimethylbenzene keeps is shorter,
This is relevant with the height of initial concentration, typically can retain 3 to 5 days.Dump the dimethylbenzene floatability in water on the water surface, or in
Grease is distributed in the water surface, can cause Fish and hydrobiological death.Therefore alkyd resin plant effluent need treated up to standard after
Just can enter environment.
Processing method containing dimethylbenzene waste water mainly has Physical, chemical method and biochemical process at present.The wherein master of chemical method
Photocatalytic oxidation to be, relatively costly, it is not suitable for actual production.It is relatively long that biochemical process processes the time, and dimethylbenzene contains
Measure too high meeting and cause microorganism deactivated.Conventional air-extraction and absorption method in Physical, wherein air-extraction is applicable to have certain life
The production line of product scale, equipment cost is higher;Absorption method is mainly used for the process of low concentration dimethylbenzene waste water, the most frequently used suction
Attached dose is activated carbon or zeolite, and disposal ability is poor.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that to diformazan in a kind of removal alkyd resin plant effluent
The inorganic agent of benzene, o-Dimethylbenzene and meta-xylene, it can be with the xylol in water, o-Dimethylbenzene and meta-xylene effect, shape
Becoming complex compound sediment, removed by filtration, have low toxicity, a non-environmental-pollution, clearance is high, applied widely, low cost excellent
Point.
The technology contents of the present invention is: a kind of remove xylol in alkyd resin plant effluent, o-Dimethylbenzene and two
The inorganic agent of toluene, including the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 10-18 part,
Poly-maleic acid 15-21 part,
Beta-carotene 0.8-1.2 part,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 8-14 part,
3-indolecarboxylic acid 4-8 part,
Cinene 14-20 part,
Sodium pentahydyoxycaproate 10-20 part,
L-AA sodium 0.5-1.1 part,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 8-12 part,
Glycocoll betaine 2-5 part,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 10-16 part,
Iron chloride 12-20 part,
P-ureidobenzenearsonic acid 2-4 part,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 6-12 part,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 6-10 part,
Caulis Marsdeniae Tenacissimae glycosides G 3-7 part.
Preferably, including the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 14 parts,
Poly-maleic acid 18 parts,
Beta-carotene 1.0 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 11 parts,
3-indolecarboxylic acid 6 parts,
Cinene 17 parts,
Sodium pentahydyoxycaproate 15 parts,
0.8 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 10 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 13 parts,
16 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 9 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 8 parts,
Caulis Marsdeniae Tenacissimae glycosides G 5 parts.
There is advantages that
(1) (1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol, poly-
Maleic acid, beta-carotene, (25R)-5 α-spiral shell steroid (alkane)-3 β-ol, five kinds of materials of 3-indolecarboxylic acid produce synergism,
Complex compound sediment can be formed with xylol effect;Cinene, sodium pentahydyoxycaproate, L-AA sodium, 4-(3-methyl butyl-
2-alkenyloxy group) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone, five kinds of materials of Glycocoll betaine produce synergism, and can be with adjacent two
Toluene effect, forms complex compound sediment;2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene, iron chloride, to urea groups phenylarsine
Acid, 5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol, (R)-N-(2,4-dihydroxy-3,3-diformazan
Base-1-oxo butyl)-Beta-alanine, six kinds of materials of Caulis Marsdeniae Tenacissimae glycosides G produce synergism, can be formed with meta-xylene effect
Complex compound sediment;
(2) strong with the complexing power of xylol, o-Dimethylbenzene and meta-xylene, form complex compound sediment speed fast, clearance
Up to more than 99.9%;
(3) hypotoxicity, consumption is few, and water body does not produce harm;
(4) only needing dosing and filtering separation device, low for equipment requirements, processing cost is low;
(5) use at any time and add at any time, do not limited by producing load.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described, but scope of the present invention is also
It is not limited to the scope that embodiment is described.
Embodiment 1
A kind of remove the inorganic agent of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, including following by
The component of weight fraction meter:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 12 parts,
Poly-maleic acid 16 parts,
Beta-carotene 0.9 part,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 9 parts,
3-indolecarboxylic acid 5 parts,
Cinene 16 parts,
Sodium pentahydyoxycaproate 14 parts,
0.7 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 9 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 12 parts,
15 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 8 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 7 parts,
Caulis Marsdeniae Tenacissimae glycosides G 4 parts.
Before process: containing xylol 10mg, o-Dimethylbenzene 10mg in 1L water sample, meta-xylene 10mg, add present treatment agent
50mg;
After process: 1L water sample does not all detect containing o-Dimethylbenzene 0.01mg, xylol and meta-xylene.
Embodiment 2
A kind of remove the inorganic agent of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, including following by
The component of weight fraction meter:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 15 parts,
Poly-maleic acid 19 parts,
Beta-carotene 1.1 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 12 parts,
3-indolecarboxylic acid 7 parts,
Cinene 18 parts,
Sodium pentahydyoxycaproate 16 parts,
0.9 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 11 parts,
Glycocoll betaine 4 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 14 parts,
17 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 10 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 9 parts,
Caulis Marsdeniae Tenacissimae glycosides G 6 parts.
Before process: containing xylol 8mg, o-Dimethylbenzene 12mg in 1L water sample, meta-xylene 12mg, add present treatment agent
50mg;
After process: in 1L water sample, xylol, o-Dimethylbenzene and meta-xylene all do not detect.
Embodiment 3
A kind of remove the inorganic agent of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, including following by
The component of weight fraction meter:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 14 parts,
Poly-maleic acid 18 parts,
Beta-carotene 1.0 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 11 parts,
3-indolecarboxylic acid 6 parts,
Cinene 17 parts,
Sodium pentahydyoxycaproate 15 parts,
0.8 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 10 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 13 parts,
16 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 9 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 8 parts,
Caulis Marsdeniae Tenacissimae glycosides G 5 parts.
Before process: containing xylol 10mg, o-Dimethylbenzene 14mg in 1L water sample, meta-xylene 14mg adds present treatment agent
50mg;
After process: in 1L water sample, xylol, o-Dimethylbenzene and meta-xylene all do not detect.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any
Those of ordinary skill in the art in the technical scope that disclosed herein, the change that can expect without creative work or
Replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims
Fixed protection domain is as the criterion.
Claims (2)
1. removing an inorganic agent for xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, its feature exists
In, including the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 10-18 part,
Poly-maleic acid 15-21 part,
Beta-carotene 0.8-1.2 part,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 8-14 part,
3-indolecarboxylic acid 4-8 part,
Cinene 14-20 part,
Sodium pentahydyoxycaproate 10-20 part,
L-AA sodium 0.5-1.1 part,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 8-12 part,
Glycocoll betaine 2-5 part,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 10-16 part,
Iron chloride 12-20 part,
P-ureidobenzenearsonic acid 2-4 part,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 6-12 part,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 6-10 part,
Caulis Marsdeniae Tenacissimae glycosides G about 3-7 part.
Xylol, o-Dimethylbenzene and meta-xylene in removal alkyd resin plant effluent the most according to claim 1
Inorganic agent, it is characterised in that include the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 14 parts,
Poly-maleic acid 18 parts,
Beta-carotene 1.0 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 11 parts,
3-indolecarboxylic acid 6 parts,
Cinene 17 parts,
Sodium pentahydyoxycaproate 15 parts,
0.8 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 10 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 13 parts,
16 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 9 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 8 parts,
Caulis Marsdeniae Tenacissimae glycosides G 5 parts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510590382.2A CN106115806A (en) | 2015-09-17 | 2015-09-17 | Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent |
Applications Claiming Priority (1)
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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GB201413051D0 (en) * | 2014-07-23 | 2014-09-03 | Givaudan Sa | Improvements in or relating to organic compounds |
CN104876317A (en) * | 2015-06-22 | 2015-09-02 | 缪琼华 | Water treatment agent for removing nitrobenzene compounds in water |
CN104891625A (en) * | 2015-06-25 | 2015-09-09 | 金双蕾 | Water treatment chemical for removing para-nitroaniline in water |
CN104891626A (en) * | 2015-06-25 | 2015-09-09 | 金双蕾 | Water treatment chemical for removing aniline compounds in water |
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Patent Citations (4)
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GB201413051D0 (en) * | 2014-07-23 | 2014-09-03 | Givaudan Sa | Improvements in or relating to organic compounds |
CN104876317A (en) * | 2015-06-22 | 2015-09-02 | 缪琼华 | Water treatment agent for removing nitrobenzene compounds in water |
CN104891625A (en) * | 2015-06-25 | 2015-09-09 | 金双蕾 | Water treatment chemical for removing para-nitroaniline in water |
CN104891626A (en) * | 2015-06-25 | 2015-09-09 | 金双蕾 | Water treatment chemical for removing aniline compounds in water |
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