CN104877432A - Scratch-resistant ink for decorating glass and preparation method thereof - Google Patents
Scratch-resistant ink for decorating glass and preparation method thereof Download PDFInfo
- Publication number
- CN104877432A CN104877432A CN201510337309.4A CN201510337309A CN104877432A CN 104877432 A CN104877432 A CN 104877432A CN 201510337309 A CN201510337309 A CN 201510337309A CN 104877432 A CN104877432 A CN 104877432A
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- China
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- parts
- phenylcarbinol
- ambetti
- resistant ink
- scrape resistant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
- C09D11/105—Alkyd resins
Abstract
The invention relates to scratch-resistant ink for decorating glass and a preparation method thereof. The ink comprises the following components in parts by weight: 65-82 parts of maleic acid resin, 10-20 parts of ethylene glycol butyl ether, 3-11 parts of ethyl acetate, 2-7 parts of butanone, 65-76 parts of polyamide resin, 9-15 parts of fatty alcohol, 10-18 parts of benzyl alcohol, 33-42 parts of benzyl alcohol, 30-40 parts of high-boiling-point kerosene, 8-16 parts of cyclohexanone, 7-15 parts of diacetone alcohol, 2-8 parts of sodium fluosilicate, 7-16 parts of alkyd resin, 0.24-0.65 part of dibutyltin oxide and 0.6-4.2 parts of methacrylic acid. The ink is coated on the surface of the glass, has an excellent decorating effect on the glass, meanwhile has the effects of strong adhesion, impact resistance, scratch resistance and fog resistance and is suitable for coating the surface of the glass on various occasions.
Description
Technical field
The present invention relates to decorative materials technology, particularly relate to a kind of ambetti scrape resistant ink and preparation method thereof.
Background technology
In material of construction, glass sometimes can be used as barrier and decoration.The functions such as ambetti has the lighting performance that can improve interior of building, the developing people visual field.In order to improve the aesthetics of ambetti, need at ambetti surface-coated ink.
The sticking power of current existing glass surface ink, scraping and wiping resistance performance, shock resistance are not high, and can not effectively prevent glass surface from hazing.Such as Chinese invention patent (the patent No. 201310242073.7, applying date 2013.06.18) disclose a kind of OGS glass protection ink, its preparation method and application thereof, this protection ink by weight, comprise following component: aliphatic urethane acrylate 6-10 part, N-vinyl pyrrolidone 3-5 part, 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide 0.3-0.5 part, stearyl alcohol 1-2 part, defoamer 0.1-0.2 part, flow agent 0.1-0.2 part, softening agent 0.3-0.4 part, phthalocyanine blue 1-2 part, this protection ink energy available protecting glass substrate, stop that hydrofluoric acid is to the erosion of glass, mechanical resistant is cut and is applicable to produce in enormous quantities, save manpower, material resources.
Summary of the invention
the technical problem solved:for the shortcoming such as the sticking power of existing glass surface ink, scraping and wiping resistance performance, shock resistance be not high, the invention provides a kind of ambetti scrape resistant ink and preparation method thereof.
technical scheme:a kind of ambetti scrape resistant ink, in mass parts containing following composition: maleic acid resin 65 ~ 82 parts, butyl glycol ether 10 ~ 20 parts, vinyl acetic monomer 3 ~ 11 parts, butanone 2 ~ 7 parts, polyamide resin 65 ~ 76 parts, fatty alcohol 9 ~ 15 parts, phenylcarbinol 10 ~ 18 parts, phenylcarbinol 33 ~ 42 parts, high-boiling point kerosene 30 ~ 40 parts, pimelinketone 8 ~ 16 parts, Pyranton 7 ~ 15 parts, Sodium Silicofluoride 2 ~ 8 parts, Synolac 7 ~ 16 parts, Dibutyltin oxide 0.24 ~ 0.65 part, methacrylic acid 0.6 ~ 4.2 part.
A kind of ambetti scrape resistant ink described above, in mass parts containing following composition: maleic acid resin 68 ~ 78 parts, butyl glycol ether 12 ~ 18 parts, vinyl acetic monomer 5 ~ 10 parts, butanone 3 ~ 6 parts, polyamide resin 68 ~ 73 parts, fatty alcohol 11 ~ 14 parts, phenylcarbinol 11 ~ 17 parts, phenylcarbinol 36 ~ 40 parts, high-boiling point kerosene 32 ~ 38 parts, pimelinketone 9 ~ 15 parts, Pyranton 9 ~ 13 parts, Sodium Silicofluoride 3 ~ 7 parts, Synolac 9 ~ 15 parts, Dibutyltin oxide 0.3 ~ 0.6 part, methacrylic acid 1.2 ~ 3.8 parts.
A kind of ambetti scrape resistant ink described above, in mass parts containing following composition: maleic acid resin 70 parts, butyl glycol ether 14 parts, vinyl acetic monomer 6 parts, butanone 4 parts, polyamide resin 69 parts, fatty alcohol 12 parts, phenylcarbinol 13 parts, phenylcarbinol 37 parts, high-boiling point kerosene 34 parts, pimelinketone 10 parts, Pyranton 10 parts, Sodium Silicofluoride 4 parts, Synolac 11 parts, Dibutyltin oxide 0.4 part, methacrylic acid 1.8 parts.
A kind of ambetti scrape resistant ink described above, in mass parts containing following composition: maleic acid resin 73 parts, butyl glycol ether 15 parts, vinyl acetic monomer 8 parts, butanone 4.5 parts, polyamide resin 70 parts, fatty alcohol 13 parts, phenylcarbinol 14 parts, phenylcarbinol 38 parts, high-boiling point kerosene 35 parts, pimelinketone 12 parts, Pyranton 11 parts, Sodium Silicofluoride 5 parts, Synolac 12 parts, Dibutyltin oxide 0.45 part, methacrylic acid 2.5 parts.
The preparation method of a kind of ambetti scrape resistant ink described above, the preparation process of the method is as follows:
The first step: add in reactor by maleic acid resin, butyl glycol ether, polyamide resin, is uniformly mixed at temperature is 250 ~ 270 DEG C;
Second step: adding vinyl acetic monomer, butanone, fatty alcohol, phenylcarbinol, phenylcarbinol, pimelinketone, Pyranton, Sodium Silicofluoride, is uniformly mixed at temperature is 180 ~ 200 DEG C;
3rd step: finally add Synolac, Dibutyltin oxide, methacrylic acid, high-boiling point kerosene, is uniformly mixed rear mistake 20 ~ 40 mesh sieve, obtains ambetti scrape resistant ink.
Being uniformly mixed at temperature is 260 DEG C in the first step described above.
Being uniformly mixed at temperature is 190 DEG C in second step described above.
Rear mistake 30 mesh sieve is uniformly mixed in the 3rd step described above.
beneficial effect:a kind of ambetti scrape resistant ink provided by the invention and preparation method thereof, this ink is coated in glass surface, to glass, there is good decoration function, there is strong adhesion, shock resistance, scrape resistant, antifog effect simultaneously, be applicable to the application of the glass surface of various occasion.
Embodiment
embodiment 1
A kind of ambetti scrape resistant ink, in mass parts containing following composition: maleic acid resin 65 parts, butyl glycol ether 10 parts, vinyl acetic monomer 3 parts, butanone 2 parts, polyamide resin 65 parts, fatty alcohol 9 parts, phenylcarbinol 10 parts, phenylcarbinol 33 parts, high-boiling point kerosene 30 parts, pimelinketone 8 parts, Pyranton 7 parts, Sodium Silicofluoride 2 parts, Synolac 7 parts, Dibutyltin oxide 0.24 part, methacrylic acid 0.6 part.
A preparation method for ambetti scrape resistant ink, the preparation process of the method is as follows:
The first step: add in reactor by maleic acid resin, butyl glycol ether, polyamide resin, is uniformly mixed at temperature is 250 DEG C;
Second step: adding vinyl acetic monomer, butanone, fatty alcohol, phenylcarbinol, phenylcarbinol, pimelinketone, Pyranton, Sodium Silicofluoride, is uniformly mixed at temperature is 180 DEG C;
3rd step: finally add Synolac, Dibutyltin oxide, methacrylic acid, high-boiling point kerosene, is uniformly mixed rear mistake 20 mesh sieve, obtains ambetti scrape resistant ink.
embodiment 2
A kind of ambetti scrape resistant ink, in mass parts containing following composition: maleic acid resin 82 parts, butyl glycol ether 20 parts, vinyl acetic monomer 11 parts, butanone 7 parts, polyamide resin 76 parts, fatty alcohol 15 parts, phenylcarbinol 18 parts, phenylcarbinol 42 parts, high-boiling point kerosene 40 parts, pimelinketone 16 parts, Pyranton 15 parts, Sodium Silicofluoride 8 parts, Synolac 16 parts, Dibutyltin oxide 0.65 part, methacrylic acid 4.2 parts.
A preparation method for ambetti scrape resistant ink, the preparation process of the method is as follows:
The first step: add in reactor by maleic acid resin, butyl glycol ether, polyamide resin, is uniformly mixed at temperature is 270 DEG C;
Second step: adding vinyl acetic monomer, butanone, fatty alcohol, phenylcarbinol, phenylcarbinol, pimelinketone, Pyranton, Sodium Silicofluoride, is uniformly mixed at temperature is 200 DEG C;
3rd step: finally add Synolac, Dibutyltin oxide, methacrylic acid, high-boiling point kerosene, is uniformly mixed rear mistake 40 mesh sieve, obtains ambetti scrape resistant ink.
embodiment 3
A kind of ambetti scrape resistant ink, in mass parts containing following composition: maleic acid resin 78 parts, butyl glycol ether 18 parts, vinyl acetic monomer 10 parts, butanone 6 parts, polyamide resin 73 parts, fatty alcohol 14 parts, phenylcarbinol 17 parts, phenylcarbinol 40 parts, high-boiling point kerosene 38 parts, pimelinketone 15 parts, Pyranton 13 parts, Sodium Silicofluoride 7 parts, Synolac 15 parts, Dibutyltin oxide 0.6 part, methacrylic acid 3.8 parts.
A preparation method for ambetti scrape resistant ink, the preparation process of the method is as follows:
The first step: add in reactor by maleic acid resin, butyl glycol ether, polyamide resin, is uniformly mixed at temperature is 260 DEG C;
Second step: adding vinyl acetic monomer, butanone, fatty alcohol, phenylcarbinol, phenylcarbinol, pimelinketone, Pyranton, Sodium Silicofluoride, is uniformly mixed at temperature is 190 DEG C;
3rd step: finally add Synolac, Dibutyltin oxide, methacrylic acid, high-boiling point kerosene, is uniformly mixed rear mistake 30 mesh sieve, obtains ambetti scrape resistant ink.
embodiment 4
A kind of ambetti scrape resistant ink, in mass parts containing following composition: maleic acid resin 70 parts, butyl glycol ether 14 parts, vinyl acetic monomer 6 parts, butanone 4 parts, polyamide resin 69 parts, fatty alcohol 12 parts, phenylcarbinol 13 parts, phenylcarbinol 37 parts, high-boiling point kerosene 34 parts, pimelinketone 10 parts, Pyranton 10 parts, Sodium Silicofluoride 4 parts, Synolac 11 parts, Dibutyltin oxide 0.4 part, methacrylic acid 1.8 parts.
A preparation method for ambetti scrape resistant ink, the preparation process of the method is as follows:
The first step: add in reactor by maleic acid resin, butyl glycol ether, polyamide resin, is uniformly mixed at temperature is 260 DEG C;
Second step: adding vinyl acetic monomer, butanone, fatty alcohol, phenylcarbinol, phenylcarbinol, pimelinketone, Pyranton, Sodium Silicofluoride, is uniformly mixed at temperature is 190 DEG C;
3rd step: finally add Synolac, Dibutyltin oxide, methacrylic acid, high-boiling point kerosene, is uniformly mixed rear mistake 30 mesh sieve, obtains ambetti scrape resistant ink.
embodiment 5
A kind of ambetti scrape resistant ink, in mass parts containing following composition: maleic acid resin 73 parts, butyl glycol ether 15 parts, vinyl acetic monomer 8 parts, butanone 4.5 parts, polyamide resin 70 parts, fatty alcohol 13 parts, phenylcarbinol 14 parts, phenylcarbinol 38 parts, high-boiling point kerosene 35 parts, pimelinketone 12 parts, Pyranton 11 parts, Sodium Silicofluoride 5 parts, Synolac 12 parts, Dibutyltin oxide 0.45 part, methacrylic acid 2.5 parts.
A preparation method for ambetti scrape resistant ink, the preparation process of the method is as follows:
The first step: add in reactor by maleic acid resin, butyl glycol ether, polyamide resin, is uniformly mixed at temperature is 260 DEG C;
Second step: adding vinyl acetic monomer, butanone, fatty alcohol, phenylcarbinol, phenylcarbinol, pimelinketone, Pyranton, Sodium Silicofluoride, is uniformly mixed at temperature is 190 DEG C;
3rd step: finally add Synolac, Dibutyltin oxide, methacrylic acid, high-boiling point kerosene, is uniformly mixed rear mistake 30 mesh sieve, obtains ambetti scrape resistant ink.
comparative example 1
Patent of invention publication number is the patent of CN 103319949 A, and this protection ink by weight, comprises following component: aliphatic urethane acrylate 6 parts; N-vinyl pyrrolidone 3 parts; 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide 0.3 part; stearyl alcohol 1 part; defoamer 0.1 part, flow agent 0.1 part, 0.3 part, softening agent; phthalocyanine blue 1 part
The above-mentioned technical performance index stating the ink of embodiment 1 ~ embodiment 5 and comparative example 1, its detected result is as follows:
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (8)
1. an ambetti scrape resistant ink, to it is characterized in that in mass parts containing following composition: maleic acid resin 65 ~ 82 parts, butyl glycol ether 10 ~ 20 parts, vinyl acetic monomer 3 ~ 11 parts, butanone 2 ~ 7 parts, polyamide resin 65 ~ 76 parts, fatty alcohol 9 ~ 15 parts, phenylcarbinol 10 ~ 18 parts, phenylcarbinol 33 ~ 42 parts, high-boiling point kerosene 30 ~ 40 parts, pimelinketone 8 ~ 16 parts, Pyranton 7 ~ 15 parts, Sodium Silicofluoride 2 ~ 8 parts, Synolac 7 ~ 16 parts, Dibutyltin oxide 0.24 ~ 0.65 part, methacrylic acid 0.6 ~ 4.2 part.
2. a kind of ambetti scrape resistant ink according to claim 1, to it is characterized in that in mass parts containing following composition: maleic acid resin 68 ~ 78 parts, butyl glycol ether 12 ~ 18 parts, vinyl acetic monomer 5 ~ 10 parts, butanone 3 ~ 6 parts, polyamide resin 68 ~ 73 parts, fatty alcohol 11 ~ 14 parts, phenylcarbinol 11 ~ 17 parts, phenylcarbinol 36 ~ 40 parts, high-boiling point kerosene 32 ~ 38 parts, pimelinketone 9 ~ 15 parts, Pyranton 9 ~ 13 parts, Sodium Silicofluoride 3 ~ 7 parts, Synolac 9 ~ 15 parts, Dibutyltin oxide 0.3 ~ 0.6 part, methacrylic acid 1.2 ~ 3.8 parts.
3. a kind of ambetti scrape resistant ink according to claim 1, to is characterized in that in mass parts containing following composition: maleic acid resin 70 parts, butyl glycol ether 14 parts, vinyl acetic monomer 6 parts, butanone 4 parts, polyamide resin 69 parts, fatty alcohol 12 parts, phenylcarbinol 13 parts, phenylcarbinol 37 parts, high-boiling point kerosene 34 parts, pimelinketone 10 parts, Pyranton 10 parts, Sodium Silicofluoride 4 parts, Synolac 11 parts, Dibutyltin oxide 0.4 part, methacrylic acid 1.8 parts.
4. a kind of ambetti scrape resistant ink according to claim 1, to is characterized in that in mass parts containing following composition: maleic acid resin 73 parts, butyl glycol ether 15 parts, vinyl acetic monomer 8 parts, butanone 4.5 parts, polyamide resin 70 parts, fatty alcohol 13 parts, phenylcarbinol 14 parts, phenylcarbinol 38 parts, high-boiling point kerosene 35 parts, pimelinketone 12 parts, Pyranton 11 parts, Sodium Silicofluoride 5 parts, Synolac 12 parts, Dibutyltin oxide 0.45 part, methacrylic acid 2.5 parts.
5. the preparation method of a kind of ambetti scrape resistant ink as claimed in claim 1, is characterized in that the preparation process of the method is as follows:
The first step: add in reactor by maleic acid resin, butyl glycol ether, polyamide resin, is uniformly mixed at temperature is 250 ~ 270 DEG C;
Second step: adding vinyl acetic monomer, butanone, fatty alcohol, phenylcarbinol, phenylcarbinol, pimelinketone, Pyranton, Sodium Silicofluoride, is uniformly mixed at temperature is 180 ~ 200 DEG C;
3rd step: finally add Synolac, Dibutyltin oxide, methacrylic acid, high-boiling point kerosene, is uniformly mixed rear mistake 20 ~ 40 mesh sieve, obtains ambetti scrape resistant ink.
6. the preparation method of a kind of ambetti scrape resistant ink according to claim 5, is characterized in that: being uniformly mixed at temperature is 260 DEG C in the described the first step.
7. the preparation method of a kind of ambetti scrape resistant ink according to claim 5, is characterized in that: being uniformly mixed at temperature is 190 DEG C in described second step.
8. the preparation method of a kind of ambetti scrape resistant ink according to claim 5, is characterized in that: be uniformly mixed rear mistake 30 mesh sieve in the 3rd described step.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510337309.4A CN104877432A (en) | 2015-06-18 | 2015-06-18 | Scratch-resistant ink for decorating glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510337309.4A CN104877432A (en) | 2015-06-18 | 2015-06-18 | Scratch-resistant ink for decorating glass and preparation method thereof |
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| CN104877432A true CN104877432A (en) | 2015-09-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510337309.4A Pending CN104877432A (en) | 2015-06-18 | 2015-06-18 | Scratch-resistant ink for decorating glass and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275999A (en) * | 1997-10-15 | 2000-12-06 | 美国3M公司 | Abrasion-resistant ink compositions and methods of use |
| US7169219B1 (en) * | 2002-03-06 | 2007-01-30 | Wynne John H | Peelable stenciling ink and method of using |
| CN103333547A (en) * | 2013-06-05 | 2013-10-02 | 苏州凹凸彩印厂 | Gravure ink for glass protection and preparation method thereof |
-
2015
- 2015-06-18 CN CN201510337309.4A patent/CN104877432A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275999A (en) * | 1997-10-15 | 2000-12-06 | 美国3M公司 | Abrasion-resistant ink compositions and methods of use |
| US7169219B1 (en) * | 2002-03-06 | 2007-01-30 | Wynne John H | Peelable stenciling ink and method of using |
| CN103333547A (en) * | 2013-06-05 | 2013-10-02 | 苏州凹凸彩印厂 | Gravure ink for glass protection and preparation method thereof |
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Application publication date: 20150902 |
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