CN110450436A - The high-intensitive ultralight insulated pipes used production line of basalt compound resin and production method - Google Patents

The high-intensitive ultralight insulated pipes used production line of basalt compound resin and production method Download PDF

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Publication number
CN110450436A
CN110450436A CN201910852345.2A CN201910852345A CN110450436A CN 110450436 A CN110450436 A CN 110450436A CN 201910852345 A CN201910852345 A CN 201910852345A CN 110450436 A CN110450436 A CN 110450436A
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CN
China
Prior art keywords
equipment
basalt
pond
asa
ultralight
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Pending
Application number
CN201910852345.2A
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Chinese (zh)
Inventor
蒋文君
蒋佳芸
陈超
梁国祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU YUNXIN ELECTRICAL CO Ltd
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JIANGSU YUNXIN ELECTRICAL CO Ltd
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Priority to CN201910852345.2A priority Critical patent/CN110450436A/en
Publication of CN110450436A publication Critical patent/CN110450436A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10Coating or impregnating independently of the moulding or shaping step
    • B29B15/12Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/14Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length of filaments or wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C69/00Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore
    • B29C69/001Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore a shaping technique combined with cutting, e.g. in parts or slices combined with rearranging and joining the cut parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • B29L2023/22Tubes or pipes, i.e. rigid

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Textile Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The present invention provides a kind of high-intensitive ultralight insulated pipes used production line of basalt compound resin and production methods, immerse basalt yarn by vertical pond of immersing, then glass fabric and glass mat are under the traction of traction device, by glass fabric felt bracket and basalt yarn commonly through pond is immersed in transverse direction after, it is fixed by mold fixed equipment, multiple tracks winding is carried out by Wiring apparatus again, heat cure in heat cure molding equipment is finally entered to form, finally polish, ASA injection molding, the techniques such as cutting obtain finished product.The present invention thoroughly passes through vertical horizontal and repeatedly immerses, and thoroughly solves the problems, such as that insulated pipes used immerses deficiency, and the novel high-strength ultrathin insulating tubing mechanical strength developed and gone out in this way is big, and light-weight, amount of deflection is small, has excellent weather resistance, and carries easy to use.

Description

The high-intensitive ultralight insulated pipes used production line of basalt compound resin and production method
Technical field
The present invention relates to production of resins technical field, the high-intensitive ultralight insulated pipes used of specifically a kind of basalt compound resin Production line and production method.
Background technique
Insulating materials has very important effect in livewire work, is to ensure that operating personnel's personal safety and electrically sets The important leverage of standby safety.It not only plays a part of for high potential insulation against ground being isolated, and also plays the work for undertaking mechanical load With.The insulation of insulating materials and mechanical property decide safety and the operating efficiency of livewire work.
Composite material has had relatively broad application in livewire work field, insulate as used in livewire work Work tool, aerial lift device with insulated arm etc. are hung in operational instrument, insulation branch drawing.In recent years, composite material is also gradually applied to electric force pole tower And cross-arm.
Insulating tool is one of most common electric power instrument, and rigid insulation Work tool is by glass fiber reinforcement epoxy The insulating composite materials such as resin are the operational instrument such as insulating bar made of main material.Insulating bar includes solid insulated rod, hollow insulation Pipe and foam fill insulation tube.
At present the country field operation it is very high for the length requirement of insulating bar, such as 10kV low potential brake pull-rod, 220kV with The operating stick of upper voltage grade transformer substation low potential operating personnel, 500kV above hot line maintenance are used Operating stick, to the length requirement of insulating bar in 6m ~ 15m, using the composite material of existing glass fiber reinforced epoxy resin It insulate less than normal in bending strength and bending modulus, leads to that long insulating bar amount of deflection is excessive, heavier-weight, the convenience of carrying and behaviour The accuracy of work is unable to satisfy the demand of field operation.
Basalt fibre have high intensity, high-modulus, high-low temperature resistant, chemical corrosion resistance, uvioresistant, hygroscopicity it is low, The performance characteristics such as sound-insulating and heat-insulating, environmental resistance be excellent can be widely used for civil engineering traffic, energy environment protection, automobile ship, aviation boat It, the fields such as petrochemical industry and weaponry.Basalt fibre be using volcanic rock as raw material, be in all high technical fibres only The raw material of one pure natural unartificial synthesis;Its line of production technology is short out, is nearly free from " three wastes ", in all high technical fibres Energy consumption is minimum (energy consumption of basalt fibre be carbon fiber 1/16) in production, it be a kind of typical resource-conserving, Environmentally friendly green high technical fibre.In the scope of high technical fibre, the production of basalt fibre is to resource and the energy Consumption is minimum, meets the policy of national energy conservation and emission reduction, meets the requirement of low-carbon economy.Further more, basalt fibre is a basis Material can derive many very long industrial chains by it, can not only drive the development of related new industry, but also can be national economy phase The upgrading in pass field provides the support and guarantee of new material.
Compared with glass fibre, carbon fibre material, basalt fibre and the compatible degree of adhesion of other materials are stronger, therefore, The basalt fibre product properties obtained in conjunction with different materials is excellent, and mechanical strength and elasticity modulus can be mentioned obviously It rises.For example, it is multiple to carry out surface coating modified manufactured basalt fibre/epoxy resin to basalt fibre using graphene oxide The breaking strength of condensation material improves 30.8%, and shearing force improves 10.6%.Unidirectionally enhancing is multiple made of continuous basalt fiber Condensation material is suitable with E- glass in terms of intensity, but elasticity modulus has a clear superiority in various fibers.
Resistance to environmental aging performance is poor for a long time for existing insulated pipes used currently on the market, and organic resin composite material is organic The weatherability of resin, the ultraviolet ageing in especially resistance to daylight, is the deadly defect of its outdoor application, in order to promote insulated pipes used Weatherability, carried out many respective material Research on Weatherability, relatively common has surface weathering resistance coatings method, surface weatherable materials Composite algorithm.
Summary of the invention
The present invention in order to solve problems in the prior art, provides a kind of high-intensitive ultralight insulation tube of basalt compound resin Material production line and production method are repeatedly immersed by vertical horizontal, thoroughly solve the problems, such as that insulated pipes used immerses deficiency, are developed in this way And the novel high-strength ultrathin insulating tubing mechanical strength gone out is big, light-weight, amount of deflection is small, has excellent weather resistance, and carries easy to use.
The present invention provides a kind of high-intensitive ultralight insulated pipes used production lines of basalt compound resin, including draw along tubing The tensioning that direction is set gradually immerse equipment, mold fixed equipment, Wiring apparatus, heat cure molding equipment, the first pulling equipment, Grinding apparatus, ASA molding equipment, water cooling molding equipment, the second pulling equipment, cutting equipment, pipeline lock, High power Traction Machine, the tensioning immerse equipment and include that vertical immerse set gradually immerses pond in pond, transversal sinking soaking pit and transverse direction, wherein The vertical pond entrance that immerses is connect by upper bracket idler wheel with basalt creel, and vertical pond outlet of immersing is equipped with lower bracket idler wheel, under It is provided with tensioning bracket between bracket idler wheel and transversal sinking soaking pit entrance, immerses between pond and sets on transversal sinking soaking pit and transverse direction It is equipped with glass fabric felt bracket.
Be further improved, the ASA molding equipment include sequentially connected stirring mixer, heat riser, cooling set Standby, charging equipment and double screw extruder, the ASA that double screw extruder squeezes out melting are molded in tube surfaces.
It is further improved, is provided with tensioning bracket pinch roller controller on the tensioning bracket.
It being further improved, vertical immerse is provided with the first environmental protection equipment above pond, the mold fixed equipment, It is provided with the second environmental protection equipment at Wiring apparatus and heat cure molding equipment, is provided with cleaner at the grinding apparatus.
The present invention also provides a kind of high-intensitive ultralight insulated pipes used production methods of basalt compound resin, including following step It is rapid:
1) the basalt yarn on basalt creel immerses pond into vertical by upper bracket idler wheel under traction device traction;
2) after basalt yarn is by vertical immerse, pre- tensioning is carried out by tensioning bracket, subsequently into transversal sinking soaking pit;
3) glass fabric and glass mat pass through glass fabric felt bracket and basalt yarn under the traction of traction device It after immersing pond in transverse direction, is fixed by mold fixed equipment, then multiple tracks winding is carried out by Wiring apparatus, most Enter heat cure molding in heat cure molding equipment afterwards;
4) enter ASA molding equipment after the tubing that heat cure forms is polished by grinding apparatus, be molded in tube surfaces ASA;
5) tubing of injection molding cuts to obtain the tubing of corresponding size by cutting equipment.
6) it is latched with pipeline and the tubing after cutting is connected with non-incising pipes, after High power Traction machine, unclamped Lock obtains finished product tubing.
It is further improved, injection molding ASA process described in step 4), the specific steps are first mix in proportion by ASA raw material and stir It mixes and heats up, double screw extruder is entered by hopper after then being cooled down by cooling bay and carries out shear extrusion, melting ASA is molded in tube surfaces out.
The beneficial effects of the invention are that:
1, compound resin tubing intensity is high, and rigidity is big, and fatigue performance is good;ASA material is more able to satisfy the demand of anti-time property.To multiple Resin tube surfaces are molded ASA, and to improve its anti-time, the advanced composite material (ACM) tubing intensity developed in this way is high, rigidity Greatly, anti-time property is excellent.
2, compared with glass fibre, carbon fibre material, basalt fibre and the compatible degree of adhesion of other materials are stronger, because This, the basalt fibre product properties obtained in conjunction with different materials is excellent, and mechanical strength and elasticity modulus can obtain obviously It is promoted.
3, pond is immersed and two kinds of levels immerse being used in mixed way for pond by vertical, solving conventional flat and immersing technique causes Immerse insufficient problem.
4, prestressed stretch-draw is carried out to basalt fibre yarn, glass fabric and glass mat, is produced by the technique Pulling winding ultrathin insulating tubing, mechanical strength is big, and light-weight, amount of deflection is small, have excellent weather resistance, carry it is easy to use.
Detailed description of the invention
Fig. 1 is the high-intensitive ultralight insulated pipes used production line structural schematic diagram of basalt compound resin.
Fig. 2 is the high-intensitive ultralight insulated pipes used production method flow diagram of basalt compound resin.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
The present invention provides a kind of high-intensitive ultralight insulated pipes used production line of basalt compound resin, structure such as Fig. 1 institutes Show, equipment, mold fixed equipment 11, Wiring apparatus 12, heat cure are immersed in the tensioning including setting gradually along tubing lead Molding equipment 13, the first pulling equipment 14, grinding apparatus 15, ASA molding equipment 16, the traction of water cooling molding equipment 17, second are set Standby 18, cutting equipment 19, pipeline latch 23, High power Traction machine 24, the tensioning immerse equipment include set gradually it is vertical Formula is immersed and immerses pond 10 in pond 5, transversal sinking soaking pit 9 and transverse direction, wherein it is vertical immerse pond entrance by upper bracket idler wheel 4 with it is profound Military rock creel 1 connects, and vertical pond outlet of immersing is equipped with lower bracket idler wheel 6, between lower bracket idler wheel 6 and transversal sinking soaking pit entrance It is provided with tensioning bracket 2, is immersed on transversal sinking soaking pit and transverse direction and is provided with glass fabric felt bracket, including glass between pond Fiber cloth felt upper bracket 7 and glass fabric felt lower bracket 8, glass fabric felt near support are provided with glass fabric felt heap Put frame 22.
Be further improved, the ASA molding equipment include sequentially connected stirring mixer, heat riser, cooling set Standby, charging equipment and double screw extruder, the ASA that double screw extruder squeezes out melting are molded in tube surfaces.
It is further improved, is provided with tensioning bracket pinch roller controller 3 on the tensioning bracket 2.
It is further improved, vertical immerse is provided with the first environmental protection equipment 20 above pond, the mold fixation is set It is provided with the second environmental protection equipment 21 at standby, Wiring apparatus and heat cure molding equipment, is provided with dedusting at the grinding apparatus Equipment.
The present invention also provides a kind of high-intensitive ultralight insulated pipes used production methods of basalt compound resin, as shown in Fig. 2, The following steps are included:
1) the basalt yarn on basalt creel immerses pond into vertical by upper bracket idler wheel under traction device traction;
2) after basalt yarn is by vertical immerse, pre- tensioning is carried out by tensioning bracket, subsequently into transversal sinking soaking pit;
3) basalt cloth and basalt felt are common by glass fabric felt bracket and basalt yarn under the traction of traction device It after immersing pond in transverse direction, is fixed by mold fixed equipment, then multiple tracks winding is carried out by Wiring apparatus, it is most laggard Enter heat cure in heat cure molding equipment to form;
4) enter ASA molding equipment after the tubing that heat cure forms is polished by grinding apparatus, be molded in tube surfaces ASA;
5) tubing of injection molding cuts to obtain the tubing of corresponding size by cutting equipment.
6) it is latched with pipeline and the tubing after cutting is connected with non-incising pipes, after High power Traction machine, unclamped Lock obtains finished product tubing.
It is further improved, injection molding ASA process described in step 4), the specific steps are first mix in proportion by ASA raw material and stir It mixes and heats up, double screw extruder is entered by hopper after then being cooled down by cooling bay and carries out shear extrusion, melting ASA is molded in tube surfaces out.
There are many concrete application approach of the present invention, the above is only a preferred embodiment of the present invention, it is noted that for For those skilled in the art, without departing from the principle of the present invention, it can also make several improvements, this A little improve also should be regarded as protection scope of the present invention.

Claims (6)

1. a kind of high-intensitive ultralight insulated pipes used production line of basalt compound resin, it is characterised in that: including along tubing traction side Equipment is immersed to the tensioning set gradually, mold fixed equipment, Wiring apparatus, heat cure molding equipment, the first pulling equipment, is beaten Equipment, ASA molding equipment, water cooling molding equipment, the second pulling equipment, cutting equipment, pipeline lock, High power Traction machine are ground, It includes that vertical immerse set gradually immerses pond in pond, transversal sinking soaking pit and transverse direction that equipment is immersed in the tensioning, neutral Formula is immersed pond entrance and is connect by upper bracket idler wheel with basalt creel, and vertical pond outlet of immersing is equipped with lower bracket idler wheel, lower branch It is provided with tensioning bracket between frame idler wheel and transversal sinking soaking pit entrance, immerses between pond and is arranged on transversal sinking soaking pit and transverse direction There is glass fabric felt bracket.
2. the high-intensitive ultralight insulated pipes used production line of basalt compound resin according to claim 1, it is characterised in that: institute The ASA molding equipment stated includes that sequentially connected stirring mixer, heat riser, cooling equipment, charging equipment and twin-screw squeeze Machine out, the ASA that double screw extruder squeezes out melting are molded in tube surfaces.
3. the high-intensitive ultralight insulated pipes used production line of basalt compound resin according to claim 1, it is characterised in that: institute Tensioning bracket pinch roller controller is provided on the tensioning bracket stated.
4. the high-intensitive ultralight insulated pipes used production line of basalt compound resin according to claim 1, it is characterised in that: institute Vertical immerse stated is provided with the first environmental protection equipment above pond, the mold fixed equipment, Wiring apparatus and heat cure molding It is provided with the second environmental protection equipment at equipment, is provided with cleaner at the grinding apparatus.
5. a kind of high-intensitive ultralight insulated pipes used production method of basalt compound resin, it is characterised in that the following steps are included:
1) the basalt yarn on basalt creel immerses pond into vertical by upper bracket idler wheel under traction device traction;
2) after basalt yarn is by vertical immerse, pre- tensioning is carried out by tensioning bracket, subsequently into transversal sinking soaking pit;
3) glass fabric and glass mat pass through glass fabric felt bracket and basalt yarn under the traction of traction device It after immersing pond in transverse direction, is fixed by mold fixed equipment, then multiple tracks winding is carried out by Wiring apparatus, most Enter heat cure molding in heat cure molding equipment afterwards;
4) enter ASA molding equipment after the tubing that heat cure forms is polished by grinding apparatus, be molded in tube surfaces ASA;
5) tubing of injection molding cuts to obtain the tubing of corresponding size by cutting equipment;
6) it is latched with pipeline and the tubing after cutting is connected with non-incising pipes, after High power Traction machine, unclamp lock Obtain finished product tubing.
6. the high-intensitive ultralight insulated pipes used production method of basalt compound resin according to claim 5, it is characterised in that: Injection molding ASA process described in step 4), the specific steps are be first mixed in proportion by ASA raw material and heat up, then pass through Cooling bay enters double screw extruder by hopper after being cooled down and carries out shear extrusion, melts out ASA and carries out in tube surfaces Injection molding.
CN201910852345.2A 2019-09-09 2019-09-09 The high-intensitive ultralight insulated pipes used production line of basalt compound resin and production method Pending CN110450436A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112715459A (en) * 2020-12-24 2021-04-30 重庆四通八达管业有限公司 Basalt fiber tank fish-vegetable symbiotic system equipment and manufacturing process
CN114311735A (en) * 2021-07-23 2022-04-12 江苏芯安新材料科技有限公司 Production method of conical electric wire tower production line

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CN1426888A (en) * 2001-12-15 2003-07-02 周献刚 Method of making pipe using basalt fiber as reinforcing material
JP2007203579A (en) * 2006-02-01 2007-08-16 Nitto Boseki Co Ltd Glass fiber preform substrate for fiber-reinforced plastics, glass fiber preform, its manufacturing process, and fiber-reinforced plastic
CN101284422A (en) * 2008-04-22 2008-10-15 申瑞山 Glass fibre reinforced vertical pultruded tubular product device and method
CN101440899A (en) * 2008-12-18 2009-05-27 李长城 Stainless steel fiber reinforced plastic pipeline and producing process thereof
CN101913253A (en) * 2010-08-17 2010-12-15 西安交通大学 Method and device for rolling and molding fiber reinforced composite board
CN104629222A (en) * 2015-03-05 2015-05-20 贵州国塑科技管业有限责任公司 High-intensity high-modulus high-weather-resistance co-extruded long glass fiber reinforced PVC and ASA pipe and preparation method thereof
CN105003753A (en) * 2015-08-07 2015-10-28 广东宝通玻璃钢有限公司 Thermoplastic pipeline related to continuous fiber reinforcement and producing method
CN106426977A (en) * 2016-08-30 2017-02-22 李鹏飞 Vertical type composite material pipeline production line
CN210820992U (en) * 2019-09-09 2020-06-23 江苏云芯电气有限公司 Production line of basalt composite resin high-strength ultra-light insulating pipe

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1426888A (en) * 2001-12-15 2003-07-02 周献刚 Method of making pipe using basalt fiber as reinforcing material
JP2007203579A (en) * 2006-02-01 2007-08-16 Nitto Boseki Co Ltd Glass fiber preform substrate for fiber-reinforced plastics, glass fiber preform, its manufacturing process, and fiber-reinforced plastic
CN101284422A (en) * 2008-04-22 2008-10-15 申瑞山 Glass fibre reinforced vertical pultruded tubular product device and method
CN101440899A (en) * 2008-12-18 2009-05-27 李长城 Stainless steel fiber reinforced plastic pipeline and producing process thereof
CN101913253A (en) * 2010-08-17 2010-12-15 西安交通大学 Method and device for rolling and molding fiber reinforced composite board
CN104629222A (en) * 2015-03-05 2015-05-20 贵州国塑科技管业有限责任公司 High-intensity high-modulus high-weather-resistance co-extruded long glass fiber reinforced PVC and ASA pipe and preparation method thereof
CN105003753A (en) * 2015-08-07 2015-10-28 广东宝通玻璃钢有限公司 Thermoplastic pipeline related to continuous fiber reinforcement and producing method
CN106426977A (en) * 2016-08-30 2017-02-22 李鹏飞 Vertical type composite material pipeline production line
CN210820992U (en) * 2019-09-09 2020-06-23 江苏云芯电气有限公司 Production line of basalt composite resin high-strength ultra-light insulating pipe

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112715459A (en) * 2020-12-24 2021-04-30 重庆四通八达管业有限公司 Basalt fiber tank fish-vegetable symbiotic system equipment and manufacturing process
CN114311735A (en) * 2021-07-23 2022-04-12 江苏芯安新材料科技有限公司 Production method of conical electric wire tower production line
CN114311735B (en) * 2021-07-23 2023-08-18 江苏芯安新材料科技有限公司 Production method of conical wire pole tower production line

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