CN104884032B - Skin gel-form composition - Google Patents
Skin gel-form composition Download PDFInfo
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- CN104884032B CN104884032B CN201480003318.3A CN201480003318A CN104884032B CN 104884032 B CN104884032 B CN 104884032B CN 201480003318 A CN201480003318 A CN 201480003318A CN 104884032 B CN104884032 B CN 104884032B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a kind of skin gel-form composition, even if its in the environment of it there is electrolyte can also easily gelation, the effect of the excellent in stability of its gelation preparation can be played, and the ductility and use feeling when being coated with when in use are also excellent.The skin gel-form composition of the present invention is characterised by, containing (A) electrolyte, (B) non-ionic polysaccharide based compound and (C) cross-linked polymer, the cross-linked polymer be using (C1) (methyl) acrylamido methylpropane sulfonic acid salt, (C2) dimethyl (methyl) acrylamide, (C3) (methyl) alkyl acrylate, (C4) (methyl) acrylic acid polyoxyethylene alkyl ether formed by necessary monomer component.
Description
Technical field
The present invention relates to skin gel-form composition.
Background technology
For mixture has electrolyte, the particularly composition of polyvalent cation, its gelation easily causes aggregation, difficult
To obtain sufficient thickening effect, and the precipitate from electrolyte is easily produced, therefore gelation is extremely difficult in itself.Such as
This makes the composition gelsization comprising electrolyte there are very many technical problems.
For the influence of the salt that reduces electrolyte, it is also contemplated that height mixture thickener, but this trial also has following ask
Topic：Preparation stability is poor, and poor ductility during coating, generates uneven attachment, and the use feeling such as sticky feeling is deteriorated.
Therefore, use is have also been attempted it is said that being suitable for the stabilized non-ionic polysaccharide system chemical combination of electrolyte mixture system
Thing.Specifically, it is proposed that the cosmetics containing vitamin C derivatives, rubber mass and cellulose polymer are (for example, see special
Sharp document 1)；Gelation topical compositions containing activating agent used for cosmetic, electrolyte and cetyl hydroxyethyl cellulose
(for example, see patent document 2)；Contain xanthans or kappa carrageenan, locust bean gum, hyaluronic acid or its salt or ethoxy
The skin preparations for extenal use of cellulose, multivalent metal salt (for example, see patent document 3)；Contain methylcellulose, emulsifying agent, fluid oil
Oil-in-water type bubbles cosmetics (for example, see patent document 4) of agent and electrolyte etc..
But, although stability, non-ionic polysaccharide thickener sheet can be improved in a way by these trials
The thickening effect of body is weak, in order that its gelation, it is necessary to height mixture, exists and glutinous slip and the use feeling such as tackiness are caused not
The problem of good influence.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 04-077409 publications
Patent document 2：Japanese Unexamined Patent Publication 09-202708 publications
Patent document 3：Japanese Unexamined Patent Publication 07-233045 publications
Patent document 4：Japanese Unexamined Patent Publication 2006-273752 publications
The content of the invention
The invention problem to be solved
The present invention be in view of above-mentioned prior art and complete, its problem is that provide a kind of skin is combined with gel
Thing, even if its in the environment of it there is electrolyte can also easily gelation, the stability of its gelation preparation can be played
Excellent effect, and the ductility and use feeling when being coated with when in use are also excellent.
Scheme for solving problem
That is, the present invention relates to following technical proposals.
[1] a kind of skin gel-form composition, its contain (A) electrolyte, (B) non-ionic polysaccharide based compound, with
And (C) is cross-linked polymer formed by necessary monomer component with following (C1)~(C4),
(C1) (methyl) acrylamido methylpropane sulfonic acid salt,
(C2) dimethyl (methyl) acrylamide,
(C3) (methyl) alkyl acrylate,
(C4) (methyl) acrylic acid polyoxyethylene alkyl ether.
[2] skin gel-form composition as described above described in [1], wherein, above-mentioned (B) composition be selected from locust bean gum,
At least one of tara gum, guar gum and hydroxypropylguar.
[3] skin gel-form composition as described above described in [1] or [2], wherein, above-mentioned (C) composition is (methyl) third
Acrylamide methyl propane sulfonic acid ammonium/dimethyl (methyl) acrylamide/(methyl) lauryl acrylate/(methyl) acrylic acid polyoxy second
Alkene lauryl ether cross-linked polymer.
[4] skin gel-form composition as described above any one of [1]~[3], wherein, above-mentioned (B) composition
Content is the mass % of 0.2 mass %~1, and the content of above-mentioned (C) composition is the mass % of 0.1 mass %~2.
[5] skin gel-form composition as described above any one of [1]~[4], it further contains (D) pectin
Form.And,
[6] skin gel-form composition as described above described in [5], wherein, the content of above-mentioned (D) composition is 0.1 matter
Measure the mass % of %~1.5, (D) composition than D/ (B+D) is 0.1~0.8 relative to the content of (B) composition and the total amount of (D) composition
Scope.
The effect of invention
Even if the skin gel-form composition of the present invention can also easily coagulate for example in the environment of it there is electrolyte
Gel, the gel-form composition of the preparation can play the effect with especially excellent stability.In addition, the skin of the present invention is used
Ductility when gel-form composition is coated with when in use is excellent, can equably extend, and in the absence of glutinous sliding and tacky, can send out
Wave the excellent effect of use feeling.
Embodiment
The present invention skin gel-form composition contain (A) electrolyte, (B) non-ionic polysaccharide based compound and
(C) cross-linked polymer, the cross-linked polymer is with (C1) (methyl) acrylamido methylpropane sulfonic acid salt, (C2) dimethyl (methyl)
Acrylamide, (C3) (methyl) alkyl acrylate, (C4) (methyl) acrylic acid polyoxyethylene alkyl ether are necessary monomer component
Formed by.
As the electrolyte of (A) composition, whitening effect, moistening effect, anti-inflammatory effects, convergence effect, purple are typically expected
Outside line assimilation effect, antiperspirancy performance etc. and the material of mixture.In the present invention, as long as it generally can act as the thing of cosmetic material
Matter is just not particularly limited, according to the appropriate mixture of purpose.
As used (A) composition, for example, it can enumerate organic acid and its salt, inorganic acid and its salt.Specifically, may be used
To enumerate the inorganic salts such as inorganic calcium salt, inorganic potassium salt, inorganic sodium, inorganic magnesium salt；The lactic acid such as sodium lactate, magnesium lactate, calcium lactate
Salt；The chondroitin sulfate salt such as sodium chondroitin sulfate, stearoyl sodium chondroitin sulfate；The dermatan sulfate salt such as dermatan sulfate sodium；
The phosphate such as potassium phosphate, sodium phosphate, sodium pyrophosphate；The glycyrrhetates such as dipotassium glycyrrhizinate salt；MAP, Vitamin C
The ascorbates such as acid phosphoric acid ester sodium, sodium ascorbate, L-AA sulfuric ester disodium；Pyrrolidone sodium carboxylate, pyrrolidines
The pyrrolidone carboxylic acid salts such as keto carboxylic acid zinc；Glycine, threonine, alanine, tyrosine, valine, leucine, arginine, dried meat
The amino acid such as propylhomoserin, aspartic acid, glutamic acid, serine and their derivative；ESCALOL 567-5-
The ultra-violet absorber such as sulfonic acid and its sodium salt；Antiperspirant such as chlorination hydroxyl aluminium, p-phenolsulfonic acid's zinc etc..These (A) compositions can be single
Solely using a kind of, appropriately combined it can also be used two or more.
Content to (A) composition is not particularly limited, generally from assigning desired effect aspect, in composition
In be preferably more than 0.01 mass %, more preferably more than 0.05 mass %.In addition, from preparation stability aspect, it is excellent
Elect as below 15 mass %, be more preferably below 10 mass %.From the viewpoint of these, the content of (A) composition is preferably 0.01
The mass % of the mass % of quality %~15, more preferably 0.05 mass %~10.
As the non-ionic polysaccharide based compound of (B) composition, for example, it can enumerate non-ionic polysaccharide and/or it spreads out
It is biological.Specifically, in the monosaccharide such as can enumerate glucose, galactolipin, mannose, arabinose, xylose a kind or
Two or more polysaccharide constituted；And be modified these polysaccharide obtained from modified such as alkyl, particularly hydroxy alkyl
Polysaccharide etc..
As specific (B) composition, for example, it can enumerate dextran, amylopectin, locust bean gum, arabinogalactan
Sugar, tara gum, guar gum, tamarind seeds glue, konjac glucomannan, hydroxypropylguar etc..These (B) compositions can be with
It is used alone a kind of, appropriately combined can also be used two or more.As preferred (B) composition, from can easily gel
Set out in terms of the aspect and preparation stability of change, preferably use locust bean gum, tara gum, guar gum, hydroxypropyl guar
Bean gum.
It should be noted that (B) composition can also use commercially available product.As the commercially available product of locust bean gum, for example, it can lift
Go out Inagel Locust bean gum CS (trade name, the manufacture of Yi Na food industry society), Meypro-LBG Fleur M-
175th, Meypro-LBG Fleur M-200, Meypro-LBG LAC (trade name, the manufacture of Danisco societies), GENU GUM RL-
200-J (trade name, the manufacture of CP Kelco societies) etc..
As the commercially available product of tara gum, for example, it can enumerate spino gum (trade name, three brilliant society's manufactures), PVC ス ト ッ プ
D-2101 (trade name, San-Ei Gen F.F.I., Inc. manufacture) etc..
As the commercially available product of guar gum, for example, it can enumerate Inagel guar gum CS (trade name, her that food work
Industry society manufactures), MEYPRO-GUAR (trade name, Danisco societies manufacture) etc..
As the commercially available product of hydroxypropylguar, for example, it can enumerate JAGUAR HP-8 (trade name, three brilliant society's manufactures)
Deng.
Content to (B) composition is not particularly limited, generally from can easily gelation, assign excellent preparation stabilization
The aspect of property；And ductility, the aspect that equably extends when improving coating are set out, preferably 0.1 matter in the composition
Measure more than %, more preferably more than 0.2 mass %.It is preferably below 3 mass %, more excellent in addition, from use feeling aspect
Elect as below 1 mass %.From the viewpoint of these, the content of (B) composition is preferably the mass % of 0.1 mass %~3, more preferably
The mass % of 0.2 mass %~1.
It with following (C1)~(C4) is cross-linked polymer formed by necessary monomer component that (C) composition of the present invention, which is,.Need
It is noted that in this specification, " (methyl) acrylic acid " refers to both " methacrylic acid " and " acrylic acid " or one.
(C1) (methyl) acrylamido methylpropane sulfonic acid salt,
(C2) dimethyl (methyl) acrylamide,
(C3) (methyl) alkyl acrylate,
(C4) (methyl) acrylic acid polyoxyethylene alkyl ether.
The salt of (methyl) acrylamido methylpropane sulfonic acid salt as necessary monomer component (C1) is not particularly limited, example
Sodium salt, sylvite, ammonium salt can such as be enumerated.In the present invention, from can easily gelation aspect, preferably use (first
Base) acrylamido methylpropane sulfonic acid ammonium salt.
The alkyl chain length of (methyl) alkyl acrylate as necessary monomer component (C3) is not particularly limited, for example
The alkyl that carbon number is 6~22 can be illustrated.In the present invention, from can easily gelation aspect, preferably use
With (methyl) alkyl acrylate of carbon number for 10~16 alkyl, wherein being 12 more preferably using having carbon number
Alkyl (methyl) lauryl acrylate.
It is not special to the alkyl chain length of (methyl) acrylic acid polyoxyethylene alkyl ether as necessary monomer component (C4)
Limit, for example, can illustrate the alkyl that carbon number is 6~22.In the present invention, from can easily gelation aspect,
(methyl) acrylic acid polyoxyethylene alkyl ether for 10~16 alkyl with carbon number is preferably used, wherein, more preferably make
With with (methyl) the acrylic acid polyoxyethylene lauryl ether of carbon number for 12 alkyl.It should be noted that to oxidation second
The average addition molal quantity of alkene is not particularly limited, and preferably 1~30.
As specific (C) composition, for example, it can enumerate with INCI (International Cosmetic
Ingredient Dictionary and Handbook (international cosmetic raw material dictionary and handbook), the 14th edition, volume 2,
CTFA, 2012, p.2481)：POLYACRYLATE CROSSPOLYMER-6 (polyacrylate cross-linked polymer -6) are marked
, (methyl) acrylamido methylpropane sulfonic acid ammonium/dimethyl (methyl) acrylamide/(methyl) lauryl acrylate/(methyl)
Acrylic acid polyoxyethylene (4) lauryl ether cross-linked polymer etc..
It should be noted that (C) composition can also use commercially available product.It is used as POLYACRYLATE CROSSPOLYMER-6
Commercially available product, can for example enumerate SEPIMAX ZEN (trade name, SEPPIC societies manufacture) etc..
Content to (C) composition is not particularly limited, generally from can easily gelation, assign excellent preparation stabilization
The aspect of property；And ductility, the aspect that equably extends when improving coating are set out, in the composition, preferably 0.05 matter
Measure more than %, more preferably more than 0.1 mass %.It is preferably below 5 mass %, more excellent in addition, from use feeling aspect
Elect as below 2 mass %.From the viewpoint of these, the content of (C) composition is preferably the mass % of 0.05 mass %~5, more preferably
For the mass % of 0.1 mass %~2.
Improve in terms of glutinous sliding and tacky, the further raising use feeling of further suppression and also the side of preparation stability
Face is set out, and (D) pectin can be contained in skin gel-form composition of the invention.
Refer to as the pectin of (D) composition in the vegetables such as the fruits such as citrus, apple, pears, grape or carrot, beans
The material contained, is composition obtained from by being extracted as fruit or vegetables.Main component is made up of galacturonic acid, galactolipin
Aldehydic acid has the structure that the carboxyl for the polygalacturonic acid for having carried out α -1,4 glycoside links with chain is esterified by part methyl.Really
Glue includes making the different pectin of methyl-esterified degree (%) (hereinafter referred to as DE values (%)), Yi Jili because abstraction process is different
Demethylation esterification is carried out with acid or alkali and pectin obtained from adjusting DE values (%) etc..It should be noted that described in the present invention
DE values (%) represent the galacturonic acid number through methyl-esterified relative to total galacturonic acid number ratio.
On the DE values (%) of used pectin, just it is not particularly limited as long as desired effect can be assigned fully,
From it is further suppress it is glutinous it is sliding and tacky, further improve use feeling in terms of and raising preparation stability aspect, it is excellent
Choosing uses the pectin that DE values (%) are 20%~70%.In the present invention, can be used alone DE values (%) is 20%~70%
Pectin, can also be used the different pectin of more than two kinds of DE values (%) is appropriately combined.
It should be noted that (D) composition can also use commercially available product.It is 20%~70% pectin as DE values (%)
Commercially available product, for example, can enumerate Neo soft P-3 (trade name, the manufacture of sun chemistry society), GENU PECTIN LM-106AS-
YA-J、LM-104AS-BG-J、LM-104AS-FS-J、LM-104AS-J、X-211-04、LM-84AS、LM-102AS-J、LM-
(trade name is by 101AS-J, LM-101AS-JS-J, LM-105AS-J, BETA BI-J, JM-150-J, JMJ-J, DF-Z-J
Copenhagen Pectin Factory societies manufacture) etc..
Content to (D) composition is not particularly limited, and is generally used from glutinous sliding and tacky, the further raising of further suppression
The aspect of sense and set out in terms of improving preparation stability, in the composition, preferably more than 0.05 mass %, more preferably
More than 0.1 mass %.In addition, from use feeling aspect, preferably below 3 mass %, more preferably 1.5 mass % with
Under.From the viewpoint of these, the content of (D) composition be preferably the mass % of 0.05 mass %~3, more preferably 0.1 mass %~
1.5 mass %.
In the present invention, by further containing above-mentioned (D) composition, it is possible to reduce the content of (B) composition, glutinous cunning can be reduced
And it is tacky, it is also one of key character that can further improve use feeling.
In order to give full play to such feature, for above-mentioned (B) composition content and (D) composition content, as (D) into
Split-phase for (B) composition and the total amount of (D) composition content than D/ (B+D), prepared by the preferably scope 0.05~1, more
It is preferred that prepared by the scope 0.1~0.8.
From can easily gelation, and can play its gelation preparation excellent in stability effect in terms of go out
Hair, skin of the invention preferably contains substantially no ethanol with gel-form composition.It should be noted that " real in the present invention
Ethanol is not contained in matter " refer to " not containing ethanol in addition ", it is not excluded that contained micro ethanol in each compounding ingredients.
As long as in the range of the effect of the present invention is not damaged, in addition to mentioned component, in the skin gel of the present invention
The composition that can generally be used in shape composition according to the appropriate mixture of purpose in cosmetics, such as purified water, surfactant,
Freshener, screening agent, preservative, plant extracts, spices etc..
The skin of the present invention is not particularly limited with the manufacture method of gel-form composition, for example can be according to known
Method is manufactured.Specifically, such as can enumerate add mentioned component it is outer and using dispersing mixer, impeller mixer
Method that known mixing arrangement is mixed etc., the present invention is not only limited to these manufacture methods.
Embodiment
Below, based on embodiment, the present invention will be described in more detail, but the present invention is not limited to these embodiments.
It should be noted that unless otherwise specified, otherwise blend amount represents " quality % ".In addition, evaluating all in 23 DEG C, humidity 60%
Constant temperature and humidity certain condition under implement.
Following compositions are used in embodiment and comparative example.
((A) electrolyte)
※1：P-phenolsulfonic acid's zinc (Matsumoto Fine Chemical societies manufacture, [zinc sulfocarbolate])
※2：Chlorination hydroxyl aluminium (Summit Research Labs societies manufacture, [Micro-Dry 3115])
※3：Zinc pyrrolidone carboxylate (aginomoto society manufactures, [AJIDEW ZN-100])
※4：Calcium lactate (manufacture of Musashi open country chemistry institute society, [calcium lactate])
※5：Dipotassium glycyrrhizinate (Wan Shan pharmacy society manufactures, [dipotassium glycyrrhizinate])
((B) non-ionic polysaccharide thickener)
Locust bean gum (Yi Na food industry society manufactures, [Inagel Locust bean gum CS])
Tara gum (three brilliant society's manufactures, [spino gum])
Guar gum (Yi Na food industry society manufactures, [Inagel guar gum CS])
Hydroxypropylguar (three brilliant society's manufactures, [JAGUAR HP-8])
((C) cross-linked polymer)
※6：POLYACRYLATE CROSSPOLYMER-6 (SEPPIC societies manufacture, [SEPIMAX ZEN])
((D) pectin)
※7：Pectin (Copenhagen Pectin Factory societies manufacture, [LM-104AS-J], DE values 27%)
※8：Pectin (Copenhagen Pectin Factory societies manufacture, [LM-101AS-J], DE values 35%)
※9：Pectin (Copenhagen Pectin Factory societies manufacture, [BETA BI-J], DE values 55%)
※10：Pectin (Copenhagen Pectin Factory societies manufacture, [JMJ-J], DE values 70%)
(other compositions)
Xanthans (big Japanese pharmaceutical society manufacture, [Ekogum])
Hydroxypropyl cellulose (Japanese Cao Da societies manufacture, [hydroxypropyl cellulose])
※11：Carboxyl vinyl polymer (BF Goodrich societies manufacture, [CARBOPOL940])
※12：Modified carboxyl polyvinyl (LUBRIZOL societies manufacture, [PEMULEN TR-1])
(preparation 1 of sample)
Composition according to described in Tables 1 and 2, conventionally by embodiment 1~15 and the skin of comparative example 1~15
Gel is prepared with composition, is evaluated for following.Result is remembered in Tables 1 and 2 in the lump.It should be noted that mixed in table
Dosage is the value for being converted into pure composition.
(test example 1：Formulation evaluation)
The character after the firm manufacture of each sample obtained in embodiment and comparative example is visually observed, according to following evaluation base
Standard is evaluated.
<Formulation metewand>
Zero (good)：Precipitate and dehydration can not be produced and carried out formulation (can gelation).
△ (insufficient)：A small amount of precipitate is produced, but can be formulation；Or a small amount of dehydration is produced, but can make
Agent (can gelation).
× (bad)：Produce obvious precipitate, it is impossible to formulation；Or produce obvious dehydration, it is impossible to it is formulation (no
Gelation).
(test example 2：The evaluation of preparation stability)
Each sample obtained in embodiment and comparative example is enclosed in volume 50mL transparent glass container respectively, visually seen
The state of system when being preserved 1 week in 5 DEG C of thermostat is examined, is evaluated according to following metewand.Need explanation
It is, on the sample of not gelation in test example 1, the not evaluation for preparation stability.
<The metewand of preparation stability>
Zero (good)：It is completely unconfirmed to arrive precipitate, maintain gel state.
△ (insufficient)：A small amount of precipitate is confirmed, but maintains gel state.
× (bad)：Obvious precipitate is confirmed, gel state, or precipitate increase are not maintained, gel is not maintained
State.
(test example 3：The evaluation of ductility)
Please 20 professional judging panels by each sample coating obtained in embodiment and comparative example to face, progress uses experiment,
Ductility during on coating, sense evaluation is carried out according to following metewand.It should be noted that in test example 1
The sample of not gelation, the not evaluation for ductility.
<The metewand of ductility>
◎ (very good)：In 20 more than 16 answer without hanging, ductility it is excellent.
Zero (good)：In 20 11~15 answer without hanging, ductility it is excellent.
△ (insufficient)：In 20 6~10 answer without hanging, ductility it is excellent.
× (bad)：In 20 less than 5 answer without hanging, ductility it is excellent.
(test example 4：The evaluation of use feeling)
Please be equally 20 professional judging panels, according to following metewand to coating part after the evaluation 5 minutes of test example 3
Glutinous sliding sense and sticky feeling carry out sense evaluation.It should be noted that the sample on not gelation in test example 1, is not supplied
In the evaluation of use feeling.
<The metewand of use feeling>
◎ (very good)：Answered in 20 without glutinous sliding, tacky for more than 16.
Zero (good)：Answered in 20 without glutinous sliding, tacky for 11~15.
△ (insufficient)：Answered in 20 without glutinous sliding, tacky for 6~10.
× (bad)：Answered in 20 without glutinous sliding, tacky for less than 5.
From the result shown in Tables 1 and 2, the skin gel-form composition obtained in each embodiment and each comparative example
In obtained material compare, even if the generation and dehydration of precipitate, Ke Yirong can also be suppressed in the environment of it there is electrolyte
Change places gelation, and its character can stably continue.In addition we know, ductility when being not only coated with is excellent, and without glutinous cunning
And it is tacky, the excellent effect of use feeling can be played.
The Formulation Example of the skin gel-form composition of the present invention is illustrated below.It should be noted that content is quality %.
(Formulation Example 1)
(Formulation Example 2)
(Formulation Example 3)
Industrial applicibility
Even if the present invention skin gel-form composition in the environment of it there is electrolyte can also easily gelation,
The effect of the excellent in stability of its gelation preparation can be played, the ductility and use feeling during coating are excellent, thus preferably use
It is used as the cosmetics of skin.
Claims (5)
1. a kind of skin gel-form composition, it contains (A) electrolyte, (B) non-ionic polysaccharide based compound and (C)
It is cross-linked polymer formed by necessary monomer component with following (C1)~(C4),
(C1) (methyl) acrylamido methylpropane sulfonic acid salt,
(C2) dimethyl (methyl) acrylamide,
(C3) (methyl) alkyl acrylate,
(C4) (methyl) acrylic acid polyoxyethylene alkyl ether,
The content of (C) composition is below the mass % of more than 0.05 mass % 2,
(B) composition is selected from least one of locust bean gum, tara gum, guar gum and hydroxypropylguar.
2. skin gel-form composition as claimed in claim 1, wherein, (C) composition is (methyl) acrylamide first
Base propane sulfonic acid ammonium/dimethyl (methyl) acrylamide/(methyl) lauryl acrylate/(methyl) acrylic acid polyoxyethylene laural base
Ether cross-linked polymer.
3. skin gel-form composition as claimed in claim 1 or 2, wherein, the content of (B) composition is 0.2 matter
Measure the mass % of %~1, the content of (C) composition is the mass % of 0.1 mass %~2.
4. skin gel-form composition as claimed in claim 1 or 2, it is further formed containing (D) pectin.
5. skin gel-form composition as claimed in claim 4, wherein, the content of (D) composition for 0.1 mass %~
1.5 mass %, (D) composition relative to (B) composition and the total amount of (D) composition content than scope that D/ (B+D) is 0.1~0.8.
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| JP2013-038761 | 2013-02-28 | ||
| JP2013038761 | 2013-02-28 | ||
| JP2013-038760 | 2013-02-28 | ||
| JP2013038760 | 2013-02-28 | ||
| PCT/JP2014/053003 WO2014132783A1 (en) | 2013-02-28 | 2014-02-10 | Gel composition for skin |
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| CN104884032A CN104884032A (en) | 2015-09-02 |
| CN104884032B true CN104884032B (en) | 2017-07-25 |
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| CN201480003318.3A Active CN104884032B (en) | 2013-02-28 | 2014-02-10 | Skin gel-form composition |
| CN201480003315.XA Pending CN104837475A (en) | 2013-02-28 | 2014-02-10 | Gel composition for skin |
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| CN201811249671.6A Pending CN109481329A (en) | 2013-02-28 | 2014-02-10 | Skin gel-form composition |
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| JP (2) | JP5989227B2 (en) |
| CN (3) | CN109481329A (en) |
| WO (2) | WO2014132784A1 (en) |
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| CN109843254B (en) * | 2016-10-18 | 2022-04-29 | 花王株式会社 | Cosmetic preparation |
| KR102635087B1 (en) * | 2017-08-31 | 2024-02-08 | 가부시키가이샤 시세이도 | Cosmetic base and skin cosmetics using it |
| DE212017000348U1 (en) * | 2017-12-18 | 2020-09-11 | Suzhou Synerguar Hydrocolloid Technology Co., Ltd. | Hydroxypropyl guar gum |
| CN111818903B (en) * | 2018-03-05 | 2024-05-24 | 松下知识产权经营株式会社 | Cosmetic or medical material |
| JP2020152688A (en) * | 2019-03-22 | 2020-09-24 | 株式会社マンダム | Cosmetic composition |
| FR3106979B1 (en) * | 2020-02-12 | 2022-07-22 | Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic | Composition for topical use in the form of a gel comprising mineralization water |
| WO2024128168A1 (en) | 2022-12-15 | 2024-06-20 | L'oreal | Composition comprising electrolyte and combination of polysaccharides |
Citations (1)
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|---|---|---|---|---|
| CN101843567A (en) * | 2009-03-25 | 2010-09-29 | 积水化成品工业株式会社 | Gel for cosmetic mask |
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| GB8813552D0 (en) * | 1988-06-08 | 1988-07-13 | Unilever Plc | Thickening system |
| JP4695249B2 (en) * | 2000-08-02 | 2011-06-08 | 株式会社コーセー | Gel cosmetic |
| JP3814224B2 (en) * | 2001-04-25 | 2006-08-23 | エーザイ株式会社 | Composition for external use |
| JP2003012453A (en) * | 2001-06-29 | 2003-01-15 | Kose Corp | Gel-like cosmetic |
| FR2832156B1 (en) * | 2001-11-15 | 2004-05-28 | Oreal | PREPARATION OF POLYSACCHARIDE BETAINATE COMPOUNDS, COMPOUNDS OBTAINED, THEIR USE AND COMPOSITIONS COMPRISING THE SAME |
| KR101521315B1 (en) * | 2007-09-26 | 2015-05-18 | 다우 코닝 코포레이션 | Personal care compositions containing silicone-organic gels from polyalkyloxylene crosslinked silicone elastomers |
| JP5398062B2 (en) * | 2009-03-16 | 2014-01-29 | 積水化成品工業株式会社 | Hydrogel external preparation |
| JP5414421B2 (en) * | 2009-08-21 | 2014-02-12 | 株式会社マンダム | Non-aerosol type antiperspirant composition |
| BR112012028274B1 (en) * | 2010-05-05 | 2018-01-16 | L'oreal S.A. | ANYDRIC CYCLE MASK, METHODS FOR MAKING CIRCLES, VOLUMEING AND REMOVING FROM AN CYCLES ANYDRIC MASK COMPOSITION |
| CN102920615A (en) * | 2011-08-08 | 2013-02-13 | 陈明智 | Gum composition for external use on skin |
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- 2014-02-10 CN CN201811249671.6A patent/CN109481329A/en active Pending
- 2014-02-10 JP JP2015502845A patent/JP5989227B2/en active Active
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- 2014-02-10 WO PCT/JP2014/053003 patent/WO2014132783A1/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101843567A (en) * | 2009-03-25 | 2010-09-29 | 积水化成品工业株式会社 | Gel for cosmetic mask |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN104837475A (en) | 2015-08-12 |
| JP5989227B2 (en) | 2016-09-07 |
| WO2014132784A1 (en) | 2014-09-04 |
| CN109481329A (en) | 2019-03-19 |
| WO2014132783A1 (en) | 2014-09-04 |
| JPWO2014132783A1 (en) | 2017-02-02 |
| JPWO2014132784A1 (en) | 2017-02-02 |
| CN104884032A (en) | 2015-09-02 |
| JP5989226B2 (en) | 2016-09-07 |
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