CN106115806A - Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent - Google Patents

Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent Download PDF

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Publication number
CN106115806A
CN106115806A CN201510590382.2A CN201510590382A CN106115806A CN 106115806 A CN106115806 A CN 106115806A CN 201510590382 A CN201510590382 A CN 201510590382A CN 106115806 A CN106115806 A CN 106115806A
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parts
methyl
dimethylbenzene
xylol
meta
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CN201510590382.2A
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Chinese (zh)
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叶澄
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Wenzhou Hongchengxiang Technology Co Ltd
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Wenzhou Hongchengxiang Technology Co Ltd
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Abstract

The present invention relates to xylol in a kind of removal alkyd resin plant effluent, o-Dimethylbenzene and the inorganic agent of meta-xylene, formed by following components is compounding: (1R, 2R, 8aS) decahydro 1 (3 hydroxyl 3 methyl 4 pentenyl) 2, 5, 5, 8a tetramethyl 2 naphthalene alcohol, poly-maleic acid, bata-carotene, (25R) 5 α spiral shell steroid (alkane) 3 β alcohol, 3 indolecarboxylic acids, 4 acetoxyl group 3 methoxyl group (2 acrylic) benzene, L sodium ascorbate, 4 (3 methyl fourth 2 alkenyloxy group) furo [3, 2 g] .alpha.-5:6-benzopyran 7 ketone, Glycocoll betaine etc..This inorganic agent is strong with the complexing power of target substance, forms complex compound sediment speed fast, and clearance is up to 99.9%, and consumption is few, and water body does not produce harm.

Description

Remove xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent Inorganic agent
Technical field
The present invention relates to a kind of remove the process of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent Agent, belongs to environmental protection technical field.
Background technology
Alkyd resin synthesis is main uses solvent method to produce.In solvent method, the evaporator strip of conventional dimethylbenzene goes out esterification water, warp Again flow back to reactor after crossing the oil-water separation of water knockout drum, the most repeatedly, promote the carrying out of polyesterification reaction, generate alkyd tree Fat.Therefore alkyd resin plant effluent is mixed with a large amount of benzene kind solvent, predominantly dimethylbenzene.Dimethylbenzene can quite be permanently present in In drinking-water.When in tap water, the concentration of dimethylbenzene is 5mg/L, its odour intensity is equivalent to 5 grades, and the distinctive smell of dimethylbenzene is then wanted Spending 7 to 8 days could disappear;Then need 4 to 5 days when odour intensity is 3 grades.The time that in river, the abnormal smells from the patient of dimethylbenzene keeps is shorter, This is relevant with the height of initial concentration, typically can retain 3 to 5 days.Dump the dimethylbenzene floatability in water on the water surface, or in Grease is distributed in the water surface, can cause Fish and hydrobiological death.Therefore alkyd resin plant effluent need treated up to standard after Just can enter environment.
Processing method containing dimethylbenzene waste water mainly has Physical, chemical method and biochemical process at present.The wherein master of chemical method Photocatalytic oxidation to be, relatively costly, it is not suitable for actual production.It is relatively long that biochemical process processes the time, and dimethylbenzene contains Measure too high meeting and cause microorganism deactivated.Conventional air-extraction and absorption method in Physical, wherein air-extraction is applicable to have certain life The production line of product scale, equipment cost is higher;Absorption method is mainly used for the process of low concentration dimethylbenzene waste water, the most frequently used suction Attached dose is activated carbon or zeolite, and disposal ability is poor.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that to diformazan in a kind of removal alkyd resin plant effluent The inorganic agent of benzene, o-Dimethylbenzene and meta-xylene, it can be with the xylol in water, o-Dimethylbenzene and meta-xylene effect, shape Becoming complex compound sediment, removed by filtration, have low toxicity, a non-environmental-pollution, clearance is high, applied widely, low cost excellent Point.
The technology contents of the present invention is: a kind of remove xylol in alkyd resin plant effluent, o-Dimethylbenzene and two The inorganic agent of toluene, including the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 10-18 part,
Poly-maleic acid 15-21 part,
Beta-carotene 0.8-1.2 part,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 8-14 part,
3-indolecarboxylic acid 4-8 part,
Cinene 14-20 part,
Sodium pentahydyoxycaproate 10-20 part,
L-AA sodium 0.5-1.1 part,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 8-12 part,
Glycocoll betaine 2-5 part,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 10-16 part,
Iron chloride 12-20 part,
P-ureidobenzenearsonic acid 2-4 part,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 6-12 part,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 6-10 part,
Caulis Marsdeniae Tenacissimae glycosides G 3-7 part.
Preferably, including the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 14 parts,
Poly-maleic acid 18 parts,
Beta-carotene 1.0 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 11 parts,
3-indolecarboxylic acid 6 parts,
Cinene 17 parts,
Sodium pentahydyoxycaproate 15 parts,
0.8 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 10 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 13 parts,
16 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 9 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 8 parts,
Caulis Marsdeniae Tenacissimae glycosides G 5 parts.
There is advantages that
(1) (1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol, poly- Maleic acid, beta-carotene, (25R)-5 α-spiral shell steroid (alkane)-3 β-ol, five kinds of materials of 3-indolecarboxylic acid produce synergism, Complex compound sediment can be formed with xylol effect;Cinene, sodium pentahydyoxycaproate, L-AA sodium, 4-(3-methyl butyl- 2-alkenyloxy group) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone, five kinds of materials of Glycocoll betaine produce synergism, and can be with adjacent two Toluene effect, forms complex compound sediment;2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene, iron chloride, to urea groups phenylarsine Acid, 5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol, (R)-N-(2,4-dihydroxy-3,3-diformazan Base-1-oxo butyl)-Beta-alanine, six kinds of materials of Caulis Marsdeniae Tenacissimae glycosides G produce synergism, can be formed with meta-xylene effect Complex compound sediment;
(2) strong with the complexing power of xylol, o-Dimethylbenzene and meta-xylene, form complex compound sediment speed fast, clearance Up to more than 99.9%;
(3) hypotoxicity, consumption is few, and water body does not produce harm;
(4) only needing dosing and filtering separation device, low for equipment requirements, processing cost is low;
(5) use at any time and add at any time, do not limited by producing load.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described, but scope of the present invention is also It is not limited to the scope that embodiment is described.
Embodiment 1
A kind of remove the inorganic agent of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, including following by The component of weight fraction meter:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 12 parts,
Poly-maleic acid 16 parts,
Beta-carotene 0.9 part,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 9 parts,
3-indolecarboxylic acid 5 parts,
Cinene 16 parts,
Sodium pentahydyoxycaproate 14 parts,
0.7 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 9 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 12 parts,
15 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 8 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 7 parts,
Caulis Marsdeniae Tenacissimae glycosides G 4 parts.
Before process: containing xylol 10mg, o-Dimethylbenzene 10mg in 1L water sample, meta-xylene 10mg, add present treatment agent 50mg;
After process: 1L water sample does not all detect containing o-Dimethylbenzene 0.01mg, xylol and meta-xylene.
Embodiment 2
A kind of remove the inorganic agent of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, including following by The component of weight fraction meter:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 15 parts,
Poly-maleic acid 19 parts,
Beta-carotene 1.1 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 12 parts,
3-indolecarboxylic acid 7 parts,
Cinene 18 parts,
Sodium pentahydyoxycaproate 16 parts,
0.9 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 11 parts,
Glycocoll betaine 4 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 14 parts,
17 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 10 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 9 parts,
Caulis Marsdeniae Tenacissimae glycosides G 6 parts.
Before process: containing xylol 8mg, o-Dimethylbenzene 12mg in 1L water sample, meta-xylene 12mg, add present treatment agent 50mg;
After process: in 1L water sample, xylol, o-Dimethylbenzene and meta-xylene all do not detect.
Embodiment 3
A kind of remove the inorganic agent of xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, including following by The component of weight fraction meter:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 14 parts,
Poly-maleic acid 18 parts,
Beta-carotene 1.0 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 11 parts,
3-indolecarboxylic acid 6 parts,
Cinene 17 parts,
Sodium pentahydyoxycaproate 15 parts,
0.8 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 10 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 13 parts,
16 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 9 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 8 parts,
Caulis Marsdeniae Tenacissimae glycosides G 5 parts.
Before process: containing xylol 10mg, o-Dimethylbenzene 14mg in 1L water sample, meta-xylene 14mg adds present treatment agent 50mg;
After process: in 1L water sample, xylol, o-Dimethylbenzene and meta-xylene all do not detect.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any Those of ordinary skill in the art in the technical scope that disclosed herein, the change that can expect without creative work or Replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims Fixed protection domain is as the criterion.

Claims (2)

1. removing an inorganic agent for xylol, o-Dimethylbenzene and meta-xylene in alkyd resin plant effluent, its feature exists In, including the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 10-18 part,
Poly-maleic acid 15-21 part,
Beta-carotene 0.8-1.2 part,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 8-14 part,
3-indolecarboxylic acid 4-8 part,
Cinene 14-20 part,
Sodium pentahydyoxycaproate 10-20 part,
L-AA sodium 0.5-1.1 part,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 8-12 part,
Glycocoll betaine 2-5 part,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 10-16 part,
Iron chloride 12-20 part,
P-ureidobenzenearsonic acid 2-4 part,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 6-12 part,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 6-10 part,
Caulis Marsdeniae Tenacissimae glycosides G about 3-7 part.
Xylol, o-Dimethylbenzene and meta-xylene in removal alkyd resin plant effluent the most according to claim 1 Inorganic agent, it is characterised in that include the component of the following meter of mark by weight:
(1R, 2R, 8aS)-decahydro-1-(3-hydroxy-3-methyl-4-pentenyl)-2,5,5,8a-tetramethyl-2-naphthalene alcohol 14 parts,
Poly-maleic acid 18 parts,
Beta-carotene 1.0 parts,
(25R)-5 α-spiral shell steroid (alkane)-3 β-ol 11 parts,
3-indolecarboxylic acid 6 parts,
Cinene 17 parts,
Sodium pentahydyoxycaproate 15 parts,
0.8 part of L-AA sodium,
4-(3-methyl but-2-ene epoxide) furo [3,2-g] .alpha.-5:6-benzopyran-7-ketone 10 parts,
Glycocoll betaine 3 parts,
2-methyl-5-(1-Methylethyl)-1,3-cyclohexadiene 13 parts,
16 parts of iron chloride,
P-ureidobenzenearsonic acid 3 parts,
5 α, 8 α-table dioxy-(22E, 24R)-Ergota steroid-6,22-diene-3 β-ol 9 parts,
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-Beta-alanine 8 parts,
Caulis Marsdeniae Tenacissimae glycosides G 5 parts.
CN201510590382.2A 2015-09-17 2015-09-17 Remove xylol, o-Dimethylbenzene and the inorganic agent of meta-xylene in alkyd resin plant effluent Pending CN106115806A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201413051D0 (en) * 2014-07-23 2014-09-03 Givaudan Sa Improvements in or relating to organic compounds
CN104876317A (en) * 2015-06-22 2015-09-02 缪琼华 Water treatment agent for removing nitrobenzene compounds in water
CN104891625A (en) * 2015-06-25 2015-09-09 金双蕾 Water treatment chemical for removing para-nitroaniline in water
CN104891626A (en) * 2015-06-25 2015-09-09 金双蕾 Water treatment chemical for removing aniline compounds in water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201413051D0 (en) * 2014-07-23 2014-09-03 Givaudan Sa Improvements in or relating to organic compounds
CN104876317A (en) * 2015-06-22 2015-09-02 缪琼华 Water treatment agent for removing nitrobenzene compounds in water
CN104891625A (en) * 2015-06-25 2015-09-09 金双蕾 Water treatment chemical for removing para-nitroaniline in water
CN104891626A (en) * 2015-06-25 2015-09-09 金双蕾 Water treatment chemical for removing aniline compounds in water

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