CN104890262A - Method for manufacturing corrosion-resistant and flame-retardant glass steel grid through pultrusion profile production system - Google Patents

Method for manufacturing corrosion-resistant and flame-retardant glass steel grid through pultrusion profile production system Download PDF

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Publication number
CN104890262A
CN104890262A CN201510285316.4A CN201510285316A CN104890262A CN 104890262 A CN104890262 A CN 104890262A CN 201510285316 A CN201510285316 A CN 201510285316A CN 104890262 A CN104890262 A CN 104890262A
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China
Prior art keywords
guide plate
glass fiber
enter
curing
production system
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Granted
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CN201510285316.4A
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Chinese (zh)
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CN104890262B (en
Inventor
季宏亮
陈道斌
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Jiangsu Oland New Material Technology Co ltd
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NANTONG AULLAND COMPOSITES CO Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/521Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement before the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10Coating or impregnating independently of the moulding or shaping step
    • B29B15/12Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/14Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length of filaments or wires
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Moulding By Coating Moulds (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

The invention discloses a method for manufacturing a corrosion-resistant and flame-retardant glass steel grid through a pultrusion profile production system. The method comprises the following steps: glass fiber filaments are leaded into a guide system; and unsaturated polyester resins, a flame retardant, an antiaging agent, a curing agent, an accelerant and a reduction inhibitor are formed to flame-retardant resin mixed liquid for filling in an impregnation device with the mass proportion of 100: 10-30: 3-5: 1-2: 2-3: 0.5-1.5, then enter a molding system for dipping, enter a heating curing device for curing, are cooled and demolded to enter a reciprocating traction device for towing, and enter a cutting device for cutting and finishing to obtain a product. The method can flexibly manufacture according to the production requirements, adopts a continuous production process to cut according to a specified dimension, and is high in production efficiency, stable, safe and reliable.

Description

The method of corrosion resistant fireproof glass steel grating is manufactured by drawing and extruding section bar production system
Technical field
The present invention relates to composite and manufacture field, be specifically related to a kind of method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system.
Background technology
Glass fibre is a kind of Inorganic Non-metallic Materials of excellent performance, of a great variety, and advantage is good insulating, heat resistance is strong, corrosion resistance good, and mechanical strength is high, but shortcoming is that property is crisp, and wearability is poor.It with glass marble or discarded glass for raw material becomes through high temperature melting, wire drawing, doff, the manufacture technics such as to weave cotton cloth, the diameter of its monofilament is that several micron is to twenties meters microns, be equivalent to the 1/20-1/5 of a hairline, every bundle fiber precursor all by hundreds of even thousands of monofilament form.Glass fibre is typically used as the reinforcing material in composite, electrically insulating material and heat-insulating material, the national economy every field such as circuit substrate.
Fiberglass (FRP) is also called GFRP, i.e. fiber-reinforced plastic, refers generally to glass fiber reinforcement unsaturated polyester, epoxy resin and phenolic resin as matrix resin.Make the reinforced plastics of reinforcing material with glass fibre or its goods, appellation is fiberglass reinforced plastics, or appellation fiberglass.Because used resin variety is different, therefore there is the title of organic toughened glass, fiber glass epoxy, phenolic fiberglass reinforced plastics.Light weight and hard, non-conductive, mechanical strength is high, recycles few, corrosion-resistant.Steel manufacturing machine part and automobile, ship housing etc. can be replaced.
The basis of pulling and extruding glass fiber section bar is resin and glass fibre (comprising cloth, felt etc.), it is for reinforcing material with fiber (comprising glass fibre, carbon fiber, organic fiber and other metals, non-metallic fibers), with resin (mainly epoxy resin, alkyd resin, phenolic resins) be glue crosslinking agent, auxiliary other auxiliary material (major auxiliary burden: releasing agent, curing agent, catalyst, the agent of envelope mould, UV light stabilizer, clean mould water, gel coat etc.) are composited.It has a series of excellent specific properties such as high temperature resistant, anticorrosive, intensity is high, proportion is little, moisture absorption is low, it is little to extend and insulation is good.
Summary of the invention
Object of the present invention, be to overcome above-mentioned limitation, thus provide one flexibly according to production requirement manufacture, to adopt continuous production processes by given size cutting, production efficiency is high, the stable and safe and reliable method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system.
Object of the present invention is achieved through the following technical solutions: a kind of method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system, and step is as follows:
A, glass fiber uniform winding is become hollow tubular, hollow cylinder is placed in rotating roller, multiple glass fiber rotating roller is placed on the creel on yarn field for subsequent use, the silk head of glass fiber is involved preparation simultaneously and put into guide plate;
B, silk head to be imported in guidance system, guidance system comprises the first guide plate, the second guide plate and the 3rd guide plate, be provided with live-roller between second guide plate and the 3rd guide plate, silk head is fixed by each guide plate, live-roller so that glass fiber can continue to drive to impregnation equipment;
C, glass fiber yarn be wound in rotating roller and be placed in dipping device side, glass fiber yarn one being placed in glass fiber silk head both sides simultaneously, treating to enter dipping device simultaneously;
D, unsaturated polyester resin, fire retardant, age resister, curing agent, promoter, anti-depressant prescription composition flame-retarded resin mixed liquor are injected dipping device, its mass ratio is 100:10-30:3-5:1-2:2-3:0.5-1.5;
E, glass fiber and glass fiber yarn are imported dipping device fully flood, then enter formation system, formation system comprises the dipping tank of multiple tape guide plastotype function;
Enter the device that is heating and curing after F, dip forming, the device that is heating and curing has pressurization function simultaneously, cooling and demolding after solidification;
Enter reciprocating traction device after G, cooling and demolding to draw, then enter cutter sweep carry out cutting finishing, obtain goods.
Preferably, the first guide plate, the second guide plate and the 3rd guide plate all have transverse groove and cannelure.
Preferably, formation system has three-decker, and upper strata is transverse holes arrangement, and plastotype function is the upper surface of grid sheet material; Middle level is longitudinal hole arrangement, and plastotype function is the left and right side of grid sheet material; Lower floor is liquid storage tank, and plastotype function is the lower surface of grid sheet material, and the glass fiber after the dipping that three-decker derives enters the device that is heating and curing.
Preferably, curing agent is peroxidating ketone mixture, and described promoter is cobalt class promoter, and described anti-depressant prescription is silica, and described age resister is UV type age resister.
Preferably, the temperature that is heating and curing is 120-150 DEG C, and the heat time keeps 1.5-2 hour.
Preferably, reciprocating type tracting device is provided with the first hauling machine and the second hauling machine, and two hauling machine asynchronous workings, goods are imported cutter sweep by the second hauling machine.
Preferably, need inspection after obtaining goods, and defective goods are repaired by other filler or does over again.
In sum, the present invention has the following advantages: can flexibly according to production requirement manufacture, and adopt continuous production processes by given size cutting, production efficiency is high, stable and safe and reliable.
Accompanying drawing explanation
Fig. 1 is drawing and extruding section bar operation system structure sketch;
Number in the figure: 1-first guide plate, 2-second guide plate, 3-the 3rd guide plate, 4-dipping device, 5-formation system, 6-are heating and curing device, 7-reciprocating traction device, 8-cutter sweep.
Detailed description of the invention
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, and this embodiment only for explaining the present invention, does not form limiting the scope of the present invention.
Embodiment 1: a kind of method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system, step is as follows: glass fiber uniform winding is become hollow tubular, hollow cylinder is placed in rotating roller, multiple glass fiber rotating roller is placed on the creel on yarn field for subsequent use, the silk head of glass fiber is involved preparation simultaneously and put into guide plate; Silk head is imported in guidance system, guidance system comprises the first guide plate 1, second guide plate 2 and the 3rd guide plate 3, be provided with live-roller between second guide plate 2 and the 3rd guide plate 3, silk head is fixed by each guide plate, live-roller so that glass fiber can continue to drive to impregnation equipment 4; First guide plate 1, second guide plate 2 and the 3rd guide plate 3 all have transverse groove and cannelure; Glass fiber yarn to be wound in rotating roller and to be placed in dipping device 4 side, glass fiber yarn one being placed in glass fiber silk head both sides simultaneously, treating to enter dipping device 4 simultaneously; Unsaturated polyester resin, fire retardant, age resister, curing agent, promoter, anti-depressant prescription composition flame-retarded resin mixed liquor are injected dipping device 4, and its mass ratio is 100:20:2:1.5:2.5:1; Glass fiber and glass fiber yarn are imported dipping device 4 fully flood, then enter formation system 5, formation system comprises the dipping tank of multiple tape guide plastotype function; Enter the device 6 that is heating and curing after dip forming, the device 6 that is heating and curing has pressurization function simultaneously, cooling and demolding after solidification; Enter reciprocating traction device 7 after cooling and demolding to draw, then enter cutter sweep 8 carry out cutting finishing, obtain goods; Formation system 5 has three-decker, and upper strata is transverse holes arrangement, and plastotype function is the upper surface of grid sheet material; Middle level is longitudinal hole arrangement, and plastotype function is the left and right side of grid sheet material; Lower floor is liquid storage tank, and plastotype function is the lower surface of grid sheet material, and the glass fiber after the dipping that three-decker derives enters the device 6 that is heating and curing.Curing agent is peroxidating ketone mixture, and described promoter is cobalt class promoter, and described anti-depressant prescription is silica, and described age resister is UV type age resister.The temperature that is heating and curing is 135 DEG C, and the heat time keeps 1.75 hours.Reciprocating type tracting device 7 is provided with the first hauling machine and the second hauling machine, and two hauling machine asynchronous workings, goods are imported cutter sweep 8 by the second hauling machine.Need inspection after obtaining goods, and defective goods are repaired by other filler or does over again.
Embodiment 2: unsaturated polyester resin, fire retardant, age resister, curing agent, promoter, anti-depressant prescription composition flame-retarded resin mixed liquor inject dipping device 4, its mass ratio is 100:10:3:1:2:0.5, curing agent is peroxidating ketone mixture, promoter is cobalt class promoter, anti-depressant prescription is silica, and age resister is UV type age resister; The device 6 that is heating and curing has pressurization function simultaneously, and the temperature that is heating and curing is 120 DEG C, and the heat time keeps 1.5 hours, cooling and demolding after solidification.
Embodiment 3: unsaturated polyester resin, fire retardant, age resister, curing agent, promoter, anti-depressant prescription composition flame-retarded resin mixed liquor inject dipping device 4, its mass ratio is 100:30:5:2:3:1.5, curing agent is peroxidating ketone mixture, promoter is cobalt class promoter, anti-depressant prescription is silica, and age resister is UV type age resister; The device 6 that is heating and curing has pressurization function simultaneously, and the temperature that is heating and curing is 150 DEG C, and the heat time keeps 2 hours, cooling and demolding after solidification.

Claims (7)

1. manufactured a method for corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system, it is characterized in that, step is as follows:
A, glass fiber uniform winding is become hollow tubular, hollow cylinder is placed in rotating roller, multiple glass fiber rotating roller is placed on the creel on yarn field for subsequent use, the silk head of glass fiber is involved preparation simultaneously and put into guide plate;
B, silk head to be imported in guidance system, guidance system comprises the first guide plate (1), the second guide plate (2) and the 3rd guide plate (3), be provided with live-roller between described second guide plate (2) and the 3rd guide plate (3), silk head fixed by each guide plate, live-roller so that glass fiber can continue to drive to impregnation equipment (4);
C, glass fiber yarn be wound in rotating roller and be placed in dipping device (4) side, glass fiber yarn one being placed in glass fiber silk head both sides simultaneously, treating to enter dipping device (4) simultaneously;
D, unsaturated polyester resin, fire retardant, age resister, curing agent, promoter, anti-depressant prescription composition flame-retarded resin mixed liquor are injected dipping device (4), its mass ratio is 100:10-30:3-5:1-2:2-3:0.5-1.5;
E, glass fiber and glass fiber yarn are imported dipping device (4) fully flood, then enter formation system (5), formation system comprises the dipping tank of multiple tape guide plastotype function;
Enter the device that is heating and curing (6) after F, dip forming, described in the device (6) that is heating and curing there is pressurization function, cooling and demolding after solidification simultaneously;
Enter reciprocating traction device (7) after G, cooling and demolding to draw, then enter cutter sweep (8) carry out cutting finishing, obtain goods.
2. the method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system according to claim 1, be is characterized in that: described first guide plate (1), the second guide plate (2) and the 3rd guide plate (3) all have transverse groove and cannelure.
3. the method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system according to claim 1, be is characterized in that: described formation system (5) has three-decker, and upper strata is transverse holes arrangement, and plastotype function is the upper surface of grid sheet material; Middle level is longitudinal hole arrangement, and plastotype function is the left and right side of grid sheet material; Lower floor is liquid storage tank, and plastotype function is the lower surface of grid sheet material, and the glass fiber after the dipping that three-decker derives enters the device that is heating and curing (6).
4. the method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system according to claim 1, it is characterized in that: described curing agent is peroxidating ketone mixture, described promoter is cobalt class promoter, described anti-depressant prescription is silica, and described age resister is UV type age resister.
5. the method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system according to claim 1, be is characterized in that: described in the temperature that is heating and curing be 120-150 DEG C, the heat time keeps 1.5-2 hour.
6. the method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system according to claim 1, it is characterized in that: described reciprocating type tracting device (7) is provided with the first hauling machine and the second hauling machine, two hauling machine asynchronous workings, goods are imported cutter sweep (8) by the second hauling machine.
7. the method being manufactured corrosion resistant fireproof glass steel grating by drawing and extruding section bar production system according to claim 1, be is characterized in that: need inspection after described acquisition goods, and repaired by other filler by defective goods or do over again.
CN201510285316.4A 2015-05-29 2015-05-29 Method for manufacturing corrosion-resistant and flame-retardant glass steel grid through pultrusion profile production system Expired - Fee Related CN104890262B (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105742999A (en) * 2016-04-12 2016-07-06 许玉蕊 Three-proof power distribution box with automatic fire extinguishing function
CN107415277A (en) * 2017-06-16 2017-12-01 新誉集团有限公司 A kind of preparation method of track traffic air-conditioning composite material grid
CN108102407A (en) * 2017-12-28 2018-06-01 江苏飞博尔新材料科技有限公司 A kind of manufacturing method of high fire-retardance FRP pultruded products
CN108481764A (en) * 2018-05-21 2018-09-04 泰安市中研复合材料科技有限公司 A kind of method and device preparing grating band using composite fibre
CN109457685A (en) * 2018-09-28 2019-03-12 李宏福 A kind of thermoplastic molding grating, preparation method, application and its intermediary material
CN110591281A (en) * 2019-04-01 2019-12-20 洛阳双瑞橡塑科技有限公司 Grid and preparation method thereof
CN110591282A (en) * 2019-04-01 2019-12-20 洛阳双瑞橡塑科技有限公司 Fireproof grating and preparation method thereof
CN110641050A (en) * 2019-09-28 2020-01-03 山东北方玻璃钢工程有限公司 Manufacturing process of composite material bracket for supporting crops
CN112795157A (en) * 2021-01-12 2021-05-14 江苏时瑞新材料科技有限公司 Novel heavy-duty glass fiber reinforced plastic grid and preparation method thereof
KR20220089256A (en) * 2020-12-21 2022-06-28 주식회사 효진엔지니어링 Semi-incombustible resin composition for FRP pultrusion

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CN101316695A (en) * 2005-11-23 2008-12-03 米尔加德制造有限公司 Method for producing pultruded components
CN103468015A (en) * 2013-08-08 2013-12-25 南通时瑞塑胶制品有限公司 Fiber reinforced plastic grid with automatic luminescence function, and production process thereof
CN103660314A (en) * 2013-12-18 2014-03-26 冀州中意复合材料科技有限公司 Automatic continuous production device for fiber reinforced plastic gratings

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Publication number Priority date Publication date Assignee Title
CN101316695A (en) * 2005-11-23 2008-12-03 米尔加德制造有限公司 Method for producing pultruded components
CN103468015A (en) * 2013-08-08 2013-12-25 南通时瑞塑胶制品有限公司 Fiber reinforced plastic grid with automatic luminescence function, and production process thereof
CN103660314A (en) * 2013-12-18 2014-03-26 冀州中意复合材料科技有限公司 Automatic continuous production device for fiber reinforced plastic gratings

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105742999A (en) * 2016-04-12 2016-07-06 许玉蕊 Three-proof power distribution box with automatic fire extinguishing function
CN107415277A (en) * 2017-06-16 2017-12-01 新誉集团有限公司 A kind of preparation method of track traffic air-conditioning composite material grid
CN107415277B (en) * 2017-06-16 2019-07-26 新誉集团有限公司 A kind of preparation method of rail traffic air-conditioning composite material grid
CN108102407A (en) * 2017-12-28 2018-06-01 江苏飞博尔新材料科技有限公司 A kind of manufacturing method of high fire-retardance FRP pultruded products
CN108481764A (en) * 2018-05-21 2018-09-04 泰安市中研复合材料科技有限公司 A kind of method and device preparing grating band using composite fibre
CN109457685A (en) * 2018-09-28 2019-03-12 李宏福 A kind of thermoplastic molding grating, preparation method, application and its intermediary material
CN110591281A (en) * 2019-04-01 2019-12-20 洛阳双瑞橡塑科技有限公司 Grid and preparation method thereof
CN110591282A (en) * 2019-04-01 2019-12-20 洛阳双瑞橡塑科技有限公司 Fireproof grating and preparation method thereof
CN110641050A (en) * 2019-09-28 2020-01-03 山东北方玻璃钢工程有限公司 Manufacturing process of composite material bracket for supporting crops
KR20220089256A (en) * 2020-12-21 2022-06-28 주식회사 효진엔지니어링 Semi-incombustible resin composition for FRP pultrusion
KR102438624B1 (en) * 2020-12-21 2022-08-31 주식회사 효진엔지니어링 Semi-incombustible resin composition for FRP pultrusion
CN112795157A (en) * 2021-01-12 2021-05-14 江苏时瑞新材料科技有限公司 Novel heavy-duty glass fiber reinforced plastic grid and preparation method thereof

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