CN104877509A - Heat reflection and dissipation type automotive clear top finish - Google Patents
Heat reflection and dissipation type automotive clear top finish Download PDFInfo
- Publication number
- CN104877509A CN104877509A CN201510295046.5A CN201510295046A CN104877509A CN 104877509 A CN104877509 A CN 104877509A CN 201510295046 A CN201510295046 A CN 201510295046A CN 104877509 A CN104877509 A CN 104877509A
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- acrylic resin
- agent
- finish
- heat reflection
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to heat reflection and dissipation type automotive clear top finish. The heat reflection and dissipation type automotive clear top finish comprises, by weight, 10-30 parts of high-hydroxyl-value acrylic resin, 15-35 parts of low-hydroxyl-value acrylic resin, 1-5 parts of gloss enhancer, 18-25 parts of heat reflection solution, 1-5 parts of esters solvent, 1-5 parts of alcohol ether solvent, 1-3 parts of aliphatic dibasic esters, 0.1-1.0 part of levelling agent, 0.1-0.5 part of defoamer and 0.1-0.5 part of wetting agent. The heat reflection solution comprises acrylic resin, aluminium nitride, indium tin oxide, nanometer yttrium oxide, wetting dispersant, anti-flooding agent, xylene, butyl acetate, alcohol ether solvent, dibasic ester and graphene. The heat reflection and dissipation type automotive clear top finish plays roles in detecting, protecting finish paint in the under layer and convecting and dissipating heat reflected by the finish paint in the under layer, and stereoscopic impression, metal effect impression and mirror-surface impression of the sparkling finish are enhanced.
Description
Technical field
The present invention relates to a kind of Automobile Coatings, particularly the anti-hot heat radiating type Automobile Coatings of one.
Background technology
General automobile finish has the functions such as protection and attractive, decorative; as high gloss, high-weatherability, ornamental decorative, strong corrosion resistant, color keep permanence, resistance to mechanical collision, anti-scratch flower, resistance to gasoline, machine oil, acid rain resistant, resistance to birds droppings etc.; anti-hot heat insulation type automobile polychromatic finish, except having the function of general automobile finish, also has effect that is anti-hot heat insulation and energy saving and pollution alleviation.Therefore, by the temperature in anti-hot heat insulation type automobile polychromatic finish controllable body of a motor car and car, realize cool in summer and warm in winter, to reduce automative air conditioning energy consumption, reduce motor vehicle emission, improve the comfort level of occupant and have great importance.Visible, anti-hot heat insulation type automobile polychromatic finish wide market.
Current market is commonly used OEM Automobile Coatings and mostly is acrylic paint, and its fullness ratio and high gloss, weather-proof erosion resistance are all satisfactory.But it does not have anti-hot merit energy, to support the use effect undesirable with anti-heat-lightening lac varnish.
Summary of the invention
The technical problem to be solved in the present invention is: provide a kind of and play decoration, protection lower floor's finish paint and carry out to the heat that lower floor's metallic finishes reflects the effect that convection current distributes; and enhance the anti-hot heat radiating type Automobile Coatings of the stereoscopic sensation of polychromatic finish, metallic appearance sense, minute surface sense; meanwhile, this anti-hot heat radiating type Automobile Coatings itself also has heat reflection effect.
The technical scheme solved the problems of the technologies described above is: a kind of anti-hot heat radiating type Automobile Coatings, it is made up of following component and parts by weight proportioning: high hydroxyl value acrylic resin 10 ~ 30 parts, low hydroxyl value acrylic resin 15 ~ 35 parts, optical brightener 1 ~ 5 part, anti-hot solution 18 ~ 25 parts, esters solvent 1 ~ 5 part, alcohol ether solvents 1 ~ 5 part, dibasic ester 1 ~ 3 part, flow agent 0.1 ~ 1.0 part, defoamer 0.1 ~ 0.5 part, wetting agent 0.1 ~ 0.5 part;
Component and the parts by weight proportioning of described anti-hot solution are: acrylic resin 25 ~ 28 parts, aluminium nitride 3 ~ 10 parts, phosphide tin compound 27 ~ 33 parts, nano yttrium oxide 17 ~ 23 parts, wetting dispersing agent 2 ~ 4 parts, anti-flooding agent 0.3 ~ 0.8 part, dimethylbenzene 3 ~ 5 parts, N-BUTYL ACETATE 3 ~ 5 parts, alcohol ether solvents 3 ~ 5 parts, dibasic ester 2 ~ 4 parts, Graphene 0.01 ~ 0.5 part.
Described high Hydroxylated acrylic resin refers to that hydroxy radical content is the acrylic resin of 3 ~ 4%, and described low hydroxyl value acrylate refers to that hydroxy radical content is the acrylic resin of 1 ~ 2%.
Acrylic resin in described anti-hot solution refers to that hydroxy radical content is the acrylic resin of 3 ~ 4%.
The major ingredient of the finishing paint of the present invention is colourless transparent resin; after the material adding anti-heat and heat radiation; form a kind of colored transparent varnish; film forming is attached on metallic finishes; play the effect of decoration and protection lower floor finish paint, and enhance the stereoscopic sensation of polychromatic finish, metallic appearance sense, minute surface sense.In this product, the convection current that finishing paint also will bear the heat that metallic finishes reflects is distributed.For this reason, the anti-hot material simultaneously imported and heat sink material, the anti-heat effect of collaborative metallic finishes, and constantly dispel the heat in air.This is also a kind of perfectly innovation result.
Coating varnish of the present invention, on the basis of this existing acrylic acid or the like Automobile Coatings, adds anti-hot merit energy, and can keep the weather-proof and decorate properties of conventional mask lac varnish, energy-conservation and have important realistic meaning on people and vehicles are in harmony.On the other hand, anti-heat-lightening lac varnish uses finishing paint, heat reflecting cover light varnish of the present invention must be supported the use, effectively could ensure its overall anti-thermal effect, if use traditional finishing paint, the heat reflection effect of anti-heat-lightening lac varnish will be reduced.
The beneficial effect that the present invention has is described below:
1, the new function of imparting is painted at orthodox car.
(1) energy saving and pollution alleviation: because the exhausted major part of solar heat is reflected in atmospheric layer, vehicle interior temperature obviously declines, and automative air conditioning just can be opened less or not open, minimizing oil, reduces waste gas to the discharge of environment.
(2) the temperature difference is obvious: the summer of room temperature at 35 DEG C, parked in outdoor automobile, under solar light irradiation, vehicle interior temperature can up to more than 50 DEG C, if cross car load with anti-hot paint spraying, because solar heat is scattering in air by reflection, vehicle interior temperature is at most at about 40 DEG C, similar with envrionment temperature, the temperature difference is very remarkable, and people's car more becomes natural harmony.
(3) lower the temperature and be also incubated: winter is cold, the outer temperature of car, than much lower in car, because finish paint is heat insulation, effectively prevent the convection current of car internal and external temperature, thus reaches warming object.
(4) hot merit index
Sunlight reflectivity white >=0.8
Other look >=0.6
Hemispherical emissivity >=0.85
Near infrared light reflectivity salable product >=0.6
Acceptable end product >=0.7
Premium grads >=0.8
2, the function of general automobile finish is possessed, as high gloss, high-weatherability, ornamental decorative, strong corrosion resistant, color keep permanence, resistance to mechanical collision, anti-scratch flower, resistance to gasoline, machine oil, acid rain resistant, resistance to birds droppings etc.
Below, the technical characteristic of a kind of anti-hot heat radiating type Automobile Coatings of the present invention is further described in conjunction with the embodiments.
Embodiment
Embodiment 1 ~ embodiment 3: a kind of anti-hot heat radiating type Automobile Coatings, its component and parts by weight proportioning are as subordinate list one.
Subordinate list one
In subordinate list one, described optical brightener is a kind of commercial polyester resin class additive.The component of described anti-hot solution and parts by weight proportioning are as formula arbitrary in subordinate list two, described esters solvent is dimethylbenzene, alcohol ether solvents is CAC(ethylene glycol ether acetate), dibasic ester is DBE(diester mixture), flow agent is BYK306 flow agent, defoamer be type siloxane as BYK141, wetting agent is BYK163 wetting dispersing agent.Described high Hydroxylated acrylic resin refers to that hydroxy radical content is the acrylic resin of 3 ~ 4%, and described low hydroxyl value acrylate refers to that hydroxy radical content is the acrylic resin of 1 ~ 2%.
The technological operation of embodiment 1 ~ embodiment 3: the high-speed stirring that feeds intake successively after 20 minutes sample presentation detect, be qualifiedly finished product.
The component of the anti-hot solution of subordinate list two and parts by weight proportioning table look-up.
In subordinate list two, described acrylic resin refers to that hydroxy radical content is the acrylic resin of 3 ~ 4%, wetting dispersing agent is BYK163 wetting dispersing agent, anti-flooding agent is BYK-P104S anti-flooding agent, alcohol ether solvents is CAC(ethylene glycol ether acetate), dibasic ester is DBE(diester mixture).
Anti-hot solution preparation method is: after feeding intake after dispersion grinding to fineness≤10 μ, discharging is for subsequent use.
The construction requirement of the anti-hot heat radiating type Automobile Coatings of the present invention:
1, adapted thinner is X--3000 thinner, and solidifying agent is CR205.
X-3000 diluent formulation: XYL:BAC:CAC=60:30:10.
CR205 hardener formula: N3390:BAC=66:34
Note: N 3390 is Bayer A.G's product
2, proportioning is: paint: solidifying agent: thinner=3:1:2--3
3, to paint construction requirement identical for other and tradition
The technical parameter of the anti-hot heat radiating type Automobile Coatings of the present invention: perform by HG/T 4341-2012 standard.
Simultaneous test:
The treating processes of laboratory vehicle: vehicle complete vehicle or the anti-hot heat insulation type automobile metal sparkling finish paint of parts → surface treatment → priming paint → middle painting → supporting the present invention →
the anti-hot heat radiating type Automobile Coatings of the present invention.
The treating processes of contrast car: vehicle complete vehicle or parts → surface treatment → priming paint → middle painting → conven-tional luster finish paint → conventional finishing paint.
1, heat insulating temperature difference testing experiment: be under the condition of 35 ± 1 DEG C in external temperature, laboratory vehicle and contrast car are placed on same outdoor place, irradiate 3 ~ 5 hours under sunlight, the vehicle interior temperature of contrast car is 55 ± 1 DEG C, and the vehicle interior temperature of laboratory vehicle is 40 ± 5 DEG C.Result shows, and the vehicle interior temperature of laboratory vehicle is at least lower more than 10 DEG C than the vehicle interior temperature of contrast car, illustrates that the anti-hot radiating effect of the anti-hot heat insulation type automobile metal sparkling finish paint of the present invention is remarkable.
2, temperature test experiment is incubated: be 5 ± 1 DEG C in external temperature, without under the condition of solar light irradiation, laboratory vehicle and contrast car are placed on same outdoor place, after 3 ~ 5 hours, the vehicle interior temperature of contrast car is 5 ± 1 DEG C, and the vehicle interior temperature of laboratory vehicle is 10 ± 3 DEG C.Result shows, and the vehicle interior temperature of laboratory vehicle is at least higher more than 5 DEG C than the vehicle interior temperature of contrast car, illustrates that the heat insulation effect of the anti-hot heat insulation type automobile metal sparkling finish paint of the present invention is also good.
In simultaneous test, the priming paint that laboratory vehicle and contrast car use and middle painting are identical, and " the anti-hot heat insulation type automobile metal sparkling finish paint of supporting the present invention " the applicant that laboratory vehicle uses has applied for the patent of invention that name is called " a kind of anti-hot heat insulation type automobile paint gloss oil and metallized finish " on the same day.
Described supporting anti-hot heat insulation type automobile metal sparkling finish paint, its each component and parts by weight proportioning are: anti-hot heat insulation type automobile paint gloss oil 80 ~ 90 parts, aluminium powder or pearlescence spangles 1.0 ~ 20 parts, various pigment toner is appropriate, for adjusting the thinner of viscosity appropriate.Making method is, adds flash silver slurry or pearlescence and various mill base, thinner and namely obtain finished product paint in paint gloss oil.
Component and the parts by weight proportioning of described anti-hot heat insulation type automobile paint gloss oil are: location agent 17 ~ 23 parts, anti-settling agent 8 ~ 15 parts, synergistic agent 10 ~ 18 parts, anti-hot solution 17 ~ 23 parts, BYK410 thickening material 0.3 ~ 0.8 part, BYK306 flow agent 0.1 ~ 0.3 part, BYK-P104S anti-flooding agent 0.5 ~ 1 part, brightening agent 0.2 ~ 0.5 part, acrylic resin 27 ~ 33 parts, for adjusting the thinner of viscosity appropriate.Preparation method is: stir after blanking successively, and its technical parameter is: outward appearance and color: milky white translucent liquid; Viscosity >=80S/T-4; Fineness≤10 μ.
Component and the parts by weight proportioning of the anti-hot solution of the anti-hot heat insulation type automobile metal sparkling finish paint of supporting the present invention are: urea formaldehyde 25 ~ 28 parts, nano-titanium system tired holder 10 ~ 18 parts, powder, phosphide tin compound 17 ~ 23 parts, nano yttrium oxide 17 ~ 23 parts, spinel powder 8 ~ 15 parts, wetting dispersing agent 2 ~ 4 parts, anti-flooding agent 0.3 ~ 0.8 part, dimethylbenzene 3 ~ 5 parts, N-BUTYL ACETATE 3 ~ 5 parts, alcohol ether solvents 3 ~ 5 parts, dibasic ester 2 ~ 4 parts, Graphene 0.01 ~ 0.5 part.Described urea formaldehyde refers to the urea formaldehyde of molecular weight between 300-500, wetting dispersing agent is BYK163 wetting dispersing agent, anti-flooding agent is BYK-P104S anti-flooding agent, and alcohol ether solvents is CAC(ethylene glycol ether acetate), dibasic ester is DBE(diester mixture).Preparation method is: stir after feeding intake successively, then after dispersion grinding to fineness≤10 μ, and discharging.
Component and the parts by weight proportioning of described location agent are: cellulose acetate butyrate 25 ~ 38 parts, N-BUTYL ACETATE 40 ~ 50 parts, dimethylbenzene 10 ~ 18 parts, 8 ~ 15 parts, butanols.The preparation method of this location agent is: add cellulose acetate butyrate again after first adding solvent (N-BUTYL ACETATE, dimethylbenzene and butanols), stirs until dissolve completely under the low speed.Its technical parameter is: outward appearance and color: colourless transparent solution, mechanical impurity; Viscosity >=100S/T-4; Fineness≤10 μ.
Component and the parts by weight proportioning of described anti-settling agent are: polyamide wax 17 ~ 23 parts, 45 ~ 55 parts, vibrin, BYK163 wetting dispersing agent 0.5 ~ 1.5 part, solvent or diluent 27 ~ 33 parts.The preparation method of this anti-settling agent is: after feeding intake successively, high-speed stirring is disperseed at once to abundant for about 30 minutes.Its technical parameter is: oyster white paste fluid, and fineness reading within three seconds is 10 below μ.
Component and the parts by weight proportioning of described synergistic agent are: polyamide wax 45 ~ 55 parts, and location agent 45 ~ 55 parts, stirs.
Described thinner is N-BUTYL ACETATE.
Claims (3)
1. an anti-hot heat radiating type Automobile Coatings, it is characterized in that: it is made up of following component and parts by weight proportioning: high hydroxyl value acrylic resin 10 ~ 30 parts, low hydroxyl value acrylic resin 15 ~ 35 parts, optical brightener 1 ~ 5 part, anti-hot solution 18 ~ 25 parts, esters solvent 1 ~ 5 part, alcohol ether solvents 1 ~ 5 part, dibasic ester 1 ~ 3 part, flow agent 0.1 ~ 1.0 part, defoamer 0.1 ~ 0.5 part, wetting agent 0.1 ~ 0.5 part;
Component and the parts by weight proportioning of described anti-hot solution are: acrylic resin 25 ~ 28 parts, aluminium nitride 3 ~ 10 parts, phosphide tin compound 27 ~ 33 parts, nano yttrium oxide 17 ~ 23 parts, wetting dispersing agent 2 ~ 4 parts, anti-flooding agent 0.3 ~ 0.8 part, dimethylbenzene 3 ~ 5 parts, N-BUTYL ACETATE 3 ~ 5 parts, alcohol ether solvents 3 ~ 5 parts, dibasic ester 2 ~ 4 parts, Graphene 0.01 ~ 0.5 part.
2. the anti-hot heat radiating type Automobile Coatings of one according to claim 1, it is characterized in that: described high Hydroxylated acrylic resin refers to that hydroxy radical content is the acrylic resin of 3 ~ 4%, described low hydroxyl value acrylate refers to that hydroxy radical content is the acrylic resin of 1 ~ 2%.
3. the anti-hot heat radiating type Automobile Coatings of one according to claim 1 and 2, is characterized in that: the acrylic resin in described anti-hot solution refers to that hydroxy radical content is the acrylic resin of 3 ~ 4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510295046.5A CN104877509B (en) | 2015-06-02 | 2015-06-02 | A kind of anti-hot heat radiating type Automobile Coatings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510295046.5A CN104877509B (en) | 2015-06-02 | 2015-06-02 | A kind of anti-hot heat radiating type Automobile Coatings |
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| CN104877509A true CN104877509A (en) | 2015-09-02 |
| CN104877509B CN104877509B (en) | 2017-06-30 |
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| CN201510295046.5A Expired - Fee Related CN104877509B (en) | 2015-06-02 | 2015-06-02 | A kind of anti-hot heat radiating type Automobile Coatings |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752516A (en) * | 2016-12-14 | 2017-05-31 | 张学健 | A kind of heat radiation coating of electronic device and preparation method thereof |
| CN107245278A (en) * | 2017-05-28 | 2017-10-13 | 安徽康瑞高科新材料技术工程有限公司 | A kind of anti-fingerprint coating varnish |
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2015
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106752516A (en) * | 2016-12-14 | 2017-05-31 | 张学健 | A kind of heat radiation coating of electronic device and preparation method thereof |
| CN107245278A (en) * | 2017-05-28 | 2017-10-13 | 安徽康瑞高科新材料技术工程有限公司 | A kind of anti-fingerprint coating varnish |
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| Publication number | Publication date |
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| CN104877509B (en) | 2017-06-30 |
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